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At least 109 records · Page 6

Relating flow resistance to equivalent roughness

Describing flow resistance using the physical properties of an underlying surface is a recalcitrant problem in overland flow models. If discharge measurements are available, an equivalent roughness (e.g., Manning’s n) can be calibrated to represent the effects of surface properties within the domain with a single numerical value. Alternatively, the flow resistance can be estimated from discharge and velocity measured at a point, typically a runoff plot outlet. However, such experimental estimates are often inconsistent with the equivalent roughness determined from calibration to discharge, even if both derive from the same dataset. For example, if Manning’s equation is used to parameterize flow resistance, the Manning’s n obtained by calibrating a model to discharge differs from the value of n calculated from measured flow and velocity at the hillslope outlet. Here, this discrepancy is resolved by deriving a correction factor relating experimentally-determined flow resistance to the equivalent roughness. The derived correction factor is tested for four commonly-used resistance formulations using 129 rainfall simulator experiments. The correction factor is necessary to reproduce measured velocities, and yields minor improvements in discharge prediction. Plain Language Summary: Accurate runoff prediction is needed for land and water management in dryland regions, where sporadic and limited rainfall necessitate efficient water use and drought mitigation strategies. The skill of runoff models is known to be hindered by out ability to estimate flow resistance, which is the quantity that describes how energy is lost from flowing water to the underlying surface. Typically, models represent flow resistance with an equivalent roughness, e.g., Manning’s n, that is adjusted until the model can reproduce available discharge observations at watershed scale. However, the flow resistance measured in plot-scale experiments (1–10 m) often exceeds equivalent roughness coefficients by a factor of 10. This means that the direct use of plot-scale experimental data to parameterize runoff models could cause errors in discharge and runoff velocity predictions. Here, we resolve these differences by deriving an analytic correction factor that relates flow resistance to the equivalent roughness required for models to reproduce experimental velocity and discharge data. This correction factor is tested using rainfall simulator data from 129 experiments performed in the US Southwest covering a wide range of precipitation intensities, soil textures and vegetation types. Use of the correction factor substantially improves model prediction of flow velocity, which is needed for reproducing the timing of flood events and the estimation of erosion.

54 ENVIRONMENTAL SCIENCES

Validating the rhenium proxy for rock organic carbon oxidation using weathering profiles

Chemical weathering over geological timescales acts as a source or sink of atmospheric carbon dioxide (CO 2 ), while influencing long-term redox cycling and atmospheric oxygen (O 2 ) at Earth's surface. There is a growing recognition that the oxidative weathering of rock organic carbon (OC petro ) can release more CO 2 than is locally drawn down by silicate weathering, and may vary due to changes in erosion and climate. The element rhenium (Re) has emerged as a proxy to track the oxidative weathering of OC petro , yet uncertainties in its application remain namely that we lack a systematic assessment of the comparative mobility of Re and OC petro during sedimentary rock weathering. Here we measure Re and OC petro loss across gradients in rock weathering at 9 global sites, spanning a range of initial OC petro values from ~0.2 % to >10 %. We use titanium to account for volume changes during weathering and assess Re and OC petro loss alongside major elements that reflect silicate (Na, Mg), carbonate (Ca, Mg) and sulfide (S) weathering. Across the dataset, Re loss is correlated with OC petro loss but not with loss of any other major element. Further, across the weathering profiles, the average molar ratio of OC petro to Re loss was 0.84 ± 0.15, with 8 out of 9 sites having a ratio >0.74. At one site (Marcellus Shale), the average ratio was lower at 0.58 ± 0.11. The excess loss of Re matches expectations that, typically, between ~0 and 20 % of the Re liberated by sedimentary rock weathering derives from silicate or sulfide phases, while some OC petro may be physically or chemically protected from weathering. Overall, our measurements provide validation for the Re proxy of OC petro oxidation and allow future work to further improve our knowledge of regional and global-scale rates of this important source of CO 2 in the geochemical carbon cycle.

