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NASA NTRS2021

A lingering local exopshere created by a gas plume of a lunar lander

We model the expected local exosphere created by outgassing from a lunar lander plume water deposit located adjacent to a lunar lander. We assume the landing is near dawn within Lacus Mortis at 45oN. We consider a set of water desorption scenarios especially focusing on the water-surface desorption activation energy that can possess a distribution of energy states. Our initial simulation starts with a deposition surface having 1020 water molecules per square meter in a 2 km × 2 km region where 90% of the water is retained by weak water-water sorption interactions and 10% are bound by water-regolith sorption interactions. We find that the loosely bound water molecules in water-water interactions quickly desorb within hours after landing. However, water molecules bound to surface sites having a desorption activation greater than 0.7 eV were found to be retained until the source region rotated to later local times (i.e., surface temperature becomes relatively high). We found such time-delayed desorption leads to a tenuous but lingering exosphere emitted from the lander plume deposit region for many 10's of hours after landing. We also adjusted the initial condition by considering different landing local times and considered a case where 100% of the water is bound by water-regolith interactions (mimicking a porous regolith).

W.M. Farrell↗
NASA NTRSDate not supplied

Lunar TLP's and the Tectonic Processes of the Earth and the Moon

We study the transient lunar phenomena (TLP) as an indicator of lunar tectonic. Seismic phenomena can be used as a direct indicator of some tectonic activities of the planets The Moon-Earth gravitational interaction has been studied extensively as a triggering mechanism to geodynamics. In this work, we study the reverse interaction Earth-Moon in relation to the TLP activities. The lunar outgassing potentially is the leading cause for TLP activities resulting from the lunar interior's dynamic mechanism. We have studied Earth venting and earthquakes processes and have found that radon was frequently activated before significant seismic events due to Moon-Sun interaction with Earth (Ouzounov et al., 2018). Earthquake lights, an associated phenomenon reported before some major earthquakes, are analog to TLP activities on the moon. In 1972, N. Kozyrev suggested a possible moon response to the significant seismic events on Earth. To understand whether TLP's activities have any possible connection with Earth geodynamics, we perform a statistical check between the significant seismic activities from the NEIC catalog and lunar TLPs for 1907-1977 for four lunar areas :Aristarchus, Plato, Gassendi, and Alphonsus. We use TLP compiled catalog based on Middlehurst et al. (1968), Cameron (2006a,b), and Crotts (2008) catalogs. Our results revealed a causal relationship between significant earthquakes and TLP events. However, this relation varies from the location and depth of the seismic events. Deformation triggers the degassing process, and TLPs are indicators for those underlying activities. Our work can provide new information about the origin of TLP and the existence of a possible relationship between the tectonic processes of Earth and the Moon.

D Ouzonov↗
NASA NTRSDate not supplied

Direct Simulation Monte Carlo Studies of the Gas Sampling for the VATMOS-SR Mission Concept

VATMOS-SR (Venus ATMOSpheric - Sample Return) is a small spacecraft mission concept which would return a gas sample from the upper atmosphere of Venus to Earth for scientific analysis. This could be the first sample return mission for an extra-terrestrial atmosphere, and potentially the first sample return from an Earth-sized planet. The VATMOS-SR mission concept consists of a SmallSat atmospheric sampling probe (45 deg. sphere/cone geometry, <1 m diameter) that is designed to skim through the Venus upper atmosphere and acquire gas samples below the homopause altitude (around ~110 km altitude), where the different atmospheric gases are mixed. The velocity of the spacecraft where sampling would occur is expected to be between ~10.5 km/s and ~13.1 km/s, depending on the trajectory chosen. This presentation will discuss hypervelocity sampling in the upper atmosphere of Venus, with respect to the VATMOS-SR mission concept. VATMOS-SR would enable critical atmospheric measurements to form a full picture of how, why, and when Venus evolved to be so different from Earth and Mars. The abundances and isotopic compositions of volatile elements (such as N, C, S, O and the noble gases) in planetary atmospheres record volatile delivery during accretion, outgassing from planetary interiors, and atmospheric loss to space. Precise and accurate determinations of atmospheric volatile signatures are the key to understanding the origins and geodynamical evolution of Venus compared to the other terrestrial planets. Hypersonic sampling poses unique technical and scientific challenges. To ensure it is possible to relate the composition of the sampled gases to the free stream atmospheric composition, large-scale numerical simulations are employed to model the flow through the VATMOS-SR sampling system. In particular, an emphasis is placed on quantifying noble gas isotopic fractionation that occurs during the sample acquisition and transfer process in order to determine how measured isotopic ratios of noble gases in the sample compare to actual isotopic ratios in the Venusian atmosphere. The Direct Simulation Monte Carlo (DSMC) code SPARTA, an open source software package developed by Sandia National Laboratories, is used in this work. SPARTA, based on Bird’s DSMC method, is a molecular-level gas-kinetic technique. As SPARTA is able to model hypervelocity reacting flows in strong chemical and thermal non-equilibrium, this software package is well suited to determine relevant flow properties for the VATMOS-SR mission concept, and to numerically quantify the expected level of elemental and/or isotopic fractionation in the sample acquired by VATMOS-SR. This presentation will show results from 3D simulations correlating the noble gas isotopic fractionation in the gas acquired at hypervelocity speeds to its ambient atmosphere value. In particular, emphasis will be placed at Xenon isotopes of masses 128 and 130, as precise measurements of that ratio would yield a comparison to Earth’s atmosphere. Additionally, sensitivity studies that quantify the uncertainties due to the freestream parameters as well as the modeling parameters will be performed.

