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DOE OSTI2023

Development of an Advanced Hydrogen Energy Storage System using Aerogel in a Cryogenic Flux Capacitor

The Cryogenic Flux Capacitor (CFC) is a cold, dense fluid storage core with integrated design features that afford the designer flexibility and provide new possibilities for the storage and discharge of energy. The stored energy, in this case, is represented by hydrogen physically bonded within the nanoscale pores within the aerogel composite blanket material, and the process of bonding or debonding is governed by the principles of physical adsorption (physisorption) and thermodynamics. The large surface area afforded by the nanoporous aerogel (~1,000 m 2 /g) allows for storage densities close to, or in some cases exceeding, that of normal boiling point liquids. Its performance easily exceeds what can be achieved via ambient temperature and high-pressure gas storage for an equivalent volume. CFC storage is predicted to be easily scalable, constructed from readily available commercial materials, and lends itself to a range of pressure applications. The project team designed and manufactured the CFC, integrating it into a set of temperature-controlled flow loops. The CFC test setup was validated against existing data from previous NASA work. Tests used bottled hydrogen gas for test validation. A cryogenic fluid, nitrogen, flowed through a metered control system. Hydrogen temperature, pressure, and flow rates, as well as the temperature control targets, provided all necessary control targets. The team analyzed the recorded data and updated the Technology Maturation Plan based on the results of the test, making recommendations for a follow-up test, scale-up, and maturation pathway. For the engineering development and maturation of CFC hydrogen storage technology, a Techno-Economic Assessment (TEA) and Commercialization Plan for the integration of this technology with various power generation assets were produced. A companion analytical model was developed, experimentally validated, compared against performance metric, and used to tune the model and scale up the technology.

08 HYDROGEN↗

NASA NTRS1991

CFM technology needs for future space transportation systems

Several technological capabilities must be developed to realize the vision of the Space Exploration Initiative (SEI). Cryogenic fluid management (CFM) is one technology area common to virtually every space transportation propulsion concept envisioned. The physics of storage, supply, transfer, and handling of subcritical cryogenic fluids in the reduced gravity environment of space present fundamental challenges. The CFM state of the art relative to future mission requirements is reviewed and associated technology challenges are outlined.

Hastings, L. J.↗

NASA NTRSDate not supplied

Validation of Accurate Cryogenic Fluid Vapor-Liquid Boundary Conditions Via Molecular Simulations

Vapor-liquid interfaces drive many important phenomena in cryogenic fluid management, including heat transfer, evaporation, and capillary flow. Design of cryogenic fluid systems, such as propellant storage, requires accurate predictions of fluid behavior, including evaporation rates. Many models have been proposed for heat and mass transfer at vapor liquid interfaces, but the accuracy of these models in the context of cryogenic fluids has not been performed. We use molecular dynamics simulations, which allow for nanometer scale resolution of fluid phenomena, to evaluate the accuracy of a variety of vapor-liquid boundary conditions at evaporating and condensing interfaces. We find that an anisotropic temperature distribution is a critical ingredient for accurate prediction of intensive evaporation and condensation.

Daniel Vigil↗

NASA NTRSDate not supplied

Development of a Test Article to Demonstrate the Long Duration Storage of Liquid Hydrogen via a Two-Stage Active Cooling Approach

A NASA team is developing a test article for the purpose of demonstrating the long duration storage of liquid hydrogen utilizing passive Cryogenic Fluid Management and cryocoolers via a two-stage active cooling approach. Funded by NASA’s Technology Demonstration Mission Program and managed by the Cryogenic Fluid Management Portfolio Project, the team is leveraging demonstrations conducted under pervious NASA activities to develop a fully integrated test article that will demonstrate the zero boil-off storage of liquid hydrogen. This paper discusses the previous activities being leveraged from NASA’s Cryogenic Propellant Storage and Transfer project, the test article design and build, hardware and instrumentation selections, control methodology, and the planned primary and secondary test objectives. The test article assembly and demonstration are both to be conducted in the East Test Area at NASA Marshall Space Flight Center and are currently scheduled for Fiscal Year 2024.

Active Cooling↗

NASA NTRS2013

No Vent Tank Fill and Transfer Line Chilldown Analysis by Generalized Fluid System Simulation Program (GFSSP)

The purpose of the paper is to present the analytical capability developed to model no vent chill and fill of cryogenic tank to support CPST (Cryogenic Propellant Storage and Transfer) program. Generalized Fluid System Simulation Program (GFSSP) was adapted to simulate charge‐holdvent method of Tank Chilldown. GFSSP models were developed to simulate chilldown of LH2 tank in K‐site Test Facility and numerical predictions were compared with test data. The report also describes the modeling technique of simulating the chilldown of a cryogenic transfer line and GFSSP models were developed to simulate the chilldown of a long transfer line and compared with test data.