58 GEOSCIENCES

Supersonic hot jet ablative testing and analysis of boron nitride nanotube hybrid composites

Boron nitride nanotubes (BNNTs) are high-strength, high-modulus nanotubes with high thermal and oxidative stabilities. Two hybrid composites were prepared with satin weave carbon fiber (CF) and resole-type phenolic resin: one with surface layers of BNNTs and one with alternating interlayers of BNNTs. The samples were subjected to hot jet tests that simulate realistic high-pressure-temperature conditions to understand the behavior of BNNTs under high-pressure erosion. Adding BNNTs to CF/phenolic laminates enhanced the ablation resistance by reinforcing the char material and mitigated localized thermal damage. Hybrid laminates exhibited up to 14% lower weight loss, 55% increase in flexural modulus, higher thermal diffusivity, and improved char yield and microstructure compared to CF/phenolic samples. The surface layer hybrid had many surviving nanotubes reinforcing the char and crystalline oxide structures that could mitigate further oxygen diffusion. Further, various characterization methods were used to deduce possible mechanisms and their products, indicating that BNNTs could serve as growth templates for direct crystalline boron oxide formation. Overall, hybrid BNNT/CF/phenolic laminates displayed better ablation resistance and favorable microstructure evolution under high-pressure conditions.

42 ENGINEERING

Effects of substrate bias and tilt on magnetron sputtered boron carbide films

Maintaining high density and good mechanical properties at oblique angles for magnetron sputtered amorphous boron carbide films remains a challenge. In this study, we investigate the effect of the substrate bias on density, residual stress, mechanical properties, and morphology of boron carbide films deposited via direct current magnetron sputtering with a full-face erosion magnetron source in a mixed Ar-Ne plasma. Results show that films deposited at oblique substrate tilt angles on substrates biased at -50 V possess significantly lower oxygen content, superior mechanical properties, and higher density compared to their electrically grounded counterparts. In conclusion, these enhancements observed at oblique angles, while promising, come at the cost of larger residual compressive stress and higher Ne incorporation in films.

Materials science

A multi-objective optimization model for cropland design considering profit, biodiversity, and ecosystem services

More sustainable agricultural methods are needed to alleviate the decreases in biodiversity and ecosystem services that have occurred because of industrial agriculture. One such method is the inclusion of alternative crops into croplands that can support biodiversity, reduce erosion and chemical runoff, and sequester carbon in the soil. However, the question of where such crops should be planted to balance competing economic and environmental objectives remains open. To this end, we develop a mixed-integer quadratically constrained program to optimize the layout of a cropland considering economic, biodiversity, greenhouse gas emissions, and water quality objectives. We include spatially varying fertilization as a decision variable in addition to crop establishment location. We further include the effect of core area and edges between different crops on biodiversity. To demonstrate the applicability of the model, we apply it to an example field, showing how the optimal cropland design changes as a decision-maker prioritizes different objectives and as edges have different impacts on biodiversity.

54 ENVIRONMENTAL SCIENCES

Earthquake-triggered submarine canyon flushing transfers young terrestrial and marine organic carbon into the deep sea

Submarine canyons transfer substantial amounts of sediment and organic carbon (OC) into the deep ocean, nourishing deep-sea ecosystems and contributing to the global carbon cycle through OC burial and sequestration. Tracking lateral OC transport through submarine canyon systems is challenged by the deep-ocean setting, difficulties with constraining episodic depositional events, and the need to assess the composition and age of marine and terrestrial organic matter. We apply innovative parallel ramped pyrolysis oxidation accelerator mass spectrometry and pyrolysis-gas chromatography-mass spectrometry with isotope analyses to track OC age and sources in the 2016 Kaikoura earthquake-triggered, canyon-flushing event that deposited along >1300 km of a submarine canyon-channel system, offshore Aotearoa New Zealand. Specifically, these techniques allow us to determine the ages, sources, and partitioning of OC within the Kaikoura turbidite deposit and test hypotheses of how submarine canyon systems contribute to lateral OC flux and burial. Our results show that, despite considerable canyon floor erosion, substantial amounts of young OC were flushed into the deep sea, with relatively little (~2%) pre-Holocene OC contributions. Even without a direct connection between rivers and submarine canyons, most (~55%) of the OC in the Kaikoura event bed is from terrestrial sources. However, the deposit also contains substantial amounts (~22%) of marine-derived OC and ~23% of the material is of unassignable origin. Particle sorting imparts variability on the age and composition of OC within turbidite deposits and along the turbidity current flow path. Terrestrial-derived OC is preferentially older than marine-derived OC and concentrated in coarser particle sizes found more commonly at the deposit base and in proximal settings. Young, marine-derived OC is concentrated at the surface of the deposits and tends to be enriched in finer particle sizes. Such OC partitioning in turbidites supports the relevance of depositional models for predicting and quantifying distribution of OC in deep-sea deposits. Earthquake-triggered, canyon flushing events and resulting turbidites enhance OC burial efficiency and can sequester OC effectively, contributing an important carbon sink to the sedimentary carbon cycle.