direct simulation Monte Carlo↗
NASA NTRS2022

Further Development of a Function Generator Technique

Further features and properties of functions generated by generalization of the process originally uncovered to describe the evolution of pressure in a rigid volume due to outgassing or desorption are explored. Properties presented include development of a general Maclaurin series associated with these functions, a limitation in using integration by parts to produce asymptotic expansions, and a general description of an implicit Adams-Moulton method for numerical quadrature of transformed functions. These developments are then applied to develop and explore functions that solve the Sievert integral and the modified Bessel function of the first kind, order zero. Features of the error function and the incomplete lower gamma function are also considered.

Michael S. Woronowicz↗
NASA NTRSDate not supplied

Mars Sample Receiving Facility Research and Development to Enable Preservation, Safe Containment, and Scientific Research of Martian Samples on Earth

NASA and ESA are working together to plan a joint campaign to potentially bring back the first Martian samples to Earth in the early 2030s. On the surface of Mars, the Mars 2020Perseverance Rover is selecting and packaging samples that could be returned to Earth for careful examination by an international team of scientists. In preparation for this historic sample return, advance planning is underway to design and build a Mars Sample Receiving Facility (SRF) in the mid-2020s. In 2022, a Mars Sample Receiving Facility Assessment Study(MSAS) will be conducted to further define construction modality and capability options for a facility in the conterminous United States. Since Mars Sample Return (MSR) is currently categorized as a planetary protection restricted Earth return, this new facility would feature biosafety level 4 (BSL-4)-like high containment to protect Earth’s biosphere from any potential hazard. In addition, the facility also requires integration of cleanroom technologies to mitigate against terrestrial contamination and preserve sample integrity for science investigations. The integration of both clean handling and high containment requires significant technology research and development (R&D) by the mid-2020s to support the definition and planning of a SRF before commencing the site specific design phase. The SRF project will need to solidify the inorganic, organic, and biological contamination control (CC) requirements for the facility. This could entail a translation of Mars 2020 mission CC requirements for geologic material to engineering requirements for surfaces and airborne molecular contamination inside isolators and cleanrooms. In tandem, the project will need to determine precision cleaning and sterilization approaches for cleanrooms, isolators, equipment, and tools. Initial material selections for the facility construction materials, cleanrooms, isolators, and BSL-4 suits/garments are an important activity. The recent construction of the OSIRIS-REx and Hayabusa2 curation cleanroom laboratories greatly benefited from early materials testing, before the design phase, to reduced organic outgassing and particulate shedding inside the laboratory. While the early biohazard investigations in the SRF may deem the samples safe to release to laboratories throughout the world, sterilization methods need to be defined to safely release Martian samples. One key aspect of enabling simultaneous sample containment and cleanliness is the concept of a Double-Walled Isolator (DWI) that ESA has been pursuing. Further R&D is needed about DWIs, sample handling, and instrumentation interfaces before beginning the SRF site specific design phase. A working isolator/DWI engineering model should be developed and fabricated. Isolator sizes, connections, pass-through antechambers, and configurations and basic interfaces with instruments and tools as well as the use of robotic, mechanical, and/or human manipulation need to be considered. Inert high purity gas supply (one-pass or recirculation) and other isolator utilities must be determined. Special accommodations for large instruments (e.g., XCT,SEM, etc.) need to be developed. Techniques for opening the sample tubes packaged by M2020and extracting the headspace gas while keeping samples pristine will be challenging, requiring additional R&D, and engagement of the M2020 project. In addition, careful micromanipulation for subdivision and packaging of samples will also need to be included. These combined R&D activities are important before commencing the SRF design phase to ensure safe biohazard containment, sample preservation, and science integrity for the samples that would be studied in the SRF and in laboratories around the world.

