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Materials Science

The Materials Science Program is structured so that NASA s headquarters is responsible for the program content and selection, through the Enterprise Scientist, and MSFC provides for implementation of ground and flight programs with a Discipline Scientist and Discipline Manager. The Discipline Working Group of eminent scientists from outside of NASA acts in an advisory capacity and writes the Discipline Document from which the NRA content is derived. The program is reviewed approximately every three years by groups such as the Committee on Microgravity Research, the National Materials Advisory Board, and the OBPR Maximization and Prioritization (ReMaP) Task Force. The flight program has had as many as twenty-six principal investigators (PIs) in flight or flight definition stage, with the numbers of PIs in the future dependent on the results of the ReMaP Task Force and internal reviews. Each project has a NASA-appointed Project Scientist, considered a half-time job, who assists the PI in understanding and preparing for internal reviews such as the Science Concept Review and Requirements Definition Review. The Project Scientist also insures that the PI gets the maximum science support from MSFC, represents the PI to the MSFC community, and collaborates with the Project Manager to insure the project is well-supported and remains vital. Currently available flight equipment includes the Materials Science Research Rack (MSRR-1) and Microgravity Science Glovebox. Ground based projects fall into one or more of several categories. Intellectual Underpinning of Flight Program projects include theoretical studies backed by modeling and computer simulations; bring to maturity new research, often by young researchers, and may include preliminary short duration low gravity experiments in the KC-135 aircraft or drop tube; enable characterization of data sets from previous flights; and provide thermophysical property determinations to aid PIs. Radiation Shielding and preliminary In Situ Resource Utilization (ISRU) studies work towards future long duration missions. Biomaterials support materials issues affecting crew health. Nanostructured Materials are currently considered to be maturing new research, and Advanced Materials for Space Transportation has as yet no PIs. PIs are assigned a NASA Technical Monitor to maintain contact, a position considered to be a 5 percent per PI effort. Currently 33 PIs are supported on the 1996 NRA, which is about to expire, and 59 on the 1998 NRA. Two new NRAs, one for Radiation Shielding and one for Materials Science for Advanced Space Propulsion are due to be announced by the 2003 fiscal year. MSFC has a number of facilities supporting materials science. These include the Microgravity Development Laboratory/SD43; Electrostatic Levitator Facility; SCN Purification Facility; Electron Microscope/Microprobe Facility; Static and Rotating Magnetic Field Facility; X-Ray Diffraction Facility; and the Furnace Development Laboratory.

Source record↗

Testing Protocol Proposal to Identify and Evaluate Candidate Materials to Substitute for Silverized Teflon in Thermal Control Applications

Electrostatic discharge (ESD) has been shown to be the primary cause of several glitches in spacecraft operations. It appears that charged particles encountered in the natural environment in certain orbits can collect on the outer surfaces of a spacecraft, building up a charge of several thousand volts. If the potential exceeds the breakdown voltage of the charged material, then an ESD will occur. ESD events involving relatively low voltages, on the order of 100 V, have been shown to damage electronic components. When ESD occurs, electronic and electrical components can be damaged, computer instructions can be garbled, and ablation of material from the spacecraft may occur; degrading both the performance of the thermal control blankets, and the cleanliness of any surfaces on which the detritus becomes deposited. There appear to be six ways to prevent or mitigate the effects of ESD: (1) Choose an orbit where charging is not a problem; (2) Carry extra electromagnetic shielding; (3) Provide redundancy in components and programming; (4) Provide for active dissipation of the charge, by generating a plasma with which to bathe susceptible surfaces; (5) Provide for passive dissipation from a plasma contactors on the susceptible surfaces; and (6) Provide thermal control blankets that do not hold a charge, i.e., that are conductive enough to bleed a charge off harmlessly. These six options are discussed in detail in Losure (1996). Of these six options, number 1 is not always practical, given other requirements of the mission; 2, 3, 4 and 5 will require that extra mass in the form of shielding, etc., be carried by the spacecraft. The most attractive option from a mass and energy point of view seems to be that of finding a material which matches the other performance characteristics of the current thermal control blankets without their tendency to build up an electrostatic charge. The goal of this paper is to describe and justify a testing program which will lead to the approval of materials of this kind.

