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At least 109 records · Page 6

Mitigation for Removal of Building 01-103 in the Area 1 Subdock, Nevada National Security Site, Nye County, Nevada

Building 01-103, the Drill Bit Repair Building was originally recorded as SHPO Resource No. B18848 in 2020 during an architectural survey of the Area 1 Subdock (Collins et al. 2022). It was recommended individually eligible for listing in the NRHP under Criteria A and C and contributing to the significance of the Area 1 Subdock Historic District. The SHPO concurred with these determinations in a letter dated April 29, 2022 (Reed 2022). The Drill Bit Repair Building retains all seven aspects of integrity. The location, materials, workmanship, feeling, and association have not changed since its original construction. The design was modified slightly in 1996 with the addition of a removable and non-destructive chain-link fence. Nearby buildings 01-101 and 01-102 were removed (Collins and Menocal 2020) but the other buildings and storage yards remain. Therefore, the integrity of setting has been changed, but not to the degree that the building no longer conveys its significance (see Figures 4 and 5 for comparison). Building 01-103 was constructed in 1985 to coincide with the relocation of the Area 3 Subdock to Area 1. The design for the new Subdock provided a centralized cluster of buildings surrounded by two large storage yards. The buildings included administrative and engineering office space, warehouses, a radiograph building, and Building 01-103 as the drill bit maintenance and repair building, among others. The Drill Bit Repair Building was critical to the success of underground nuclear testing and is eligible under Criterion A for its contribution to broad patterns of history by maintaining specially designed equipment for underground nuclear testing at the NNSS. It is also eligible under Criterion C as it is the only recorded example of a facility built specifically for the maintenance of big-hole drill bits on the NNSS. As it retains both significance and integrity, it remains individually eligible under Criteria A and C. In addition to its individual significance, the Drill Bit Repair Building also contributes to the significance of the Area 1 Subdock Historic District as a representative of a big-hole drilling support facility necessary for underground nuclear testing. The building and the equipment therein were designed specifically for testing at the NNSS, where much of the early technology and methods for big-hole drilling were developed. Its removal will result in not only the demolition of a contributing element but also a change in the physical features of the district’s setting that contribute to its historic significance. The change in setting will diminish the district’s integrity. However, the district still contains numerous examples of other buildings constructed for the purpose of supporting big-hole drilling and remains eligible under Criteria A and C.

54 ENVIRONMENTAL SCIENCES↗

Mitigation for Removal of Building 01-202681 in the Main Storage Yard of the Area 1 Subdock, Nevada National Security Site, Nye County, Nevada

The Main Storage Yard was originally recorded as SHPO Resource No. S2772 in 2020 during an architectural survey of the Area 1 Subdock (Collins et al. 2022). It was recommended individually eligible for listing in the NRHP under Criteria A and C and as contributing to the significance of the potential Area 1 Subdock Historic District. The SHPO concurred with these determinations in a letter dated April 29, 2022 (Reed). The Main Storage Yard retains all seven aspects of integrity. The location, design, materials, workmanship, feeling, and association have not changed since the original construction. Since the purpose of the yard is to maintain storage equipment that is actively being used, the design and feeling will change each time equipment is moved. Such actions reinforce the integrity of design and feeling. Buildings 01-101 and 01-102 were removed (Collins and Menocal 2020), but the other buildings and storage yard remain. Therefore, the setting has been changed, but not to the degree that the Main Storage Yard no longer conveys its significance (see Figures 4 and 5 for comparison). The Main Storage Yard was designed to facilitate the relocation of the Area 3 Subdock to Area 1 in 1985. The design for the overall Subdock provided a centralized cluster of buildings surrounded by two large storage yards. While the North Storage Yard largely serves as overflow storage, the Main Storage Yard holds the majority of drill rigs and drilling equipment needed to support big hole drilling. The Main Storage Yard and its contents were essential elements of the nuclear testing drilling program on the NNSS thus making it eligible for the NRHP under Criterion A for its contribution to broad patterns of history by storing specially designed equipment for underground nuclear testing at the NNSS. It is also eligible under Criterion C as it is an engineered landscape that now serves as an open-air repository of drilling technology and nuclear testing. In addition to its individual significance, the Main Storage Yard also contributes to the significance of the Area 1 Subdock Historic District as it showcases a variety of big-hole drilling equipment, support facilities, and warehouses that were specially designed for nuclear testing at the NNSS. Despite the demolition of two contributing elements to date, the district still contains numerous examples of other facilities with the purpose of supporting big-hole drilling; therefore, the district still remains eligible under Criteria A and C.