Majumdar, Alok↗

NASA NTRS1989

Tank Pressure Control Experiment on the Space Shuttle

The tank pressure control experiment is a demonstration of NASA intent to develop new technology for low-gravity management of the cryogenic fluids that will be required for future space systems. The experiment will use freon as the test fluid to measure the effects of jet-induced fluid mixing on storage tank pressure and will produce data on low-gravity mixing processes critical to the design of on-orbit cryogenic storage and resupply systems. Basic data on fluid motion and thermodynamics in low gravity is limited, but such data is critical to the development of space transfer vehicles and spacecraft resupply facilities. An in-space experiment is needed to obtain reliable data on fluid mixing and pressure control because none of the available microgravity test facilities provide a low enough gravity level for a sufficient duration to duplicate in-space flow patterns and thermal processes. Normal gravity tests do not represent the fluid behavior properly; drop-tower tests are limited in length of time available; aircraft low-gravity tests cannot provide the steady near-zero gravity level and long duration needed to study the subtle processes expected in space.

Source record↗

NASA NTRS2024

Validation & Verification of CFD Models for Cryogenic Fluid Management of Propellant Tanks in Space

This article describes the need and the strategy for CFD model development, validation, and verification for Cryogenic Fluid Management (CFM) of Propellant Tanks in Space. It describes the type of CFD models that must be developed to address the future needs of Space CFM. It also discusses the two classes of experiments currently used to validate the fidelity of the CFD models. These two experiment classes are: (a) the small-scale simulant fluid science experiments that are equipped with scientific diagnostics to elucidate the underlying two-phase fluid physics of the CFM processes; and (b) the large-scale cryogenic experiments that assess the engineering performance of the propellant tank for storage and transfer. The current status of the CFD model development and validation is briefly assessed by presenting examples of segregated two-phase flow problems that have been successfully modeled. The future model development directions for CFM situations involving more complex interpenetrating phases are also defined.

Cryogenic Fluid Management↗

NASA NTRS2000

Magnetically Actuated Propellant Orientation, Controlling Fluids in a Low-Gravity Environment

Cryogenic fluid management (CFM) is a technology area common to virtually every space transportation propulsion concept envisioned. Storage, supply, transfer and handling of sub-critical cryogenic fluids are basic capabilities that have long been needed by multiple programs and the need is expected to continue in the future. The use of magnetic fields provides another method, which could replace or augment current/traditional approaches, potentially simplifying vehicle operational constraints. The magnetically actuated propellant orientation (MAPO) program effort focused on the use of magnetic fields to control fluid motion as it relates to positioning (i.e. orientation and acquisition) of a paramagnetic substance such as LO2. Current CFM state- of-the-art systems used to control and acquire propellant in low gravity environments rely on liquid surface tension devices which employ vanes, fine screen mesh channels and baskets. These devices trap and direct propellant to areas where it's needed and have been used routinely with storable (non-cryogenic) propellants. However, almost no data exists r,egarding their operation in cryogenics and the use of such devices confronts designers with a multitude of significant technology issues. Typical problems include a sensitivity to screen dry out (due to thermal loads and pressurant gas) and momentary adverse accelerations (generated from either internal or external sources). Any of these problems can potentially cause the acquisition systems to ingest or develop vapor and fail. The use of lightweight high field strength magnets may offer a valuable means of augmenting traditional systems potentially mitigating or at least easing operational requirements. Two potential uses of magnetic fields include: 1) strategically positioning magnets to keep vent ports clear of liquid (enabling low G vented fill operations), and 2) placing magnets in the center or around the walls of the tank to create an insulating vapor pocket (between the liquid and the tank wall) which could effectively lower heat transfer to the liquid (enabling increased storage time).

Martin, James J.↗

NASA NTRS1984

Cryogenic Fluid Management Facility

The Cryogenic Fluid Management Facility (CFMF) is a reusable test bed which is designed to be carried into space in the Shuttle cargo bay to investigate systems and technologies required to efficiently and effectively manage cryogens in space. The facility hardware is configured to provide low-g verification of fluid and thermal models of cryogenic storage, transfer concepts and processes. Significant design data and criteria for future subcritical cryogenic storage and transfer systems will be obtained. Future applications include space-based and ground-based orbit transfer vehicles (OTV), space station life support, attitude control, power and fuel depot supply, resupply tankers, external tank (ET) propellant scavenging, space-based weapon systems and space-based orbit maneuvering vehicles (OMV). This paper describes the facility and discusses the cryogenic fluid management technology to be investigated. A brief discussion of the integration issues involved in loading and transporting liquid hydrogen within the Shuttle cargo bay is also included.

