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At least 109 records · Page 6

Pressure broadening and line coupling in bending bands of CO2

The pressure broadening and line coupling cross sections in the Fano-Ben Reuven theory of line shapes are calculated for bending bands of CO2 in a bath of He atoms. Molecular collision dynamics are simplified by invoking the infinite order sudden (IOS) approximation for molecular rotational and vibrational angular momentum in a manner similar to but not identical with the method developed by Clary and shown to be accurate for CO2-He. Numerical values are obtained using a pairwise additive interaction potential developed by Clary. Predictions are in good accord with data for various infrared bands and pure rotational Raman spectra. It is found that all pressure broadening and state-to-state cross sections depend on only a few dynamical factors (generalized IOS cross sections) and are therefore closely interrelated. Results are used to assess models developed previously to analyze line shapes in this and similar systems.

Green, Sheldon↗

Molecular Dynamics Simulation and Theoretical Analysis of Structural Relaxation, Bond Exchange Dynamics, and Glass Transition in Vitrimers

Vitrimers are a class of polymer networks featuring dynamic covalent cross-links that can undergo associative bond exchange. There has been recent interest in these materials due to their promise as recyclable thermosets or self-healing polymers because of the ability of vitrimer networks to rearrange at the molecular level and undergo macroscopic flow. However, the practical use of these materials often occurs in the supercooled regime or glassy state, where the implications of dynamic bonds are complicated by the interplay between slow activated segmental dynamics, cross-link (i.e., bond-exchange) kinetics, and ultimately material properties. Here, in this paper, we combine coarse-grained molecular dynamics simulation and microscopic statistical mechanical theory to understand how cross-linking kinetics affect material dynamics and how this couples to segmental relaxation of the polymeric network strands across a spectrum of length and time scales, especially in the supercooled regime. We characterize the Kuhn segmental alpha relaxation time and bond exchange time for vitrimer systems across various cross-link densities, temperatures, and bond exchange rates. Simulation and theory both exhibit a bending-up behavior for bond exchange time upon cooling, suggesting a coupling between bond exchange dynamics and segmental relaxation that intensifies with faster bond exchange kinetics. We also found bond exchange dynamics have an impact on Kuhn segment alpha relaxation time, which is most significant at higher cross-link densities. Both these effects are most prominent when the bond exchange time is similar to the Kuhn segment alpha relaxation time, and the resulting coupling of these two relaxation processes is tied to both the probability of a free end to find a bonded pair and the time scale of the constraints imposed by the dynamic cross-links. This relationship is reflected by a cross-link dependence of a theoretical parameter which represents the quantitative degree of coupling between bond exchange and segmental dynamics. Overall, the combination of simulation and theory clarifies the intricate interaction between bond kinetics and segmental relaxation and demonstrates the ability to provide molecular-level insights into vitrimer dynamics over a wide temperature range.

dynamic relaxation↗

The crack problem in a specially orthotropic shell with double curvature

The crack problem of a shallow shell with two nonzero curvatures is considered. It is assumed that the crack lies in one of the principal planes of curvature and the shell is under Mode I loading condition. The material is assumed to be specially orthotropic. After giving the general formulation of the problem the asymptotic behavior of the stress state around the crack tip is examined. The analysis is based on Reissner's transverse shear theory. Thus, as in the bending of cracked plates, the asymptotic results are shown to be consistent with that obtained from the plane elasticity solution of crack problems. Rather extensive numerical results are obtained which show the effect of material orthotropy on the stress intensity factors in cylindrical and spherical shells and in shells with double curvature. Other results include the stress intensity factors in isotropic toroidal shells with positive or negative curvature ratio, the distribution of the membrane stress resultant outside the crack, and the influence of the material orthotropy on the angular distribution of the stresses around the crack tip.

Delale, F.↗

Geometrically nonlinear analysis of layered composite shells

Two kinds of finite-element analyses are developed for the geometrically nonlinear study of the large deformations in laminated composite structures, especially shells. The first kind of finite-element analysis utilizes the general incremental variational formulation as well as the total Lagrangian description of motion, and a three-dimensional degenerate element is adopted. The second kind of analysis employs a formulation based on deformable shell theory, and the plate-bending element is used. Numerical results for bending are presented for five plate and shell structures of isotropic as well as orthotropic composition, including an isotropic cylindrical panel with uniform loading and a laminated cylindrical panel with uniform loading. The results obtained using these analyses are found to be in good agreement with those available in the literature.

