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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Model predictive control for demand flexibility: Real-world operation of a commercial building with photovoltaic and battery systems

Hundreds of studies have investigated Model Predictive Control (MPC) for the optimal operation of building energy systems in the past two decades. However, MPC field tests are still uncommon, especially for small- and medium-sized commercial buildings and for buildings integrated with onsite renewables. This paper describes the implementation and the long-term performance evaluation of an MPC controller in a small commercial building equipped with behind-the-meter photovoltaics and electrochemical batteries. MPC controls space conditioning, commercial refrigeration, and the battery system. We tested two types of demand flexibility applications in the field: electricity bill minimization under time-of-use tariffs and responses to grid flexibility events. Results show that the proposed controller achieves 12% of annual electricity cost savings and 34% peak demand reduction against the baseline, while respecting thermal comfort and food safety. The field tests also demonstrate the ability of the MPC controller to provide a multitude of grid services including real-time pricing, demand limiting, load shedding, load shifting, and load tracking, using the same optimization framework.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Understanding particle size effect on fast-charging behavior of graphite anode using ultra-thin-layer electrodes

Extreme fast charging (≤ 15 min) of lithium-ion batteries is highly desirable to accelerate mass-market adoption of electric vehicles. However, significant capacity fading, as well as safety issues due to the lithium plating caused by the fast charging rate, limit its implementation. In this study, we investigated the fast-charging capability of graphite materials with various particle sizes. To eliminate the Li + ion concentration gradient effect across the thickness of the electrode, ultra-thin-layer graphite electrodes were developed to investigate the "real" fast-charging capability of graphite at the particle level. Electrochemical assessments as well as microscopic characterizations revealed that smaller particles exhibited superior fast-charging performance, featuring enhanced capacity reversibility, faster charging rate, and less lithium plating under the same fast-charging conditions. It is shown that small-particle graphite (mean radius of 3.3 μm) could withstand a 4C charge (to 80 % state-of-charge) without plating, with minimal plating occurring at 6C. Thicker particles exhibited plating at lower C-rates. Since the experimental data could not directly explain whether intra-particle diffusion limitations or interfacial reaction limitations dominated the plating mechanism, the pseudo-2-dimensional model was used to evaluate the most likely plating mechanism. The model suggested that particle-level diffusion is the dominant mechanism contributing to plating at high rates. Finally, this work provides comprehensive insights into the particle size effects on fast-charging capability, offering a better understanding of fast-charging behavior and valuable guidance for designing optimal electrode architecture for high-rate lithium-ion batteries.

25 ENERGY STORAGE↗

An energy storage dispatch optimization for demand-side management in industrial facilities

An energy storage (ES) dispatch optimization was implemented to test lithium-ion battery ES, supercapacitor ES, and compressed air ES on two different industrial facilities – one intermittent process facility and one continuous process facility. The model first shows the capability of optimizing the size of a single technology on a single industrial facility to maximize the return on investment. Then, for the same profile, the model identifies significant differences in the optimal size for different technologies based on their performance parameters. Third, the model identifies differences in the optimal size for each technology based on the facilities profile. Here the results show compressed air ES yields the highest return on investment for both facilities and provides insight for future development of ES systems.

25 ENERGY STORAGE↗

Occupant Preference-Aware Load Scheduling for Resilient Communities

The load scheduling of resilient communities in the islanded mode is subject to many uncertainties such as weather forecast errors and occupant behavior stochasticity. To date, it remains unclear how occupant preferences affect the effectiveness of the load scheduling of resilient communities. This paper proposes an occupant thermal preference-aware load scheduler for resilient communities operating in the islanded mode. First, key resilience indicators are selected to quantify its impacts on the load scheduling of a resilient community. A deterministic model predictive control-based load scheduling framework is adopted as the baseline. Then, a chance-constrained controller is proposed to address the occupant-induced uncertainty in room temperature setpoints. Finally, the chance-constrained controller is compared with the deterministic controller on a virtual community testbed based on a real-world net-zero energy community in Florida, U.S. Results have shown that the proposed chance-constrained controller performs better in terms of serving occupants’ thermal preference and the required battery sizes compared to the deterministic controller with the presence of the assumed stochastic occupant behavior. This work indicates that it is necessary to consider the stochasticity of the occupant behavior when designing optimal load schedulers for resilient communities.