Eberhardt, R. N.↗

DOE OSTI2021

Development of an Advanced Hydrogen Energy Storage System using Aerogel in a Cryogenic Flux Capacitor (CFC)

The Cryogenic Flux Capacitor (CFC) is a cold, dense fluid storage core with integrated design features that afford the designer flexibility and provide new possibilities for the storage and discharge of energy. The stored energy, in this case, is represented by hydrogen physically bonded within the nanoscale pores within the aerogel composite blanket material, and the process of bonding or debonding is governed by principles of physical adsorption (physisorption) and thermodynamics. The large surface area afforded by the nanoporous aerogel (~1,000 m2/g) allows for storage densities close to, or in some cases exceeding, that of normal boiling point liquids. Its performance easily exceeds what can be achieved via ambient temperature, high-pressure gas storage for an equivalent volume. CFC storage is predicted to be easily scalable, is constructed from readily available commercial materials, lends itself to a range of pressure applications, and is geometry insensitive. They can also be used in modular designs, affording even more flexibility for potential deployment. In addition to the aerogel adsorbent within the blanket material, a CFC includes thermally-conductive membrane layered with the aerogel, which acts as a large-area, quick-response thermal management system. The system conducts heat throughout the volume to discharge the unit quickly. This same thermal management system can also be connected to a refrigeration system, or cold fluid such as liquid nitrogen (LN2), to facilitate the charging up of the CFC. The charging and discharging can be performed as fast or as slow as desired by controlling the cooling or heating supplied to the CFC.

08 HYDROGEN↗

NASA NTRS1987

Propellant Tanks for Tethered Orbital Refueling Facility

Thermodynamics, mechanical stability, and mass penalties affect design. Pair of reports presents design study for propellant tanks used in low gravity. Each tank, which most likely contains liquid H2 or O2, part of fuel depot tethered to station in orbit around Earth. Some engineering concepts in study applied to design of tanks for use on Earth in transport and storage of cryogenic liquids and other fluids requiring special handling.

Rudolph, L. Kevin↗

NASA NTRS2019

Flight Servicing of Robotic Refueling Mission 3

The Robotic Refueling Mission 3 (RRM3) payload launched aboard a SpaceX rocket en route to the International Space Station on December 5th, 2018. The Goddard Space Flight Center designed payload carried approximately 50 liters of liquid methane onboard, with a mission to demonstrate long term storage and transfer of the cryogenic fluid in microgravity. Kennedy Space Center (KSC) was tasked to design, fabricate, test, and operate a system equipped to fill an RRM3 dewar with liquid methane prior to launch. Though KSC has a rich history of fueling rockets and payloads, no such operations had previously been accomplished using liquid methane. As such, all of the hardware and processes had to be developed from scratch. The completed ground system design, along with the verification and validation testing will be outlined in this paper. Several challenges that were met and overcome during procurement of the high purity methane are described. In addition, budget restrictions prohibited fueling operations from occurring in traditional processing facilities. The unique and creative solutions which were required to maintain payload cleanliness during cryogenic servicing are also detailed.

Cryogenics↗

NASA NTRS2019

Flight Servicing of Robotic Refueling Mission 3

Thermal Conductivity↗

NASA NTRS2019

Flight Servicing of Robotic Refueling Mission 3

Cryogenics↗

NASA NTRS2008

NASA's Cryogenic Fluid Management Technology Project

The Cryogenic Fluid Management (CFM) Project's primary objective is to develop storage, transfer, and handling technologies for cryogens that will support the enabling of high performance cryogenic propulsion systems, lunar surface systems and economical ground operations. Such technologies can significantly reduce propellant launch mass and required on-orbit margins, reduce or even eliminate propellant tank fluid boil-off losses for long term missions, and simplify vehicle operations. This paper will present the status of the specific technologies that the CFM Project is developing. The two main areas of concentration are analysis models development and CFM hardware development. The project develops analysis tools and models based on thermodynamics, hydrodynamics, and existing flight/test data. These tools assist in the development of pressure/thermal control devices (such as the Thermodynamic Vent System (TVS), and Multi-layer insulation); with the ultimate goal being to develop a mature set of tools and models that can characterize the performance of the pressure/thermal control devices incorporated in the design of an entire CFM system with minimal cryogen loss. The project does hardware development and testing to verify our understanding of the physical principles involved, and to validate the performance of CFM components, subsystems and systems. This database provides information to anchor our analytical models. This paper describes some of the current activities of the NASA's Cryogenic Fluid Management Project.