Chao, W. C.↗

The crack problem in a specially orthotropic shell with double curvature

The crack problem of a shallow shell with two nonzero curvatures is considered. It is assumed that the crack lies in one of the principal planes of curvature and the shell is under Mode I loading condition. The material is assumed to be specially orthotropic. After giving the general formulation of the problem the asymptotic behavior of the stress state around the crack tip is examined. The analysis is based on Reissner's transverse shear theory. Thus, as in the bending of cracked plates, the asymptotic results are shown to be consistent with that obtained from the plane elasticity solution of crack problems. Rather extensive numerical results are obtained which show the effect of material orthotropy on the stress intensity factors in cylindrical and spherical shells and in shells with double curvature. Other results include the stress intensity factors in isotropic toroidal shells with positive or negative curvature ratio, the distribution of the membrane stress resultant outside the crack, and the influence of the material orthotropy on the angular distribution of the stresses around the crack tip. Previously announced in STAR as N83-16782

Delale, F.↗

A deformation analysis of flat flexible gear and its equation of original curved surfaces

The equation of the original curved surface of end harmonic gearing is determined by displacement analysis of flat flexible gear. The displacement analysis is also used to calculate the strength and rigidity of the gear. The latter is regarded as a circular plate with two concentrated loads, since its torsional rigidity is much larger than its bending rigidity. Small-deflection theory of thin plates is used to solve for the displacement of any point in the middle plane of the gear. New expressions are given for radial and tangential displacements of the middle plane under asymmetrical loading. A digital computer is used to obtain numerical values for the displacements.

Yunwen, S.↗

Comparison between theoretical and experimental stresses in circular semimonocoque cylinders with rectangular cutouts

Comparisons are made between a theory for calculating stresses about rectangular cutouts in circular cylinders of semimonocoque construction published in NACA-TN-3200 and previously published NACA experimental data. The comparisons include stresses in the stringers and shear stresses in the center of the shear panels in the neighborhood of the cutout. The theory takes into account the bending flexibility of the rings in the structure, and this factor is found to be important in the calculation of stresses about cutouts. In general, when the ring flexibility is considered, good agreement is exhibited between the calculated and experimental results. (author)

Mccomb, Harvey G , Jr↗

Inertia and Double Bending of Light from Equivalence

Careful examination of light paths in an accelerated reference frame, with use of Special Relativity, can account fully for the observed bending of light in a gravitational field, not just half of it as reported in 1911. This analysis also leads to a Machian formulation of inertia similar to the one proposed by Einstein in 1912 and later derived from gravitational field equations in Minkowsky Space by Sciama in 1953. There is a clear inference from equivalence that there is some type of inertial mass increase in a gravitational field. It is the purpose of the current paper to suggest that equivalence provides a more complete picture of gravitational effects than previously thought, correctly predicting full light bending, and that since the theory of inertia is derivable from equivalence, any theory based on equivalence must take account of it. Einstein himself clearly was not satisfied with the status of inertia in GRT, as our quotes have shown. Many have tried to account for inertia and met with less than success, for example Davidson s integration of Sciama s inertia into GRT but only for a steady state cosmology [10], and the Machian gravity theory of Brans and Dicke [11]. Yet Mach s idea hasn t gone away, and now it seems that it cannot go away without also disposing of equivalence.

Shuler, Robert L., Jr.↗

An experimental-theoretical correlation study of non-linear bending and torsion deformations of a cantilever beam

An experimental study of the large deformation of a cantilevered beam under a gravity tip load has been made. The beam root is rotated so that the tip load is oriented at various angles with respect to the beam principal axes. Static twist and bending deflections of the tip and bending natural frequencies have been measured as a function of tip load magnitude and orientation. The experimental data are compared with the results of a recently developed non-linear structural theory. Agreement is reasonably good when bending deflections are small compared to the beam span, but systematic differences occur for larger deflections.

Dowell, E. H.↗

Characterization of the bending stiffness of large space structure joints

A technique for estimating the bending stiffness of large space structure joints is developed and demonstrated for an erectable joint concept. Experimental load-deflection data from a three-point bending test was used as input to solve a closed-form expression for the joint bending stiffness which was derived from linear beam theory. Potential error sources in both the experimental and analytical procedures are identified and discussed. The bending stiffness of a mechanically preloaded erectable joint is studied at three applied moments and seven joint orientations. Using this technique, the joint bending stiffness was bounded between 6 and 17 percent of the bending stiffness of the graphite/epoxy strut member.