Wang, Jing↗

Thick Binder-Free Electrodes for Li-Ion Battery Fabricated Using Templating Approach and Spark Plasma Sintering Reveals High Areal Capacity

The templating approach is a powerful method for preparing porous electrodes with interconnected well-controlled pore sizes and morphologies. The optimization of the pore architecture design facilitates electrolyte penetration and provides a rapid diffusion path for lithium ions, which becomes even more crucial for thick porous electrodes. In this work, NaCl microsize particles are used as a templating agent for the fabrication of 1 mm thick porous LiFePO 4 and Li 4 Ti 5 O 12 composite electrodes using spark plasma sintering technique. These sintered binder-free electrodes are self-supported and present a large porosity (40%) with relatively uniform pores. The electrochemical performances of half and full batteries reveal a remarkable specific areal capacity (20 mA h cm -2 ), which is 4 times higher than those of 100 µm thick electrodes present in conventional tape-casted Li–ion batteries (5 mA h cm -2 ). The 3D morphological study is carried out using full field transmission X-ray microscopy in microcomputed tomography mode to obtain tortuosity values and pore size distributions leading to a strong correlation with their electrochemical properties. These results also demonstrate that the coupling between the salt templating method and the spark plasma sintering technique turns out to be a promising way to fabricate thick electrodes with high energy density.

25 ENERGY STORAGE↗

Are coupled renewable-battery power plants more valuable than independently sited installations?

Coupled renewable-battery powerplants differ from the traditional concept of independent siting of electricity resources within transmission networks. Prior research on the value proposition and cost savings from coupling did not consider the geographic constraint of co-location. This paper fills the gap by assessing how pricing volatility differences between nodes within electricity markets impact the system value of coupled renewable-battery projects as compared to independent VRE and battery installations. We use wholesale power market prices from 2012–2019 across the seven main U.S. independent system operators (ISOs) with a linear optimization program to compare the electricity market value of coupled projects to the value of the same underlying sub-components, deployed separately. We find that additional value from adding a 4-hour battery sized to 50% of renewable-plant nameplate capacity is $\$$10/MWh across ISOs on average. The highest boost occurs in California ($\$$15/MWh), where the value of adding storage to solar rises over time in tandem with increased solar penetration in the region. If renewables and batteries are deployed independently, we estimate that $\$$12.5/MWh of additional value could be achieved because of more flexibility on battery siting and operation. The $\$$12.5/MWh coupling penalty is reduced to $\$$1.6/MWh when considering alternative approaches to integrating battery storage. This result implies that renewable-battery power plants will play an increasing role in electricity systems if they can be built for $\$$2–$\$$13/MWh less than independent projects of comparable size. However, the wide regional variation in coupling penalties, along with the importance of conditions captured in our sensitivity cases, suggests the tradeoff between coupling penalties and savings will vary by situation. Therefore, roles exist for independent and coupled projects from a system optimization perspective.

14 SOLAR ENERGY↗

Viscous flow properties and hydrodynamic diameter of phenothiazine-based redox-active molecules in different supporting salt environments

We report viscous flow properties of a redox-active organic molecule, N-(2-(2-methoxyethoxy)ethyl)phenothiazine (MEEPT), a candidate for non-aqueous redox flow batteries, and two of its radical cation salts. A microfluidic viscometer enabled the use of small sample volumes in determining viscosity as a function of shear rate and concentration in the non-aqueous solvent, acetonitrile, both with and without supporting salts. All solutions tested show Newtonian behavior over shear rates of up to 30 000 s−1, which was rationalized by scaling arguments for the diffusion-based relaxation time of a single MEEPT molecule without aggregation. Neat MEEPT is flowable but with a large viscosity (412 mPa⋅s at room temperature), which is ∼1000 times larger than that of acetonitrile. MEEPT solutions in acetonitrile have low viscosities; at concentrations up to 0.5 M, the viscosity increases by less than a factor of two. From concentration-dependent viscosity measurements, molecular information was inferred from intrinsic viscosity (hydrodynamic diameter) and the Huggins coefficient (interactions). Model fit credibility was assessed using the Bayesian Information Criterion. It is found that the MEEPT and its charged cations are “flowable” and do not flocculate at concentrations up to 0.5 M. MEEPT has a hydrodynamic diameter of around 8.5 Å, which is almost insensitive to supporting salt and state of charge. This size is comparable to molecular dimensions of single molecules obtained from optimized structures using density functional theory calculations. The results suggest that MEEPT is a promising candidate for redox flow batteries in terms of its viscous flow properties.

