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At least 109 records · Page 6

A purely kinetic description of the evaporation of water droplets

The process of water evaporation, although deeply studied, does not enjoy a kinetic description that captures known physics and can be integrated with other detailed processes such as drying of catalytic membranes embedded in vapor-fed devices and chemical reactions in aerosol whose volumes are changing dynamically. In this work, we present a simple, three-step kinetic model for water evaporation that is based on theory and validated by using well-established thermodynamic models of droplet size as a function of time, temperature, and relative humidity as well as data from time-resolved measurements of evaporating droplet size. Additionally, the kinetic mechanism for evaporation is a combination of two limiting processes occurring in the highly dynamic liquid-vapor interfacial region: direct first order desorption of a single water molecule and desorption resulting from a local fluctuation, described using third order kinetics. The model reproduces data over a range of relative humidities and temperatures only if the interface that separates bulk water from gas phase water has a finite width, consistent with previous experimental and theoretical studies. The influence of droplet cooling during rapid evaporation on the kinetics is discussed; discrepancies between the various models point to the need for additional experimental data to identify their origin.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Direct numerical simulation of turbulent dispersion of evaporative aerosol clouds produced by an intense expiratory event

Airborne particles are a major route for transmission of COVID-19 and many other infectious diseases. When a person talks, sings, coughs, or sneezes, nasal and throat secretions are spewed into the air. After a short initial fragmentation stage, the expelled material is mostly composed of spherical particles of different sizes. While the dynamics of the largest droplets are dominated by gravitational effects, the smaller aerosol particles, mostly transported by means of hydrodynamic drag, form clouds that can remain afloat for long times. In subsaturated air environments, the dependence of pathogen-laden particle dispersion on their size is complicated due to evaporation of the aqueous fraction. Particle dynamics can significantly change when ambient conditions favor rapid evaporation rates that result in a transition from buoyancyto-drag dominated dispersion regimes. To investigate the effect of particle size and evaporation on pathogen-laden cloud evolution, a direct numerical simulation of a mild cough was coupled with an evaporative Lagrangian particle advection model. The results suggest that while the dispersion of cough particles in the tails of the size distribution are unlikely to be disrupted by evaporative effects, preferential aerosol diameters (30-40 μm) may exhibit significant increases in the residence time and horizontal range under typical ambient conditions. Using estimations of the viral concentration in the spewed fluid and the number of ejected particles in a typical respiratory event, we obtained a map of viral load per volume of air at the end of the cough and the number of virus copies per inhalation in the emitter vicinity.

60 APPLIED LIFE SCIENCES↗

Volatile propellant droplet evaporation measurements in metered dose inhaler sprays

Many aerosol products rely on the rapid vaporization of volatile propellants to produce a fine spray. In the simplest case, these are binary mixtures of propellant and a delivered product which undergo a flash-evaporation process leaving only the less volatile product in the resultant droplet. In more complex applications, such as pressurized metered-dose inhalers, the non-propellant component may contain dissolved or suspended drug which precipitates or dries to form a matured particle. The size and morphology of the particles depend strongly on the time-history of the droplet as the propellant evaporates. However, measuring the dynamic evaporation processes that occur in dense sprays containing millions of droplets is challenging. In this paper, we demonstrate a novel application of Ultra Small Angle X-ray Scattering to measure the bulk composition of volatile HFC134a–ethanol sprays and compare the obtained results with simple evaporation models in a dry nitrogen environment. The data reveal that diffusion-limiting processes inside the droplet are equally important as external convection and mixing-limited factors in determining evaporative timescales.

42 ENGINEERING↗

Efficiency Limits of Evaporative Fabric Drying Methods

Cloth drying is a major consumer of energy, and most drying is conducted by evaporative methods. The evaporative drying energy efficiency limit is commonly assumed to be 100%: one unit of latent heat removed per unit of energy expended. However, this ignores the “free drying” available from unsaturated ambient air and the possible role of heat pumping. We demonstrate that efficiency limits for evaporative drying are fundamentally related to both drying rate and ambient psychrometric conditions. A relationship among efficiency, drying rate, and ambient conditions is quantified for several evaporative drying technologies, and a comparison among evaporative technologies is provided. In addition, a comparison is provided between efficiency limits and state of the art device performance. This research will help guide future research in the most promising directions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Factors influencing quantum evaporation of helium from polar semiconductors from first principles

