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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Impact of DORISx Post Seismic Deformation and Seasonal Corrections on the DPOD2020 Solution

As one of the tracking systems used for the altimeter missions (such as TOPEX/Poseidon, Envisat, Jason-1/-2/-3, CryoSat-2, Saral/AltiKa, Sentinel-3A/-3B, HY-2A/C/D, Jason-CS/Sentinel-6A, SWOT), the position of the DORIS tracking stations provides a fundamental reference for the estimation of the precise orbits and so, by extension is fundamental for the quality of the altimeter data analysis and derived products. Due to the time evolution of the DORIS ground network, stations included in ITRF2020 may have been decommissioned and stations that were added to the tracking network after 2021.0 are, by definition, not part of ITRF2020. Therefore, to satisfy operational requirements for precise orbit determination and routine delivery of geodetic products, the International DORIS Service maintains the DORIS terrestrial reference frame for Precise Orbit Determination (DPOD) solutions. Since 2016, the DPOD products are computed by the IDS Combination Center (CC) as a DORIS cumulative position and linear velocity solution aligned to the latest available ITRF and using the latest IDS weekly combined series. Mid-2023, the IDS CC started the computation of the second version of the DPOD2020 based on the IDS 20 weekly solutions from 1993.0 to 2023.0. With that new solution, the IDS CC will include Post Seismic Deformation (PSD) corrections for some DORIS sites such as Socorro Island. These DPOD PSD corrections are determined from the analysis of DORIS coordinate time series only. The second version will also include optional annual and semi-annual station corrections. The presentation will describe the analysis used for extracting the PSD and seasonal DORIS station corrections, compare such corrections to those derived for ITRF2020, and evaluate the impact these new corrections have on station positioning and satellite POD.

Guilhem Moreaux↗

Leveraging ­ CPF Spectral Information for Effective Angular Corrections in Sensor Inter-calibration Studies

The Climate Absolute Radiance and Refractivity Observatory Pathfinder (CPF) mission will provide a high-accuracy (0.3% radiometric uncertainty at k=1) SI-traceable on-orbit calibration reference for sensor intercalibration in reflective solar spectral region. CPF inter-calibration algorithms have been developed to address various sampling differences between CPF and target sensors, particularly in spectral, angular, spatial and temporal domains. CPF provides unique hyper-spectral measurements that allow the utilization of rich spectral information for critical inter-calibration procedures including angular correction and spectral-gap filling. The angular correction scheme of CPF mission has been constructed based on the spectral correlation relationship between CPF observed spectra and the spectra to be measured at the viewing/sun geometry angles of target sensors. The angular correction relationship is both angular and scene dependent. The scene variability issue can impose undesired uncertainties that complicates the correction for those errors. We have demonstrated that hyper-spectral radiance information can be well utilized to identify different scene types associated with CPF observations. Using spectral radiances-based scene clustering analysis can greatly reduce the uncertainty associated with the angular correction algorithm. Additionally, a reliable quality control scheme has been established, utilizing spectral similarity and regression-prediction error analyses, to ensure the successful and efficient implementation of the angular correction method.

Wan Wu↗

Error and Correction Analysis for the FFA@CEBAF Energy Upgrade

An energy upgrade design for the Continuous Electron Beam Accelerator Facility (CEBAF) is under development, using fixed field alternating gradient (FFA) return arcs to recirculate electron beam up to an additional five times through the accelerating structures at CEBAF. A necessary component of any large accelerator is a beam steering and optical correction system. Small environmental changes and system errors can lower beam quality or even shut down the machine; and in pursuit of the scientific mission of JLab, high quality electron beams must be delivered to the experimental halls on a predictable schedule. Correction in the novel FFA arcs of the current upgrade design is complicated by several factors. These complexities inform the choice of correction algorithm structure and parameter values. A baseline algorithm in addition to diagnostic and correction hardware configuration is presented. The effect of this correction protocol is shown with respect to estimated errors, and several possible extensions of the algorithm are discussed. This work presents an important proof of concept for the FFA@CEBAF design effort, and provides a functional correction strategy which may be simply adjusted and optimized for future design changes.