Wang, Yilin (ORCID:0000000316102995)↗

Lessons Learned From Techno-Economic Analysis of Solar Photovoltaics and Battery Energy Storage at a Vietnam Industrial Park

Through the Clean Energy Investment Accelerator (CEIA), engineers from the United States (U.S.) National Renewable Energy Laboratory (NREL) conducted a case study analysis evaluating the techno-economic feasibility of battery energy storage systems (BESS) at an industrial park in Vietnam. The analysis uses NREL's REopt platform, a distributed energy modeling and optimization tool, to identify the cost-optimal system sizing for BESS, in conjunction with onsite renewables such as solar photovoltaics (PV), to reduce electricity costs, increase onsite renewable energy generation utilization, and improve resilience to grid outages.

batteries↗

Optimization of a Mixed Fleet of Aerial Drones for Medical Supplies: A Case Study of Blood Delivery Logistics

Aerial drones have emerged as an innovative solution for faster transportation of time-sensitive items (e.g., emergency medical supplies), potentially reducing the transmission of contagious diseases and enhancing healthcare availability through contactless autonomous delivery. We study fleet sizing and efficient scheduling of a mixed fleet of drones for delivering time-sensitive medical items having distinct release and due times to minimize the required fleet size and fleet composition, the required number of additional batteries, and the total energy consumption. We continuously track the remaining battery energy of drones to determine the optimal timing for battery replacement, rather than replacing the battery at each node. Using actual drone flight test data, we employed a machine learning (ML) method to estimate the energy consumption of different drone types during flight segments for different operating parameters. We present a novel mixed-integer programming model to efficiently formulate the problem that integrates the estimated energy consumption functions from ML. We propose a new greedy heuristic (GH) algorithm and a customized genetic algorithm (GA) for solving large-scale instances of this problem faster. Results demonstrate that the GH algorithm is substantially faster than the accelerated CPLEX and the GA, while sacrificing the solution quality by a small amount. Results based on an actual blood sample delivery case study from Pendleton, Oregon, United States, show that using a mixed fleet of drones reduces the total cost and total energy consumption up to 18.18% and 28.7%, respectively, compared to using a homogeneous fleet.

29 - ENERGY PLANNING, POLICY AND ECONOMY↗

Optimization of Component Sizing for a Fuel Cell-Powered Truck to Minimize Ownership Cost

In this study, we consider fuel cell-powered electric trucks (FCETs) as an alternative to conventional medium- and heavy-duty vehicles. FCETs use a battery combined with onboard hydrogen storage for energy storage. The additional battery provides regenerative braking and better fuel economy, but it will also increase the initial cost of the vehicle. Heavier reliance on stored hydrogen might be cheaper initially, but operational costs will be higher because hydrogen is more expensive than electricity. Achieving the right tradeoff between these power and energy choices is necessary to reduce the ownership cost of the vehicle. This paper develops an optimum component sizing algorithm for FCETs. The truck vehicle model was developed in Autonomie, a platform for modelling vehicle energy consumption and performance. The algorithm optimizes component sizes to minimize overall ownership cost, while ensuring that the FCET matches or exceeds the performance and cargo capacity of a conventional vehicle. Class 4 delivery truck and class 8 linehaul trucks are shown as examples. We estimate the ownership cost for various hydrogen costs, powertrain components, ownership periods, and annual vehicle miles travelled.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

PV output smoothing using a battery and natural gas engine-generator.