54 ENVIRONMENTAL SCIENCES

Optimizing bioenergy sorghum productivity and nutrient removal in Illinois: Impact of nitrogen fertilization under diverse marginal conditions

Bioenergy sorghum (Sorghum bicolor L. Moench) is a promising crop for contributing to the United States bioenergy supply. However, the varying limitations of the marginal lands targeted for its cultivation present a management challenge. This two-year study aimed to investigate how the limitations associated with marginal cropland impact the effects of nitrogen fertilization on the yield of bioenergy sorghum and the uptake of 11 macro- (N, P, K, Ca, Mg, and S) and micronutrients (Fe, Mn, Zn, Cu, and B). The study contrasted prime cropland in central Illinois (Urbana) with three marginal cropland sites in southern (Ewing) and central Illinois (Fairbury and Pesotum). These marginal cropland sites are characterized by varying limitations, including low soil fertility (P and K limitations), leaching and erosion, and flooding, respectively. Four nitrogen rates (0, 56, 112, and 168 kg N ha –1 ) were tested under eight environments. The average yields and ranges of sorghum biomass were 20.2 (17.0–23.2) Mg ha –1 in Urbana, 18.1 (13.1–19.8) Mg ha –1 in Ewing, 13.8 (9.0–17.3) Mg ha –1 in Fairbury, and 23.3 (14.6–33.0) Mg ha –1 in Pesotum. Optimal N rates were 56 N in Pesotum and 112 N in Urbana, Ewing, and Fairbury. Tissue macronutrient contents in Urbana were generally higher than in the marginal croplands, while micronutrient contents did not show discernible trends. Increasing N rate generally correlated with the macronutrient removal except in Ewing. Comparable sorghum biomass yields were observed between prime and marginal croplands (averaging 18.3 Mg ha –1 ), but optimal N rates varied between 56 N and 112 N. This suggests that yield gaps can be narrowed by applying the optimal N rates for the respective locations. However, increased removals of macronutrients, especially P and K, with increasing yields indicate the need to revise fertilizer recommendations, particularly for soils deficient in these nutrients.

09 BIOMASS FUELS

Shock wave formation in the thermosphere by an earthgrazing fireball: Empirical evidence for volatile-enhanced hydrodynamic shielding

Hydrodynamic shielding is a theoretically well-established but observationally elusive and experimentally difficult-to-replicate phenomenon with implications that extend far beyond meteor physics. Rare earthgrazing meteoroids with infrasound signatures that penetrate to the ground can be used to probe hydrodynamic shielding that leads to strong shock formation at high altitude. Here, we report the first coordinated optical and multi-station infrasound observations of a centimeter-scale earthgrazing fireball that generated sustained cylindrical line shock at thermospheric altitudes near 92 km. The event was recorded by numerous optical stations and three infrasound arrays, allowing trajectory reconstruction, ablation behavior, acoustic source localization, and shock characteristics. Optical observations indicate early mechanical erosion and ablation/evaporation at exceptionally low dynamic pressure, consistent with a cometary or a porous, volatile-bearing CM chondritic object. Independent infrasound detections localize shock generation to multiple points along a 164 km trajectory segment near perigee. Weak-shock modeling yields a consistent blast radius of ∼30 m, implying an acoustic-equivalent source size far exceeding the physical dimensions of the ∼45 g nucleus. We demonstrate that classical gas dynamics and ablation-driven hydrodynamic shielding alone cannot account for these observations under ambient thermospheric conditions. We show that volatile release provides the additional flow-field density enhancement required to amplify hydrodynamic shielding, reduce the effective local Knudsen number, and sustain a shock envelope capable of radiating detectable infrasound. Furthermore, these results demonstrate that small, volatile-rich meteoroids can transiently establish continuum-like flow in rarefied environments.