Losure, Nancy S.↗

Saturn's electrostatic discharges - Could lightning be the cause?

It is proposed that Saturn's electrostatic discharges (SED) might be generated in the planet's equatorial atmosphere, perhaps as lightning from a storm system. The 10-h-10-min periodicity of the signal envelope duplicates that of Saturn's equatorial jet. The rings shield the atmosphere from solar EUV photons, and thereby substantially reduce the local ionospheric cutoff frequency to allow low-frequency SED to leak out. Many of the unusual properties of SED could be explained in terms of changes in the storm system, the relative spacecraft position in the beaming pattern of the source, local refraction of the signal by the highly disturbed ionosphere, and the influence of the ring particles on the highest frequency component of SED. A comparison of SED with planetary lightning on other planets shows that the two are similar in general character and some time behavior; the power output of SED may be higher than most planetary lightning, but that is unclear because of uncertainties in the measurements and variations in the signal's spectrum. It is suggested that lightning could be a viable source for SED and that exotic ring mechanisms are not necessarily required.

Burns, J. A.↗

The force exerted by the membrane potential during protein import into the mitochondrial matrix

The force exerted on a targeting sequence by the electrical potential across the inner mitochondrial membrane is calculated on the basis of continuum electrostatics. The force is found to vary from 3.0 pN to 2.2 pN (per unit elementary charge) as the radius of the inner membrane pore (assumed aqueous) is varied from 6.5 to 12 A, its measured range. In the present model, the decrease in force with increasing pore width arises from the shielding effect of water. Since the pore is not very much wider than the distance between water molecules, the full shielding effect of water may not be present; the extreme case of a purely membranous pore without water gives a force of 3.2 pN per unit charge, which should represent an upper limit. When applied to mitochondrial import experiments on the protein barnase, these results imply that forces between 11 +/- 2 pN and 13.5 +/- 2.5 pN catalyze the unfolding of barnase in those experiments. A comparison of these results with unfolding forces measured using atomic force microscopy is made.

Models, Molecular↗

Microshutter Arrays for the NGST NIRSpec

We are developing a programmable multiobject field selector for the NGST NIRSpec. This device is a microshutter array, a close-packed 2000 x 2000 array of 100 micrometer x 100 micrometer shutters fabricated with Micro-ElectroMechanical Systems (MEMS) technologies. The shutters are opened using a magnet scanned over the array. The shutters are held open by electrostatic potentials on adjacent vertical electrodes. Modeling of the magnetic actuation of the microshutters allowed optimization of the magnetic field configuration, the distance between magnet and shutters, and the force and torque produced by the magnet. The results of laboratory tests are consistent with our modeling. We have demonstrated actuation, latching and addressing. We are able to rotate shutters out of the plane up to 90 degree and more, to latch them electrostatically to the walls and release them selectively. During the last six month all critical elements of the array have been demonstrated. Fabrication processes were developed to deposit vertical electrodes on support grid side walls and insulated light-shields that block the gaps between shutters and the support grid. Physical optics analysis was performed to assess the expected optical performance of the microshutters. A preliminary Fourier optics analysis on the microshutter array performance has been carried out. More detailed analysis of wave propagation through 3D structures is a next step. An optical test station for verifying optical parameters of the shutter array at room temperature has been developed. It allows to measure parameters, such as transmission, scattering, contrast ratio, and diffraction of the array structure. Initial data have been acquired and are being analyzed and compared to theoretical predictions.