In some situations involving weak grids or high penetration scenarios, the variability of photovoltaic systems can affect the local electrical grid. In order to mitigate destabilizing effects of power fluctuations, an energy storage device or other controllable generation or load can be used. This paper describes the development of a controller for coordinated operation of a small gas engine-generator set (genset) and a battery for smoothing PV plant output. There are a number of benefits derived from using a traditional generation resource in combination with the battery; the variability of the photovoltaic system can be reduced to a specific level with a smaller battery and Power Conditioning System (PCS) and the lifetime of the battery can be extended. The controller was designed specifically for a PV/energy storage project (Prosperity) and a gas engine-generator (Mesa Del Sol) currently operating on the same feeder in Albuquerque, New Mexico. A number of smoothing simulations of the Prosperity PV were conducted using power data collected from the site. By adjusting the control parameters, tradeoffs between battery use and ramp rates could be tuned. A cost function was created to optimize the control in order to balance, in this example, the need to have low ramp rates with reducing battery size and operation. Simulations were performed for cases with only a genset or battery, and with and without coordinated control between the genset and battery, e.g., without the communication link between sites or during a communication failure. The degree of smoothing without coordinated control did not change significantly because the battery dominated the smoothing response. It is anticipated that this work will be followed by a field demonstration in the near future.

Johnson, Jay Dean↗

Modeling and Simulation of a Parallel Hybrid Electric Regional Aircraft for the Electrified Powertrain Flight Demonstration (EPFD) Program

This paper presents a parametric modeling and integrated aircraft sizing and synthesis approach for a charge depleting parallel hybrid electric architecture. The developed models are integrated within the baseline thin-haul and regional aircraft. In addition to the physical architecture, different modes of operation enabled by propulsion system electrification are also modeled parametrically. The modes of operation presented in this paper are the peak power shaving, climb power electric boost, in-flight battery recharging, and electric taxi. The sizing of the powertrain and the aircraft are performed within the multidisciplinary analysis and optimization environment, E-PASS. The consideration of the physical system and its operation together provides a holistic approach where the propulsion system and the airframe are designed under an optimized power and energy management strategy. The parametric nature of the work enables the design space exploration for electrification and lays the groundwork for future technology projection and uncertainty quantification studies. The developed capability is generic and can be applied on other aircraft classes. The work is done as part of the Electrified Powertrain Flight Demonstration program.

electrified powertrain flight demonstration↗

Long duration battery sizing, siting, and operation under wildfire risk using progressive hedging

Battery sizing and siting problems are computationally challenging due to the need to make long-term planning decisions that are cognizant of short-term operational decisions. This paper considers sizing, siting, and operating batteries in a power grid to maximize their benefits, including price arbitrage and load shed mitigation, during both normal operations and periods with high wildfire ignition risk. Here we formulate a multi-scenario optimization problem for long duration battery storage while considering the possibility of load shedding during Public Safety Power Shutoff (PSPS) events that de-energize lines to mitigate severe wildfire ignition risk. To enable a computationally scalable solution of this problem with many scenarios of wildfire risk and power injection variability, we develop a customized temporal decomposition method based on a progressive hedging framework. Extending traditional progressive hedging techniques, we consider coupling in both placement variables across all scenarios and state-of-charge variables at temporal boundaries. This enforces consistency across scenarios while enabling parallel computations despite both spatial and temporal coupling. The proposed decomposition facilitates efficient and scalable modeling of a full year of hourly operational decisions to inform the sizing and siting of batteries. With this decomposition, we model a year of hourly operational decisions to inform optimal battery placement for a 240-bus WECC model in under 70 min of wall-clock time.