mars sample return↗
NASA NTRS2022

Volatile Abundances, Extended Coma Sources, and Nucleus Ice Associations in Comet C/2014 Q2 (Lovejoy)

High-resolution infrared spectra of comet C/2014 Q2 Lovejoy were acquired with NIRSPEC at the W. M. Keck Observatory on two post-perihelion dates(UT 2015 February 2 and 3).H2O was measured simultaneously with CO,CH3OH, H2CO, CH4, C2H6,C2H4, C2H2, HCN, and NH3 on both dates, and rotational temperatures, production rates, relative abundances, H2O ortho-to-para ratios, and spatial distributions in the coma were determined. The first detection of C2H4in a comet from ground-based observations is reported. Abundances relative to H2O for all species were found to be in the typical range compared with values for other comets in the overall population to date. There is evidence of variability in rotational temperatures and production rates on timescales that are small compared with the rotational period of the comet. Spatial distributions of volatiles in the coma suggest complex outgassing behavior.CH3OH, HCN, C2H6, and CH4 spatial distributions in the coma are consistent with direct release from associated ices in the nucleus and are peaked in a more sunward direction compared with co-measured dust. H2O spatial profiles are clearly distinct from these other four species, likely due to a sizable coma contribution from icy grain sublimation.Spatial distributions for C2H2,H2CO, and NH3suggest substantial contributions from extended coma sources, providing further evidence for distinct origins and associations for these species in comets. CO shows a different spatial distribution compared with other volatiles, consistent with jet activity from discrete nucleus ice sources.

Neil Dello Russo↗
NASA NTRS2021

A Deep Search for Five Molecules in the 49 Ceti Debris Disk

Surprisingly strong CO emission has been observed from more than a dozen debris disks around nearby main-sequence stars. The origin of this CO is unclear, in particular whether it is left over from the protoplanetary disk phase or is second-generation material released from collisions between icy bodies like debris dust. The primary unexplored avenue for distinguishing the origin of the material is understanding its molecular composition. Here we present a deep search for five molecules (CN, HCN, HCO+, SiO, and CH3OH) in the debris disk around 49 Ceti. We take advantage of the high sensitivity of the Atacama Large Millimeter/submillimeter Array at Band 7 to integrate for 3.2 hr at modest spatial (1′′) and spectral (0.8 km s−1) resolution. Our search yields stringent upper limits on the flux of all surveyed molecular lines, which imply abundances relative to CO that are orders of magnitude lower than those observed in protoplanetary disks and solar system comets, and also those predicted in outgassing models of second-generation material. However, if CI shielding is responsible for extending the lifetime of any CO produced in second-generation collisions as proposed by Kral et al., then the line ratios do not reflect true ice phase chemical abundances but rather imply that CO is shielded by its own photodissociation product, CI, and other molecules are rapidly photodissociated by the stellar and interstellar radiation field.

Debris disks↗
NASA NTRS2022

A SUBLIME 3D Model for Cometary Coma Emission: The Hypervolatile-rich Comet C/2016 R2 (PanSTARRS)