54 ENVIRONMENTAL SCIENCES↗

Prototype Hanford Barrier Performance Monitoring Report: Fiscal Year 2024

This report provides an annual update on performance monitoring of the Prototype Hanford Barrier (PHB) at the Hanford Site. The PHB is part of a long-term study that serves as the scientific basis for many of the evapotranspiration-capillary barrier designs currently used globally and for future engineered barrier designs planned for remedial actions over waste and demolition sites at the Hanford Site. The PHB allows us to identify potential future issues and develop better monitoring techniques before these engineered barriers are constructed. Surface barriers like the PHB are essential for preventing water infiltration and curbing the spread of contaminants to groundwater. Effective monitoring of soil moisture levels above and below these barriers is crucial given that performance metrics could span up to 1,000 years. From July 2023 to June 2024, the water flux (as measured by tipping buckets) through the 2-m-thick silt loam layer of the PHB – a fine silty material that stores water under high capillary tension – remained well below the 0.5-mm-per-year performance threshold, demonstrating its effectiveness in preventing water penetration. In 2024, degraded tipping bucket gauges were replaced to ensure the accuracy of future data. Additionally, neutron probes revealed that the wetting front from the rainy season only penetrated to a maximum depth of 1.2 m into the silt loam. This further demonstrated the barrier's efficiency, as the wetting front did not fully penetrate the 2-m-thick capillary barrier. The western gravel slope of the PHB, composed of Hanford Site pit gravel of varying sizes, demonstrated low flux rates. In contrast, the eastern riprap slope exhibited higher flux rates. Zhang (2017) found that the riprap side slope of the PHB had the highest drainage rates in January and the lowest in late summer or early fall, indicating significant summer evaporation. Drainage rates increased significantly under enhanced precipitation conditions, far exceeding the design criterion, which could lead to water infiltration into the waste zone. The study introduced the “edge effect,” where elevated drainage rates from the riprap may migrate laterally beneath the barrier, compromising its ability to isolate waste, and recommended expanding the barrier and conducting further research to mitigate this issue. This report provides a review on surface barrier edge effects and their potential impact to subsurface contaminant migration.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Detonation Waves in High Explosives

A material at high temperature can react or decompose. For an energetic material, the reaction is exothermic and releases chemical energy that would further increase the temperature. Under some circumstances, when a reaction is triggered, such a reaction can propagate and the material rapidly releases a large amount of energy giving rise to an explosion. Examples of such materials are aerosols, suspensions of solid particles or liquid droplets in a gas; such as coal dust, grain dust and fuel-air explosions. Frequently, explosions are due to accidents. A spectacularly destructive example is the recent explosion of a large quantity of ammonium nitrate (thousands of tons) in Beirut, Lebanon (August 2020); see for example Beirut explosion. Ammonium nitrate is used as a fertilizer. It and the aerosols are not considered to be explosives due to the limited conditions for which an explosion can occur. An aerosol gets the oxidizer from the surrounding air. Burning requires diffusion of the oxidizer to the particle surface where the reaction occurs. A large density of small particles is required for a fast enough reaction to support an explosion. In contrast, an explosive is an energetic material with both fuel and oxidizer mixed on a molecular scale (either premixed gases or within molecules of a solid). This allows fast enough reactions over a wide range of conditions to support a self-propagating reactive wave known as a detonation wave. A detonation wave can be controlled and an explosive used for useful purposes such as in mining, construction, demolition, explosive welding, argon flash lamp, pulsed power using a magnetic flux generator [see also Goforth et al., 2015], jet cutter with shaped charge, explosive art, and generating conditions to study the response of materials at high strain rates and high pressures [see for example, Marsh, 1980]. Explosives are also used in conventional munitions and nuclear weapons. The focus of this book is on the theory and phenomenology of solid high explosives (HEs); in particular, plastic-bonded explosives (PBXs). Some aspects of detonation wave theory are needed to interpret explosive data. Hence, the theory is presented before the detonation wave phenomenology. A familiarity with fluid flow, specifically the notion of shock waves and the shock loci are assumed. In the remainder of this chapter we give a brief overview on the basic properties of detonation waves and PBXs.