Coxe, Alex [Old Dominion Univ., Norfolk, VA (Unite↗

Demystifying Piecewise and Localized Scatter Correction Methods

Multiplicative scatter is a common source of noise in near-infrared spectroscopy and other related instrumental techniques. A wide variety of methods are commonly used for the correction of multiplicative scatter. However, the majority of such methods assume that the parameters that describe the scatter are constant throughout the measured spectrum, which is often not the case. This work investigates a family of methods that perform scatter correction using local regions of neighboring wavelengths in order to better account for wavelength-dependent scattering. The methods in question are piecewise standard normal variate, localized standard normal variate, piecewise multiplicative scatter correction, and localized multiplicative scatter correction. This work describes the theoretical and algorithmic foundations of the family of local region-based scatter correction methods and compares their application and optimization at a qualitative and quantitative level using several datasets.

NIR spectroscopy↗

Enhancing quantum memory lifetime with measurement-free local error correction and reinforcement learning

Reliable quantum computation requires systematic identification and correction of errors that occur and accumulate in quantum hardware. To diagnose and correct such errors, standard quantum error-correcting protocols utilize global error information across the system obtained by mid-circuit readout of ancillary qubits. We investigate circuit-level error-correcting protocols that are measurement-free and based on local error information. Such a local error correction (LEC) circuit consists of faulty multi-qubit gates to perform both syndrome extraction and ancilla-controlled error removal. We develop and implement a reinforcement learning framework that takes a fixed set of faulty gates as inputs and outputs an optimized LEC circuit. To evaluate this approach, we quantitatively characterize an extension of logical qubit lifetime by a noisy LEC circuit. For the two-dimensional (2D) classical Ising model and four-dimensional toric code, our optimized LEC circuit performs better at extending a memory lifetime compared with a conventional LEC circuit based on Toom's rule in a subthreshold gate error regime. We further show that such circuits can be used to reduce the rate of mid-circuit readouts to preserve a 2D toric code memory. Lastly, we discuss the application of the LEC protocol on dissipative preparation of quantum states with topological phases.

74 ATOMIC AND MOLECULAR PHYSICS↗

Continental-scale Validation of MODIS-based and LEDAPS Landsat ETM+ Atmospheric Correction Methods

The potential of Landsat data processing to provide systematic continental scale products has been demonstrated by several projects including the NASA Web-enabled Landsat Data (WELD) project. The recent free availability of Landsat data increases the need for robust and efficient atmospheric correction algorithms applicable to large volume Landsat data sets. This paper compares the accuracy of two Landsat atmospheric correction methods: a MODIS-based method and the Landsat Ecosystem Disturbance Adaptive Processing System (LEDAPS) method. Both methods are based on the 6SV radiative transfer code but have different atmospheric characterization approaches. The MODIS-based method uses the MODIS Terra derived dynamic aerosol type, aerosol optical thickness, and water vapor to atmospherically correct ETM+ acquisitions in each coincident orbit. The LEDAPS method uses aerosol characterizations derived independently from each Landsat acquisition and assumes a fixed continental aerosol type and uses ancillary water vapor. Validation results are presented comparing ETM+ atmospherically corrected data generated using these two methods with AERONET corrected ETM+ data for 95 10 km×10 km 30 m subsets, a total of nearly 8 million 30 m pixels, located across the conterminous United States. The results indicate that the MODIS-based method has better accuracy than the LEDAPS method for the ETM+ red and longer wavelength bands.

Landsat↗

Statistical Downscaling and Bias Correction of Climate Model Outputs for Climate Change Impact Assessment in the U.S. Northeast

Statistical downscaling can be used to efficiently downscale a large number of General Circulation Model (GCM) outputs to a fine temporal and spatial scale. To facilitate regional impact assessments, this study statistically downscales (to 1∕8deg spatial resolution) and corrects the bias of daily maximum and minimum temperature and daily precipitation data from six GCMs and four Regional Climate Models (RCMs) for the northeast United States (US) using the Statistical Downscaling and Bias Correction (SDBC) approach. Based on these downscaled data from multiple models, five extreme indices were analyzed for the future climate to quantify future changes of climate extremes. For a subset of models and indices, results based on raw and bias corrected model outputs for the present-day climate were compared with observations, which demonstrated that bias correction is important not only for GCM outputs, but also for RCM outputs. For future climate, bias correction led to a higher level of agreements among the models in predicting the magnitude and capturing the spatial pattern of the extreme climate indices. We found that the incorporation of dynamical downscaling as an intermediate step does not lead to considerable differences in the results of statistical downscaling for the study domain.