The coma of comet C/2016 R2 (PanSTARRS) is one of the most chemically peculiar ever observed, in particular due to its extremely high CO/H2O and N(+2)/H2O ratios, and unusual trace volatile abundances. However, the complex shape of its CO emission lines, as well as uncertainties in the coma structure and excitation, has lead to ambiguities in the total CO production rate. We performed high-resolution, spatially, spectrally, and temporally resolved CO observations using the James Clerk Maxwell Telescope and Submillimeter Array to elucidate the outgassing behavior of C/2016 R2. Results are analyzed using a new, time-dependent, three-dimensional radiative transfer code (SUBlimating gases in LIME; SUBLIME, based on the open-source version of the LIne Modeling Engine), incorporating for the first time, accurate state-to-state collisional rate coefficients for the CO–CO system. The total CO production rate was found to be in the range of (3.8 − 7.6) × 10^(28) per s between 2018 January 13 and February 1 (at r(H) = 2.8–2.9 au), with a mean value of (5.3 ± 0.6) × 10^(28) per s. The emission is concentrated in a near-sunward jet, with a half-opening angle of ∼62° and an outflow velocity of 0.51 ± 0.01 km/s, compared to 0.25 ± 0.01 km/s in the ambient (and nightside) coma. Evidence was also found for an extended source of CO emission, possibly due to icy grain sublimation around 1.2 × 10^(5) km from the nucleus. Based on the coma molecular abundances, we propose that the nucleus ices of C/2016 R2 can be divided into a rapidly sublimating apolar phase, rich in CO, CO2, N2, and CH3OH, and a predominantly frozen (or less abundant), polar phase containing more H2O, CH4, H2CO, and HCN.

Martin Andrew Cordiner↗
NASA NTRS2021

Comparison of SAR and CYNSS surface water extent metrics over the Yucatan Lake wetland site

Wetlands have a major role in the carbon cycle, outgassing large quantities of carbon dioxide and methane through processes that are directly and strongly influenced by the duration and timing of inundation. Therefore, understanding the seasonal pattern of inundation can be a component for regional to global scale carbon models. Measurement of inundation extent also establishes a benchmark for the current status of wetland areas, useful in assessing the future impacts of climate change. The incorporation of frequent measurements of inundation extent into large-scale hydrological models would permit the evaluation of more detailed seasonal and longer-term floodplain dynamics and their associated management implications.The Cyclone GNSS (CYGNSS) constellation of satellites launched in 2016, and carries receivers capable of receiving data from L-band GNSS reflections. Delay Doppler maps (DDM) are generated on board and telemetered to the ground, along with a small number of raw data takes that can be used for special processing on the ground for evaluation purposes. It has been previously shown that these data can be sensitive to inundation.The NASA ISRO Synthetic Aperture Radar, currently planned for launch in January 2023, has both an L-band and S-band SAR for earth imaging. The L-band SAR, which will image the Earth's land mass twice every 12 days, has a requirement for measuring wetland inundation extent at the 1 ha scale. One of the sites that will be used to validate this requirement is Yucatan Lake, Louisiana. This oxbow lake and surrounding area located adjacent to the Mississippi river experiences periodic and extensive flooding in the surrounding forest areas.In 2019, NASA's UAVSAR fully polarimetric airborne L-band SAR conducted a flight campaign to image a dozen sites in the SE USA at approximately 12-day intervals and both in the morning and evening, to simulate the type of data NISAR will obtain. One site imaged during this campaign was the Yucatan Lake area, spanning water stages from low to high flood conditions.It has been demonstrated previously that GNSS reflectometry such as that measured by CYGNSS may be used to characterize surface inundation. It has also been known for decades that L-band SAR may be used to characterize not only the presence of open water, but also the presence of subcanopy inundation in forested areas. In this paper we will present results comparing data from these two types of instruments.

Lavalle, Marco↗
NASA NTRS2021

On the effects of the ocean on atmospheric CFC-11 lifetimes and emissions

The ocean is a reservoir for CFC-11, a major ozone-depleting chemical. Anthropogenic production of CFC-11 dramatically decreased in the 1990s under the Montreal Protocol, which stipulated a global phase out of production by 2010. However, studies raise questions about current overall emission levels and indicate unexpected increases of CFC-11 emissions of about 10 Gg/yr after 2013 (based upon measured atmospheric concentrations and an assumed atmospheric lifetime). These findings heighten the need to understand processes that could affect the CFC-11 lifetime, including ocean fluxes. We evaluate how ocean uptake and release through 2300 affects CFC-11 lifetimes, emission estimates, and the long-term return of CFC-11 from the ocean reservoir. We show that ocean uptake yields a shorter total lifetime and larger inferred emission of atmospheric CFC-11 from 1930 to 2075 compared to estimates using only atmospheric processes. Ocean flux changes over time result in small but not completely negligible effects on the calculated unexpected emissions change (decreasing it by 0.4 ± 0.3 Gg/yr). Moreover, it is expected that the ocean will eventually become a source of CFC-11, increasing its total lifetime thereafter. Ocean outgassing should produce detectable increases in global atmospheric CFC-11 abundances by the mid-2100s, with emission of around 0.5 Gg/yr; this should not be confused with illicit production at that time. An illustrative model projection suggests that climate change is expected to make the ocean a weaker reservoir for CFC-11, advancing the detectable change in the global atmospheric mixing ratio by about 5 yr.

