In Situ Observations of Phase Changes in Shock Compressed Forsterite
Abstract not provided
SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Abstract not provided
A spectroscopic study of a pulsed plasma deflagration accelerator is carried out that confirms the existence of a strong compression in the emerging jet at the exit plane of the device. An imaging spectrometer is used to collect broadened Hα emission from a transaxial slice of the emerging jet at high spatial resolution, and the radial plasma density profile is computed from Voigt fits of the Abel inverted emissivity profiles. The plasma temperature, determined via Doppler broadening of impurity line emission, is compared against the temperature predictions of a radial magnetohydrodynamic equilibrium model applied to the measured density profiles. Empirical scaling laws developed for the plasma density, combined with the measured and predicted temperatures, indicate that a radially equilibrated Z-pinch is formed within the expelled plasma jet at the exit plane during the deflagration process.
We are planning a new beam diagnostic based on Compressed Ultrafast Photography (CUP)1.A foil inserted in the beam path is used to generate a continuous optical image of the beam, which is the same technique used on the existing DARHT II beam imaging diagnostic. This existing diagnostic compresses the beam image with anamorphic lenses into four views that are streaked simultaneously on two streak cameras. In our new beam diagnostic design the anamorphic lenses are replaced with regular lenses and the beam image is stamped with a pseudo-random mask pattern. The full image is imaged onto a streak camera with its entrance slit expanded. Modifying the CUP technique, which uses a single streaked image, our design splits the image into four rotated copies and puts all four images on two streak cameras. A data cube of multiple image frames is reconstructed from the streak camera data through the use of the TwiST algorithm2 combined with total variation denoising3. The additional rotated images improve spatial resolution and reduce noise and image artifacts compared to using a single streaked image. In reconstructions of simulated data, fine detail in the beam profile can be seen and there is a remarkable absence of image artifacts compared to the existing DARHT II beam imaging diagnostic. Performance was evaluated using a pseudo-MTF derived from a simulated wave pattern test object.
The present paper represents a small piece of an extensive experimental effort investigating the dual-fuel operation of a light-duty spark ignited engine. Natural gas (NG) was directly injected into the cylinder and gasoline was injected into the intake-port. Direct injection (DI) of NG was used in order to overcome the power density loss usually experienced with NG port-fuel injection (PFI) as it allows an injection after intake valve closing. Having two separate fuel systems allows for a continuum of in-cylinder blend levels from pure gasoline to pure NG operation. The huge benefit of gasoline is its availability and energy density, whereas NG allows efficient operation at high load due to improved combustion phasing enabled by its higher knock resistance. Furthermore, using NG allowed a reduction of carbon dioxide emissions across the entire engine map due to the higher hydrogen-to-carbon ratio. Exhaust gas recirculation (EGR) was used to (a) increase efficiency at low and part-load operation and (b) reduce the propensity of knock at higher compression ratios (CRs) thereby enabling blend levels with greater amount of gasoline across a wider operating range. Two integral engine parameters, CR and in cylinder turbulence levels, were varied in order to study their influence on efficiency, emissions, and performance over a specific speed and load range. Increasing the CR from 10.5 to 14.5 allowed an absolute increase in indicated thermal efficiency of snore than 3% for 7.5% NG (2.5% gasoline) operation at 8 bar net indicated mean effective pressure (IMEP) and 2500 rpm. However, as anticipated, the achievable peak load at CR 14.5 with 100% gasoline was greatly reduced due to its lower knock resistance. The in cylinder turbulence level was varied by means of tumble plates (TPs) as well as an insert for the NG injector that guides the injection "spray" to augment the tumble motion. The usage of TPs showed a significant increase in EGR dilution tolerance for pure gasoline operation, however, no such impact was found for blended operation of gasoline and NG.
We present that distinguishing whether a signal corresponds to a single source or a limited number of highly overlapping point spread functions (PSFs) is a ubiquitous problem across all imaging scales, whether detecting receptor-ligand interactions in cells or detecting binary stars. Super-resolution imaging based upon compressed sensing exploits the relative sparseness of the point sources to successfully resolve sources which may be separated by much less than the Rayleigh criterion. However, as a solution to an underdetermined system of linear equations, compressive sensing requires the imposition of constraints which may not always be valid. One typical constraint is that the PSF is known. However, the PSF of the actual optical system may reflect aberrations not present in the theoretical ideal optical system. Even when the optics are well characterized, the actual PSF may reflect factors such as non-uniform emission of the point source (e.g. fluorophore dipole emission). As such, the actual PSF may differ from the PSF used as a constraint. Similarly, multiple different regularization constraints have been suggested including the l 1 -norm, l 0 -norm, and generalized Gaussian Markov random fields (GGMRFs), each of which imposes a different constraint. Other important factors include the signal-to-noise ratio of the point sources and whether the point sources vary in intensity. In this work, we explore how these factors influence super-resolution image recovery robustness, determining the sensitivity and specificity. In conclusion, we determine an approach that is more robust to the types of PSF errors present in actual optical systems.