36 MATERIALS SCIENCE↗

NRIC DOME Crane Trade Study and Recommendation

The National Reactor Innovation Center (NRIC) is a national program that was established as part of the Nuclear Energy Innovation Capabilities Act (NEICA). NRIC’s mission is to accelerate the demonstration and deployment of advanced nuclear energy through its mission to inspire stakeholders and the public, empower innovators, and deliver successful outcomes through efficient coordination of partners and resources. NRIC is designed to bridge the gap between research, development, and the marketplace to help convert some of the nation’s most promising advanced nuclear reactors into commercial applications. The NRIC Demonstration of Microreactor Experiments (DOME) facility, formerly known as Experimental Breeder Reactor II (EBR II), located at the Materials and Fuels Complex (MFC) at the Idaho National Laboratory (INL) is intended to allow industrial and other partners the opportunity to test Advanced Microreactors up to 20MW thermal power. The 75-ton capacity polar crane located in the EBR II facility was rendered inoperable to support planned facility demolition in 2015; small holes were flame cut in the girders; hoists and cables were removed; oil was drained from gear boxes; trolley drive, and then filled with absorbent; and the electrical and control umbilical’s were disconnected, removed and disposed. Subsequently, the decision was made to convert the EBR II facility into the DOME test bed.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗

Recommendations for an Applicant to Calculate Activity Data for Greenhouse Gases Estimates