While there is much indirect evidence for the existence of dark matter (DM), to date it has evaded detection. Current efforts focus on DM masses over ~GeV—to push the sensitivity of DM searches to lower masses, new DM targets and detection schemes are needed. In this work, we focus on the latter—a novel detection scheme recently proposed to detect 10–100 meV phonons in polar target materials. Previous work showed that well-motivated models of DM can interact with polar semiconductors to produce an athermal population of phonons. This new sensing scheme proposes that these phonons then facilitate quantum evaporation of 3 He from a van der Waals film deposited on the target material. However, a fundamental understanding of the underlying process is still unclear, with several uncertainties related to the precise rate of evaporation and how it can be controlled. In this work, we use ab initio density functional theory calculations to compare the adsorption energies of helium atoms on a polar target material, sodium iodide, to understand the underlying evaporation physics. We explore the role of surface termination, monolayer coverage, and elemental species on the rate of He evaporation from the target material. Using this, we discuss the optimal target features for He-evaporation experiments and their range of tunability through chemical and physical modifications such as applied field and surface termination.

36 MATERIALS SCIENCE↗

Psychrometric Analysis for New NuMI Evaporator Weather Station

Tritium (H-3) is a weakly radioactive isotope of hydrogen and is a byproduct of accelerator operations at Fermi National Accelerator Laboratory (Fermilab). The Neutrinos at the Main Injector (NuMI) target produced tritiated condensate exhausted via the MI-65 building evaporators. Re-condensation of tritium evaporate was observed on the MI-65 rooftop, on nearby buildings, and on the surrounding grounds due to inefficiency of the existing evaporator system. A new evaporator system is being designed to eliminate re-condensation, and psychrometric data (temperature, humidity and dew point) plays a vital role in determining the location of a weather station to control the new evaporator system.

Alvarado-Anderson, Chase↗

Review of Dew Point Evaporative Cooling Technology for Air Conditioning Applications

Indirect evaporative cooling has the potential to significantly improve the natural environment. It follows from a significant reduction in electricity consumption in the hot period, and hence lower operating costs for cooling systems. This paper presents the current state of knowledge and research directions on dew point indirect evaporative cooling. It was found that researchers focus on the development of dew point indirect evaporative coolers (DPIEC) by improving its design, geometry, water distribution, and new porous materials implementation. To evaluate the performance of new types of DPIEC, different methods are used by the scientists. Finally, optimized devices are studied in terms of their performance in different systems, like hybrid and desiccant systems, considering different climate conditions. Potential directions of development of evaporative technologies were indicated, such as increasing the coefficient of performance of solid desiccant evaporative cooling systems, developing novel geometry, and efficient water distribution, including development of porous materials.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Real-World Evaluation of National Energy Efficiency Potential of Cold Storage Evaporator Technology in the Context of Engine Start-Stop Systems

National concerns over energy consumption and emissions from the transportation sector have prompted regulatory agencies to implement aggressive fuel economy targets for light-duty vehicles through the U.S. National Highway Traffic Safety Administration/Environmental Protection Agency (EPA) Corporate Average Fuel Economy (CAFE) program. Automotive manufacturers have responded by bringing competitive technologies to market that maximize efficiency while meeting or exceeding consumer performance and comfort expectations. In a collaborative effort among Toyota Motor Corporation, Argonne National Laboratory (ANL), and the National Renewable Energy Laboratory (NREL), the real-world savings of one such technology is evaluated. A commercially available Toyota Highlander equipped with two-phase cold storage technology was tested at ANL’s chassis dynamometer testing facility. The cold storage technology maintains the thermal state of air-conditioning evaporators to enable longer and more frequent engine-off operation in vehicles equipped with start-stop functionality. Test results were analyzed and provided to NREL where a novel simulation framework was developed and calibrated to the test data. The vehicle model was then exercised over a large set of real-world drive cycle and ambient condition data to estimate national-level fuel economy benefits. Results indicate that the cold storage evaporator provided national fuel consumption reductions of 0.113% relative to a conventional evaporator in the same vehicle. In addition, when the cold storage evaporator engine stop/start was enabled for any temperature and the baseline was limited to the EPA menu, Start and Stop credit assumption of 27°C, a national fuel savings of 0.497% was found. Fuel savings resulted from a combination of extended engine-off duration during idle events and increased frequency of deceleration fuel cutoff, both enabled by the ability of the cold storage evaporator to maintain thermal state in situations where air conditioning is active.

