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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
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NASA NTRS1990

Explosive nucleosynthesis in SN 1987A. II - Composition, radioactivities, and the neutron star mass

The 20 solar mass model of Nomoto and Hashimoto (1988) is utilized with a 6 solar mass. He core is used to perform explosive nucleosynthesis calculations. The employed explosion energy of 10 to the 51st ergs lies within the uncertainty range inferred from the bolometric light curve. The nucleosynthesis processes and their burning products are discussed in detail. The results are compared with abundances from IR observations of SN 1987A and the average nucleosynthesis expected for Type II supernovae in Galactic chemical evolution. The abundances of long-lived radioactive nuclei and their importance for the late light curve and gamma-ray observations are predicted. The position of the mass cut between the neutron star and the ejecta is deduced from the total amount of ejected Ni-56. This requires a neutron star with a baryonic mass of 1.6 + or - 0.045 solar mass, which corresponds to a gravitational mass of 1.43 + or - 0.05 solar mass after subtracting the binding energy of a nonrotating neutron star.

Thielemann, Friedrich-Karl↗
NASA NTRS1992

Analysis of the photospheric epoch spectra of type 1a supernovae SN 1990N and SN 1991T

This paper presents an LTE analysis of the photospheric epoch optical and IUE UV spectra of the recent Type Ia supernovae SN 1990N and SN 1991T. It is found that SN 1990N has matter moving as fast as 40,000 km/s, while SN 1991T has matter moving as fast as 20,000 km/s. The exponential density profile with e-folding velocity of 3160 km/s suggested by deflation and delayed/late-detonation explosion models is adequate for calculating fits to the observed spectra. Findings on the iron peak elements suggest that in both SNe some nuclear burning continues into the outer ejecta or the newly synthesized elements are mixed into the outer ejecta. The observed spectra of SN 1990N are consistent with a composition of the inner envelope like that of model W7. Intermediate-mass elements with abundances higher than solar are probably in the outer ejecta of both SNe, while silicon, sulfur, and calcium are underabundance in SN 1991T relative to SN 1990N by factors of order 3, 3, and 120, respectively.

Jeffery, David J.↗
DOE OSTI2025

The occurrence and impact of carbon-oxygen shell mergers in massive stars

In their final stages before undergoing a core-collapse supernova, massive stars may experience mergers between internal shells where carbon (C) and oxygen (O) are consumed as fuels for nuclear burning. This interaction, known as a C-O shell merger, can dramatically alter the internal structure of the star, leading to peculiar nucleosynthesis and potentially influencing the supernova explosion and the propagation of the subsequent supernova shock. Our understanding of the frequency and consequences of C-O shell mergers remains limited. This study aims to identify, for the first time, early diagnostics in the stellar structure that lead to C-O shell mergers in more advanced stages. We also assess their role in shaping the chemical abundances in the most metal poor stars of the Galaxy. We analyzed a set of 209 stellar evolution models available in the literature, with different initial progenitor masses and metallicities. We then compared the nucleosynthetic yields from a subset of these models with the abundances of odd-Z elements in metal-poor stars. We find that the occurrence of C-O shell mergers in stellar models can be predicted with a good approximation based on the outcomes of the central He burning phase, specifically, from the CO core mass (M CO ) and the 12 C central mass fraction (X C12 ): 90% of models with a C-O merger have X C12 <0.277 and M CO <4.90 M ⊙ , with average values of M CO = 4.02 M ⊙ and X C12 = 0.176. The quantities X C12 and M CO are indirectly affected from several stellar properties, including the initial stellar mass and metallicity. Additionally, we confirm that the Sc-rich and K-rich yields from models with C-O mergers would solve the long-standing underproduction of these elements in massive stars. Our results emphasize the crucial role of C-O shell mergers in enriching the interstellar medium, particularly in the production of odd-Z elements. This highlights the necessity of further investigations to refine their influence on presupernova stellar properties and their broader impact on Galactic chemical evolution.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1939

The Influence of Directed Air Flow on Combustion in Spark-Ignition Engine

The air movement within the cylinder of the NACA combustion apparatus was regulated by using shrouded inlet valves and by fairing the inlet passage. Rates of combustion were determined at different inlet-air velocities with the engine speed maintained constant and at different engine speeds with the inlet-air velocity maintained approximately constant. The rate of combustion increased when the engine speed was doubled without changing the inlet-air velocity; the observed increase was about the same as the increase in the rate of combustion obtained by doubling the inlet-air velocity without changing the engine speed. Certain types of directed air movement gave great improvement in the reproducibility of the explosions from cycle to cycle, provided that other variables were controlled. Directing the inlet air past the injection valve during injection increased the rate of burning.