In 2009, the U.S. Nuclear Regulatory Commission (NRC) directed the NRC staff to address climate change issues and consider the impacts of the emissions of carbon dioxide (CO 2 ) and other greenhouse gases (GHGs) in its environmental reviews for major licensing actions (NRC 2009b). To implement this direction from the Commission, the staff issued guidance in 2011 and updated guidance in 2014 in Attachment 1 to Interim Staff Guidance COL/ESP-ISG-026 (NRC 2011; NRC 2014). This guidance provides a simpler method than the method described in RG 4.2 Rev. 3, that an applicant can use to meet the plant parameter envelope (PPE) value from the Generic Environmental Impact Statement for Licensing of New Nuclear Reactors (NR GEIS). NRC staff estimated the 97-year lifecycle GHG emissions from a reference 1000 megawatt electrical (MWe) light-water reactor (LWR) for various activities associated with construction, operation (including uranium fuel cycle), and decommissioning of nuclear power plants and presented the results in Appendix H of the NR GEIS. Appendix H of the NR GEIS includes estimates of direct emissions from construction equipment and emergency diesel engines in a nuclear facility and indirect emissions from workforce vehicular traffic, fuel transportation and the uranium fuel cycle. The NR GEIS Section 3.3 extended the estimates in Appendix H for the installation of two 1000 MWe nuclear reactors on the same site. Scaling factors were used to extrapolate the GHG emissions of a reference 1000 MWe reactor to a two-unit nuclear reactor plant (each reactor unit generating 1000 MWe). GHG emission estimates for building, operation, decommissioning and safe storage (SAFSTOR) for a two-unit nuclear reactor plant would be based on the plant’s physical size, and therefore estimates for these source categories were assumed to be twice the value of the reference 1000 MWe reactor. However, GHG emissions from the fuel cycle (including fuel transportation) were scaled upward by a factor of 3, based on plant efficiencies greater than the 80 percent assumption in Appendix H. Table 1 below shows the PPE emissions for two 1000 MWe nuclear reactors as provided in NR GEIS. The total GHG emissions for two 1000 MWe reactors were calculated as 2,534,000 metric tons (MT) of CO 2 equivalent (CO 2 (e)) based on a 97 year GHG life cycle period. The GHG emissions lifetime of 97 years for a reference nuclear reactor includes a 7-year building phase, 40 years of operation, 10 years of active decommissioning, and 40 years of SAFSTOR operations (NRC 2024). Construction equipment and vehicular traffic from workers commute would contribute to the GHG emissions during a 7-year building phase. Uranium fuel cycle, vehicular traffic, fuel and waste transportation, and testing of standby diesel generators would contribute to GHG emissions during the 40-year operations phase. While NRC’s regulations allow up to 60 years of reactor facility decommissioning, Appendix H estimated that most of the GHGs would occur over an estimated 10-year period during which to the licensee would engage in significant demolition and earth-moving activities, as discussed in Supplement 1 to NUREG-0586 (NRC 2002). Vehicular traffic by the workforce during a 40-year SAFSTOR period would additionally contribute GHG emissions. The carbon footprint for a 40-year SAFSTOR period was separately analyzed from the decommissioning activities as provided in Table YYYY-2 of the staff issued guidance in 2011 (NRC 2011).

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Evaluation of Technologies to Mitigate the Presence of Gaseous Elemental Mercury in Waste Disposal Containers

A study was conducted to evaluate sorbent technologies that can mitigate the presence of elemental mercury (Hg⁰) in waste containers for mercury-contaminated debris (MCD). Decontamination and demolition (D&D) activities at the Y-12 National Security Complex (Y-12) and other U.S. Department of Energy (DOE) Oak Ridge Reservation (ORR) facilities generate MCD requiring offsite disposal. The debris is packaged in appropriate waste containers and may be temporarily stored onsite prior to transport for treatment and/or disposal. During transportation of loads that had no visible liquid Hg at the point of origin, temperature changes can cause Hg⁰ to evaporate, condense, and form droplets on container walls. Furthermore, vibration during transportation could cause beads of Hg to be released from the debris, container walls, and ceiling, resulting in pools of liquid Hg⁰ on the container floor. Waste acceptance criteria (WAC) limitations for commercial disposal facilities, the Nevada National Security Site (NNSS), and ORR mixed low-level waste landfills prohibit the presence of any free liquids in containers identified as a solid waste form. Potential solutions to mitigate the presence of residual liquids that could be formed through vapor condensation include the use of sorbents or similar materials to capture and stabilize volatile Hg⁰ vapors and thus ensure compliance with landfill WAC requirements. This report summarizes data from small-scale laboratory experiments conducted to evaluate sorbent materials for Hg⁰ vapor suppression and sorption of liquid Hg⁰ that could form under relevant transportation and disposal conditions. A series of experiments was conducted to evaluate commercial sorbent materials and their effectiveness for Hg⁰ sorption across a temperature range from 19.4°C to 60°C. The impact of residual moisture on sorption was investigated under relevant conditions, and leaching tests were performed to assess the stability of Hg⁰ captured sorbent materials. The results provide estimates for sorbent quantities needed for a given Hg⁰ mass loading based on experimental results exposing sorbents to gaseous and liquid Hg⁰ at various mass ratios. Overall, sorbents that were most effective for Hg⁰ vapor suppression were brominated activated carbons, mackinawite-based sorbents coated on vermiculite, and sulfur-modified granular activated carbon. Elevated temperatures and moisture conditions did not result in significant increases of Hg⁰ headspace concentrations, and the materials also demonstrated high sorption capacities for the sorption of liquid Hg⁰.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Closure Report for Corrective Action Unit 572: Test Cell C Ancillary Building and Structures, Nevada National Security Site, Nevada, Revision 0

