Search NASA⌕ Search

SEARCH · Search NASA

Results for “Carbon-Rich”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

Synthetic spectra of cool stars for the wavelength range 2550-3200 A

In order to interpret the ultraviolet spectra of cool stars obtained with IUE and to determine the physical conditions in their outer atmospheres, synthetic IUE spectra of stars cooler than the Sun, mainly the Sun and the metal-deficient, carbon-rich CH stars were calculated. Results are encouraging. Synthetic spectra for the Sun over the range 2550 to 3300 A give roughly the observed level of overall emission and relative strengths or various absorption features (Fe II, Mg II, Mg I, and Fe I) although they still require extra sources of continuous opacity longward of 2650 A. Spectra of the CH stars have roughly the correct shape in the ultraviolet continuum for the expected effective temperature, although these models are problematic in that the electron density, hence H(-) opacity, is directly proportional to the Mg-Si-Fe density and the ratio of line to continuum opacity is only slightly affected by changing metallicity.

Eaton, Joel A.↗

New CO and HCN sources associated with IRAS carbon stars

Emission of CO and HCN was detected in 22 out of a sample of 53 IRAS sources classified as unidentified carbon-rich objects. The sample was selected according to the presence of the silicon carbide feature as revealed by low-resolution spectra. The molecular line widths indicate that the CO and HCN emission arises from the circumstellar envelopes of very highly evolved stars undergoing mass loss. The visible stars tend to be deficient in CO as compared with unidentified sources. Most the detected CO and HCN IRAS stars are distinct and thick-shelled objects, but their infrared and CO luminosities are similar to those of IRC + 102156 AFGL and IRC-CO evolved stars. The 12 micron flux seems to be a good indicator of the distance, hence a guide for molecular searches.

NGUYEN-Q-RIEU↗

Properties of evolved mass-losing stars in the Milky Way and variations in the interstellar dust composition

A large sample of evolved carbon-rich and oxygen-rich objects has been studied using data from the IRAS Point Source Catalog. The number density of infrared-emitting 'carbon' stars shows no variation with Galactocentric radius, while the evolved 'oxygen' star volume density can be well fitted by a given law. A law is given for the number of carbon stars; a total is found in the Galaxy of 48,000 highly evolved oxygen stars. The mass-return rate for all evolved stars is found to be 0.35 solar mass/yr, with a small percentage contribution from carbon stars. The mass-loss rates for both types of stars are dominated by the small number of objects with the smallest rates. A mean lifetime of about 200,000 yr is obtained for both carbon and oxygen stars. Main-sequence stars in the mass range of three to five solar masses are the probable precursors of the carbon stars.

Thronson, Harley A., Jr.↗

On graphite in primitive meteorites, chondritic interplanetary dust, and interstellar dust

Vapor phase-condensed primary and secondary graphites require prolonged solid-state thermal annealing and are less likely than amorphous graphitizable carbons to occur in the interstellar medium as dust. Some unknown fraction of this amorphous carbon may be converted to secondary graphite by radiative annealing due to UV photons. Grain size distribution may differentiate between primary and secondary graphites; secondary graphite should, moreover, be associated with poorly graphitized carbon. Small, as-yet undetected amounts of small secondary graphite particles may exist in carbon-rich astrophysical environments.

Rietmeijer, Frans J. M.↗

Discovery of very high velocity outflow in V Hydra - Wind from an accretion disk in a binary?

High-resolution observations of lines from the CO v = 1-0 vibration-rotation band at 4.6 microns, taken with the FTS/KPNO 4-m telescope, are reported for the carbon-rich red giant V Hydra, which is surrounded by an extended expanding molecular envelope resulting from extensive mass loss. The spectrum shows, in addition to the expected absorption at the outflow velocity of the envelope, absorption extending up to 120 km/s bluewards of the stellar velocity. A comparison of the spectrum observed at two epochs shows that the high-velocity absorption features change with time. It is suggested that the observed high-velocity features in V Hydra arise in a high-velocity polar outflow from an accretion disk in a binary system, as proposed in the mass-loss model for bipolar envelopes by Morris (1988).