Rothrock, A M↗
DOE OSTI2025

NFPA Distributed Energy Resources Safety Training (DERST) For Emergency Responders

The National Fire Protection Association, with support from the Department of Energy, executed a multi-year initiative to develop, enhance, and disseminate Distributed Energy Resources Safety Training (DERST) tools for U.S. emergency responders. As Distributed Energy Resources (DER)—such as solar photovoltaics, battery energy storage systems (ESS), electric vehicles (EVs), and associated infrastructure—become increasingly prevalent, the NFPA identified a critical need for up-to-date standardized, accessible, and effective safety training tailored for the fire service and related public safety professionals. The project delivered a comprehensive suite of educational resources to improve responders’ abilities to safely manage DER-related incidents. This included: • Revised Modular Training Courses: Updated classroom-based DER safety courses, now modular and accessible nationwide through fire academies and the North American Fire Training Directors (NAFTD) network. • Live Burn Testing & Research: A full-scale controlled burn of a DER-equipped residential structure provided real-world data and insights, forming the basis for updated best practices. • A Gamified Simulation Tool – Firefighters Incident Response Simulation Tool (FIRST): A first-of-its-kind, multiplayer, scenario-based simulation using the Unreal Engine 5.0 to train responders in a realistic virtual, multi-DER incident environment. • Field Familiarization Software Tools & Prop Guide: Digital DER field familiarization evolutions software guide and a prop development manual to support field-based DER training exercises, enhancing responders' hands-on familiarity with DER infrastructure and collaboration on virtual incident responses. • National Dissemination Strategy: Strategic partnerships with NAFTD, Vector Solutions, and others enabled wide-scale distribution, with over 5,000 departments accessing resources and 1,100+ departments adopting the simulator in the first seven months. Also provided a web portal for easy access to all training and simulation programs developed under this grant for the U.S. responder community. Key findings from the project—particularly from the burn test—led to paradigm shifts in fire response tactics. For example, traditional approaches to garage fires may be hazardous if DERs are present, due to explosive off gassing and thermal runaway risks. The new training emphasizes scene assessment, stand-off approaches, thermal imaging verification, and careful post-incident cooling of DER components to prevent reignition. This initiative has had a significant national impact, raising awareness, enhancing preparedness, and supporting safer DER incident response practices. Significant engagement from the media, public safety organizations, and PBS coverage has further amplified the reach and adoption of NFPA’s DER safety training, tools, and simulations.

14 SOLAR ENERGY↗
NASA NTRS1980

Numerical calculation of shock-induced initiation of detonations

Results of numerical calculations of the impact of steel cylinders and spheres on the plastic bonded high explosive PBX 9501 are described. The calculations were carried out by a reactive, multicomponent, two dimensional, Eulerian hydrodynamic computer code, 2DE. The 2DE computer code is a finite difference code that uses the donor acceptor cell method to compute mixed cell fluxes. The parameters in the Forest Fire burn model are developed from experiments where the induced shock approximates a plane wave and are applied, in this case, to a situation where the induced shock is a divergent wave with curvature that depends on the size and shape of the projectile. The calculated results are compared with results from experiments involving instrumented mock and live high explosives, with projectiles of varying size, shapes, and velocities.