High-precision studies of the volume and the electrical resistivity of g-As{sub 2}Te{sub 3} glasses at a high hydrostatic pressure up to 8.5 GPa at room temperature are performed. The glasses exhibit elastic behavior in compression only at a pressure up to 1 GPa, and a diffuse structural transformation and inelastic density relaxation (logarithmic in time) begin at higher pressures. When the pressure increases further, the relaxation rate passes through a sharp maximum at 2.5 GPa, which is accompanied by softening the relaxing bulk modulus, and then decreases, being noticeable up to the maximum pressure. When pressure is relieved, an unusual inflection point is observed in the baric dependence of the bulk modulus near 4 GPa. The polyamorphic transformation is only partly reversible and the residual densification after pressure release is 2%. In compression, the electrical resistivity of the g-As{sub 2}Te{sub 3} glasses decreases exponentially with increasing pressure (at a pressure up to 2 GPa); then, it decreases faster by almost three orders of magnitude in the pressure range 2–3.5 GPa. At a pressure of 5 GPa, the electrical resistivity reaches 10{sup –3} Ω cm, which is characteristic of a metallic state; this resistivity continues to decrease with increasing pressure and reaches 1.7 × 10{sup –4} Ω cm at 8.1 GPa. The reverse metal–semiconductor transition occurs at a pressure of 3 GPa when pressure is relieved. When the pressure is decreased to atmospheric pressure, the electrical resistivity of the glasses is below the initial pressure by two–three orders of magnitude. Under normal conditions, both the volume and the electrical resistivity relax to quasi-equilibrium values in several months. Comparative structural and Raman spectroscopy investigations demonstrate that the glasses subjected to high pressure have the maximum chemical order. The glasses with a higher order have a lower electrical resistivity. The polyamorphism in the As{sub 2}Te{sub 3} glasses is caused by both structural changes and chemical ordering. The g-As{sub 2}Te{sub 3} compound is the first example of glasses, where the reversible metallization under pressure has been studied under hydrostatic conditions.
This paper highlights the importance of improving compressed air systems, outlines the tool’s development and features, and underscores its value as a nonbiased resource for system evaluation and optimization. Additionally, the paper presents a case study based on a food manufacturing facility to demonstrate the practical application of the tool. Furthermore, the paper discusses potential future opportunities for enhancing the CA Scoping Tool.
Explore the source record for details and available documents.
As theoretically hypothesized for several decades in group IV transition metals, we have discovered a dynamically stabilized body-centered cubic (bcc) intermediate state in Zr under uniaxial loading at sub-nanosecond timescales. Under ultrafast shock wave compression, rather than the transformation from α-Zr to the more disordered hex-3 equilibrium ω-Zr phase, in its place we find the formation of a previously unobserved nonequilibrium bcc metastable intermediate. We probe the compression-induced phase transition pathway in zirconium using time-resolved sub-picosecond x-ray diffraction analysis at the Linac Coherent Light Source. We also present molecular dynamics simulations using a potential derived from first-principles methods which independently predict this intermediate phase under ultrafast shock conditions. In contrast with experiments on longer timescale (> 10 ns) where the phase diagram alone is an adequate predictor of the crystalline structure of a material, our recent study highlights the importance of metastability and time dependence in the kinetics of phase transformations.
Not provided.
Water, an important constituent in bone, resides in different compartments in bone matrix and may impose significant effects on its bulk mechanical properties. However, a clear understanding of the mechanistic role of water in toughening bone is yet to emerge. To address this issue, this study used a progressive loading protocol, coupled with measurements of in situ mineral and collagen fibril deformations using synchrotron X-ray diffraction techniques. Using this unique approach, the contribution of water to the ultrastructural behavior of bone was examined by testing bone specimens in different loading modes (tension and compression) and hydration states (wet and dehydrated). The results indicated that the effect of water on the mechanical behavior of mineral and collagen phases at the ultrastructural level was loading mode dependent and correlated with the bulk behavior of bone. Tensile loading elicited a transitional drop followed by an increase in load bearing by the mineral phase at the ultrastructural level, which was correlated with a strain hardening behavior of bone at the bulk level. Compression loading caused a continuous loss of load bearing by the mineral phase, which was reflected at the bulk level as a strain softening behavior. In addition, viscous strain relaxation and pre-strain reduction were observed in the mineral phase in the presence of water. Taken together, the results of this study suggest that water dictates the bulk behavior of bone by altering the interaction between mineral crystals and their surrounding matrix.
The Neutralized Drift Compression Experiment-II (NDCX-II) is an induction linac that generates intense pulses of 1.2 MeV helium ions for heating matter to extreme conditions. Here, we present recent results on optimizing beam transport. The NDCX-II beamline includes a 1-m-long drift section downstream of the last transport solenoid, which is filled with charge-neutralizing plasma that enables rapid longitudinal compression of an intense ion beam against space-charge forces. The transport section on NDCX-II consists of 28 solenoids. Finding optimal field settings for a group of solenoids requires knowledge of the envelope parameters of the beam. Imaging the beam on the scintillator gives the radius of the beam, but the envelope angle is not measured directly. We demonstrate how the parameters of the beam envelope (radius, envelop angle, and emittance) can be reconstructed from a series of images taken by varying the B-field strengths of a solenoid upstream of the scintillator. We use this technique to evaluate emittance at several points in the NDCX-II beamline and for optimizing the trajectory of the beam at the entry of the plasma-filled drift section.