Astrometry

Evaluating post-fire watershed response to varying burn severity and precipitation regimes using fully-distributed and integrated hydrologic models

Wildfires can cause significant changes in vegetation and soil, which may lead to increased surface runoff and soil erosion, thereby affecting water cycling within ecosystems. This study uses the Advanced Terrestrial Simulator (ATS), an integrated and fully distributed hydrologic model at the watershed scale, to examine post-fire hydrologic responses in selected watersheds with varying burn severities in the Pacific Northwest region of the United States. The model integrates surface overland flow, subsurface flow, and canopy biophysical processes. We have developed a new fire module in ATS to account for changes in soil hydraulic properties caused by fire in the topsoil layer. Modeling results indicate that, in the year following a high-severity burn, watershed-averaged evapotranspiration decreases by 25%. Additionally, post-fire peak flows increase by 18-29% in watersheds burned with medium to high severity due to changes in soil properties. Conversely, a low-severity burn results in less than a 1% increase in post-fire peak flow. Furthermore, a high-severity fire causes a 38% reduction in the infiltration rate within the affected watershed during the first post-fire wet season. Hypothetical numerical experiments with varying precipitation regimes after a high-severity fire show that post-fire peak flows can increase by 1-29% due to fire-induced changes in soil hydraulic properties. This study highlights the importance of using fully distributed hydrologic models to quantify disturbance-feedback loops, which are essential for understanding the complexities brought about by spatial heterogeneity in post-fire landscapes.

ATS

XPS post-mortem analysis of plasma-facing units extracted from WEST after the C3 (2018) and C4 (2019) campaigns

Four monoblocks coming from one ITER-like plasma-facing unit from the Q3B sector of the lower divertor, named as monoblock (MB)3, MB9, MB20, and MB30, were exposed to the deuterium and helium plasma mixture during the C3 (2018) and C4 (2019) campaigns of the Tungsten Environment in Steady-state Tokamak (WEST), followed by a detailed ex-situ X-ray photoelectron spectroscopy investigation. The surface and in-depth chemistry of the tungsten monoblocks indicated the formation of a re-deposited mixture in the deposition-dominated area of the divertor, thicker than 218 and 172 nm for MB3 and MB9, respectively. The redeposition layer was dominated by a mixture of boron carbides accompanied by tungsten carbides in MB3, while in MB9, the redeposition layer was dominated by tungsten borides. The remaining two monoblocks, MB20 and MB30, were collected from the erosion region and showed similar chemical behavior with a blended mixture of oxidized and metallic tungsten followed by boron carbides within a 50 nm depth range. Boron fixation in the layers is an expected consequence of the boronizations used during the operation, but the chemical status of redeposited elements was characterized for the first time in this work.

Marin, Alexandru [Pennsylvania State University]

Suppressed deprotonation enables a durable buried interface in tin-lead perovskite for all-perovskite tandem solar cells

Low-band-gap tin (Sn)-lead (Pb) perovskites are a critical component in all-perovskite tandem solar cells (APTSCs). Current state-of-the-art Sn-Pb perovskite devices exclusively use poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) as the hole-transport layer (HTL) but suffer from undesired buried-interface degradation. Here, we show that the deprotonation of the –SO 3 H group in PSS is the root cause of the interface degradation due to its low acid dissociation constant (pK a ), leading to acidic erosion and iodine volatilization in Sn-Pb perovskites. We identify that HTL featuring the carboxyl (–COOH) group with a higher pK a , such as poly[3-(4-carboxybutyl)thiophene-2,5-diyl] (P3CT), can suppress deprotonation and strengthen the interface, mitigating the buried-interface degradation. Motivated by established P3CT modification, we introduce Pb doping to P3CT to increase its work function and reduce interfacial energy loss. Furthermore, we fabricate APTSCs with a champion efficiency of 27.8% and an operational lifetime of over 1,000 h, with 97% retaining efficiency under maximum power point tracking.

08 HYDROGEN

Quantification and evaluation of strain reduction from small-bubble gas injection in Spallation Neutron Source target vessels

Small-bubble gas injection has been routinely utilized in the operation of Spallation Neutron Source (SNS) mercury targets since 2017 to mitigate cavitation-induced erosion damage to target vessels. Strain measurements of target vessels collected in-situ during initial operation with gas injection were used to study the gas injection effect on the structural response of targets to proton pulses. A significant strain reduction owing to gas injection was found by comparing the strain measurement data during operation with and without gas injection. The research presented here focuses on quantifying strain reductions in SNS targets and evaluating the effect of small-bubble gas injection by comparing different bubbler types and target designs. The strain measurement results show the gas injection significantly reduced strain in SNS target vessels; strain values decreased by 30% to 80% for targets operating with gas injection. Stress and strain responses of SNS targets were simulated to numerically evaluate the gas injection effect. Based on the predicted stresses with and without gas injection, the fatigue lifetimes of SNS jet-flow design target were estimated using fe-safe fatigue analysis software. The simulations show these reductions should improve the fatigue life of target vessels and allow SNS targets to meet their fatigue design goal.