25 ENERGY STORAGE↗

Development of an Unmanned Mobile Current Turbine Platform: Preprint

The design and development of a prototype unmanned mobile floating platform, equipped with a custom low-flow marine current turbine for autonomously seeking and harnessing tidal/coastal currents is described. The platform is an unmanned surface vehicle in the form of a catamaran with two electric outboard motors and capabilities for autonomous navigation. An undershot water wheel, aided by a custom flow concentrator, has been selected as the basic design for the marine current turbine, which is mounted on the stern of the unmanned surface vehicle platform. The concept of operation is that the platform would navigate to a designated marine current resource, autonomously anchor at the location, align itself in the current and deploy the current turbine using a custom cable-lift deployment mechanism. As the turbine harnesses the local current, an onboard power-take-off device converts the harnessed mechanical energy to electricity which is stored in onboard batteries. Considerations of deployment in tidal and coastal waters required obtaining the necessary environmental permits for conducting in-water testing; developing required mitigation measures in protecting local wildlife and their habitats; and identifying potential in-water test sites and surveying them for their suitability in terms of the current resource, bottom type, water depth, and local boat traffic. The design and development of the turbine and the results of initial in-water testing are discussed. The potential for scaling up the system for extended capacity is presented.

ENGINEERING,TIDAL AND WAVE POWER↗

A Multiphysics Study to Improve Specific Energy of Primary Batteries for Low Temperature Operation for Deep Space Missions

Several lander missions on the outer planets such as Europa, Enceladus, and Titan require electrical power to operate scientific and communication equipment. The traditional power generation methods, such as a photovoltaic array, are not feasible as their efficiency drops significantly at these vast distances. The novel radioisotope power systems are not practical today based on current lander designs and the effectiveness of these systems. To perform in situ science on distant planets, a high specific energy battery (>700 Wh/kg) needs to operate for about 480 hours under cold temperatures (-40C or 0C) [1]. While a primary battery such as Li-CFx can provide high specific energy at room temperature, its specific capacity decreases significantly at low temperatures. One of the causes for this drop is low ion and electrical conductivity, and slower reaction kinetics. Slower transport and facile kinetics lead to an increase in the battery’s resistance and higher voltage drops during the cell operation, thus reducing specific capacity. Both the transport and kinetics show a strong dependence on temperature. Thus, a small temperature rise can lead to an increase in the reaction rate and ion conductivity; since the temperature, cell resistance, and specific capacity are interdependent. A conventional battery model accounts for ohmic, thermodynamic, and, electrochemical, and chemical decomposition heating. The ohmic heating can be controlled by designing a resistive microstructure and varying the ratios of the active materials [2]. The kinetics can be improved by increasing the surface area, reducing the particle size, or adding a catalyst. These parameters are often optimized to achieve high specific energy at room temperatures. A similar optimization study is not available at low temperatures and for a primary (high specific energy) battery. For this presentation, we will explore the effect of geometrical, microstructural, and material properties on optimal specific capacity at low temperatures through multiphysics simulations. The ion transport resistance depends on the porosity and the tortuosity of an electrode and the separator.

M. Mehta↗

Effect of Calcination Temperature on the Electrochemical Properties of Nickel-rich LiNi0.76Mn0.14Co0.10O2 Cathodes for Lithium-ion Batteries

High energy density nickel (Ni)-rich layered LiNixMnyCozO2 (NMC, x = 0.6) materials are promising cathodes for lithium-ion batteries. However, several technical challenges, such as fast capacity fading, are hampering their large scale application. Herein, we demonstrate that a Ni-rich cathode LiNi0.76Mn0.14Co0.10O2 (NMC76) calcined at an optimal temperature of 750~775oC exhibits a high discharge capacity (~215 mAh g-1 when charged to 4.5 V) and an excellent high rate capability. Even at a 10C rate, it still exhibits a capacity of more than 160 mAh g-1 and retains ca. 79% of its initial capacity after 200 cycles. The high performance of NMC76 is directly related to its optimized primary particle size (that constitute the spherical secondary particles of >10 m) and cation mixing. Higher calcination temperature (= 800 oC) leads to rapid increase of primary particle size, poor cycling stability, and inferior rate capability of NMC76 due to its severe micro strain and crack formation upon repeated lithium ion de/intercalations. Therefore, NMC76 calcined at 750~775oC is a very good candidate for the next generation of Li ion batteries.

nickel-rich cathodes, calcination temperature, cyc↗