Tramel, Terri L.↗

NASA NTRSDate not supplied

Modeling Self-Pressurization and Spray Bar Pressure Control of a Cryogenic Storage Tank in Normal Gravity

This paper presents Computational Fluid Dynamics (CFD) models for simulating self-pressurization and spray bar cooling processes in a large-scale liquid hydrogen storage tank under normal gravity. The self-pressurization model utilizes the kinetics-based Schrage equation with the Volume-Of-Fluid (VOF) model to account for the evaporative and condensing interfacial mass fluxes. It uses a laminar approach to model natural convection and compares the pressures and temperatures predicted by the CFD model with experimental data from the Multipurpose Hydrogen Test Bed (MHTB) self-pressurization experiment. Additionally, the predicted interfacial mass flux is presented. A CFD model for simulating pressure control using a spray bar is also presented. An Eulerian-Lagrangian approach models the interactions between the discrete droplets and the continuous ullage phase. The spray model is coupled with the VOF model by tracking particles in the ullage, removing particles from the ullage when they reach the interface, and then adding their contributions to the liquid. The T-sat model is used to calculate the droplet-ullage heat and mass transfer. In this model, droplets warm up to the saturation temperature corresponding to the ullage vapor pressure thereafter evaporating while remaining at the saturation temperature. The tank pressure, vapor, and liquid temperature evolutions are validated against data from the MHTB spray bar mixing experiment.

Self-Pressurization↗

NASA NTRS2004

Transition from Pool to Flow Boiling: The Effect of Reduced Gravity

Applications of boiling heat transfer in space can be found in the areas of thermal management, fluid handling and control, power systems, on-orbit storage and supply systems for cryogenic propellants and life support fluids, and for cooling of electronic packages for power systems associated with various instrumentation and control systems. Recent interest in exploration of Mars and other planets, and the concepts of in-situ resource utiliLation on Mars highlights the need to understand the effect of gravity on boiling heat transfer at gravity levels varying from 1>= g/g(sub e) >=10(exp -6). The objective of the proposed work was to develop a mechanistic understanding of nucleate boiling and critical heat flux under low and micro-gravity conditions when the velocity of the imposed flow is small. For pool boiling, the effect of reduced gravity is to stretch both the length scale as well as the time scale for the boiling process. At high flow velocities, the inertia of the liquid determines the time and the length scales and as such the gravitational acceleration plays little role. However, at low velocities and at low gravity levels both liquid inertia and buoyancy are of equal importance. At present, we have little understanding of the interacting roles of gravity and liquid inertia on the nucleate boiling process. Little data that has been reported in the literature does not have much practical value in that it can not serve as a basis for design of heat exchange components to be used in space. Both experimental and complete numerical simulations of the low velocity, low-gravity nucleate boiling process were carried out. A building block type of approach was used in that first the growth and detachment process of a single bubble and flow and heat transfer associated with the sliding motion of the bubble over the heater surface after detachment was studied. Liquid subcooling and flow velocity were varied parametrically. The experiments were conducted at 1 g(sub e), while varying the orientation of surface with respect to the gravity vector. In the laboratory experiments, holographic interferometry was used to obtain data on velocity and temperature fields associated with a bubble prior to, and after detachment and during sliding motion. A test rig for conducting experiments in the KC-135 was developed, but experiments could not be conducted due to the unavailability of the aircraft prior to completion of the project. Numerical simulations modeling the micro and macro regions of the bubble were carried out in three dimensions. The results of the experiments were used to validate analytical/numerical models.

Dhir, Vijay K.↗

NASA NTRSDate not supplied

Long Duration Storage of Liquid Hydrogen via Two-Stage Active Cooling Hardware Characterization and Test Planning

The zero boil-off storage of liquid hydrogen using active cooling (cryocoolers) with a two-stage cooling approach is being investigated by NASA. In interest of advancing the technology to enable extended duration storage for the agency’s future long duration missions, NASA’s Technology Demonstration Mission Program has funded this five-year effort which includes the design, build and testing of a test article to demonstrate this concept. This paper includes discussions of the multiple Cryogenic Fluid Management technologies that were studied under NASA’s Cryogenic Propellant Storage and Transfer project, design of the test article to be demonstrated, then the planned test objectives which include characterization testing of the active cooling system, demonstration of the control system, preliminary testing with liquid nitrogen, and a complete demonstration of zero boil-off storage of liquid hydrogen. The full demonstration will be conducted in the East Test Area at NASA Marshall Space Flight Center and is currently scheduled to begin on October 1st, 2024.

Cryogenic Fluid Management↗