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At least 109 records · Page 6

Surface waves generated by shallow underwater explosions

Surface water waves generated by surface and near surface point explosions are calculated. Taking the impulse distribution imparted at the water surface by the explosion as the overriding mechanism for transferring energy of the explosive to surface wave motion, the linearized theory of Kranzer and Keller is used to obtain the wave displacement in the far field. The impulse distribution is obtained by integrating the pressure wave over an appropriate time interval on a horizontal surface just beneath the undisturbed water surface. For surface explosions, a modified form of the similarity method first used by Collins and Holt is used to obtain the flow field. In the case of submerged explosions, the flow field is estimated by making necessary modifications to Sedov's similarity solution to account for the venting that accompanies the interaction of the leading (blast) wave with the ocean surface. Surface waves generated by a charge at six depths of placement (0.15 m, 0.30 m, 0.61 m, 0.91 m, 1.37 m, 3.05 m) are considered in addition to surface explosions. The results seem to support the existence of an upper critical depth phenomenon (of the type already established for chemical explosions) for point (nuclear) explosions.

Falade, A.↗

Explosive Welding of Aluminum, Titanium and Zirconium to Copper Sheet Metal

The main material properties affecting the explosive weldability of a certain metal combination are the yield strength, the ductility, the density and the sonic velocity of the two metals. Successful welding of the metal combination depends mainly on the correct choice of the explosive welding parameters; i.e., the stand off distance, the weight of the explosive charge relative to the weight of the flyer plate and the detonation velocity of the explosive. Based on the measured and the handbook values of the properties of interest, the explosive welding parameters were calculated and the arrangements for the explosive welding of the Al alloy 6061-T6, titanium and zirconium to OFHC copper were determined. The relatively small sheet metal thickness (1/8") and the fact that the thickness of the explosive layer must exceed a certain minimum value were considered during the determination of the explosive welding conditions. The results of the metallographic investigations and the measurements of the shear strength at the interface demonstrate the usefulness of these calculations to minimize the number of experimental trials.

Hegazy, A. A.↗

Explosive assembly and method

An explosive assembly includes a first explosive unit having a first longitudinal end portion having a first mechanical coupling feature, a second explosive unit having a second longitudinal end portion having a second mechanical coupling feature, and a tubular connector having a first end portion mechanically coupled to the first mechanical coupling feature and a second end portion mechanically coupled to the second mechanical coupling feature, such that the first explosive unit, the connector, and the second explosive unit are connected together end-to-end along a common longitudinal axis. Each explosive unit can contain a high explosive material and a detonator, and the connector can comprise a detonation control module electrically coupled to the detonators and configured to detonate the explosive units.

Mace, Jonathan L.↗

2023 Annual Explosives Inventory Completion

The 2023 Lawrence Livermore National Laboratory (LLNL) annual explosives inventory was executed from May 18, 2023 to September 27, 2023 and was verified for accuracy effective September 28, 2023 following the LLNL Explosive Materials Inventory Plan. This year’s annual inventory includes changes incorporated based on the Department of Energy (DOE) Office of Inspector General (OIG) Audit Report DOE-OIG-20-50, The Department of Energy’s Storage and Disposition of Explosives Material at Selected Sites, dated July of 2020. Based on the associated recommendations, explosives at DOE and National Nuclear Safety Administration (NNSA) sites are considered "sensitive personal property" and applicable inventories must comply with 41 CFR 109, Personal Property Management. This regulation adds additional stipulations which require the annual inventory to include accountability of the total site inventory. In addition, the inventory must be performed by personnel other than the property owner, or alternatively must include independent verification. The development of the inventory plan was agreed to by the LLNL Explosives Safety Committee in conjunction with the LLNL Property and Business Division Leader. The LLNL Explosive Materials Inventory Plan was reviewed and approved by the DOE Explosives Safety Committee Chair on May 17, 2023 and by the NNSA Property Management Office on May 25, 2023.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

3D Time-Lapse Electrical Resistivity Imaging of Rock Damage Patterns and Gas Flow Paths Resulting from Two Underground Chemical Explosions