DIRECT ENERGY CONVERSION↗

Evaporation in space manufacturing

'Normal evaporation' equations for predicting the compositional changes with time and temperature have been developed and correlated with actual experimental data. An evaporative congruent temperature is defined and used to explain, predict, or plan space experiments on anomalous constitutional melting (on cooling) or solidification (on heating). Uneven evaporation causes reactive jetting forces capable of initiating new convection currents, nongravitational accelerations, surface vibrations, or other disturbances. Applications of evaporation to space manufacturing are described concerning evaporative purification, surface cooling, specimen selection, particles splitting, freezing data interpretation, material loss and dimensional control, and surface contamination or compositional changes.

Li, C. H.↗

Evaporative winds in X-ray binaries

Evaporation of gas from the surface of HZ Her by Her X-1 and its implications regarding the mass transfer process are examined further. The powerful soft X-ray flux results in an evaporation rate greater than previous estimates. The evaporative flow is shown to be subsonic at first, with the result that the capture of evaporated gas by Her X-1 may be efficient, and the self-excited wind mechanism is possible. A criterion for stabilization of mass transfer by stellar wind mass loss is derived. Possible mechanisms for the long-period variability of HZ Her are discussed. Evaporative winds are also estimated for Sco X-1 and Cyg X-2 spectra.

Basko, M. M.↗

Evaporation of ice in planetary atmospheres: Ice-covered rivers on Mars

The evaporation rate of water ice on the surface of a planet with an atmosphere involves an equilibrium between solar heating and radiative and evaporative cooling of the ice layer. The thickness of the ice is governed principally by the solar flux which penetrates the ice layer and then is conducted back to the surface. Evaporation from the surface is governed by wind and free convection. In the absence of wind, eddy diffusion is caused by the lower density of water vapor in comparison to the density of the Martian atmosphere. For mean martian insolations, the evaporation rate above the ice is approximately 10 to the minus 8th power gm/sq cm/s. Evaporation rates are calculated for a wide range of frictional velocities, atmospheric pressures, and insolations and it seems clear that at least some subset of observed Martian channels may have formed as ice-chocked rivers. Typical equilibrium thicknesses of such ice covers are approximately 10m to 30 m; typical surface temperatures are 210 to 235 K.

Wallace, D.↗

Direct evidence for chromospheric evaporation in a well-observed compact flare

Observations of the solar flare of May 7, 1980 using several Solar Maximum Mission instruments are presented as an investigation of the phenomenon of chromospheric evaporation. The total amount of plasma at temperatures greater than 2 x 10 to the 6th K were determined from the X-ray data, and the amount of plasma that was evaporated from the chromosphere was determined from the H-alpha data. The H-alpha profiles indicate that for the flare as a whole, at the time of peak soft X-ray emission measure, the number of atoms evaporated from the chromosphere was 7 x 10 to the 37th. The soft X-ray emission measure of 1 x 10 to the 49th/cu cm, coupled with the flare volume estimate of 10 to the 26th cu cm, indicates that there were 3 x 10 to the 37th electrons in the soft X-ray plasma with temperatures greater than 2 x 10 to the 6th K. These results indicate that enough material had been evaporated from the chromosphere to account for the X-ray plasma. Taken together, the H-alpha, soft X-ray, and hard X-ray images indicate that chromospheric evaporation is driven both by flare-accelerated electrons during the impulsive phase and by conduction during the thermal phase.

Canfield, R. C.↗

Multi-leg heat pipe evaporator

A multileg heat pipe evaporator facilitates the use and application of a monogroove heat pipe by providing an evaporation section which is compact in area and structurally more compatible with certain heat exchangers or heat input apparatus. The evaporation section of a monogroove heat pipe is formed by a series of parallel legs having a liquid and a vapor channel and a communicating capillary slot therebetween. The liquid and vapor channels and interconnecting capillary slots of the evaporating section are connected to the condensing section of the heat pipe by a manifold connecting liquid and vapor channels of the parallel evaporation section legs with the corresponding liquid and vapor channels of the condensing section.

Alario, J. P.↗

Relating evaporative fraction to remotely sensed data at the FIFE site

Evaporative fractions at surface flux stations on the Konza Prairie are investigated by means of heat-flux estimation, evaporative fractions, and other remotely sensed parameters. Radiometric surface-temperature measurements are used to calculate sensible heat, and evaporative fraction is characterized by comparing systematic differences and consistencies at 21 stations. The evaporative fractions are related to soil and vegetation data collected concurrently with attention given to specific correlations. Little variation is found in the evaporative fraction during the day for the four periods studied, although the most significant change corresponded with the lowest values of soil moisture, leaf-area indices, and simple ratio. Uncertainties in air/surface temperature differences and in small wind speeds affect the reliability of estimates of the surface fluxes.

