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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

MATERIALS AND INTERFACIAL ENGINEERING FOR HIGH- PERFORMANCE ALL-SOLID-STATE BATTERIES

Developing advanced energy storage systems may address the increasing concerns of energy shortage and environmental issues. Among many energy storage technologies, electrochemical energy storage systems such as lithium-ion batteries have been widely used in various applications. However, current lithium-ion batteries using flammable liquid electrolytes may cause a safety risk. All-solid-state sodium batteries (ASSSBs) have been attracting considerable attention as safe and low-cost alternatives to Li-ion batteries. However, the performance of ASSSBs falls short of the requirements for commercial applications mainly due to the challenges at the electrode-solid electrolyte interface. The goal of this dissertation is to develop new materials and interfacial engineering methods for high-performance ASSSBs with favorable electrode-electrolyte interfaces. In this dissertation, I demonstrate three effective strategies to address the interfacial challenges, namely through the use of organic cathode materials, new solid electrolyte development, and interfacial engineering.

Hao, Fang↗

Advanced manufacturing and digital twin technology for nuclear energy*

Advanced manufacturing techniques and digital twin technology are rapidly transforming the nuclear industry, offering the potential to enhance productivity, safety, and cost-effectiveness. Customized parts are being produced using additive manufacturing, automation, and robotics, while digital twin technology enables the virtual modeling and optimization of complex systems. These advanced technologies can significantly improve operational efficiency, predict system behavior, and optimize maintenance schedules in the nuclear energy sector, leading to heightened safety and reduced downtime. However, the nuclear industry demands the highest levels of safety and security, as well as intricate manufacturing processes and operations. Thus, challenges such as data management and cybersecurity must be addressed to fully realize the potential of advanced manufacturing techniques and digital twin technology in the nuclear industry. This comprehensive review highlights the critical role of digital twin technology with advanced manufacturing toward nuclear energy to improve performance, minimize downtime, and heighten safety, ultimately contributing to the global energy mix by providing dependable and low-carbon electricity.

36 MATERIALS SCIENCE↗

Advanced Hydrogen Compressor for Hydrogen Storage Integrated with a Powerplant

This report summarizes work performed by Siemens Energy (SE) to design, build and test an advanced hydrogen compressor stage suitable for use in a hydrogen electrolysis system integrated with a powerplant to achieve energy storage in the form of compressed hydrogen. As hydrogen utilization increases to achieve energy storage and decarbonization of a variety of industries, the need is growing for improved and more cost-effective hydrogen compression technologies. The counter-rotating compression stage concept demonstrated under this contract and presented in this report offers a novel approach to achieve significantly more head rise per stage of compression, resulting in the potential for decreased capital cost and footprint compared to current state of the art centrifugal compression technologies. This report includes details of the design, testing, results, and subsequent validation of aerodynamic performance predictions.

08 HYDROGEN↗

Development of Creep-Fatigue Design Methodology for Base Metal and Weldments of G91

This report provides an update on research activity at the Argonne National Laboratory (ANL) in the area of high temperature materials design methodology for advanced ferritic-martensitic steels for advanced Small Module Reactor (aSMR) Concepts. This is a Level 2 report delivered in FY15 (M2AT-15AN1602013) under the work package AT-15AN160201 “Materials Design Technology for Advanced SMR Concepts” performed by ANL for the Department of Energy, Office of Nuclear Energy. The overall objective of the Materials for Advanced SMR Concepts is to address key long-term design needs for applications of advanced materials. Advanced materials are a critical element in the development of advanced SMR concepts. High temperature materials design technology must be developed to realize the benefits of advanced materials in advanced reactor designs. Among a number of technical issues relevant to materials performance criteria and high temperature design methodology, creep, creep-fatigue, weldment design methodologies, and long-term thermal aging effects are of the highest priority. The effort in this project has focused on improvement of current ASME creep-fatigue design rules and development of a mechanism-based creep-fatigue design method for ferritic-martensitic steels, G91 and G92. This report presents the development of a fundamentally new creep-fatigue life model for G91 base metal and improvements of understanding of creep-fatigue interactions and creep-fatigue design rules for G91 weldments.