Abstract Rock damage from underground nuclear explosions (UNEs) has a strong influence on sub-surface gas movement and on seismic waveform characteristics, both of which are used to detect UNEs. Although advanced numerical simulation capabilities exist to predict rock damage patterns and corresponding detection signals, those predictions are dependent on (generally) unknown properties of the host rock. For example, the effects of in-situ mechanical heterogeneities on the explosively generated damage/fractures that provide gas flow pathways to the surface are not well understood, due largely to the difficulty in accessing and characterizing the near-source region. In this paper we demonstrate the emerging use of electrical resistivity tomography (ERT) for imaging rock damage and gas flow patterns resulting from two relatively small-scale underground chemical explosions. Pre-explosion ERT and crosshole seismic imaging revealed a natural fracture zone within the test bed. Post-explosion imaging revealed that the damage zone was non-symmetric and was focused primarily within the pre-existing fracture zone, located 10 m above the first explosion and 5 m above the second explosion. Time-lapse ERT imaging of heated air injected into the detonation borehole revealed the primary gas flow paths to be within the upper margin of the same primary damage zone. These results point to the utility of ERT imaging for understanding rock damage and gas flow patterns under experimental conditions, and to the importance of understanding the effects of geologic heterogeneity on UNE detection signals, particularly gas surface breakthrough times.

58 GEOSCIENCES↗

An updated technique to obtain explosive kinetics data on microsecond timescales

There are few techniques available for chemists to obtain time-to-explosion data with known temperature inputs at the early stages of the design and synthesis of new explosives. In the 1960s, a technique was developed to rapidly heat milligram-quantities of confined explosives to ~1000 K on microsecond timescales. Wenograd loaded explosives inside stainless steel hypodermic needles, connected them to a fireset and rapidly discharged a capacitor through the steel. He obtained the temperature by measuring the needle resistance in a Wheatstone bridge arrangement and the time to explosion from a needle rupture. However, owing to the narrow-gauge needles used in the original research, the experiment was only possible with melt-castable explosives; it was never replicated, and modern diagnostics are now available with advances beyond the 1960s. Here, we report the development of the High Explosives Initiation Time (HEIT) test, which utilizes a 250 J pulsed power system to heat the needles. This work extends the Wenograd approach by using optical diagnostics, computational modeling, and advanced techniques to measure needle resistance and needle rupture. Preliminary rate information for pentaerythritol tetranitrate (PETN) will be presented.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

High-Fidelity Mock Development for the Insensitive High Explosive TATB

Due to the violent reaction potential of high explosives, in tests where a reaction is not desired, it can be safe and convenient to use an inert mock that can mimic relevant properties of the associated explosive. Use of mock materials is well-established in explosives work, but most existing mocks are generally meant to mimic only one or two properties of a given explosive, potentially failing to match the explosive in other critical ways. Recently, there has been interest in developing robust thermomechanical mocks for many common explosives. Here, eleven materials are systematically chosen and investigated as potential thermomechanical mocks for TATB, the explosive component of PBX 9502. DSC, nanoindentation, and compression testing are used to narrow down to most appropriate mocks and identify their advantages and limitations. Hardness and elastic modulus are reported for the first time for the molecular crystals iodoanthranilic acid, hexamine, melamine, and trithiolane dioxide, and the crystal structure is reported for the first time for the molecular crystals iodoanthranilic acid and iodosalicylic acid.

36 MATERIALS SCIENCE↗

Direct measurement of energy loss due to aging effects in the condensed phase explosive PBX 9404

The explosive performance of PBX 9404, a condensed phase explosive with HMX and nitrocellulose reactive ingredients, was evaluated using the detonation cylinder expansion test after it had been naturally aged for over 46 years. Nitrocellulose is known to chemically degrade with age, but the corresponding effect on explosive performance is currently unknown. Two new cylinder tests were fielded with the oldest known PBX 9404 explosive (>46 years) and the data was compared with prior PBX 9404 cylinder test data. A method for comparing wall motion data collected by streak camera and laser interferometry diagnostics was also introduced. Analysis of the cylinder motion indicated that the aged explosive exhibits decreased performance, which varied with cylinder expansion radius and product specific volume. This energy decrement was found to be 0.8% of the total initial explosive energy per decade of age at a product volume of 7.0 cc/g. In conclusion, the measured energy decrement in explosives older than 37 years exceeds the chemical energy content of nitrocellulose, indicating that nitrocellulose decomposition radicals are likely degrading the normally stable HMX molecules during the aging process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Experimental measurement of energy release from an initiating layer in an insensitive explosive