Anthropogenic production of CFC-11↗
NASA NTRS2021

Designing a Decontamination Solution for the Low-Earth-Orbit, Cryogenic SPHEREx Mission

To address the scientific goals of NASA’s astrophysics division, the JPL and Caltech’s SPHEREx mission conducts the first near-infrared all-sky spectral survey in low-earth-orbit using a passively-cooled, cryogenic telescope. Several unique water contamination issues arise due to the combination of cryogenic operation temperatures and the limited temperature control authority of passive cooling. Because water molecules have adsorption bands within the wavelengths of interest for SPHEREx’s survey, it is imperative that water contamination be controlled and minimized. In this work, a model is developed for the SPHEREx mission to predict the transport and accumulation of outgassed water onto sensitive payload components. The model utilizes the time dependent thermal profiles of the individual payload components, initial water content, and spacecraft geometry to calculate the time dependent water diffusion, transport, and adsorption. This model is subsequently used to predict water contamination risks and design decontamination solutions for each risk. Two major water contamination risks were predicted, water accumulation during cooldown and on cryogenic surfaces during the mission. The first risk occurs during the cooldown of the payload to cryogenic temperatures, predicting water accumulation on optical surfaces in excess of the allowable levels. To mitigate this accumulation, the temperature of the optical surfaces is controlled during cooldown through a combination of heaters and spacecraft pointing. The second risk is that over the course of the mission, is unavoidable water accumulation onto the payload thermal system’s cryogenic surfaces, possibly jeopardizing thermal performance and temperature stability, both of which are required for science success. To decontaminate any water that had collected onto cryogenic thermal system surfaces, a decontamination maneuver was designed. In this decontamination maneuver, cryogenic surfaces of the thermal system are warmed to a temperature where water will desorb by spacecraft pointing while still meeting all avoidance constraints, and thereby avoiding undue risk to the observatory hardware. Through application of the developed analytical model and inclusion of the decontamination maneuver in the mission design, SPHEREx can confidently demonstrate that it is able to decontaminate, at the start of and during the mission as needed to meet its end of life science performance requirements.

Soares, Carolos E.↗
NASA NTRSDate not supplied

The VATMOS-SR Mission Concept: DSMC Studies of the Gas Sampling

VATMOS-SR (Venus ATMOSpheric - Sample Return) is a small spacecraft mission concept that would return a gas sample from the upper atmosphere of Venus to Earth for scientific analysis. This could be the first sample return mission for an extra-terrestrial atmosphere and potentially the first sample return from an Earth-sized planet. The VATMOS-SR mission concept consists of a SmallSat atmospheric sampling probe (45 deg. sphere/cone geometry, <1 m diameter) that is designed to skim through the Venus upper atmosphere and acquire gas samples below the homopause altitude (around ~110 km altitude), where the different atmospheric gases are mixed. The velocity of the spacecraft where sampling would occur is expected to be between ~10.5 km/s and ~13.1 km/s, depending on the trajectory chosen. This presentation will discuss hypervelocity sampling in the upper atmosphere of Venus with respect to the VATMOS-SR mission concept. VATMOS-SR would enable critical atmospheric measurements to form a complete picture of how, why, and when Venus evolved to be so different from Earth and Mars. The abundances and isotopic compositions of volatile elements (such as N, C, S, O, and the noble gases) in planetary atmospheres record volatile delivery during accretion, outgassing from planetary interiors, and atmospheric loss to space. Precise and accurate determinations of volatile atmospheric signatures are the key to understanding the origins and geodynamical evolution of Venus compared to the other terrestrial planets. Hypersonic sampling poses unique technical and scientific challenges. To ensure it is possible to relate the composition of the sampled gases to the free stream atmospheric composition, large-scale numerical simulations are employed to model the flow through the VATMOS-SR sampling system. In particular, an emphasis is placed on quantifying noble gas isotopic fractionation that occurs during the sample acquisition and transfer process to determine how measured isotopic ratios of noble gases in the sample compared to actual isotopic ratios in the Venusian atmosphere. The Direct Simulation Monte Carlo (DSMC) code SPARTA, an open-source software package developed by Sandia National Laboratories, is used in this work. SPARTA, based on Bird’s DSMC method, is a molecular-level gas-kinetic technique. As SPARTA is able to model hypervelocity reacting flows in strong chemical and thermal non-equilibrium, this software package is well suited to determine relevant flow properties for the VATMOS-SR mission concept and to numerically quantify the expected level of elemental and/or isotopic fractionation in the sample acquired by VATMOS-SR. This presentation will show results from 3D simulations correlating the noble gas isotopic fractionation in the gas acquired at hypervelocity speeds to its ambient atmosphere value. In particular, emphasis will be placed on Xenon isotopes of masses 128 and 130, as precise measurements of that ratio would yield comparison to Earth’s atmosphere. Additionally, sensitivity studies that quantify the uncertainties due to the freestream parameters, as well as the modeling parameters, will be performed.