Moseley, Harvey↗

Cross-field Streaming Instabilities in the Lower Hybrid Frequency Near the Front Pole Regions of a Magnetically Shielded Hall Thruster

The mechanism that led to the erosion of the inner front pole cover in wear tests of the Hall-effect Rocket with Magnetic Shielding (HERMeS) at 300 V and 12.5 kW has been elusive. Several classical mechanisms have been considered yet none has explained conclusively the source of the discrepancy between wear measurements and simulations. In this article we consider a new mechanism. The electrostatic dispersion relation for an unbounded, homogeneous plasma in a fixed magnetic field is solved numerically in the near-plume region of this thruster. The plasma conditions have been obtained from Hall2De (r-z) multifluid-PIC simulations. We find that the modified two-stream instability can be excited in most regions of the domain, with the fastest growth approaching the fluid-limit value of ωLH/2 near the magnetic poles where ωpe/ωce~1. In this region the relative drift between magnetized electrons and beam ions perpendicular to the magnetic field can exceed 3uTi, while that between counter-streaming beam and cathode ions can exceed 4uTi. The latter suggests that the ion-ion cross-field lower hybrid instability may also be active here. Unlike the classical ion-acoustic instability, lower hybrid instabilities can heat ions to temperatures that are comparable to the electron temperature. Such anomalous heating would enhance the average energy of these ions and, in turn, the erosion of the nearby surfaces they sputter. An idealized model that scales the anomalous ion heating with ωLH has been incorporated in Hall2De and the simulations now yield significantly improved agreement with the measured wear rates and IVDFs, as reported in our companion paper.

Ortega, Alejandro Lopez↗

History and Flight Devleopment of the Electrodynamic Dust Shield

The surfaces of the moon, Mars, and that of some asteroids are covered with a layer of dust that may hinder robotic and human exploration missions. During the Apollo missions, for example, lunar dust caused a number of issues including vision obscuration, false instrument readings, contamination, and elevated temperatures. In fact, some equipment neared failure after only 75 hours on the lunar surface due to effects of lunar dust. NASA's Kennedy Space Center has developed an active technology to remove dust from surfaces during exploration missions. The Electrodynamic Dust Shield (EDS), which consists of a series of embedded electrodes in a high dielectric strength substrate, uses a low power, low frequency signal that produces an electric field wave that travels across the surface. This non-uniform electric field generates dielectrophoretic and electrostatic forces capable of moving dust out of these surfaces. Implementations of the EDS have been developed for solar radiators, optical systems, camera lenses, visors, windows, thermal radiators, and fabrics The EDS implementation for transparent applications (solar panels, optical systems, windows, etc.) uses transparent indium tin oxide electrodes on glass or transparent lm. Extensive testing was performed in a roughly simulated lunar environment (one-sixth gravity at 1 mPa atmospheric pressure) with lunar simulant dust. EDS panels over solar radiators showed dust removal that restored solar panel output reaching values very close to their initial output. EDS implementations for thermal radiator protection (metallic spacecraft surfaces with white thermal paint and reflective films) were also extensively tested at similar high vacuum conditions. Reflectance spectra for these types of implementations showed dust removal efficiencies in the 96% to 99% range. These tests indicate that the EDS technology is now at a Technology Readiness Level of 4 to 5. As part of EDS development, a flight version is being prepared for several flight opportunities. The flight version of the EDS will incorporate significantly smaller electronics, with an expected mass and volume of 500 g and 350 cm(exp. 3) respectively. One of the opportunities is an International Space Station (ISS) experiment: Materials for International Space Station Experiment 10 (MISSE-10). This experiment aims to verify the EDS can withstand the harsh environment of space and will look to closely replicate the solar environment experienced on the moon. A second flight opportunity exists to provide an EDS to several companies as part of NASA's Lunar CATALYST program. The current mission concept would fly the EDS on the footpad of one of the Lunar CATALYST vehicles. Dust will likely deposit on the footpad through normal surface rover activities, but also upon landing where lunar dust is expected to be uplifted. To analyze the e effectiveness of the EDS system, photographs of the footpad with one of the spacecrafts onboard cameras are anticipated. If successful in these test flights, the EDS technology will be ready to be used in the protection of actual mission equipment for future NASA and commercial missions to the moon, asteroids, and Mars.