Sahai, R.↗

Electrical conductivity of chondritic meteorites

The electrical conductivity of samples of the Murchison and Allende carbonaceous chondrites is 4 to 6 orders of magnitude greater than rock forming minerals such as olivine for temperatures up to 700 C. The remarkably high electrical conductivity of these meteorites is attributed to carbon at the grain boundaries. Much of this carbon is produced by pyrolyzation of hydrocarbons at temperatures in excess of 150 C. As the temperature increases, light hydrocarbons are driven off and a carbon-rich residue or char migrates to the grain boundaries enhancing electrical conductivity. Assuming that carbon was present at the grain boundaries in the material which comprised the meteorite parent bodies, the electrical heating of such bodies was calculated as a function of body size and solar distance during a hypothetical T-Tauri phase of the sun. Input conductivity data for the meteorite parent body were the present carbonaceous chondrite values for temperatures up to 840 C and the electrical conductivity values for olivine above 840 C.

Duba, AL↗

Spatially resolved quantitative spectroscopy of comets

Because of their temporal and spatial variations, modern ground-based studies of comets within approximately 4 A.U. of the sun are observationally demanding tasks. Over the years, researchers have attempted resolved spectroscopy of comets covering a wide range of intrinsic luminosity. Recently this group has developed spectral and direct-imaging procedures to detect weak ion tails submerged into the comae of even fairly faint comets. Although the last year was devoid of any really bright comet, re-analysis of older dust and gas production data of the 1986 P/Halley apparition has been almost completed. The main changes are that the nucleus does make a significant contribution to continuum light, and that the gravity effect in the dust escape velocity is somewhat larger than previously assumed. On the direct observational side, spectral studies of the 1987's Comet Bradfield show it to be qualitatively carbon-rich, at least in the outer coma ratio of CO(+) and CO2(+), compared the H2O(+) with respect to Halley at similar heliocentric distances.

Spinrad, Hyron↗

The age of the LMC globular cluster NGC 1783

The age of the LMC red globular cluster NGC 1783 is estimated as 0.9 + or - 0.4 billion yr by photometry of the main-sequence turnoff. The accuracy of the estimate is limited chiefly by the uncertainty in the distance modulus of the cluster. At (m - M)0 = 18.2 the cluster is aged 1.1 + or - 0.2 Gyr; at (m - M)0 = 18.7 it is 0.7 + or - 0.2 Gyr. NGC 1783 is a sufficiently rich cluster that one can see the full development of red giants on the asymptotic giant branch from the M type, through S, to carbon-rich atmospheres.

Mould, Jeremy↗

Titanium carbide and titania phases on Antarctic ice particles of probable extraterrrestrial origin

Two unique titania-rich particles, found within ancient Antarctic ice have been discovered and characterized, and are believed to be of extraterrestrial origin. Both particles contain abundant submicron-sized crystals of Magneli phases (Ti(n)O(2n-1). In addition, one particle contains a core of TiC. Whereas the Magneli phases would have been stable in the early solar nebula, and so probably formed there, the TiC is more likely to have condensed in the cool, dusty, carbon-rich outer shell of a red giant star. It is suggested that both particles are interplanetary dust particles whose Magneli phases carry a record of the PO2-T conditions of the early solar nebula. It is further suggested that the TiC grain in particle 705 is remnant interstellar dust.

Zolensky, M. E.↗

Dust-enshrouded asymptotic giant branch stars in the solar neighborhood

Using available infrared catalogs, an inventory is taken of the AGB star losing large amounts of mass within about 1 kpc of the sun. A surface density of these stars is estimated of about 25/sq kpc projected onto the plane of the Galaxy. Of these stars, about one-half are oxygen-rich while the other half are carbon-rich. The total mass-loss rate from AGB stars into the interstellar medium is probably between 3 and 6 x 10 to the -4th solar mass/sq kpc/yr. Within the uncertainties, this is in reasonable agreement with an estimated net loss rate of about 8 x 10 to the -4th solar mass/sq kpc/yr for main-sequence stars with initial masses between 1 and 5 solar masses as they evolve to white dwarfs. However, it is possible that there are important sources of mass loss which have not yet been identified. In the solar neighborhood, about one-half of all about 1.2 solar mass main-sequence stars spend greater than 30,000 yr in a carbon-star phase where they lose 1-2 x 10 to the -5th solar mass/yr and then become white dwarfs with about 0.7 solar mass.