Cort, G. E.↗
NASA NTRS1999

Environmental Conditions and Threatened and Endangered Species Populations near the Titain, Atlas, and Delta Launch Complexes, Cape Canaveral Air Station

Launches of Delta, Atlas, and Titan rockets from Cape Canaveral Air Station (CCAS) have potential environmental effects. These could occur from direct impacts of launches or indirectly from habitat alterations. This report summarizes a three-year study (1995-1998) characterizing the environment, with particular attention to threatened and endangered species, near Delta, Atlas, and Titan launch facilities. Cape Canaveral has been modified by Air Force development and by 50 years of fire suppression. The dominant vegetation type around the Delta and Atlas launch complexes is coastal oak hammock forest. Oak scrub is the predominant upland vegetation type near the Titan launch complexes. Compositionally, these are coastal scrub communities that has been unburned for greater than 40 years and have developed into closed canopy, low-stature forests. Herbaceous vegetation around active and inactive facilities, coastal strand and dune vegetation near the Atlantic Ocean, and exotic vegetation in disturbed areas are common. Marsh and estuarine vegetation is most common west of the Titan complexes. Launch effects to vegetation include scorch, acid, and particulate deposition. Discernable, cumulative effects are limited to small areas near the launch complexes. Water quality samples were collected at the Titan, Atlas, and Delta launch complexes in September 1995 (wet season) and January 1996 (dry season). Samples were analyzed for heavy metals, chloride, total organic carbon, calcium, iron, magnesium, sodium, total alkalinity, pH, and conductivity. Differences between fresh, brackish, and saline surface waters were evident. The natural buffering capacity of the environment surrounding the CCAS launch complexes is adequate for neutralizing acid deposition in rainfall and launch deposition. Populations of the Florida Scrub-Jay (Aphelocoma coerulescens), a Federally- listed, threatened species, reside near the launch complexes. Thirty-seven to forty-one scrub-jay territories were located at Titan, Atlas, and Delta launch complexes between 1995 and 1997. No direct impacts to scrub-jays were observed as a result of normal launches. The explosion of the Delta rocket in January 1997 caused direct impacts to the habitat of several scrub-jays families, from fire and debris; however, no scrub-jay mortality was observed. Mortality exceeded reproductive output at all areas over the course of the study. Populations of the southeastern beach mouse (Peromyscus polionotus niveiventris) populations, a Federally listed, threatened species, reside near all the launch complexes. Hurricane Erin and several other tropical storms impacted several areas at the inception of the study in 1995 causing coastal habitat alterations as a result of salt-water intrusion. Both the habitat and the beach mice populations recovered during the course of the study. No direct impacts to southeastern beach mice were observed as a result of normal launch operations. Direct impacts were observed to the habitat as a result of the explosion of the Delta rocket in January 1997. This alteration of the habitant resulted in a shift in use with the mice moving on to the newly burned part of the site. Waterbirds use wetlands and aquatic systems near the launch complexes. Species include the Federally-listed, endangered Wood Stork (Mycteria americana) and several state-listed species of special concern including the Snowy Egret (Egretta thula thula), Reddish Egret (Egretta rufescens rufescens), White Ibis (Eudocimus albus), Roseate Spoonbill (Ajaia ajaja), Tricolored Heron (Egretta tricolor ruficolis), and Little Blue Heron (Egretta caerulea). No impacts to these populations resulting from any launch operations were observed. Gopher tortoises (Gopherus polyphemus) also occur around the launch complexes. Most of those observed appeared to be in good condition; however, upper respiratory tract disease is known to occur in the population. Cape Canaveral Air Station, including areas near active launch complexes, remains important habitat for a variety of native plants and animals including threatened and endangered species. Direct negative effects of current launch systems appear limited. Additional monitoring of these populations and habitats is required to determine if subtle, long-term changes are occurring, to determine if new launch systems and facilities cause other effects, and to determine the effects of habitat restoration and management.

Oddy, Donna M.↗
NASA NTRS1999

Environmental Conditions and Threatened and Endangered Species Populations near the Titan, Atlas, and Delta Launch Complexes, Cape Canaveral Air Station