The purpose of this CR is to provide documentation supporting the completed corrective actions and data confirming that the closure objectives for CAU 572 were met. To achieve this, the following actions were performed: • Corrective action investigation (CAI) activities were performed from August 2020 through May 2023, as set forth in the SAFER Plan for CAU 572; and in accordance with the Soils Activity Quality Assurance Plan, which establishes requirements, technical planning, and general quality practices. • Corrective actions were completed during decontamination and demolition (D&D) and disposal activities, and were performed from August 2022 through September 2025.

54 ENVIRONMENTAL SCIENCES↗

Predicting Building Envelope Construction from In-Situ Thermal Testing

When embarking on a retrofit of a building envelope, it is critical to understand the composition of its assembly. This practice is currently done by destructive and invasive material testing or demolition, which is sometimes not possible when in historic or protected buildings. To address this problem, in-situ thermal testing can be utilized along with machine learning classification algorithms to infer the composition of an assembly. In this paper, a proof-of-concept K-nearest neighbors classification model is developed to classify assembly composition from effective thermal resistance, effective thermal mass, and assembly cladding. This model was trained and tested utilizing a synthetic dataset producing an F1-score of 94.6%. This model was also validated with experimental data from a 100-year old wall assembly, confirming the model’s real-world validity. The paper presents a framework for inferring as-built envelope assemblies, all without having to damage or disturb the building and its occupants.

Pilet, Tyler J.↗

Material flows and GHG emissions from housing stock evolution in US counties, 2020–60

The evolution of housing stocks determines demand for construction materials and energy, and associated emissions of greenhouse gasses (GHGs). The contribution of construction to building life-cycle emissions is growing as buildings become more energy efficient and the energy supply decarbonizes. A housing stock model is developed for counties in the United States using dynamic vacancy rates which endogenously influence stock out- and inflows. Stocks of three house types and 10 construction cohorts are projected for all contiguous US counties for the period 2020–60. Inflows and outflows of construction materials are then estimated along with GHG emissions associated with material production and construction activities in scenarios defined by stock turnover rates, population share by house type, and floor area characteristics of new houses. The results provide new insights into the drivers of construction-related emissions at local and national levels, and identify opportunities for their reduction. Demolition material flows grow in relation to construction material flows over the analysis period. Increasing the stock turnover rate increases future floor area per person, material requirements, and emissions from construction. Scenarios with reduced floor area and more multifamily homes in new construction have lower floor area growth, material requirements, and emissions from construction.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Searching for Dark Matter with Superconducting Qubits

Dark matter is an enduring mystery in our quest to understand the fundamental constituents of our universe. Low mass bosons, such the axion or hidden photon, are compelling dark matter candidates. We leverage their potential interactions with electromagnetic fields, whereby the dark matter (of unknown mass) on rare occasion converts into a single photon, to devise a method of detecting these candidates. Current dark matter searches operating at microwave frequencies use a resonant cavity to coherently accumulate the field sourced by the dark matter and a near standard quantum limited (SQL) linear amplifier to read out the cavity signal. To further increase sensitivity to the dark matter signal and enable future searches, sub-SQL detection techniques are required.In this thesis, I report the development of a novel microwave photon counting technique and a new exclusion limit on hidden photon dark matter. We operate a superconducting qubit to make repeated quantum non-demolition measurements of cavity photons and apply a hidden Markov model analysis to reduce the noise to 15.7 dB below the quantum limit, with overall detector performance limited by a residual background of real photons. With the present device, we perform a hidden photon search and constrain the kinetic mixing angle to less than 1.68 x 10-15 in a band around 6.011 GHz (24.86 micro-eV) with an integration time of 8.33 s. This demonstrated noise reduction technique enables future dark matter searches to be sped up by a factor of 1300. By coupling a qubit to an arbitrary quantum sensor, more general sub-SQL metrology is possible with the techniques presented in this work.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Feedback on Forty-year Long Clean-up Operations of a Contaminated Soil for Environmental Purpose - 20026