direct simulation Monte Carlo↗
NASA NTRSDate not supplied

Analysis of the Pioneer Venus Large Probe Neutral Mass Spectrometer Data Yields New Insights into the Composition of Venus’ Atmosphere

We present a new analysis of mass spectral data obtained by the Pioneer Venus (PV) Large Probe Neutral Mass Spectrometer (LNMS). To analyze the LNMS data, we constructed an analytical model that accounts for spectrometer performance at each altitude, provides CO2 abundances in units of density (kg/m3), and retains the resolving power of the LNMS through use of a targeted data-fitting routine. Our results provide new insights into the composition of Venus’ atmosphere and show that densities for CO2 increase towards the surface, which is suggestive of surface outgassing. Additionally, the data reveal partial obstructions of the LNMS inlet at <17 km, which is an likely important consideration for future missions. Re-analysis of the LNMS data may assist in revealing the past, present and/or future habitability of Venus’ clouds.

mass spectral data↗
NASA NTRSDate not supplied

Sample Polishing Without Epoxy

In recent years, we have received requests for meteorite sample sections to be prepared without using epoxy impregnation or mounting. The reasoning for these requests ranges from potential contamination of analyses from epoxy chemical components to degradation of instrumental vacuum from epoxy outgassing (e.g., SEM, SIMS, EPMA, etc.). An alternative approach that we employ involves sawing off a 1-5 mm thick wafer of the sample. The wafer is ground using silica carbide lapping media wetted with 190 proof ethyl alcohol to make both sides flat and parallel. The sample is then polished on one or both sides using diamond paste or dry diamond powder on a rotating lap wheel until the desired finish is obtained. The sample is cleaned in between steps using 200 proof ethyl alcohol in an ultrasonic cleaner. Friable and altered samples need to have higher thickness in order for polishing to be attempted. Without epoxy to hold the sample together or a glass slide for backing, the sample needs additional material to provide the necessary support structure. The machining steps of this process need to be undertaken at a much slower speed than in traditional thin or thick section preparation.

Meteorite↗
NASA NTRS2022

The Long-Term Evolution of the Atmosphere of Venus: Processes and Feedback Mechanisms

This work reviews the long-term evolution of the atmosphere of Venus, and modulation of its composition by interior/exterior cycling. The formation and evolution of Venus’s atmosphere, leading to contemporary surface conditions, remain hotly debated topics, and involve questions that tie into many disciplines. We explore these various inter-related mechanisms which shaped the evolution of the atmosphere, starting with the volatile sources and sinks. Going from the deep interior to the top of the atmosphere, we describe volcanic out-gassing, surface-atmosphere interactions, and atmosphere escape. Furthermore, we address more complex aspects of the history of Venus, including the role of Late Accretion impacts, how magnetic field generation is tied into long-term evolution, and the implications of geochemical and geodynamical feedback cycles for atmospheric evolution. We highlight plausible end-member evolutionary pathways that Venus could have followed, from accretion to its present-day state, based on modeling and observations. In a first scenario, the planet was desiccated by atmospheric escape during the magma ocean phase. In a second scenario, Venus could have harbored surface liquid water for long periods of time, until its temperate climate was destabilized and it entered a runaway greenhouse phase. In a third scenario, Venus’s inefficient outgassing could have kept water inside the planet, where hy- drogen was trapped in the core and the mantle was oxidized. We discuss existing evidence and future observations/missions required to refine our understanding of the planet’s history and of the complex feedback cycles between the interior, surface, and atmosphere that have been operating in the past, present or future of Venus.