Jura, M.↗

Influence of interfacial shear strength on the mechanical properties of SiC fiber reinforced reaction-bonded silicon nitride matrix composites

The influence of fiber/matrix interface microstructure and interfacial shear strength on the mechanical properties of a fiber-reinforced ceramic composite was evaluated. The composite consisted of approximately 30 vol percent uniaxially aligned 142 microns diameter SiC fibers (Textron SCS-6) in a reaction-bonded Si3N4 matrix (SiC/RBSN). The interface microstructure was varied by controlling the composite fabrication conditions and by heat treating the composite in an oxidizing environment. Interfacial shear strength was determined by the matrix crack spacing method. The results of microstructural examination indicate that the carbon-rich coating provided with the as-produced SiC fibers was stable in composites fabricated at 1200 C in a nitrogen or in a nitrogen plus 4 percent hydrogen mixture for 40 hr. However this coating degraded in composites fabricated at 1350 C in N2 + 4 percent H2 for 40 and 72 hr and also in composites heat treated in an oxidizing environment at 600 C for 100 hr after fabrication at 1200 C in a nitrogen. It was determined that degradation occurred by carbon removal which in turn had a strong influence on interfacial shear strength and other mechanical properties. Specifically, as the carbon coating was removed, the composite interfacial shear strength, primary elastic modulus, first matrix cracking stress, and ultimate tensile strength decreased, but the first matrix cracking strain remained nearly the same.

Bhatt, Ramakrishna T.↗

A 21 micron emission feature in four proto-planetary nebulae

The discovery of an unidentified emission feature at 21 microns in the LRS spectra of four IRAS sources is reported. These objects all show large FIR excesses due to a circumstellar dust envelope surrounding a carbon-rich central star and are likely to be in the evolutionary phase between the asymptotic giant branch and planetary nebula stages. The strength of the feature and the carbon richness of the objects suggest that this feature is due to the bending mode of a transient carbon-bearing molecule.

Kwok, Sun↗

Grain ultraviolet extinction properties of recently discovered post asymptotic giant branch stars

The circumstellar grains of two hot evolved postasymptotic giant branch stars, HD 89353 and HD 213985, are examined, deriving the extinction around 2175 A. An unsuccessful attempt to detect 6614 A diffuse band absorption arising from the grains implies that the carrier of this diffuse band is not the carrier of the unidentified IR features reported by other investigators nor of the 2175 A bump. It is found that the linear UV extinction of the carbon-rich star HD 89353 continues across the 2175 A region with no sign of the bump; for HD 213985 the reverse is found: a strong, wide bump in the mid-UV. A wavelength of 2300 A is derived for the HD 213985 bump, which lies longward of its unusual position in the interstellar medium. Since HD 89353 is metal-poor yet rich in hydrogen and carbon, the linear extinction arises from hydrocarbon grains of radius less than 300 A.

Buss, Richard H., Jr.↗

Effect of a high temperature cycle on the mechanical properties of silicon carbide/titanium metal matrix composites

An investigation is conducted of the effects of the SPF/DB cycle on continuous SiC fiber-reinforced Ti-15V-3Cr-3Al-3Sn composite's matrix, fiber, and matrix-fiber interface. The fibers in question, designated SCS-6, have a carbon core and thin, carbon-rich surface. The fatigue endurance limit at 50,000 cycles for the SPF/DB specimens was 50 percent lower than for the as-fabricated material. The substantial changes in tensile strength, fatigue life, and fracture-surface appearance due to the SPF-DB cycle are explained by a difference in the failure mechanisms due to SPF/DB-induced changes in the fiber/matrix interface strength.