36 MATERIALS SCIENCE↗

Cross-Cutting Metrology Tools for In Operando Characterization of Carrier Dynamics in Photovoltaic Devices (Final Technical Report)

Understanding the nature of recombination and its dependence on defects and interfaces is essential for engineering materials and contacts for higher V oc and photovoltaic (PV) efficiency. Time-resolved photoluminescence (TRPL) has conventionally been used to evaluate recombination, but not all materials are strongly emissive or otherwise suitable. Time-resolved terahertz spectroscopy is a pump – probe method that presents valuable complementary information, wherein an optical pump pulse photoexcites carriers within the absorber and the transient photoconductivity is probed with a terahertz pulse. Until now, experimental constraints have prohibited the use of terahertz probes to interrogate full device stacks, and measurements were instead made on exfoliated films or films grown on unconventional substrates. However, interfaces are critical to the behavior of photoexcited carriers in solar cells, and the substrates themselves often influence the film growth and bulk properties. Therefore, it is important to probe the behavior of PV absorbers as close as possible to their normal operating conditions. Here we have developed cross-cutting metrology that enable in operando characterization of carrier dynamics and recombination mechanisms in working PV devices. Through a combination of complementary non-contact TRTS and TRPL experiments and modeling, we have obtained key parameters including photoexcited carrier bulk lifetime and interface and back surface recombination velocities with greater precision and accuracy than can be achieved with conventional TRPL alone. By varying pulsed photoexcitation conditions, the contributions of interface and bulk recombination mechanisms can be determined. We have developed and refined this characterization approach by investigating CdTe PVs, which is a well-established technology but with significant margin for further improvements in efficiency. Results were published in Journal of Applied Physics (DOI: 10.1063/5.0064730) and Proceedings of the IEEE PVSC (DOI: 10.1109/PVSC43889.2021.9518559). After validating the approach, we have applied it to correlate recombination rates to processing conditions and material properties, including composition and defects as well as interfaces and surface treatments. Such feedback can inform processing and design choices to enable higher PV efficiency, not only for CdTe, but also CdSe x Te 1-x , CIGS, perovskites, kesterites, and future technologies. A perspective on predicting solar cell performance from terahertz spectroscopy was published in Advanced Energy Materials (DOI: 10.1002/aenm.202102776). The cross-cutting metrology tools developed here will enable determination of the locus and mechanism of performance-limiting recombination in thin film PV devices. This feedback can guide the engineering of PV devices with higher V oc and efficiency, thereby leading to reductions in levelized cost of electricity to meet the SunShot 2030 target of $0.03/kWh for utility-scale PV. Lower costs will enable rapid expansion of renewable electricity generation that is nearly free of carbon emissions. Reducing carbon emissions of the electricity sector is one of the most important solutions to climate change. The project’s specific focus on CdTe PV can benefit First Solar, the US company that is the global leader in CdTe technology, through both technology and workforce development.

14 SOLAR ENERGY↗

Integrated and Advanced Lighting Controls: The Next Frontier in Energy Savings?

Lighting energy use has significantly declined as a portion of overall building energy usage due largely to the uptake of more efficient light-emitting diode technology. Although the per unit cost of lighting controls has declined, the installation and use of lighting controls are low and the installation and use of advanced controls are abysmally low. Increased use of advanced and connected lighting controls, and the ability to integrate lighting with other building systems (e.g., heat and air, plug loads, miscellaneous loads) that make the building “smarter,” offer the potential for additional energy savings. Studies into the performance of new, advanced lighting control technologies in commercial buildings have generated new findings. Although each field evaluation has interesting results individually, an analysis of their collective findings across a spectrum of commercial building types will help establish the current state of the technology and implications related to market readiness. This paper will analyze results from available field evaluation studies (recently completed as well as ongoing) of retrofit sites and share findings and insights including: • The amount of energy savings that may be expected from these systems. • Cost effectiveness, monetization, and cost points of these systems. • Ideal characteristics of these systems the most viable. • Lessons learned from the installation, commissioning, and occupant response of these systems. The results will support Department of Energy research investments and help inform efficiency programs of the potential of these emerging technologies and how they may fit within the clean energy future.