One of the CEA facilities in France is the place of miscellaneous mapping and clean-up operations since the 1980's. The final purpose of the conducted work deals with the environmental remediation of the building. In France, the absence of a regulatory framework for the management of sites polluted by radioactive substances, especially as the lack of release thresholds, has led to develop different approaches of soil radiological characterization. The geostatistical approach is part of them. Preliminary investigations are an unavoidable step prior to clearance and remediation. First, historical analysis enables to define site perimeters to investigate as well as to precisely locate expected contaminated parts. For radioactive pollutants, the media (water, soil, air) and transfer routes participate in the definition of the investigation perimeter and thus also need to be identified through a geological study. At the same time, functional analysis leads to choose the best measurement means which could provide useful information when combined with visual inspection. An equipment well adapted to easy-to-measure radionuclides as gamma emitters, such as gamma probe or on-site gamma spectrometry, is usually selected as a non-destructive assay. Coupled with spatial positions, processed on-site radiological data can be mapped. Data processing consists in mapping and kriging before a geostatistical analysis in order to identify the zones of interest to be targeted. Selected zones are not only linked to high level count rates but also to low level ones so that a pollution-free reference is known in the area. This data processing also enables to categorize waste types according to their origin and contamination levels. An expected volume of different waste then follows as well as the waste characterization equipments. In-depth investigations, e.g. core drillings and samplings, naturally ensue to aim at remediation optimization through the assessment of environmental impact. After clean-up operations, non-destructive assays as well as destructive samplings enable to check the effective clearance. Following this methodology in the present remediation work, results of the first non-destructive assay campaign highlighted a long-lived transuranic radionuclides contamination in the concrete flagstone. Successive non-destructive assays were then performed in the defined zones of interest. Count rates measured with a surface probe were first mapped. The best localization of destructive assays, i.e. core drillings at a 1 meter depth, came from this surface mapping followed by a geostatistical analysis. The concrete flagstone was totally removed. Then, the depth of soil to remove under the flagstone was optimized from the results of radiological activities measured in core drillings samples. A new surface mapping was then drawn after this partial soil excavation. The sand and demolition rubble samples, homogeneously constituted from the flagstone fragments, were analyzed by gamma spectrometry. Meanwhile, waste drums and other containers were also measured by gamma spectrometry and passive neutron measurement devices. All these results have brought miscellaneous pieces of information. In this context, major issues appear in terms of physical constraints such as the premises tininess as well as of soil sampling techniques and in terms of measurement performances assessment and the representativeness of homogeneous samples. The choice of radiological soil and waste characterization devices is described in the light of enhanced performances by keeping in mind radiation protection requirements and a willing to always optimize waste categories (very low level waste) and volume. The improvement of the characterization methods appears through this forty-year long work while sharing the feedback of encountered difficulties. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