Venus↗
NASA NTRSDate not supplied

Comparing Satellite Measurements of Volcanic SO2 Mass from OMI, OMPS and TROPOMI

Sulfur dioxide (SO2) is a major air pollutant that contributes to acid rain and aerosol formation (e.g., sulfates), adversely affects the environment and human health, and explosive volcanic SO2 emissions can impact climate. The majority of SO2 emissions are related to anthropogenic processes (e.g., fossil fuel burning, metal ore smelting operations), although natural processes such as volcanic eruptions and degassing also play an important role as anthropogenic SO2 emissions continue to decline. Generally, the most interest in volcanoes occurs during major eruptions. We will focus on comparing volcanic SO2 outgassing that occurs on an almost daily basis from lesser known volcanoes using satellite data. At NASA’s Global Sulfur Dioxide Monitoring Home page (https://so2.gsfc.nasa.gov/), we have been posting daily SO2 maps from 40 volcanic and industrial regions around the world using measurements from three satellite instruments; the Ozone Monitoring Instrument (OMI) onboard NASA’s Earth Observing System Aura satellite, the Ozone Monitoring and Profiler Suite (OMPS) onboard the NASA-NOAA Suomi National Polar-orbiting Partnership (NPP) satellite, and the TROPOspheric Monitoring Instrument (TROPOMI) onboard the ESA/Copernicus Sentinel-5 Precursor satellite. These instruments in low Earth sun-synchronous polar orbits with 1:30-2:00 pm equator crossing local time provide daily SO2 maps at different spatial resolutions: 13 x 24 km2, 50 x 50 km2 and 5.5 x 3.5 km2 for OMI, OMPS and TROPOMI respectively. Data from OMI are available since October 2004 (partial coverage since 2008), from OMPS since 2012 and from TROPOMI since 2018. We will present comparative SO2 mass time-series (see Hunga-Tonga plot) and statistical analyses of recent eruptions that have data from all the instruments.

SO2↗
NASA NTRS2016

Probing for Evidence of Plumes on Europa With HST/STIS

Roth et al. (2014a) reported evidence for plumes of water venting from a southern high latitude region on Europa: spectroscopic detection of off-limb line emission from the dissociation products of water. Here, we present Hubble Space Telescope direct images of Europa in the far-ultraviolet (FUV) as it transited the smooth face of Jupiter to measure absorption from gas or aerosols beyond the Europa limb. Out of 10 observations, we found 3 in which plume activity could be implicated. Two observations showed statistically significant features at latitudes similar to Roth et al., and the third at a more equatorial location. We consider potential systematic effects that might influence the statistical analysis and create artifacts, and are unable to find any that can definitively explain the features, although there are reasons to be cautious. If the apparent absorption features are real, the magnitude of implied outgassing is similar to that of the Roth et al. feature; however, the apparent activity appears more frequently in our data.

Planets and satellites↗
NASA NTRSDate not supplied

Characterization and Testing of Copper-Nickel Electroplated 3D Printed Parts for Space Flight Applications

3D printing enables novel designs which are impossible to replicate with conventional machining. The process involves 3D printing components from a polymer using a standard resin-based printing process, then electroplating the parts with a thin layer of copper-nickel. Initial results have shown these electroplated components have increased structural strength, while being less expensive; less massive; and can be made faster compared to conventional CNC machining. The focus and metric of success was to qualify this process and to answer the question if the 3D printed electroplated parts can be fabricated in a more cost, mass and schedule efficient manor compared to traditional CNC machining. Also, to determine if using this method will cause parts to have contamination issues or if parts can survive space environment testing. This was accomplished by conducting several critical tests such as outgassing, material testing and thermal cycling. In addition, this method is being used to develop a practical structural application for KArLE (Potassium Argon Laser Experiment).

3-D Printing↗