extreme climate index↗

An Accurate Method for Correcting Spectral Convolution Errors in Intercalibration of Broadband and Hyperspectral Sensors

The intercalibration between a broadband and a hyperspectral satellite Earth observation system requires the convolution of the hyperspectral data with the spectral response functions (SRFs) of the corresponding broadband channels. There are two potential issues associated with the convolution procedure. First, the finite resolution of a hyperspectral spectrum, that is, the deviation from the highly accurate line-by-line monochromatic radiances, will contribute to convolution errors. The magnitude of the errors depends on the spectral resolution and the SRF shape of the hyperspectral instrument. This type of the convolution error has not been well recognized, and there is a lack of corresponding discussion in most published papers. Although it is small as compared with the instrument accuracy of existing hyperspectral sounders, the error is deemed to be signicant when it is compared with the stringent calibration requirement imposed by future climate missions like the Climate Absolute Radiance and Refractivity Observatory (CLARREO). Second, some broadband channels are insufficiently covered by the hyperspectral data, causing spectral gaps that lead to convolution errors. Although several methods have been developed to fill the spectral gaps and hence compensate for the second type of convolution error, the correction accuracy may still need improvement especially when a large spectral gap needs to be lled. This paper presents a methodology to accurately quantify and compensate for both types of convolution errors. This methodology utilizes the available hyperspectral information to correct the scene-dependent convolution errors due to either the limited spectral resolution or spectral gaps. We use simulations to characterize the intercalibration errors between the Moderate resolution Imaging Spectroradiometer (MODIS) and current operational infrared sounders. We demonstrate that convolution errors can be effectively removed to meet the highly accurate intersatellite calibration requirement proposed by the Climate Absolute Radiance and Refractivity Observatory. Our methodology is also validated using real satellite data for the intercalibration between Aqua MODIS and Aqua Atmospheric Infrared Sounders (AIRS). Our study demonstrates that the accurate characterization and correction for the convolution errors greatly reduces the scene-dependent and spectrally dependent errors, being critical to the consistency check between Infrared Atmospheric Sounding Interferometer (IASI) and AIRS using the double-difference method. The convolution correction also facilitates the evaluation for other intercalibration errors (e.g., the drift of MODIS SRFs). Our derived SRF shift values from MODIS-AIRS (after convolution error corrections) and from MODIS-IASI intercalibration are consistent with each other. We further extend the methodology to study the calibration of a broadband channel which is either completely or largely uncovered bya hyperspectral measurement.The large spectral gap-filling methodology is validated by demonstrating the accurate prediction of the MODIS radiance of band 29 using the Cross-track Infrared Sounder spectra, with the real IASI spectral data being used as the reference.

Correction Method↗

Next-to-next-to-leading power corrections to unpolarized Semi-Inclusive Deep Inelastic Scattering

Semi-Inclusive Deep Inelastic Scattering (SIDIS) is a key tool for exploring the three-dimensional structure of the nucleon through Transverse Momentum Dependent parton distributions and fragmentation functions. While leading-power contributions to the SIDIS cross-section are well established, next-to-leading power (NLP) corrections of order 1/Q and next-to-next-to-leading power (NNLP) corrections of order 1/Q 2 to the hadronic tensor have only recently begun to be systematically investigated. These corrections are essential for reliable phenomenology and interpretation of modern high-precision data. In recent papers by one of the authors, NNLP corrections to the Drell-Yan process were derived using the rapidity factorization formalism. In the present work, we extend this approach to SIDIS and obtain analytic expressions for the unpolarized structure functions. We derive NNLP corrections that include convolutions of unpolarized distributions, f 1 , with unpolarized fragmentation functions, D 1 , and Boer-Mulders functions, ${h}_1^{\perp }$, with Collins fragmentation functions, ${H}_1^{\perp }$. We compare our results with previous formulations, provide numerical studies, confront our predictions with HERMES and COMPASS measurements, and present predictions for future experiments at Jefferson Lab and the Electron-Ion Collider.