When Every Drum is a Win - Tackling a Thirty-Five Thousand Drum Legacy - 20064

Cameco Corporation's (Cameco) Port Hope Conversion Facility (PHCF) was previously owned by the federal Crown Corporation, Eldorado Nuclear, which held a significant inventory of legacy waste material at the time Cameco was formed in 1988. As a result, Cameco was granted an allocation of 150,000 cubic metres of space in the Long-Term Waste Management Facility (LTWMF) located in the Municipality of Port Hope (MPH), which opened to the receipt of Cameco material in June 2018. Cameco is currently undertaking a major site cleanup and renewal of its Port Hope Conversion Facility (PHCF) which is known as the Vision in Motion (VIM) project. Over its operating history, Eldorado accumulated an inventory of over 35,000 drums of accumulated waste that was primarily stored at two offside warehouse locations. In 2017 and 2018, the project focused on repackaging two well characterized legacy wastes (magnesium fluoride slag and depleted uranium titanium oxide) from one of the two offsite locations. At the conclusion of this work, approximately 15,000 drums of these wastes had been repackaged and disposed of at the LTWMF. There remained approximately 1000 drums from this location that either could not be repackaged safely or were different waste types and required further verification and/or processing. The buildings at this location were scheduled for demolition in early 2019, which triggered the development of a process for triaging legacy drums in August 2018, which allowed for preparation and shipment of approximately half of these drums to the LTWMF by March 2019, with the remainder moved to the second offsite warehouse location in February 2019 for further characterization which is ongoing. This paper will discuss key lessons learned as the drummed legacy waste disposal inventory has been reduced to approximately half of the initial inventory. This will include the development of an alternate packaging process; prioritization of characterization activities and selection of techniques where minimal inventory information is available; determination of next step(s) for each drum as it is assessed; key safety considerations; and how to make inroads into an overwhelming task while under public and regulatory scrutiny. In a relatively short period of time, significant progress has been made to organize and gather information about the legacy waste, update the inventory records and determine the most appropriate pathways (i.e. LTWMF disposal, disposal at another appropriate facility, site storage until future processing and/or disposal). Since 2017 the volume of the decades-old legacy waste inventory has decreased significantly. With the majority of the known materials safely disposed of at the LTWMF, every drum removed from the endless rows of 20,000 pyramidally-stacked waste drums with limited history that is safely characterized, prepared and shipped is considered a win. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Tool for Developing Integrated Strategies for Decontamination and Waste Management - 20291

Management of waste from chemical, biological, and radiological incidents is complicated by the fact that decontamination decisions have a profound impact on the characteristics of resulting waste streams. Wide-area biological and radiological incidents could produce massive quantities of waste that may need to be treated on-site and sent for subsequent disposal as non-contaminated materials, or else be directly disposed of as contaminated materials. The EPA has developed the Waste Estimation Support Tool (WEST) for characterizing and quantifying biological and radiological waste that may be generated from decontamination efforts. This paper focuses on the WEST's uses for radiological incidents. WEST combines Geographic Information System (GIS)-based analysis of externally-supplied plume data, infrastructure databases derived from the Federal Emergency Management Agency's (FEMA's) Hazus tool [1], and satellite imagery surface recognition algorithms to combine the composition and square footage of the buildings in the plume with estimates of the materials between the buildings in the plume. The resulting GIS data files are then imported into a Microsoft Access database application, where they are combined with information about the nature and concentration of contaminants, and then subjected to decontamination strategies for different contaminated surfaces. The tool provides estimates of the type and quantities of potential wastes resulting from simulated decontamination and/or demolition activities and includes estimates of the remaining contamination levels including residual contamination contained within each waste stream. Estimates are presented at several levels of detail, allowing users to obtain needed data at the desired resolution. These include estimates for the total affected area, estimates by contamination zone, estimates by decontamination method(s), and estimates by building type (occupancy classification). EPA is currently developing the next version of WEST which will include several substantial enhancements. The most significant improvement for the next version of WEST will include the ability for users to develop contamination scenarios and waste estimates based on previously developed, readily available, and geographically specific infrastructure data. Instead of using WEST's default infrastructure data based on FEMA's Hazus tool, users will be able to import their own building data specific to the geographically affected area. This capability may substantially decrease uncertainties in the resulting waste estimates because the results will be based on actual building data (numbers of each type, square footage, building height, etc.). Two other significant enhancements will be the ability to generate waste estimates for vehicles and biomass. In addition to building debris and building decontamination waste, vehicles and biomass will likely constitute a significant percentage of the total waste which may result from wide area contamination events. This presentation will present the most recent version of WEST, which includes such considerations as affected biomass (e.g., trees), vehicles, and the ability to replace the default Hazus infrastructure databases with custom infrastructure databases. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Declaration of the Chemical Composition of Waste-products for the German Repository Konrad Using Substance Vectors - 20500