Launches of Delta, Atlas, and Titan rockets from Cape Canaveral Air Station (CCAS) have potential environmental effects. These could occur from direct impacts of launches or indirectly from habitat alterations. This report summarizes a three-year study (1 995-1 998) characterizing the environment, with particular attention to threatened and endangered species, near Delta, Atlas, and Titan launch facilities. Cape Canaveral has been modified by Air Force development and by 50 years of fire suppression. The dominant vegetation type around the Delta and Atlas launch complexes is coastal oak hammock forest. Oak scrub is the predominant upland vegetation type near the Titan launch complexes. Compositionally, these are coastal scrub communities that has been unburned for > 40 years and have developed into closed canopy, low-stature forests. Herbaceous vegetation around active and inactive facilities, coastal strand and dune vegetation near the Atlantic Ocean, and exotic vegetation in disturbed areas are common. Marsh and estuarine vegetation is most common west of the Titan complexes. Launch effects to vegetation include scorch, acid, and particulate deposition. Discernable, cumulative effects are limited to small areas near the launch complexes. Water quality samples were collected at the Titan, Atlas, and Delta launch complexes in September 1995 (wet season) and January 1996 (dry season). Samples were analyzed for heavy metals, chloride, total organic carbon, calcium, iron, magnesium, sodium, total alkalinity, pH, and conductivity. Differences between fresh, brackish, and saline surface waters were evident. The natural buffering capacity of the environment surrounding the CCAS launch complexes is adequate for neutralizing acid deposition in rainfall and launch deposition. Populations of the Florida Scrub-Jay (Aphelocoma coerulescens), a Federally-listed, threatened species, reside near the launch complexes. Thirty-seven to forty-one scrub-jay territories were located at Titan, Atlas, and Delta launch complexes between 1995 and 1997. No direct impacts to scrub-jays were observed as a result of normal launches. The explosion of the Delta rocket in January 1997 caused direct impacts to the habitat of several scrub-jays families, from fire and debris; however, no scrub-jay mortality was observed. Mortality exceeded reproductive output at all areas over the course of the study. Populations of the southeastern beach mouse (Peromyscus polionotus niveiventris) populations, a Federally listed, threatened species, reside near all the launch complexes. Hurricane Erin and several other tropical storms impacted several areas at the inception of the study in 1995 causing coastal habitat alterations as a result of salt-water intrusion. Both the habitat and the beach mice populations recovered during the course of the study. No direct impacts to southeastern beach mice were observed as a result of normal launch operations. Direct impacts were observed to the habitat as a result of the explosion of the Delta rocket in January 1997. This alteration of the habitat resulted in a shift in use with the mice moving on to the newly burned part of the site. Waterbirds use wetlands and aquatic systems near the launch complexes. Species include the Federally-listed, endangered Wood Stork (Mycferia americana) and several state-listed species of special concern including the Snowy Egret (Egretfa thula fhula), Reddish Egret (Egreffa rufescens rufescens), White Ibis (Eudocimus albus), Roseate Spoonbill (Ajaia ajaja), Tricolored Heron (Egreffa tricolor ruficolis), and Little Blue Heron (Egreffa caerulea). No impacts to these populations resulting from any launch operations were observed. Gopher tortoises (Gopherus polyphemus) also occur around the launch complexes. Most of those observed appeared to be in good condition; however, upper respiratory tract disease is known to occur in the population. Cape Canaveral Air Station, including areas near active launch colexes, remains important habitat for a variety of native plants and animals including threatened and endangered species. Direct negative effects of current launch systems appear limited. Additional monitoring of these populations and habitats is required to determine if subtle, long-term changes are occurring, to determine if new launch systems and facilities cause other effects, and to determine the effects of habitat restoration and management.

Oddy, Donna M.↗
DOE OSTI2025

Impact of the Latest 22 Ne+ α Reaction Rates on Nucleosynthesis in Massive Stars and Galactic Chemical Evolution

In massive stars (initial mass of ≳9 M ⊙ ), the weak s- (slow neutron capture) process produces elements between Fe and Zr, enriching the Galaxy with these elements through core-collapse supernova explosions. The weak s-process nucleosynthesis is driven by neutrons produced in the 22 Ne(α, n) 25 Mg reaction during convective He core and C shell burning. The yields of heavy elements thus depend on the 22 Ne(α, n) 25 Mg and the competitive 22 Ne(α, γ) 26 Mg reaction rates, which are dominated by several narrow-resonance reactions. While the accuracy of these rates has been under debate for decades, recent experimental efforts, including ours, drastically reduced these uncertainties. In this work, we use a set of 280 massive star nucleosynthesis models calculated using different 22 Ne(α, n) 25 Mg and 22 Ne(α, γ) 26 Mg rates and a galactic chemical evolution (GCE) study to probe their impact on the weak s-process elemental abundances in the Galaxy. The GCE was computed with the OMEGA+ code, using the new sets of stellar yields with different 22 Ne+α rates. From GCE, we find that these rates are causing up to 0.45 dex of variations in the [Cu/Fe], [Ga/Fe], and [Ge/Fe] ratios predicted at solar metallicity. The greatest impact on the stellar nucleosynthesis and GCE results derives from uncertainties in the (α, n) strength (ωγ (α,n) ) of the E x = 11.32 MeV resonance. We show that variations observed in the GCE calculations for weak s-process elements become negligibly smaller than dispersions found in observations once the ωγ (α,n) is accurately determined within the uncertainty of 10%–20% (typically reported experimental errors for the resonance) in future nuclear physics experiments.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1962