Fatigue life estimation

Deuterium retention in pre-lithiated samples and Li–D co-deposits in the DIII-D tokamak

Divertor designs involving liquid lithium have been proposed as an alternative to solid designs and wall conditioning techniques. However, Li affinity with tritium poses a risk for the fuel cycle. This study investigates deuterium retention in pre-lithiated samples and Li–D co-deposits in the DIII-D tokamak, making for the first time a direct comparison between Li–D co-deposits and pre-deposited Li films. Samples were exposed to H-mode plasmas in the far scrape-off layer (SOL), and Li powder was injected in-situ with the impurity powder dropper to study the uniformity of Li coatings, and the dependence of fuel retention on Li thickness. The results show that at temperatures below the melting point of lithium, deuterium retention is independent of the thickness of pre-deposited Li layers, with Li–D co-deposits being the primary factor for fuel retention. Both pre-deposited and in-situ deposited Li showed lower erosion than predicted by sputtering yield calculations. These results suggest that fuel retention in fusion reactors using lithium in the divertor will likely be dominated by co-deposits rather than in the divertor itself. If one desires to use Li to achieve flatter temperature profiles, operando Li injection is advantageous over pre-deposited Li films, at least at temperatures below the melting point of lithium.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Hydraulic performance and wave transmission through nature-inspired perforated hollow-base piles breakwater

Nature-based Solutions (NbS) are critical to achieving long-term sustainable coastlines in deltaic coastlines, particularly susceptible to severe impacts under climate change. In recent years, coastal erosion has accelerated in the Vietnam Mekong Delta (VMD), particularly in the West Sea (from Ca Mau to Kien Giang). Due to the characteristics of muddy coastlines and eroded mangrove forests in this region, only a few engineering solutions have effectively reduced waves and promoted sediment accumulation to facilitate beach accretion. However, these solutions require significant investment and cannot be relocated or reused. Therefore, this study introduces a coastal mangrove-inspired perforated hollow-base piles breakwater (PHBPB), which uses the principle of biomimicry by studying the ability of mangrove groups to protect the coastline, stimulate sediment deposition, and over time, restore mangrove forests in the VMD. The hydraulic parameters of PHBPB were tested in 260 scenarios using a physical model, which included varying parameters such as crest width (B), pile row numbers (n c ), crest freeboard (R c ), and wave parameters (H s , T p ) in determining the capabilities of wave transmission, reflection, and wave dissipation. The results showed that the process of wave energy dissipation through perforated hollow-base breakwaters without piles (PHBBWP) is governed by three main parameters, including the relative water depth of the crest (R c /H m0,i ), the relative width of the crest (B/H m0,i ), and the wave slope at the structure location (s m = H m0,i /L m ). In contrast, for PHBPB, the primary influencing factors are the relative submergence depth or the length of the submerged pile portion (R c /H m0,i ) and the relative width of the pile system (X b /L m ). Finally, the hollow structure is suitable for the soft, weak mud geology in this region with poor load-bearing capacity, allows for rapid installation, is reasonably cost-effective, and can be relocated and reused once regeneration has been completed in each stretch of coastline.

54 ENVIRONMENTAL SCIENCES

Fundamental flow characterization for LiCl–KCl molten salt natural circulation closed loop

Molten salt flow characterization presents numerous challenges due to the hostile environments that cause corrosion and erosion of instrumentation and structural components. To support future molten salt flow characterization under natural convection conditions, a LiCl–KCl eutectic molten salt loop was designed and constructed. The primary objective of this loop is to facilitate natural convection as the principal cooling mechanism, enabling insights into the physics behind natural convection in closed loops and serving as a baseline for loop dimensional and non-dimensional analyses. Here, this study summarizes the fundamental functions employed for flow characterization and introduces a model to estimate flow rate when intrusive instrumentation is unavailable. The approach relies solely on structural surface measurements to avoid flow disturbances. Furthermore, a comprehensive thermal–hydraulic analysis is included to deepen understanding of the system’s behavior.