deep inelastic scattering↗

Using Density-Corrected DFT to Understand Density-Driven and Functional-Dependent Errors in Ab Initio Simulations of the Hydrated Electron

The hydrated electron, an excess electron in liquid water, plays a crucial role in a plethora of chemical processes, motivating extensive research efforts to characterize its structure, dynamics, and reactivity in solution. Recent theoretical approaches to understanding this intriguing object have involved ab initio simulations based on density functional theory (DFT). Although DFT allows for the study of hydrated electron reactivity and quantum mechanical behavior, it is well-known that anionic systems can suffer from significant density-driven errors (DDEs). Density-corrected DFT (DC-DFT) provides a framework to mitigate such errors; the method reduces DDEs by replacing the self-consistent (SC) density associated with a given density functional with the Hartree–Fock (HF) density. Since HF densities tend to be more localized than DFT SC densities, the DC-DFT scheme significantly improves errors in calculations where the SC density is spuriously delocalized. Here, we investigate how the use of density correction affects the calculated properties of the DFT-simulated (PBEh) hydrated electron, a particularly challenging diffuse anionic system to simulate. First, we analyze charge delocalization in a system consisting of a model octahedral hydrated electron water cluster (the so-called Kevan structure) along with a spatially separated sulfur atom. We show that the use of density correction indeed reduces DDEs in comparison to a standard DFT global hybrid functional. We then propagate molecular dynamics trajectories of the hydrated electron using DC-DFT, where we find that DC further localizes electron density in the cavity region, a signature of reduced charge delocalization. Unfortunately, the decreased radius of gyration of the spin density and corresponding tightening of the local solvation structure from density correction causes predicted observables to deviate further from experimental measurements than when density correction is not employed. Here, we argue that DC’s worse agreement with experiment results from the removal of a fortuitous cancellation of errors that is intrinsic to the PBEh functional. This indicates that the difficulties with DFT to simulate hydrated electrons are primarily due to the inherent approximations in DFT rather than to density-driven errors.

Density functional theory↗

AutoLabs: cognitive multi-agent systems with self-correction for autonomous chemical experimentation

The automation of chemical research through self-driving laboratories (SDLs) promises to accelerate scientific discovery, yet the reliability and granular performance of the underlying AI agents remain critical, under-examined challenges. In this work, we introduce AutoLabs, a self-correcting, multi-agent architecture designed to autonomously translate natural-language instructions into executable protocols for a high-throughput liquid handler. The system engages users in dialogue, decomposes experimental goals into discrete tasks for specialized agents, performs tool-assisted stoichiometric calculations, and iteratively self-corrects its output before generating a hardware-ready file. We present a comprehensive evaluation framework featuring five benchmark experiments of increasing complexity, from simple sample preparation to multi-plate timed syntheses. Through a systematic ablation study of 20 agent configurations, we assess the impact of reasoning capacity, architectural design (single- vs. multi-agent), tool use, and self-correction mechanisms. Our results demonstrate that agent reasoning capacity is the most critical factor for success, reducing quantitative errors in chemical amounts (nRMSE) by over 85% in complex tasks. When combined with a multi-agent architecture and iterative self-correction, AutoLabs approaches expert-authored reference procedures on the benchmark (F1-score > 0.89) on challenging multi-plate syntheses. These findings establish a clear blueprint for developing robust and trustworthy AI partners for autonomous laboratories, highlighting the synergistic effects of modular design, advanced reasoning, and self-correction to ensure both performance and reliability in high-stakes scientific applications. Code: https://github.com/pnnl/autolabs

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Toward the “platinum standard” of quantum chemistry on quantum computers: Perturbative quadruple corrections in unitary coupled cluster theory