We report the highest compression reached in laboratory plasmas using eight laser beams, E laser ≈ 12 kJ, $\tau$ laser = 2 ns in third harmonic on a CD2 target at the ShenGuang-II Upgrade (SGII-Up) facility in Shanghai, China. We estimate the deuterium density ρ D kg/cm 3 , and the average kinetic energy of the plasma ions less than 1 keV. The highest reached areal density Λρ D = 4.8 ± 1.5 g/cm 2 was obtained from the measured ratio of the sequential ternary fusion reactions (dd→t+p and t+d→α+n) and the two body reaction fusions (dd→ 3 He + n). At such high densities, sequential ternary and also quaternary nuclear reactions become important as well (i.e. n(14.1 MeV) + 12 C → n' + 12 C* etc.) resulting in a shift of the neutron (and proton) kinetic energies from their birth values. The Down Scatter Ratio (DSR-quaternary nuclear reactions) method, i.e. the ratio of the 10-12 MeV neutrons divided by the total number of 14.1 MeV neutrons produced, confirms the high densities reported above. The estimated lifetime of the highly compressed plasma is 52 ± 9 ps, much smaller than the lasers pulse duration.
A series of multicyclic hydrocarbons were synthesized in high yield and under mild conditions from 2,5-hexanedione, cyclohexanone and cyclopentanone, on a scale of 200 g.
Two Hubble Space Telescope narrow-band Hα images separated in time by 1.03 years are used for a proper motion measurement of the forward shock of the LMC supernova remnant 0509–67.5, the only spectroscopically confirmed LMC remnant of Ia origin. We measure a global shock speed of 6500 ± 200 km s{sup −1} and constrain the pre-shock neutral hydrogen density to be 0.084 ± 0.003 cm{sup −3}, for a typical mean number of Hα photons produced per neutral hydrogen atom entering the forward shock. Previously published broad Hα line widths from two locations on the rim and our corresponding shock speed measurements are consistent with Balmer shock models that do not include effects of cosmic-ray acceleration. For the northeastern rim location, we limit the post-shock electron temperature to 10% of the proton temperature by also using the broad-to-narrow flux ratio. Hydrodynamic simulations for different initial ejecta density profiles constrain the age and ambient medium density; for an exponential ejecta profile and initial explosion energy of 1.4 × 10{sup 51} erg, the remnant’s age is 310{sub −30}{sup +40} years. For all evolutionary models explored, the expansion parameter falls in the range of 0.41–0.73, indicating that the remnant is still firmly in the ejecta-dominated phase of its evolution. Our measured neutral hydrogen density of the ambient medium, combined with the shocked density obtained in Williams et al., disfavors forward shock compression factors greater than ∼7.
We have commenced experiments with intense short pulses of ion beams on the Neutralized Drift Compression Experiment (NDCX-II) at Lawrence Berkeley National Laboratory, with 1-mm beam spot size within 2.5 ns full-width at half maximum. The ion kinetic energy is 1.2 MeV. To enable the short pulse duration and mm-scale focal spot radius, the beam is neutralized in a 1.5-meter-long drift compression section following the last accelerator cell. A short-focal-length solenoid focuses the beam in the presence of the volumetric plasma that is near the target. In the accelerator, the line-charge density increases due to the velocity ramp imparted on the beam bunch. The scientific topics to be explored are warm dense matter, the dynamics of radiation damage in materials, and intense beam and beam-plasma physics including select topics of relevance to the development of heavy-ion drivers for inertial fusion energy. Below the transition to melting, the short beam pulses offer an opportunity to study the multi-scale dynamics of radiation-induced damage in materials with pump-probe experiments, and to stabilize novel metastable phases of materials when short-pulse heating is followed by rapid quenching. First experiments used a lithium ion source; a new plasma-based helium ion source shows much greater charge delivered to the target.
Here, the shock Hugoniot for full-density and porous CeO 2 was investigated in the liquid regime using ab initio molecular dynamics (AIMD) simulations with Erpenbeck's approach based on the Rankine-Hugoniot jump conditions. The phase space was sampled by carrying out NVT simulations for isotherms between 6000 and 100 000 K and densities ranging from ρ = 2.5 to 20 g/cm 3 . The impact of on-site Coulomb interaction corrections +U on the equation of state (EOS) obtained from AIMD simulations was assessed by direct comparison with results from standard density functional theory simulations. Classical molecular dynamics (CMD) simulations were also performed to model atomic-scale shock compression of larger porous CeO 2 models. Results from AIMD and CMD compression simulations compare favorably with Z-machine shock data to 525 GPa and gas-gun data to 109 GPa for porous CeO 2 samples. Using results from AIMD simulations, an accurate liquid-regime Mie-Grüneisen EOS was built for CeO 2 . In addition, a revised multiphase SESAME-type EOS was constrained using AIMD results and experimental data generated in this work. This study demonstrates the necessity of acquiring data in the porous regime to increase the reliability of existing analytical EOS models.