Wu, K. Chauncey↗

Thermal static bending of deployable interlocked booms

Metal ribbons processed with a heat-forming treatment are enabled to form tubelike structures when deployed from a roll. Deployable booms of this have been utilized for gravity-gradient stabilization on the RAE, ATS, and Nimbus D satellites. An experimental thermal-mechanics test apparatus was developed to measure the thermal static bending and twist of booms up to 3 meters long. The apparatus was calibrated by using the correlation between calculated and observed thermal bending of a seamless tube. Thermal static bending values of 16 interlocked deployable booms were observed to be within a factor of 2.5 of the values calculated from seamless-tube theory. Out-of-Sun-plane thermal bending was caused by complex heat transfer across the interlocked seam. Significant thermal static twisting was not observed.

Staugaitis, C. L.↗

Handbook of structural stability part VI : strength of stiffened curved plates and shells

A comprehensive review of failure of stiffened curved plates and shells is presented. Panel instability in stiffened curved plates and general instability of stiffened cylinders are discussed. The loadings considered for the plates are axial, shear, and the combination of the two. For the cylinders, bending, external pressure, torsion, transverse shear, and combinations of these loads are considered. When possible, test data and theory were correlated. General instability in stiffened cylinders was investigated. For bending and torsion loads, test data and theory were correlated. For external pressure several existing theories were compared. As a result of this investigation a unified theoretical approach to analysis of general instability in stiffened cylinders was developed. (author)

Becker, Herbert↗

Crack Turning Mechanics of Composite Wing Skin Panels

The safety of future composite wing skin integral stiffener panels requires a full understanding of failure mechanisms of these damage tolerance critical structures under both in-plane and bending loads. Of primary interest is to derive mathematical models using fracture mechanics in anisotropic cracked plate structures, to assess the crack turning mechanisms, and thereby to enhance the residual strength in the integral stiffener composite structures. The use of fracture mechanics to assess the failure behavior in a cracked structure requires the identification of critical fracture parameters which govern the severity of stress and deformation field ahead of the flaw, and which can be evaluated using information obtained from the flaw tip. In the three-year grant, the crack-tip fields under plane deformation, crack-tip fields for anisotropic plates and anisotropic shells have been obtained. In addition, methods for determining the stress intensity factors, energy release rate, and the T-stresses have been proposed and verified. The research accomplishments can be summarized as follows: (1) Under plane deformation in anisotropic solids, the asymptotic crack-tip fields have been obtained using Stroh formalism; (2) The T-stress and the coefficient of the second term for sigma(sub y), g(sub 32), have been obtained using path-independent integral, the J-integral and Betti's reciprocal theorem together with auxiliary fields; (3) With experimental data performed by NASA, analyses indicated that the mode-I critical stress intensity factor K(sub Q) provides a satisfactory characterization of fracture initiation for a given laminate thickness, provided the failure is fiber-dominated and crack extends in a self-similar manner; (4) The high constraint specimens, especially for CT specimens, due to large T-stress and large magnitude of negative g(sub 32) term may be expected to inhibit the crack extension in the same plane and promote crack turning; (5) Crack turning out of crack plane in generally anisotropic solids under plane deformation has been studied; (6) The role of T-stress and the higher-order term of sigma(sub y) on the crack turning and stability of the kinked crack has been quantified; (7) Asymptotic crack-tip fields including the effect of transverse shear deformation (Reissner plate theory) in an anisotropic plate under bending, twisting moments, and transverse shear loads has been presented; (8) The expression of the path-independent J-integral in terms of the generalized stress and strain has been derived; (9) Asymptotic crack-tip fields including the effect of transverse shear deformation (Reissner shallow shell theory) in a general anisotropic shell has been developed; (10) The Stroh formalism was used to characterize the crack tip fields in shells up to the second term and the energy release rate was expressed in a very compact form.

Yuan, F. G.↗

Internal and edge cracks in a plate of finite width under bending

Internal and edge cracks were studied by using Reissner's transverse shear theory. The effect of stress-free boundaries on the stress intensity factors in plates under bending were investigated. Among the results found, particularly interesting are those relating to the limiting cases of the crack geometries. The numerical results are given for a single internal crack, two collinear cracks, and two edge cracks. The effect of Poisson's ratio on the stress intensity factors was studied.

Boduroglu, H.↗