When subjected to a shock of insufficient strength to trigger prompt reaction, heterogenous condensed phase explosives can form regions where significant amounts of the explosive remain unreacted for times much greater than the reaction time of the detonating explosive. This phenomena is observed for the explosive PBX 9502 (95 wt% TATB) both for planar and oblique input shocks. Here, we build on previous results by performing cylinder expansion (CYLEX) tests where the explosive charge is comprised of a faster core of PBX 9501 (95 wt% HMX) inside a slower annulus of PBX 9502. The detonation in the faster PBX 9501 drives an oblique shock into the adjacent PBX 9502, and an annular transverse initiating layer (IL) results. In the test geometry, the IL travels steadily down the length of the test after a short run distance. At radial positions beyond the IL, an annular region of detonating PBX 9502 is observed. Using standard CYLEX test diagnostics, we infer the total energy release of this experiment. By making the assumptions that (1) the combined energy release is comprised of contributions from detonating PBX 9501, detonating PBX 9502, and the IL in the PBX 9502 and (2) mass-specific energy release for the detonating explosives is approximately the same as typically observed for each explosive, the IL energy release and reaction efficiency can be computed. Results are compared to prior results for a similar geometry, and indicate that while shock deadened PBX 9502 does not detonate promptly, it does eventually release a significant portion of its chemical potential energy over longer timescales on the order of 10 µs.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A novel reversible fluorescent probe for the highly sensitive detection of nitro and peroxide organic explosives using electrospun BaWO 4 nanofibers

Fabrication of highly stable, reversible, and efficient portable sensors for the detection of explosives for safety and security is challenging due to the robustness of the currently available detection tools, limiting their mass deployment to the explosion prone areas. This paper reports a new direction towards the sensing of nitro- and peroxide-based explosives using highly stable rare-earth-doped BaWO 4 nanofibers with remarkable sensitivity and reversibility. Here, BaWO 4 nanofibers doped with Tb 3+ and Eu 3+ ions are fabricated through a sol–gel electrospinning process, and their emission characteristics and application as a fluorescent probe for the sensing of 2-nitrotoluene and H 2 O 2 , explosive taggants representing a broad class of explosives, are studied in detail. Scheelite structured BaWO 4 nanofibers exhibit excellent luminescence characteristics, and the rare-earth ion doping in the polycrystalline BaWO 4 nanofibers is tailored to achieve blue, green, red, and white light emissions. These nanofibers are extremely sensitive to 2-nitrotoluene and H 2 O 2 with rapid response time, and sensitivity is observed within the range of 1–400 ppb and 1–10 ppm, towards 2-nitrotoluene and H 2 O 2 , respectively. The fluorescence quenching of BaWO 4 nanofibers in the presence of 2-nitrotoluene and H 2 O 2 is exponential with the quenching constants up to 1.73 × 10 6 and 2.73 × 10 4 L mol –1 , respectively, which are significantly higher than those of most of the fluorescent probes based on metal–organic frameworks and conjugated organic materials. After exposing to 2-nitrotoluene, the luminescence of the nanofibers is retained completely upon heating at 120 °C for 10 min and the sensory response is retained as fresh nanofibers, and currently available fluorescent explosive sensors could not achieve such a recovery. The high sensitivity and selectivity of scalable rare-earth-doped BaWO 4 nanofibers provide a new platform for the simultaneous detection of two classes of explosives.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Progenitors and explosion properties of supernova remnants hosting central compact objects: II. A global systematic study with a comparison to nucleosynthesis models

ABSTRACT Core-collapse explosions of massive stars leave behind neutron stars, with a known diversity that includes the ‘Central Compact Objects’ (CCOs). Typified by the neutron star discovered near the centre of the Cas A supernova remnant (SNR), CCOs have been observed to shine only in X-rays. To address their supernova progenitors, we perform a systematic study of SNRs that contain a CCO and display X-ray emission from their shock-heated ejecta. We make use of X-ray data primarily using the Chandra X-ray observatory, complemented with XMM–Newton. This study uses a systematic approach to the analysis of each SNR aimed at addressing the supernova progenitor as well as the explosion properties (energy and ambient density). After fitting for the ejecta abundances estimated from a spatially resolved spectroscopic study, we compare the data to six nucleosynthesis models making predictions on supernova ejecta yields in core-collapse explosions. We find that the explosion models commonly used by the astrophysics community do not match the ejecta yields for any of the SNRs, suggesting additional physics, for example multidimensional explosion models or updated progenitor structures, are required. Overall we find low-mass (≤25 solar masses) progenitors among the massive stars population and low-energy explosions (<1051 ergs). We discuss degeneracies in our model fitting, particularly how altering the explosion energy affects the estimate of the progenitor mass. Our systematic study highlights the need for improving on the theoretical models for nucleosynthesis predictions as well as for sensitive, high-resolution spectroscopy observations to be acquired with next generation X-ray missions.