Myer, Michael↗

Snohomish Public Utility District MESA 2: An Assessment of Flow Battery Energy Storage System Technical Performance

This report investigates the technical performance of the 2.2 MW, 8 MWh MESA 2 advanced vanadium flow battery energy storage system (FBESS), consisting of four 0.55 MW, 2 MWh strings, based on a number of baseline and use case tests. The FBESS is located at the Everett, Washington substation and owned by SnoPUD. The FBESS was procured by SnoPUD with matching funds by the Washington Clean Energy. Baseline tests were intended to assess the general technical capability of the FBESS (e.g., stored energy capacity, ramp rate performance, ability to track varying charge/discharge commands, direct current (DC) battery internal resistance). Use case tests were used to examine the performance of the FBESS while engaged in specific grid services (e.g., arbitrage, power factor correction). The project measured and/or calculated parameters that are important for understanding FBESS performance when subjected to actual field operation for achieving economic benefits, e.g., round trip efficiency (RTE) with and without rest, with and without auxiliary loads, auxiliary power consumption, signal command tracking, temperature trends during operation, parasitic power loss unaccounted by auxiliary load during rest, and state of charge (SOC) excursions. These baseline and use case parameters were analyzed using recorded test results. In addition, the results and lessons presented herein are also beneficial for any task or effort that needs technical assessment on similar and different types of FBESS based on technical specifications and/or field deployment results, since the assessment methodology remains the same.

25 ENERGY STORAGE↗

Microstructure‐Dependent Sodium Storage Mechanisms in Hard Carbon Anodes

Sustainable energy storage is essential to support the transition to renewables and meet the increasing demand for energy. Sodium‐ion batteries (NIBs) are attractive for grid‐scale energy storage due to the abundance and low cost of sodium, sustainability of other battery components, and electrochemical performance. Hard carbon (HC) is a leading anode material for NIBs, but its complex microstructure complicates the understanding of sodium storage mechanisms. Using X‐ray total scattering and density functional theory calculations, this study clarifies how HC's microstructural variations influence sodium storage across the slope (high potential) and plateau (low potential) regions of the potential capacity curve. In the slope region, sodium initially adsorbs at high‐binding energy defect sites and subsequently intercalates between graphene layers, adsorbing at low‐binding energy defect sites, correlating with different slopes observed during initial sodiation. Initial irreversibility arises from sodium trapping at surface defects and solid electrolyte interface formation. In the plateau region, sodium simultaneously intercalates and fills pores, influenced by pore size, interlayer spacing, and defect concentration. HCs with larger pore sizes form larger sodium clusters. In conclusion, the proposed mechanism underscores the role of microstructure engineering in enhancing HC performance and advancing NIBs for grid‐scale energy storage.

36 MATERIALS SCIENCE↗

Integrated and Optimized Energy-Efficient Construction Package for a Community of Production Homes in the Mixed-Humid Climate

Selection and integration of high performance home features are two sides of the same coin in energy efficient sustainable construction. Many advanced technologies are available for selection, but it is in the integration of these technologies into an affordable set of features that can be used on a production basis by builders, that ensures whole-house performance meets expectations. This research high performance home analyzes how a set of advanced technologies can be integrated into a durable and energy efficient house in the mixed-humid climate while remaining affordable to homeowners. The technical solutions documented in this report are the cornerstone of the builder's entire business model based on delivering high-performance homes on a production basis as a standard product offering to all price segments of the residential market. Home Innovation Research Labs partnered with production builder Nexus EnergyHomes (CZ 4). The builder plans to adopt the successful components of the energy solution package for all 55 homes in the community. The research objective was to optimize the builder's energy solution package based on energy performance and construction costs. All of the major construction features, including envelope upgrades, space conditioning system, hot water system, and solar electric system were analyzed. The information in this report can be used by builders and designers to evaluate options, and the integration of options, for increasing the efficiency of home designs in climate zone 4. The data also provide a point of reference for evaluating estimates of energy savings and costs for specific features.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Progress on Producing an ODS Ferritic Alloy by High Deformation Processing of Reactive Powders