We propose a non-iterative, post-hoc correction to the unitary coupled cluster theory with the single, double, and triple excitations (UCCSDT) Ansatz, which considers the leading-order effects of neglected quadruple excitations. We present two ways to derive this correction, henceforth referred to as [Q-6], which leads to an improvement in the correlation energy shown to be truncated to sixth-order in many-body perturbation theory. Furthermore, a comparison between the UCC-based [Q-6] correction proposed in this work and analogous, “platinum standard” quadruple corrections proposed in conventional coupled cluster theory recognizes that [Q-6] is distinct from prior corrections since it is constructed entirely from internally connected components. Although trotterized (t) and full operator variants of UCCSDT exhibit errors in scans of small molecule potential energy surfaces that routinely exceed 1.6 mH, we find that t/UCCSDT[Q-6] is, nevertheless, able to achieve chemical accuracy as measured by the mean unsigned error.

Correlation energy↗

Analytical noise bias correction for precise weak lensing shear inference

Noise bias is a significant source of systematic error in weak gravitational lensing measurements that must be corrected to satisfy the stringent standards of modern imaging surveys in the era of precision cosmology. This paper reviews the analytical noise bias correction method and provides analytical derivations demonstrating that we can recover shear to its second order using the ‘renoising’ noise bias correction approach introduced by METACALIBRATION. We implement this analytical noise bias correction within the AnaCal shear estimation framework and propose several enhancements to the noise bias correction algorithm. We evaluate the improved AnaCal using simulations designed to replicate Rubin Legacy Survey of Space and Time (LSST) imaging data. These simulations feature semi-realistic galaxies and stars, complete with representative distributions of magnitudes and Galactic spatial density. We conduct tests under various observational challenges, including cosmic rays, defective CCD columns, bright star saturation, bleed trails, and spatially variable point spread functions. Our results indicate a multiplicative bias in weak lensing shear recovery of less than a few tenths of a per cent, meeting LSST Dark Energy Science Collaboration requirements without requiring calibration from external image simulations. Additionally, our algorithm achieves rapid processing, handling one galaxy in less than a millisecond.

79 ASTRONOMY AND ASTROPHYSICS↗

Numerical calculation of Coulomb corrections in forward elastic 𝑝↑⁢𝑝 and 𝑝↑⁢𝐴 scattering

The analysis of RHIC hydrogen gas jet target polarimeter measurements of transverse analyzing powers 𝐴 N ⁡(𝑡) in proton-nucleus scattering requires accurate Coulomb corrections to both spin-flip and nonflip amplitudes. These corrections must cover a wide range of nuclear charges 𝑍 and form factor slopes, with flexibility to vary form factors during data fitting. To avoid technically challenging calculations involving a small but finite fictitious photon mass, the Coulomb correction to the nonflip electromagnetic amplitude with an exponential form factor was related to the corresponding correction for the spin-flip amplitude. This approach allows soft photon contributions to all amplitudes, including those with nonexponential form factors, to be calculated in the massless photon limit using only analytical expressions and numerically stable integrals with nonsingular integrands and finite integration limits. In addition, an absorptive correction to the spin-flip electromagnetic amplitude, which plays a critical role in spin effects in forward polarized proton-nucleus scattering, was accurately evaluated.

43 PARTICLE ACCELERATORS↗

Z α 2 correction to superallowed beta decays in effective field theory and implications for | V u d |

Superallowed ( 0 + → 0 + ) beta decays currently provide the most precise extraction of quark mixing in the Standard Model. Their interpretation as a measurement of | V u d | relies on a reliable first-principles computation of QED radiative corrections expressed as a series in Z α and α . In this work, we provide the first model-independent result for two-loop, O ( Z α 2 ) , long-distance radiative corrections where the nuclei are treated as heavy pointlike particles. We use renormalization group analysis to obtain new results at O ( Z α 3 ) for the coefficient of double logarithms in the ratio of the maximal beta energy to the inverse nuclear size, E m / R - 1 . We use the Kinoshita-Lee-Nauenberg theorem to obtain new results at O ( Z 2 α 3 ) for the coefficient of logarithms in the ratio of maximal beta energy to the electron mass, log ( 2 E m / m ) . We identify a structure-dependent, and, therefore, short-distance, contribution to the traditional Z α 2 correction that should be revisited. We provide the first comprehensive update to the long-distance corrections in almost 40 years and comment on the impact of our findings for extractions of | V u d | . We find that shifts in the long-distance corrections are 2.5 × larger than past estimates of their uncertainty, 1.5 × larger than the statistical uncertainty from the combined fit of superallowed decays, and about 1 / 2 the size of estimated systematic error, which stems dominantly from nuclear structure effects.