22 - GENERAL STUDIES OF NUCLEAR REACTORS

Power and particle exhaust for the ARC fusion power plant

To successfully show that fusion is an attractive energy source, the ARCTM fusion power plant will need to operate with a robust, integrated power and particle exhaust solution. To maximise ARC’s fusion power output while avoiding excessive erosion of the plasma-facing components, we will need to radiatively dissipate most of the power crossing the last-closed flux surface, injecting radiating impurities such as argon or neon to access divertor detachment. Divertor detachment will need to be integrated with a high-performance core plasma, and with efficient impurity pumping to prevent the accumulation of helium ash in the core. To access and control detachment in high-performance plasmas, we have designed ARC with up–down-symmetric divertors, with secondary X-points in long, tightly baffled outer legs. Using a core-edge modelling workflow, we predict that with this divertor design, ARC will access detachment with modest argon seeding in the divertor (c Ar,div ∼0.9%), which should have minimal impact on the core ( Z eff,core <0.5) for reasonable argon enrichment (c Ar,div /c Ar,core =6). Due to the high predicted divertor neutral pressure (p div ∼20 Pa), we predict that ARC will sufficiently pump helium to limit ash accumulation in the core (c He,core <2%) for a helium enrichment of c He,div /c He,core =0.4. ARC’s divertor design is expected to increase the stability of a detachment front in the outer divertor leg, helping to prevent divertor reattachment during smaller heat-flux transients such as scrape-off-layer filaments associated with the quasi-continuous exhaust regime. However, this buffering will not be sufficient to prevent divertor reattachment during large type-I edge-localised modes (ELMs), and as such these will need to be avoided on ARC. Experiments on SPARC will be used to select an integrated scenario which avoids or mitigates type-I-ELMs while maintaining access to detachment, good core fusion performance and sufficient impurity exhaust. SPARC experiments will also be used to finalise ARC’s divertor design, by studying the impact of magnetic and first-wall geometry on detachment stability, impurity enrichment and neutral baffling under conditions similar to those expected for ARC. In conclusion, our analysis finds that ARC will have a viable power and particle exhaust solution which is compatible with high-power operations, and this solution will be validated in experiments on SPARC.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Machine learning surrogates for ion energy–angle distributions in thermal and RF plasma sheaths

Ion energy–angle distributions (IEADs) at material surfaces are a critical input for plasma–material interaction (PMI) studies in fusion devices, yet they are computationally expensive to obtain using particle-in-cell (PIC) simulations. In this work, we develop a machine learning surrogate based on a deep deconvolutional neural network (DDeCNN) trained on large databases generated with the hPIC2 code. The surrogate is capable of reconstructing IEADs from sheath parameters for both thermal and radio-frequency (RF) plasmas, including cases with multiple ion species. Across thousands of test cases, the model achieves high accuracy, with over 97 % of predictions classified as good or average based on standard error metrics (MAE, MSE, L2). Even in the more challenging RF and multi-species regimes, the surrogate reliably captures the multi-peak structure of PIC results. Once trained, the surrogate produces IEADs in milliseconds on a common workstation, yielding speedups of six to seven orders of magnitude compared with running a full PIC simulation. This computational gain enables dense parameter scans and direct coupling of IEAD predictions with PMI and erosion models on whole-device scales in fusion-relevant conditions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Wildfire Produces Transient Minerals: Speciation, Reactivity, and Fate of Iron and Manganese in Surface Soils Post Wildfire

Wildfire leads to the deposition of an ash layer at the land surface. This material typically has alkaline properties, abundant pyrogenic carbon, and elevated metal concentrations compared to surface soils. Here, we compare ash and surface soils collected three weeks and two years after the Glass Fire (St. Helena, California, USA) to determine how wildfire affects the speciation and reactivity of iron (Fe) and manganese (Mn), two micronutrients that influence many soil processes. Synchrotron-based analyses revealed that wildfire generated stable Fe oxides like maghemite (γ-Fe 2 O 3 ) and hematite (α-Fe 2 O 3 ) that likely derived from surface soil or mineral dust rather than the vegetation, and Mn oxides such as hausmannite (Mn 3 O 4 ) and bixbyite (Mn 2 O 3 ) that derived primarily from aboveground biomass. However, these pyrogenic minerals were absent in soils collected two years after the fire. Their loss from the soil surface may result from a combination of erosion, translocation to deeper soil layers, and chemical weathering. The latter hypothesis is supported by the enhanced mobilization of Fe and Mn from ash upon the addition of pyoverdine, a model biogenic ligand. The increased mobility of micronutrients from fire-derived minerals in ash in response to microbial and root exudation may facilitate postfire soil and vegetation recovery.

bixbyite