Titanium-Oxygen Reactivity Study

A program has been conducted at Astronautics to investigate the likelihood of occurrence of the catastrophic oxidation of titanium alloy sheet under conditions which simulate certain cases of accidental failure of the metal while it is in contact with liquid or gaseous oxygen. Three methods of fracturing the metal were used; they consisted of mechanical puncture, tensile fracture of welded joints, and perforation by very high velocity particles. The results of the tests which have been conducted provide further evidence of the reactivity of titanium with liquid and gaseous oxygen. The evidence indicates that the rapid fracturing of titanium sheet while it is in contact with oxygen initiates the catastrophic oxidation reaction. Initiation occurred when the speed of the fracture was some few feet per second, as in both the drop-weight puncture tests and the static tensile fracture tests of welded joints, as well as when the speed was several thousand feet per second, as in the simulated micrometeoroid penetration tests. The slow propagation of a crack, however, did not initiate the reaction. It may logically be concluded that the localized frictional heat of rapid fracture and/or spontaneous oxidation (exothermic) of minute particles emanating from the fracture cause initiation of the reaction. Under conditions of slow fracture, however, the small heat generated may be adequately dissipated and the reaction is not initiated. A portion of the study conducted consisted of investigating various means by which the reaction might be retarded or prevented. Providing a "barrier" at the titanium-oxygen interface consisting of either aluminum metal or a coating of a petroleum base corrosion inhibitor appeared to be only partially effective in retarding the reaction. The accidental puncturing or similar rupturing of thin-walled pressurized oxygen tanks on missiles and space vehicle will usually constitute loss of function, and may sometimes cause their catastrophic destruction by explosive decompression regardless of the type of material used for their construction. In the case of tanks constructed of titanium alloys the added risk is incurred of catastrophic burning of the tanks. In view of this it is recommended that thin-walled tanks constructed of titanium alloys should not be used to contain liquid or gaseous oxygen.

Chafey, J. E.↗
NASA NTRS1985

r-process nucleosynthesis in dynamic helium-burning environments

The results of an extended examination of r-process nucleosynthesis in helium-burning enviroments are presented. Using newly calculated nuclear rates, dynamical r-process calculations have been made of thermal runaways in helium cores typical of low-mass stars and in the helium zones of stars undergoing supernova explosions. These calculations show that, for a sufficient flux of neutrons produced by the C-13 neutron source, r-process nuclei in solar proportions can be produced. The conditions required for r-process production are found to be 10 to the 20th-10 to the 21st neutrons per cubic centimeter for times of 0.01-0.1 s and neutron number densities in excess of 10 to the 19th per cubic centimeter for times of about 1 s. The amount of C-13 required is found to be exceedingly high - larger than is found to occur in any current stellar evolutionary model. It is thus unlikely that these helium-burning environments are responsible for producing the bulk of the r-process elements seen in the solar system.

Cowan, J. J.↗
NASA NTRS2011

The Main Sequence of Explosive Solar Active Regions: Comparison of Emerging and Mature Active Regions

For mature active regions, an active region s magnetic flux content determines the maximum free energy the active region can have. Most Large flares and CMEs occur in active regions that are near their free-energy limit. Active-region flare power radiated in the GOES 1-8 band increases steeply as the free-energy limit is approached. We infer that the free-energy limit is set by the rate of release of an active region s free magnetic energy by flares, CMEs and coronal heating balancing the maximum rate the Sun can put free energy into the active region s magnetic field. This balance of maximum power results in explosive active regions residing in a "mainsequence" in active-region (flux content, free energy content) phase space, which sequence is analogous to the main sequence of hydrogen-burning stars in (mass, luminosity) phase space.