Lunar↗

Development of Electrostatically Clean Solar Array Panels

Certain missions require Electrostatically Clean Solar Array (ECSA) panels to establish a favorable environment for the operation of sensitive scientific instruments. The objective of this program was to demonstrate the feasibility of an ECSA panel that minimizes panel surface potential below 100mV in LEO and GEO charged particle environments, prevents exposure of solar cell voltage and panel insulating surfaces to the ambient environment, and provides an equipotential, grounded structure surrounding the entire panel. An ECSA panel design was developed that uses a Front Side Aperture-Shield (FSA) that covers all inter-cell areas with a single graphite composite laminate, composite edge clips for connecting the FSA to the panel substrate, and built-in tabs that interconnect the FSA to conductive coated coverglasses using a conductive adhesive. Analysis indicated the ability of the design to meet the ECSA requirements. Qualification coupons and a 0.5m x 0.5m prototype panel were fabricated and tested for photovoltaic performance and electrical grounding before and after exposure to acoustic and thermal cycling environments. The results show the feasibility of achieving electrostatic cleanliness with a small penalty in mass, photovoltaic performance and cost, with a design is structurally robust and compatible with a wide range of current solar panel technologies.

Stern, Theodore G.↗

Fabrication of MEMS-Based Microshutter Arrays for Optical Transmission Selection

A MEMS-based programmable aperture mask is under development at the NASA Goddard Space Flight Center. Termed the Microshutter (u-shutter) Array, the device will be used to control the transmission of light, with both high efficiency and contrast, to a multi-object spectrometer on the James Webb Space Telescope. Fabrication of the p-shutter array employs several novel designs and processing techniques. The current generation of micro-shutters consists of 128x64 pixel arrays with unit cell dimensions of 100x200 microns. Shutters are patterned in silicon nitride and sit on a 100 micron silicon frame that is DRIE etched below each shutter. The front and back sides of the device are shown. A magnetic cobalt-iron alloy patterned on top of the shutter allows it to be actuated 90 degrees out-of-plane, into the frame, by an external magnetic field. An electrode on the shutter and a vertical electrode on the sidewall of the frame, approximately 90pm deep, allow them to be electrostatically latched in their rotated position. The vertical electrode is deposited and patterned on the backside of the frame in a single step using a directionally controlled evaporation. Individual addressing of shutters for electrostatic latching is accomplished via a crosspoint addressing scheme, with no on-chip active components. A portion of an array with shutters in the open, latched, and closed positions is shown. Light loss at shutter edges is minimized by an overhanging aluminum light-shield that is anchored to the frame. A photoresist sacrificial layer is used to raise the light-shield up and over the 2 micron gap that surrounds each pixel. After completion, arrays are subjected to life cycle, environmental and optical testing. Fabricated devices have survived 10(exp 6) actuation cycles at both room and cryogenic temperatures and a 14g rms launch-simulation test. Optical testing has shown contrast measurements between open and closed shutters up to 10000:1.

Lynch, Bernard A.↗

Design of Superconducting Gravity Gradiometer Cryogenic System for Mars Mission

Measurement of a planets gravity field provides fundamental information about the planets mass properties. The static gravity field reveals information about the internal structure of the planet, including crustal density variations that provide information on the planets geological history and evolution. The time variations of gravity result from the movement of mass inside the planet, on the surface, and in the atmosphere. NASA is interested in a Superconducting Gravity Gradiometer (SGG) with which to measure the gravity field of a planet from orbit. An SGG instrument is under development with the NASA PICASSO program, which will be able to resolve the Mars static gravity field to degree 200 in spherical harmonics, and the time-varying field on a monthly basis to degree 20 from a 255 x 320 km orbit. The SGG has a precision two orders of magnitude better than the electrostatic gravity gradiometer that was used on the ESAs GOCE mission. The SGG operates at the superconducting temperature lower than 6 K. This study developed a cryogenic thermal system to maintain the SGG at the design temperature in Mars orbit. The system includes fixed radiation shields, a low thermal conductivity support structure and a two-stage cryocooler. The fixed radiation shields use double aluminized polyimide to emit heat from the warm spacecraft into the deep space. The support structure uses carbon fiber reinforced plastic, which has low thermal conductivity at cryogenic temperature and very high stress. The low vibration cryocooler has two stages, of which the high temperature stage operates at 65 K and the low temperature stage works at 6 K, and the heat rejection radiator works at 300 K. The study also designed a second option with a 4-K adiabatic demagnetization refrigerator (ADR) and two-stage 10-K turbo-Brayton cooler.