79 ASTRONOMY AND ASTROPHYSICS↗

Neutrino heating in 1D, 2D, and 3D core-collapse supernovae: characterizing the explosion of high-compactness stars

Massive stars can end their lives with a successful supernova explosion (leaving behind a neutron star or, more rarely, a black hole), or a failed explosion that leaves behind a black hole. The density structure of the pre-collapse progenitor star already encodes much of the information regarding the outcome and properties of the explosion. However, the complexity of the collapse and subsequent shock expansion phases prevents drawing a straightforward connection between the pre-collapse and post-explosion properties. In order to derive such a connection several explodability studies have been performed in recent years. However, different studies can predict different explosion outcomes. In this article, we show how compactness, which is related to the average density of the star’s core, has an important role in determining the efficiency of neutrino heating, and therefore the outcome of the explosion. Commonly, high-compactness progenitors are assumed to yield failed explosions, due to their large mass accretion rates, preventing the shock from expanding. We show by analysing ~150 2D flash and F ornax simulations and 20 3D F ornax simulations that this is not the case. Instead, due to the rapid increase of neutrino heating with compactness, high-compactness progenitors lead to successful shock revival. We also show that 1D+ simulations that include v-driven convection using a mixing-length theory approach correctly reproduce this trend. Finally, we compare 1D+ models, which we show can reproduce some aspects of multi-D simulations with reasonable accuracy, with other widely used 1D models in the literature.

neutrinos↗

The overarching framework of core-collapse supernova explosions as revealed by 3D fornax simulations

We have conducted 19 state-of-the-art 3D core-collapse supernova simulations spanning a broad range of progenitor masses. This is the largest collection of sophisticated 3D supernova simulations ever performed. We have found that while the majority of these models explode, not all do, and that even models in the middle of the available progenitor mass range may be less explodable. This does not mean that those models for which we did not witness explosion would not explode in Nature, but that they are less prone to explosion than others. One consequence is that the ‘compactness’ measure is not a metric for explodability. We find that lower-mass massive star progenitors likely experience lower-energy explosions, while the higher-mass massive stars likely experience higher-energy explosions. Moreover, most 3D explosions have a dominant dipole morphology, have a pinched, wasp-waist structure, and experience simultaneous accretion and explosion. We reproduce the general range of residual neutron-star masses inferred for the galactic neutron-star population. The most massive progenitor models, however, in particular vis à vis explosion energy, need to be continued for longer physical times to asymptote to their final states. We find that while the majority of the inner ejecta have Ye = 0.5, there is a substantial proton-rich tail. This result has important implications for the nucleosynthetic yields as a function of progenitor. Finally, we find that the non-exploding models eventually evolve into compact inner configurations that experience a quasi-periodic spiral SASI mode. We otherwise see little evidence of the SASI in the exploding models.

79 ASTRONOMY AND ASTROPHYSICS↗

Complex surface topographic changes from explosive experiments at the Dry Alluvium Geology site, southern Nevada, United States

Understanding the surface topographic change that results from underground explosions is important for global security. Current techniques to relate the surface change to underground explosion characteristics usually involve assuming the earth has homogenous properties, leading to highly variable interpretations. Here we use an unoccupied aerial platform and a digital single lens reflex camera along with 200+ ground control points surveyed with a real-time kinematic global navigation satellite system to measure the surface topographic change resulting from two underground explosions at the Dry Alluvium Geology site in Yucca Flat, Nevada National Security Site, southern Nevada, United States. We find areas of 5–7 cm of subsidence that are not directly above the explosion source but rather 200–300 m away. For experiment DAG2, this zone is located south and west of the explosion, while for DAG4, there is a zone of subsidence located northeast of the explosion. In addition, late-time measurements show as much as 5 cm of horizontal change without measurable associated vertical change in the weeks following DAG4 but not DAG2. These indicate that the deformation resulting from underground chemical explosions can be very complex and bear little to no resemblance to predictions using half-space models. It is likely the tectonic environment plays a significant role in controlling the surface change, but the details are not fully understood.