Oxide dispersion-strengthened (ODS) ferritic alloys, such as 14YWT, are considered as benchmarks for fuel cladding and core structural materials in advanced nuclear energy reactor systems that require high temperature strength and creep properties as well as resistance to radiation damage. Unfortunately, the popular processing method of mechanical alloying (MA) is time-consuming, incurs high manufacturing costs, and typically produces anisotropy in the microstructure and mechanical properties of ODS ferritic alloys. These considerations hinder their acceptance in many high-performance, high-temperature materials for advanced nuclear energy reactors. This work package is pursuing an alternative solid-state processing to MA involving high deformation at high temperatures for producing an ODS ferritic alloy for fuel cladding. This report summarizes the concept for this processing method and the progress toward selecting the reactive and ferritic alloy powders, preparing 316L stainless steel cans for filling with blended powder followed by degassing, and choosing the heat treatments and forging parameters for performing the first two forging experiments. The preliminary results of optical microscopy performed on polished samples that were cut in three orthogonal directions revealed remnant porosity in both samples. The analysis of the porosity using ImageJ revealed a lesser amount of ~2.49% in the HiLoMe-1 sample that was processed with the three heat treatments and forging parameters compared to ~5.70% for the Hi-1 sample that was processed with only the first sintering heat treatment and forging parameter. These initial results will provide insights that can be leveraged to improve the densification of the powders in future forging experiments that will be continued into FY24 for determining the optimum heat treatments and forging parameters coupled with detailed microstructure characterization studies for producing the ODS ferritic alloy.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Battery Separator Characterization and Evaluation Procedures for NASA's Advanced Lithium-Ion Batteries

To address the future performance and safety requirements for the electrical energy storage technologies that will enhance and enable future NASA manned aerospace missions, advanced rechargeable, lithium-ion battery technology development is being pursued within the scope of the NASA Exploration Technology Development Program s (ETDP's) Energy Storage Project. A critical cell-level component of a lithium-ion battery which significantly impacts both overall electrochemical performance and safety is the porous separator that is sandwiched between the two active cell electrodes. To support the selection of the optimal cell separator material(s) for the advanced battery technology and chemistries under development, laboratory characterization and screening procedures were established to assess and compare separator material-level attributes and associated separator performance characteristics.

Baldwin, Richard S.↗

Streamlining the Coupling of BISON and Dakota Through the NEAMS Workbench

Metallic nuclear fuels for use in advanced reactors are an active area of research and development. Robust, accurate metallic fuel performance models are necessary for the design, analysis, and licensing of such reactors. However, metallic fuel performance models require additional development; they are not as mature as uranium dioxide fuel performance models. To support further metallic fuel development, Oak Ridge National Laboratory and the University of Florida have streamlined the coupling of the BISON fuel performance code with Design Analysis Kit for Optimization and Terascale Applications (Dakota) statistical analysis tool through the Nuclear Energy Advanced Modeling and Simulation (NEAMS) Workbench. This work included performing three different sensitivity analyses on metallic nuclear fuel models in BISON. The analyses examined were a general model of the IFR-1 experiment, the X430 experiment T654 pin, and the X430 experiment T651 pin. The results suggest that BISON and Dakota can be integrated through NEAMS Workbench to perform sensitivity and uncertainty analyses and visualize the results.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

RTU Comparison Calculator Enhancement Plan

Over the past two years, Department of Energy’s Building Technologies Office (BTO) has been investigating ways to increase the operating efficiency of the packaged rooftop units (RTUs) in the field. First, by issuing a challenge to the RTU manufactures to increase the integrated energy efficiency ratio (IEER) by 60% over the existing ASHRAE 90.1-2010 standard. Second, by evaluating the performance of an advanced RTU controller that reduces the energy consumption by over 40%. BTO has previously also funded development of a RTU comparison calculator (RTUCC). RTUCC is a web-based tool that provides the user a way to compare energy and cost savings for two units with different efficiencies. However, the RTUCC currently cannot compare savings associated with either the RTU Challenge unit or the advanced RTU controls retrofit. Therefore, BTO has asked PNNL to enhance the tool so building owners can compare energy and savings associated with this new class of products. This document provides the details of the enhancements that are required to support estimating energy savings from use of RTU challenge units or advanced controls on existing RTUs.

Miller, James D.↗

RTU Comparison Calculator Enhancement Plan

Over the past two years, Department of Energy’s Building Technologies Office (BTO) has been investigating ways to increase the operating efficiency of the packaged rooftop units (RTUs) in the field. First, by issuing a challenge to the RTU manufactures to increase the integrated energy efficiency ratio (IEER) by 60% over the existing ASHRAE 90.1-2010 standard. Second, by evaluating the performance of an advanced RTU controller that reduces the energy consumption by over 40%. BTO has previously also funded development of a RTU comparison calculator (RTUCC). RTUCC is a web-based tool that provides the user a way to compare energy and cost savings for two units with different efficiencies. However, the RTUCC currently cannot compare savings associated with either the RTU Challenge unit or the advanced RTU controls retrofit. Therefore, BTO has asked PNNL to enhance the tool so building owners can compare energy and savings associated with this new class of products. This document provides the details of the enhancements that are required to support estimating energy savings from use of RTU challenge units or advanced controls on existing RTUs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Basic Research Needs for Future Nuclear Energy: Report of the Basic Energy Sciences Workshop for Future Nuclear Energy, August 9-11, 2017