Li, X.↗

Design of Superconducting Gravity Gradiometer Cryogenic System for Mars Mission

Measurement of a planet's gravity field provides fundamental information about the planet's mass properties. The static gravity field reveals information about the internal structure of the planet, including crustal density variations that provide information on the planet's geological history and evolution. The time variations of gravity result from the movement of mass inside the planet, on the surface, and in the atmosphere. NASA is interested in a Superconducting Gravity Gradiometer (SGG) with which to measure the gravity field of a planet from orbit. An SGG instrument is under development with the NASA PICASSO program, which will be able to resolve the Mars static gravity field to degree 200 in spherical harmonics, and the time-varying field on a monthly basis to degree 20 from a 255 x 320 km orbit. The SGG has a precision two orders of magnitude better than the electrostatic gravity gradiometer that was used on the ESA's GOCE mission. The SGG operates at the superconducting temperature lower than 6 K. This study developed a cryogenic thermal system to maintain the SGG at the design temperature in Mars orbit. The system includes fixed radiation shields, a low thermal conductivity support structure and a two-stage cryocooler. The fixed radiation shields use double aluminized polyimide to emit heat from the warm spacecraft into the deep space. The support structure uses carbon fiber reinforced plastic, which has low thermal conductivity at cryogenic temperature and very high stress. The low vibration cryocooler has two stages, of which the high temperature stage operates at 65 K and the low temperature stage works at 6 K, and the heat rejection radiator works at 300 K. The study also designed a second option with a 4-K adiabatic demagnetization refrigerator (ADR) and two-stage 10-K turbo-Brayton cooler.

Gradiometer↗

Status of the Electroforming Shield Design (ESD) project

The utilization of a digital computer to augment electrodeposition/electroforming processes in which nonconducting shielding controls local cathodic current distribution is reported. The primary underlying philosophy of the physics of electrodeposition was presented. The technical approach taken to analytically simulate electrolytic tank variables was also included. A FORTRAN computer program has been developed and implemented. The program utilized finite element techniques and electrostatic theory to simulate electropotential fields and ionic transport.

Fletcher, R. E.↗

Methods of Measuring Secondary Electron Emission and Analysis of Spacecraft Charging Simulation

The scope of the internship project was to help the Electrostatics and Surface Physics Laboratory (ESPL) at KSC gain an understanding as to what parameters related to secondary electron emission (SEE), and electrostatic discharge (ESD) could be measured within its own facilities. As well as assistance in developing a plan for the ESPL to acquire the capabilities to measure other necessary parameters, to reduce the reliance on measurement data from facilities outside of the agency. The intern also worked closely with agency customers of the Launch Services Program (LSP) in expanding the MAPTIS database to incorporate various electrostatic and physical properties of materials used in the Gateway Program. This involved cross-center collaboration with industry and NASA contracted academia members in order to fill in the gaps of data that is missing from the database. Overall, the internship provided assistance in coordinating the approval for more materials to be added to the MAPTIS database, and continuing to assist the team at the ESPL in their consulting work for the agency through the use of various spacecraft charging and ESD simulation programs (i.e., NASCAP, NUMIT2.1). As well as assisting in the CAD design and implementation of an electrodynamic dust shield (EDS) for use in upcoming spaceflight missions. This was all done with the aim of helping the ESPL demonstrate its capabilities for the agency, and to continue expanding and localizing measurement techniques at KSC to help streamline obtaining the information NASA needs to ensure safety in current and future missions.