Falconer, David↗
NASA NTRS1994

Optical Detection Of Flameout In A Combustor

Fuel supply shut down in time to prevent explosion. Optical flameout detector designed to signal control system of facility to cut off supply of fuel into combustion chamber if flame goes out. Combustor which optical flameout detector designed burns methane in air to provide hot gases for 8-ft high-temperature test chamber. Acoustical flameout detector for same combustor described in "Acoustical Detection of Flameout in Combustor" (LAR-14900). Fiber optic probes mounted to fuel-spray bar upstream of flame. No focusing optics used, and probes aimed across flow of gases at spot on combustion chamber wall downstream from spray bar. Arrangement enables flameout detection system to respond quickly to potential loss of flame since it detects movement of flame front away from spray bar face. Overall response time of detection system under 10 milliseconds.

Borg, Stephen E.↗
DOE OSTI2024

Directly driven magnetized fast-ignition targets with steep density gradients for inertial fusion energy

The development of advanced targets capable of achieving ignition with improved energy gain at lower driver energies is one of four key technical challenges to be solved in order to realize economical inertial fusion energy. We report the minimum energy necessary for a small hemispherical mass of fast-ignited high-density deuterium–tritium fuel to explosively ignite a significantly larger hemispherical mass of assembled cold fuel with much lower mass density, both with and without a flux-compressed magnetic field connecting the two regions. With the magnetic field, the burn rate improves, and lower energy states become more effective. The imploded fuel reservoir available in the lower-density, larger-mass region of the steep density gradient determines whether the fusion yield is several hundred MJ or up to a few GJ. We report a case wherein the cold reservoir ignited and produced high gain with the assistance of only ~700 kJ of hotspot yield, an amount that has already been demonstrated as feasible in laboratory experiments using indirect-drive targets.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1993

Carbon and nitrogen in Type 2 supernova diamonds

Abundant diamonds found in meteorites seem either to have condensed within supernova interiors during their expansions and coolings or to have been present around those explosions. Either alternative allows implantation of Xe-HL prior to interstellar mixing. A puzzling feature is the near normalcy of the carbon isotopes, considering that the only C-rich matter, the He-burning shell, is pure C-12 in that region. That last fact has caused many to associate supernova carbon with C-12 carbon, so that its SUNOCONS have been anticipated as very C-12-rich. We show that this expectation is misleading because the C-13-rich regions of Type 2's have been largely overlooked in this thinking. We here follow the idea that the diamonds nucleated in the C-12-rich He shell, the only C-rich site for nucleation, but then attached C-13-rich carbon during turbulent encounters with overlying C-13-rich matter. That is, the initial diamonds continued to grow during the same collisional encounters that cause the Xe-HL implantation. Instead of interacting with the small carbon mass having 13/12 = 0.2 in the upper He zone, however, we have calculated the remnants of the initial H-burning core, which left behind C-13-rich matter as it receded during core hydrogen burning. Howard et al. described why the velocity mixing would be essential to understanding the implantation of both the Xe-H and Xe-L components. Velocity mixing is now known to occur from the X-ray and gamma-ray light curves of supernova 1987A. Using the stellar evolution code developed at Goettingen, we calculated at Clemson the evolution of a grid of massive stars up to the beginning of core He burning. We paid attention to all H-burning reactions throughout the star, to the treatment of both convection and semiconvection, and to the recession of the outer boundary of the convective H-burning core as the star expands toward a larger redder state. This program was to generate a careful map of the CNO isotope distribution as He burning begins. Our result for the 30 solar mass star is shown.