Nuclear power today accounts for approximately 20% of the electrical supply for the US. It provides reliable energy that helps to stabilize the national grid. In contrast to current nuclear power facilities, future concepts operate at higher temperatures, are operationally more efficient, more fully utilize the energy stored within the fuel, and reduce the amount of waste produced. Recent advances in chemistry and materials sciences provide an unprecedented opportunity to develop the critical systems—the fuel, coolant, and structural materials—needed for deployment of advanced nuclear reactor designs. To address the challenge of stringent demands on material systems as their properties and performance continuously evolve over the operational lifetime, the frameworks to uncover the underlying processes that cause reduced performance have been developed over the last decade. There is now the prospect of designing materials that report upon their own damage, are self-healing, and leverage what would be considered deleterious chemical processes to increase their performance within advanced reactor designs. Success will provide an energy source needed to secure a stable and safe energy supply for the nation. To identify the key research directions required to discover the chemical processes and material degradation mechanisms that result in loss of performance of the fuel, coolant, and structural materials, nearly 150 theoreticians, computational experts, and experimentalists from industry, national laboratories, academia, and federal agencies participated in a workshop held in August 2017. Based on the discussions held at the workshop, five Priority Research Directions (PRDs) were identified. These PRDs defined the key scientific challenges that must be met as well as the opportunities that can be exploited to achieve a multi-scale spatial and temporal understanding of fundamental processes that govern the properties and performance of the different material systems required for advanced reactors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Application of a Physics-Informed Convolutional Neural Network for Monitoring the Temperature Fields in High-Temperature Gas Reactors

Here, this work presents current advances in applying a physics-informed convolutional neural network (CNN) to evaluate temperature distributions in advanced reactors. Our goal is to demonstrate that the CNN can reconstruct temperature fields within the solid region of a prismatic fuel assembly in a high-temperature gas reactor (HTGR) with sensor data available in only a few cooling channels. Before that, we showcase the superior performance of the physics-informed CNN in comparison to a purely data-driven multilayer perceptron (MLP), considering a canonical heated channel setup. This analysis shows the advantages of our approach and justifies its choice. The datasets employed here are obtained upon numerical simulations performed with codes under the Nuclear Energy Advanced Modeling and Simulation program. This work is important, as industry experience indicates that the assembly material in HTGR concepts is prone to large thermal-mechanical loads nearing operational limits. This makes it crucial to characterize peak temperatures and their distributions near hot spots. Modern thermocouples are unreliable in these types of harsh environments because of the high neutron fluxes and elevated temperatures involved. The CNN-based field reconstruction represents an attractive solution, enabling sensor arrays in less aggressive locations and augmenting indirect predictions for less accessible regions. The results show that the CNN reduces prediction errors by orders of magnitude in comparison to the MLP, considering the simple yet well-representative heated channel case. In the case of the HTGR fuel assembly, the CNN can successfully reconstruct temperature fields over various cooling regimes. Furthermore, we also explore the algorithm’s ability to detect abnormalities. Interestingly, the CNN proves it has the capacity to detect blockage in one of the noninstrumented cooling channels.

Machine learning↗

Integrated Modeling and Simulation Capability For Full Scale Multi-Physics Simulation and Visualization of Microreactor Concept

Microreactors are small mobile transportable nuclear reactors with thermal power less than 20 MWt that are designed to meet the needs of remote areas, military installations, emergency operations, and disaster relief zones. These reactor are concepts that are intended to be factory-manufacturable, easily transportable, and will allow for semi- or full-autonomous operation. To assist with development of microreactors, modeling and experimentation need to be performed with verification and validation to gain confidence in the models and tools. The objective of this study is apply advanced modeling and simulation capabilities being developed by the DOE Office of Nuclear Energy Nuclear Energy Advanced Modeling and Simulation (NEAMS) program to perform integrated modeling and simulation capability for multiphysics simulation of the microreactor concepts. This activity will provide an opportunity to exercise the codes to provide both gain experience and to provide feedback to the developers.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