dust↗

Stationary electrostatic solitary waves in the auroral plasma

Time-stationary fluid equations are used to describe electrostatic solitons in an auroral plasma of cold ionospheric and hot plasma sheet particles. A one-dimensional fluid analysis of the four component model auroral plasma indicates that at least two different, weakly damped, small amplitude electrostatic solitons can propagate along the geomagnetic field. The slower of the two is a generalization of an ion-acoustic solitary wave in a multi-component plasma, and ion inertia is negligible for the faster mode which is supported by the two electron components and resembles a clump of shielded negative space charge convected by the drifting plasma sheet electrons. Some expected features of the large amplitude properties are indicated qualitatively, and an analogy is considered between the theory of ion-acoustic shocks and a theory of double layers.

Lotko, W.↗

Development of an Electrostatically Clean Solar Array Panel

The results of design, analysis, and qualification of an Electrostatically Clean Solar Array (ECSA) panel are described. The objective of the ECSA design is to provide an electrostatic environment that does not interfere with sensitive instruments on scientific spacecraft. The ECSA design uses large, ITO-coated coverglasses that cover multiple solar cells, an aperture grid that covers the intercell areas, stress-relieved interconnects for connecting the aperture grid to the coverglasses, and edge clips to provides an electromagnetically shielded enclosure for the solar array active circuitry. Qualification coupons were fabricated and tested for photovoltaic response, conductivity, and survivability to launch acoustic and thermal cycling environments simulating LEO and GEO missions. The benefits of reducing solar panel interaction with the space environment are also discussed.

Stern, Theodore G.↗

Fusion power for space propulsion.

Principles of operation, interplanetary orbit-to-orbit mission capabilities, technical problems, and environmental safeguards are examined for thermonuclear fusion propulsion systems. Two systems examined include (1) a fusion-electric concept in which kinetic energy of charged particles from the plasma is converted into electric power (for accelerating the propellant in an electrostatic thrustor) by the van de Graaf generator principle and (2) the direct fusion rocket in which energetic plasma lost from the reactor has a suitable amount of added propellant to obtain the optimum exhaust velocity. The deuterium-tritium and the deuterium/helium-3 reactions are considered as suitable candidates, and attention is given to problems of cryogenic refrigeration systems, magnet shielding, and high-energy particle extraction and guidance.

Roth, R.↗

Development of a Real Time Internal Charging Tool for Geosynchronous Orbit

The high-energy electron fluxes encountered by satellites in geosynchronous orbit pose a serious threat to onboard instrumentation and other circuitry. A substantial build-up of charge within a satellite's insulators can lead to electric fields in excess of the breakdown strength, which can result in destructive electrostatic discharges. The software tool we've developed uses data on the plasma environment taken from NOAA's GOES-13 satellite to track the resulting electric field strength within a material of arbitrary depth and conductivity and allows us to monitor the risk of material failure in real time. The tool also utilizes a transport algorithm to simulate the effects of shielding on the dielectric. Data on the plasma environment and the resulting electric fields are logged to allow for playback at a variable frame rate.

Posey, Nathaniel A.↗

Injun 5 observations of vehicle potential fluctuations at 2500 km

The AFGL spherical electrostatic analyzers aboard the polar orbiting Injun 5 satellite were designed to measure the temperature and density of the plasma as well as the vehicle potential. Significant vehicle potential fluctuations were observed at altitudes near 2500 km in the nighttime, topside ionosphere. At auroral latitudes, precipitating magnetospheric electrons frequently drove the satellite to such strongly negative potentials that the ambient electrons were shielded from instruments. In such cases, simultaneous measurements can be used to calculate the vehicle potential. Potentials of up to -40 volts were observed during impulsive precipitation events. Within the plasma trough, vehicle potentials varied between -1.5 and -4 volts, as compared with the -0.5 to -1 volt observed in the polar cap. The source of this vehicle potential enhancement was ascribed to fluxes of photoelectrons that have escaped from the sunlit conjugate ionosphere.

Sagalyn, R. C.↗