The waste acceptance criteria of the German repository Konrad require beside a radiological declaration a compositional declaration to be able to avoid negative impact on the groundwater by a presumed leakage into the groundwater after complete corrosion of the containers in the future. The declaration of the composition has to specify compounds and substances not element analyses, because the chemical behavior and toxicity especially of organic compounds varies strongly The relevant compounds have to be described and quantified using defined substance codes provided by the operator. For simple waste types like pure concrete or steel components, the definition of the composition is rather simple. The composition of more complex waste streams is generally declared using producer specific material vectors, which can be derived for defined waste types (e.g. grouted fluids, ash from combustion, super-compacted mixed waste etc.). Additional substance vectors exist for containers, drums and grout, which together with the waste composition yield the total composition of the waste packages. The substance vectors for homogeneous waste streams like cementitious demolition waste, solidified fluids and ash are mostly based on analyses provided by the waste owner. In some cases, analyses from non-radioactive analogues or data sheets can also be used to demonstrate the composition. For each qualified treatment of radioactive waste streams the material composition is described and balanced on the basis of specific material vectors, which are composed of material codes from the material and cask list provided by the Federal company for radioactive waste disposal. For mixed waste streams like super-compacted or grouted mixed waste or materials simply packed in containers an analyses cannot be used. In these cases, the compositional information from the bookkeeping can be used for the entire waste stream to calculate a mean composition including a compositional range (min / max composition). Only waste packages with an approved material description can be delivered to Konrad. Therefore, the material declaration of all waste streams and the resulting waste products is crucial for all waste owners in Germany to be able to have enough waste packages ready, when the repository is going to open in 2027. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Fire Protection Design

The purpose of this project is to design the demolition and installation of a deluge valve swap from a DV-5 to a DV-5A valve.

99 GENERAL AND MISCELLANEOUS↗

West Valley Demonstration Project (WVDP) Annual Site Environmental Report (ASER) for Calendar Year 2020

West Valley Demonstration Project (WVDP) Annual Site Environmental Report (ASER) for Calendar Year 2020. The report, prepared for the U.S. Department of Energy West Valley Demonstration Project office (DOE-WVDP), summarizes the environmental protection program at the WVDP for calendar year (CY) 2020. Monitoring and surveillance of the facilities used by the DOE are conducted to verify protection of public health and safety and the environment. The report is a key component of DOE’s effort to keep the public informed of environmental conditions at the WVDP. The quality assurance protocols applied to the environmental monitoring program ensure the validity and accuracy of the monitoring data. In addition to demonstrating compliance with environmental laws, regulations, and directives, evaluation of data collected in 2020 continued to indicate that WVDP activities pose no threat to public health or safety, or to the environment.

Resource Conservation and Recovery Act↗

West Valley Demonstration Project (WVDP) Annual Site Environmental Report (ASER) for Calendar Year 2021

The report, prepared for the U.S. Department of Energy West Valley Demonstration Project office (DOE-WVDP), summarizes the environmental protection program at the WVDP for calendar year (CY) 2021. Monitoring and surveillance of the facilities used by the DOE are conducted to verify protection of public health and safety and the environment. The report is a key component of DOE’s effort to keep the public informed of environmental conditions at the WVDP. The quality assurance protocols applied to the environmental monitoring program ensure the validity and accuracy of the monitoring data. In addition to demonstrating compliance with environmental laws, regulations, and directives, evaluation of data collected in 2021 continued to indicate that WVDP activities pose no threat to public health or safety, or to the environment.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