58 GEOSCIENCES↗

Initiation Thresholds and Dynamic Characteristics of an Explosion for Thin Samples of PETN-Al Composites under Laser Irradiation

In this paper, we measured thresholds H{sub cr} of explosive decomposition of thin (h = 1 mm) samples of PETN-Al composites with densities in the range of ρ = 0.9–1.7 g/cm{sup 3} and variations in the concentration of aluminum inclusions in the range of 0.025–1.0 wt % upon exposure to pulses of a neodymium laser (λ = 1064 nm, 14 ns). For each ρ, inclusion concentrations n{sub opt}, at which the threshold for explosive decomposition of H{sub cr} is minimal, are obtained. The velocities of air shock waves (ASWs) were determined depending on sample density ρ, and the times of the start of explosive decomposition were determined depending on the inclusion concentration. The amplitude (in relative units) and time shift of the maximal pressure of an ASW at the piezodetector are determined depending on sample density. It is concluded that the explosion is governed by the SW mechanism at high densities. As sample ρ decreases, the completeness of the explosion increases, with the most likely mechanism for small ρ being explosive burning. The efficiency of explosive decomposition is higher for samples with lower densities.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Near-Field Imaging of Shallow Chemical Explosions in Granite Using Change Detection Methods with Surface and Borehole Seismic Data

Explosions detonated in geologic media damage it in various ways via processes that include vaporization, fracturing, crushing of interstitial pores, etc. Seismic waves interact with the altered media in ways that could be important to the discrimination, characterization, and location of the explosions. As part of the Source Physics Experiment, we acquired multiple pre- and post-explosion near-field seismic datasets and analyzed changes to seismic P-wave velocity. Our results indicate that the first explosion detonated in an intact media can cause fracturing and, consequently, a decrease in P-wave velocity. After the first explosion, subsequent detonations in the pre-damaged media have limited discernible effects. We hypothesize this is due to the stress-relief provided by a now pre-existing network of fractures into which gasses produced by the explosion migrate. We also see an overall increase in velocity of the damaged region over time, either due to a slow healing process or closing of the fractures by subsequent explosions.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Measurements of the Dielectric Properties of Thin High-Explosive Samples Using a Parallel Plate Test Fixture

This report presents results of a study of the dielectric properties of several high explosive materials, including Composition B, C-4, Detasheet, Semtex 1A, Semtex 1H, and Semtex 10. The capacitance and dispersion of samples up to ten mm thick were measured at 24 and 65°C using a parallel plate test fixture. In this configuration, capacitance is proportional to the real component of the complex dielectric constant (or permittivity) of the material, while the dispersion is equal to the imaginary component of the dielectric constant divided by the real component. Measurements were performed at two temperatures to determine whether these dielectric properties might be used to monitor moderate temperature changes within these materials using an external fringing field capacitor. It was found that the real dielectric constant of the high explosives generally changed by only about 1% on heating from 24 to 65°C, and that the externally measured capacitance is therefore not a reliable parameter for monitoring temperature changes in these explosives. Temperature- based changes in the dispersion were often 20% or greater, and for several materials (e.g., Composition B, Detasheet) the temperature and dispersion showed good correlation as the temperature of the explosive was cycled up and down. It is thus possible that for some high explosives the externally measured dispersion is a useful parameter for monitoring temperature changes. However, other factors may limit the usefulness of this technique, including the need to have the plates of a fringing field capacitor in direct contact with the high explosive to obtain measurements, and the limited penetration depth of the fringing field into the explosive material.

36 MATERIALS SCIENCE↗

Dust Formation and Growth in Supernovae Explosions

Dust is a multi-messenger probe able to explore the dynamics of the Supernova Engine. The yield and composition of grains formed in the supernova explosion are dependent on the initial explosion characteristics of the progenitor and on the explosion mechanism. Using dust as a prove, the dynamics of dust formation and growth is modeled in a diverse set of Core-Collapse Supernovae Explosions (CCSNe). The progenitor mass, explosion energy engine type, and composition are varied across 72 models. The explosion is evolved using a 1-D Lagrangian Hydro-dynamical code (hydrocodes) to roughly 3 years. A multigrain nucleation and dust growth model is used to post process the hydrocode results and model grain formation and growth. The results show an earlier onset of grain formation, a larger silicate grain abundance, and smaller grain sizes in high explosion energy models.

79 ASTRONOMY AND ASTROPHYSICS↗