Clayton, Donald D.↗
NASA NTRS1994

Gamma-ray constraints on supernova nucleosynthesis

Gamma-ray spectroscopy holds great promise for probing nucleosynthesis in individual supernova explosions via short-lived radioactivity, and for measuring current global Galactic supernova nucleosynthesis with longer-lived radioactivity. It was somewhat surprising that the former case was realized first for a Type II supernova, when both Co-56 and Co-57 were detected in SN 1987A. These provide unprecedented constraints on models of Type II explosions and nucleosynthesis. Live Al-26 in the Galaxy might come from Type II supernovae, and if it is eventually shown to be so, can constrain massive star evolution, supernova nucleosynthesis, and the Galactic Type II supernova rate. Type Ia supernovae, thought to be thermonuclear explosions, have not yet been detected in gamma-rays. This is somewhat surprising given current models and recent Co-56 detection attempts. Ultimately, gamma-ray measurements can confirm their thermonuclear nature, probe the nuclear burning conditions, and help evaluate their contributions to Galactic nucleosynthesis. Type Ib/c supernovae are poorly understood. Whether they are core collapse or thermonuclear events might be ultimately settled by gamma-ray observations. Depending on details of the nuclear processing, any of these supernova types might contribute to a detectable diffuse glow of Fe-60 gamma-ray lines. Previous attempts at detection have come very close to expected emission levels. Remnants of any type of age less that a few centuries might be detectable as individual spots of Ti-44 gamma-ray line emission. It is in fact quite surprising that previous surveys have not discovered such spots, and the constraints on the combination of nucleosynthesis yields and supernova rates are very interesting. All of these interesting limits and possibilities mean that the next mission, International Gamma-Ray Astrophysics Laboratory (INTEGRAL), if it has sufficient sensitivity, is very likely to lead to the realization of much of the great potential of gamma-ray spectroscopy for understanding supernovae.

Leising, Mark D.↗
DOE OSTI2024

An Ab initio based OH initiated oxidation kinetics of glycerol carbonate: A promising biofuel component

The global energy demand is steadily increasing because of the population explosion and economic growth. Fossil fuels supply around 85 % of global primary energy demand. On one hand, fulfilling the increasing energy demands is a big challenge for the next few decades. On the other hand, the continued burning of fossil fuels leads to higher CO2 emissions, severely impacting global warming. Therefore, the policymakers vow to shift from conventional fuels to renewable resources for economic, environmental, and future energy security reasons. In this context, biofuels from lignocellulosic biomass and/or carbon-neutral fuels produced in the sustainable carbon cycle can close the carbon cycle and reach net zero-carbon emission. Recently, glycerol carbonate has been proposed as a promising fuel or fuel additive for future sustainability. Therefore, we investigated the hydrogen abstraction reactions of glycerol carbonate (GC) by OH radicals using high-level ab initio and variational transition state theory calculations. We mapped out the potential energy surface using the CCSD(T)/cc-pV(D, T)Z//MP2/cc-pVTZ level of theory. Here we used the ab initio parameters to obtain the site-specific rate coefficients by employing the variational transition state theory. We observed that every hydrogen atom in GC displays a unique reactivity with OH radicals. We derived branching ratio of each channel that are difficult to access experimentally. The overall rate coefficients exhibit a strong non-Arrhenius behaviour, which can be represented as: $k^{CVT/SCT}_{ov}$ (T) = 3.39 x 10 -20 x T 2.659 x e$\frac{-750.0 Jmol^{-1}}{RT}$ $\frac{cm^{3}}{molecule s}$ This is the first reported rate data for the glycerol carbonate and OH radicals reaction.

09 BIOMASS FUELS↗
DOE OSTI2024

Present understanding of ignition and gain using indirect-drive inertial confinement fusion target designs on the U.S. National Ignition Facility

For many decades, the running joke in fusion research has been that 'fusion' is thirty years away and always will be. Yet, these past few years we find ourselves in a position where we can now talk about the milestones of burning plasmas, fusion ignition, and target energy gain greater than unity (scientific breakeven) in the past tense. Fusion is no longer a joke! Yet getting to fusion ignition, the tipping-point of thermonuclear instability resulting in an explosive increase in ion thermal temperature and fusion reaction-rate, and scientific breakeven (target gain, $G_{target} =$ fusion yield/deposited laser energy >1, in the laser-driven inertial confinement fusion context) has not been easy. Here, in this publication, we discuss our present understanding of the physics and technological challenges surrounding ignition and Gain as well as highlight some outstanding problems that still need resolution.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