Gurney, R. J.↗

The dynamics of dense and dilute clusters of drops evaporating in large, coherent vortices

The behavior of evaporating clusters of drops embedded into large, coherent vortices is described using a formulation which is valid for both dense and dilute clusters. Drops and gas interact both dynamically and thermodynamically. Dynamic coupling occurs through a force on the drops due to drag resulting from a slip velocity between the two phases. The net interaction force on the gas with drops is due to a source thrust from evaporation plus drag on each drop. The drag coefficient accounts for blowing from the drop surface. Thermodynamic coupling is a result of drop heating and evaporation. Limitations due to drop proximity on heating and evaporation are taken into account. The vortical motion of the drops in the cluster results in the formation of a core region devoid of drops at the center of the vortex, and a shell region containing the drops and surrounding the inner core. Results are presented showing the dependence of the evaporation time, the final to initial volume ratio and the final to initial shell thickness ratio upon the initial air/fuel mass ratio and as a function of the initial tangential velocities, upon the initial Stokes number, initial drop radius and initial outer cluster radius. Differences in behavior between and control parameters of dense and dilute clusters are pointed out by these new results. It is found that for dense clusters the final to initial volume ratio and final to initial shell thickness scale with the initial Stokes number, a new result which must be validated experimentally.

Bellan, J.↗

Application of self-preservation in the diurnal evolution of the surface energy budget to determine daily evaporation

Evaporation from natural land surfaces often exhibits a strong variation during the course of a day, mostly in response to the daily variation of radiative energy input at the surface. This makes it difficult to derive the total daily evaporation, when only one or a few instantaneous estimates of evaporation are available. It is often possible to resolve this difficulty by assuming self-preservation in the diurnal evolution of the surface energy budget. Thus if the relative partition of total incoming energy flux among the different components remains the same, the ratio of latent heat flux and any other flux component can be taken as constant through the day. This concept of constant flux ratios is tested by means of data obtained during the First ISLSCP Field Experiment; the instantaneous evaporation values were calculated by means of the atmospheric boundary layer bulk similarity approach with radiosonde profiles and radiative surface temperatures. Good results were obtained for evaporative flux ratios with available energy flux, with net radiation, and with incoming shortwave radiation.

Brutsaert, Wilfried↗

An Experimental Study of Pressure Oscillation in a Capillary Pumped Loop with Multiple Evaporators and Condensers

The heat transport capability of a capillary pumped loop (CPL) is limited by the pressure drop that its evaporator wick can sustain. The pressure drop in a CPL is not constant even under seemingly steady operation, but rather exhibits an oscillatory behavior. A hydrodynamic theory based on a mass-spring-dashpot model was previously developed to predict the pressure oscillation in a CPL with a single evaporator and a single condenser. The theory states that the pressure oscillation is a function of physical dimensions of the CPL components and operating conditions. Experimental data agreed very well with theoretical predictions. The hydrodynamic stability theory has recently been extended to predict the pressure oscillations in CPLs with multiple evaporators and multiple condensers. Concurrently, an experimental study was conducted to verify the theory and to investigate the effects of various parameters on the pressure oscillation. Four evaporators with different wick properties were tested using a test loop containing two condenser plates. The test loop allowed the four evaporators to be tested in a single-pump, two-pump or four-pump configuration, and the two condenser plates to be plumbed either in parallel or in series. Test conditions included varying the power input, the reservoir set point temperature, the condenser sink temperature, and the flow resistance between the reservoir and the loop. Experimental results agreed well with theoretical predictions.

Ku, Jen-Tung↗

Evaporative Cooling Membrane Device

An evaporative cooling membrane device is disclosed having a flat or pleated plate housing with an enclosed bottom and an exposed top that is covered with at least one sheet of hydrophobic porous material having a thin thickness so as to serve as a membrane. The hydrophobic porous material has pores with predetermined dimensions so as to resist any fluid in its liquid state from passing therethrough but to allow passage of the fluid in its vapor state, thereby, causing the evaporation of the fluid and the cooling of the remaining fluid. The fluid has a predetermined flow rate. The evaporative cooling membrane device has a channel which is sized in cooperation with the predetermined flow rate of the fluid so as to produce laminar flow therein. The evaporative cooling membrane device provides for the convenient control of the evaporation rates of the circulating fluid by adjusting the flow rates of the laminar flowing fluid.

Lomax, Curtis↗