Naik, R. A.↗

Airborne observations of the infrared emission bands

Earlier airborne studies of the infrared bands between 5 and 8 microns have now been extended to a sample of southern sources selected from the IRAS Low Resolution Spectra (LRS) atlas. The correlation between the strongest bands at 6.2 and 7.7 microns is now based on a total sample of 40 sources and is very strong. A new emission band at 5.2 microns, previously predicted for polycyclic aromatic hydrocarbons (PAHs), is recognized in 27 sources; it too correlates with the dominant 7.7 micron band, showing that the 5.2 micron feature also belongs to the generic spectrum of PAH features at 3.3, 5.6, 6.2, 6.2, 7.7, 8.7, 11.3, and 12.7 microns. Sufficient sources are had now to define the relative strengths of most of these bands in three separate nebular environments: planetaries, H II regions, and reflection nebulae. Significant variations are detected in the generic spectra of PAHs in these different environments which are echoed by variations in the exact wavelength of the strong 7.7 micron peak. The earlier suggestion that, in planetaries, the fraction of total emission observed by IRAS that is carried by the PAH emissions is correlated with nebular gas-phase C/O ratio is supported by the addition of newly-observed southern planetaries, including the unusually carbon-rich (WC10) nebular nuclei. These (WC10) nuclei also exhibit a strong plateau of emission linking the 6.2 and 7.7 micron features.

Cohen, M.↗

The origin of micrograins

Using ultraviolet and infrared techniques, researchers investigated the origins of the tiny (approx. 10A) grains whose presence in the interstellar medium (ISM) is inferred from near-infrared photometry (Sellgren, Werner, and Dinerstein 1983; Sellgren 1984). The authors consider two possibilities: (1) that the grains are formed by condensation in stellar atmospheres; or (2) that they are formed by fragmentation of larger grains in interstellar shocks. They searched for evidence of very small grains in circumstellar environments by analyzing ultraviolet extinction curves in binaries containing hot companions, and by searching for the 3.3-micron emission feature in similar systems. The ultraviolet extinction curve analysis could be applied only to oxygen-rich systems, where small carbonaceous grains would not be expected, so these results provide only indirect information. Researchers find a deficiency of grains smaller than 800A in oxygen-rich systems, consistent with theoretical models of grain condensation which suggest that grains grow to large sizes before injection into the interstellar medium. More direct information on carbonaceous micrograins was obtained from the search for the 3.3-micron feature in carbon-rich binaries with hot companions, whose ultraviolet flux should excite the tiny grains to emit in the infrared. No 3.3-micron feature was found, suggesting that the micrograins are absent in these systems. In addition to the negative search for micrograins in circumstellar environments, researchers have also studied the possible association of these grains with shocks in the diffuse interstellar medium. Using Infrared Astronomy Satellite (IRAS) colors as indicators of the presence or absence of the small grains (e.g., Ryter, Puget, and Perault 1987 and references cited therein), researchers systematically searched for them in regions (reflection nebulae) expected to have sufficient ultraviolet flux to make them glow in the infrared. They found that the distribution is not uniform. The researchers propose that production of micrograins by fragmentation of larger grains in shocks could explain this uneven distribution.

Snow, Theodore P., Jr.↗

Gas-phase formation of silicon carbides, oxides, and sulphides from atomic silicon ions

A systematic experimental study of the kinetics and mechanisms of the chemical reactions in the gas phase between ground-state Si(+)2p and a variety of astrophysical molecules. The aim of this study is to identify the reactions which trigger the formation of chemical bonds between silicon and carbon, oxygen and sulphur, and the chemical pathways which lead to further molecular growth. Such knowledge is valuable in the identification of new extraterrestrial silicon-bearing molecules and for an assessment of the gas-phase transition from atomic silicon to silicon carbide and silicate grain particles in carbon-rich and oxygen-rich astrophysical environments.

Bohme, Diethard K.↗

IR emission from circumstellar envelopes of C-rich stars

The reliability of a theoretical model that solves the radiative transfer equation in dust clouds surrounding a central star is checked. In particular, it is found that both classical scattering by dust and the back-heating effects are negligible in the radiative transfer when envelopes similar to IRC+10216 are taken into consideration. In addition, new fits of IRC+10216 spectra are presented which were obtained, when the source is in different luminosity phases, under the assumption that amorphous carbon grains are in the circumstellar envelope. The same model is currently used to simulate the emission from carbon-rich sources showing the silicon carbide feature at 11.3 microns.

Blanco, A.↗