Cao, Zehua [Kentucky U.] (ORCID:0009000354256423)↗

Renormalons and power corrections in pseudo- and quasi-GPDs

High-order behavior of the perturbative expansion for short-distance observables in QCD is intimately related to the contributions of small momenta in the corresponding Feynman diagrams and this correspondence provides one with a useful tool to investigate power-suppressed nonperturbative corrections. We use this technique to study the structure of power corrections to parton quasi- and pseudo-GPDs which are used in lattice calculations of generalized parton distributions. As the main result, we predict the functional dependence of the leading power corrections to quasi(pseudo)-GPDs on x variable for nonzero skewedness parameter ξ . The kinematic point x = ± ξ turns out to be special. We find that the nonperturbative corrections to quasi-GPDs at this point are suppressed by the first power of the hard scale only. These contributions come from soft momenta and have nothing to do with the known UV renormalon in the Wilson line. We also show that power corrections can be strongly suppressed by the normalization procedure. Published by the American Physical Society 2024

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Quasiprobabilistic Readout Correction of Midcircuit Measurements for Adaptive Feedback via Measurement Randomized Compiling

Quantum measurements are a fundamental component of quantum computing. However, on present-day quantum computers, measurements can be more error prone than quantum gates and are susceptible to nonunital errors as well as nonlocal correlations due to measurement crosstalk. While readout errors can be mitigated in postprocessing, this is inefficient in the number of qubits due to a combinatorially large number of possible states that need to be characterized. In this work, we show that measurement errors can be tailored into a simple stochastic error model using randomized compiling, enabling the efficient mitigation of readout errors via quasiprobability distributions reconstructed from the measurement of a single preparation state in an exponentially large confusion matrix. We demonstrate the scalability and power of this approach by correcting readout errors without matrix inversion on a large number of different preparation states applied to a register of eight superconducting transmon qubits. Moreover, we show that this method can be extended to midcircuit measurements used for active feedback via quasiprobabilistic error cancellation, and we demonstrate the correction of measurement errors on an ancilla qubit used to detect and actively correct bit-flip errors on an entangled memory qubit. Our approach enables the correction of readout errors on large numbers of qubits and offers a strategy for correcting readout errors in adaptive circuits in which the results of midcircuit measurements are used to perform conditional operations on nonlocal qubits in real time.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Deep Learning-based Non-Stationary Bias Correction (NSBC)

This work develops the NSBC (non-stationary bias correction) methodology to correct temperature projection bias from E3SM. The NSBC deep learning framework consists of a three-part architecture: an auto-encoder for compressing the spatial information, an LSTM for predicting annual temperature mean, and a U-Net for capturing the residual bias in temperature. The non-stationary bias correction (NSBC) framework can correct the non-stationarity of the biases of the climate models, which significantly improves the accuracy of future temperature prediction and improves the overestimation of extreme high temperatures that many existing bias correction methods suffer from. Getting started 1. Obtain the historical climate simulation and observation data. The E3SM simulation data are available through https://aims2.llnl.gov/search/cmip6/. The pseudo observations, the Geophysical Fluid Dynamics Laboratory (GFDL)-ESM4 model (Krasting et al., 2018) are available through https://aims2.llnl.gov/search/cmip6/. The spatial resolution of E3SM and pseudo observation datasets are both regridded to a common 1° resolution grid using conservative interpolation. The regridded E3SM and pseudo observation with 1° resolution can be found throught ./data/. 2. Train the Auto-encoder model. Python 0-autoencoder.py 3. Train the LSTM Python 1-LSTM.py 4. Generate the annual mean temperature based on trained LSTM Python 2-generate_annual_mean_LSTM.py 5. Train the U-Net. Python 3-unet.py 6. Evaluation and compared with the baseline Python 4_evaluation.py Is there a deadline approaching that requires the release of yo

Lucas, Donald↗