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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Development of an All-Aqueous Thermally Regenerative Redox Flow Battery to Support Fossil Fuel Assets

Low-temperature thermal energy, a largely untapped resource, holds significant promise for large-scale electrical power generation globally. Various stationary sources, including industrial entities and thermal power plants, emit considerable low-temperature heat that currently remains unutilized. This energy is often overlooked because its low temperature renders it unsuitable for efficient power generation using conventional methods. However, current research is exploring diverse technologies capable of converting low-temperature heat into grid-scale power, aiming to enhance grid efficiency, further decarbonization initiatives, and facilitate a shift toward more decentralized power systems. One such innovative technology is the thermally regenerative battery (TRB), noted for its high power and energy densities compared to similar technologies, positioning it as a potential game-changer in power generation. TRBs integrate two scalable and well-established unit operations: a redox flow battery and a distillation column. This integration suggests that once an effective TRB chemistry is established, the pathway to commercialization could be expedited. The copper-based thermally regenerative ammonia battery (Cu aq -TRAB) stands out as the first TRB that circumvents electrodeposition/dissolution reactions, stabilizing Cu(I) and Cu(II) within the electrolyte and maintaining stability of all electroactive species in an aqueous phase. This stabilization has led to improvements in coulombic efficiency, open circuit potential, and copper solubility, thereby enhancing power density, energy density, and overall energy efficiency. Preliminary tests were conducted to determine the effects of various electrolyte species on the performance metrics of the battery, both theoretically and experimentally. These tests revealed that the solubility of copper in the Cu aq -TRAB electrolyte was constrained by the Cu(I)-NH 3 complex. Adjusting the background electrolyte to 5 M NH4Br and the ligand concentration to 4 M NH 3 enabled the copper concentration to reach a maximum of 0.6 M. This modification led to an estimated theoretical maximum energy density of 9.5 Wh L -1 for the Cu aq -TRAB. Additionally, full cell testing indicated a tradeoff between peak power and energy density with varying copper and ammonia concentrations. Increasing the applied current density during discharge linearly raised the average power output, with a minimal reduction in energy density due to a balance between higher ohmic overpotential and reduced time for undesirable ammonia crossover. Furthermore, a comprehensive numerical sensitivity analysis of the complete Cu aq -TRAB system was performed. This analysis aimed to assess how the battery and the distillation column responded to changes in system input parameters, providing insights into optimal research directions for enhancing system performance. The analysis revealed that at room temperature, battery power was significantly more sensitive to ohmic losses than to mass transfer, with reaction rates having minimal impact. This trend continued even at higher temperatures. Also, the thermal energy required for ammonia separation was studied, showing that increased temperatures generally reduced energy requirements, except in low-pressure scenarios above 65 °C. An investigation into membrane performance in the Cu aq -TRAB was undertaken, given the significant impact of ammonia transport control and ohmic losses on system performance. Various membranes were evaluated to identify key performance metrics. Among the tested membranes, Selemion CMVN exhibited the highest performance, with a peak power density of 84 mW cm -2 and average values of 26 ± 6.8 mW cm -2 for power density and 2.9 Wh L -1 for energy density at an applied current density of 50 mA cm -2 . An economic assessment indicated a levelized cost of storage at $410 per MWh under optimal conditions, highlighting the commercial potential of the Cu aq -TRAB when utilizing cost-effective, readily available materials.

25 ENERGY STORAGE↗
DOE OSTI2024

From Fossil Fuels to Green Mines: Understanding Hydrogen-Shale Interactions for Secure Underground Storage

Hydrogen-powered mining trucks are rapidly gaining traction as a key driver of decarbonization in the mining industry. This surge necessitates a decisive shift towards renewable energy sources, primarily for hydrogen production. However, the inherent intermittency of renewables poses a challenge for continuous operations, demanding efficient storage solutions for hydrogen fuel. Hydrogen, derived from renewables, requires large-scale storage, with underground hydrogen storage (UHS) in depleted oil and gas reservoirs projected to provide this capacity. An impermeable seal (caprock) overlying depleted reservoirs is crucial for preventing leakage and ensuring secure storage. Shale, a potential caprock, has been recognized for its effectiveness in containing natural gas for geological time-periods. This study investigates the impact of hydrogen exposure on the matrix permeability of Marcellus shale, a key factor influencing its sealing capacity. A novel time-resolved approach was employed, measuring matrix permeability after each exposure to understand the dynamic interactions between hydrogen and the shale matrix. Samples were exposed to hydrogen in pressure reactions at realistic reservoir conditions at varying time durations. Preliminary results reveal an initial increase in permeability, while subsequent exposures show a decrease, indicating potential microstructural changes.

08 HYDROGEN↗
DOE OSTI2023

Fossil Fuel Transitions Framework: Case studies of the decision-making process for energy and economic development pathways

The Net Zero World Initiative leverages expertise across U.S. government agencies and the U.S. Department of Energy’s (DOE) national laboratories, in partnership with other governments and philanthropies, to accelerate the decarbonization of global energy systems. This whole-of-government approach supports countries committed to raising their climate ambitions by co-creating and implementing highly tailored, actionable technical and investment strategies that put just and sustainable net-zero solutions within reach. The Net Zero World Initiative enables country partners to harness the convening power and technical expertise of U.S. and international industry, think tanks, and technical institutions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2024

Coupling of the Electricity and Transportation Sectors - Part I: Sector Overviews

“Sector coupling” is a concept that addresses potential designs for the future power industry. Traditionally, the energy sectors, i.e., electricity supply, transport, and industry, have functioned largely independently from one another. Thus, the concept of sector coupling means that the electricity sector would become the central pillar of the energy system, supplying the other sectors – transportation and industry – with energy in various ways, a scheme described by the term “Power-to-X”. This report delves into the ambitious goal set by the United States to achieve net-zero emissions by 2050, with a pivotal milestone of making half of all passenger vehicles sold in America zero-emission by 2030. Central to achieving this objective is the electrification of the transportation sector, resulting in complex interactions between this sector and the electric industry. As electric vehicles become more prevalent, a shift in the dependency on electricity for vehicle charging emerges, alongside a reduction in the electricity demand associated with maintaining the fossil fuel supply chain. Both the electricity and fossil fuel have been identified as critical infrastructure sectors, the transportation sector's historical reliance on fossil fuels, and the mature supply chain supporting them are explored. This study emphasizes the existing sectoral coupling between the electric energy and transportation sectors, extending beyond vehicle charging to essential operations at refineries, pipeline facilities, storage, and fuel extraction. Recognizing the critical dependency of fossil fuel supply chain operations on the electric sector, this research underscores the need for a comprehensive view of the evolving dynamics between the transportation and electric sectors. This study has been split into two segments, Part-I provides an overview of the existing fossil fuel supply chain architecture and the electrical sector. We provide an in-depth analysis of the grid-transportation sectoral coupling, its interactions, the vulnerabilities and essential take-aways that would help us to address them and apply towards an electrified transportation sector in the future. We engaged with stakeholders to understand their expectations in enabling an electrified transportation. We accumulate the understandings from the current fossil fuel-based system in developing a risk matrix, by identifying all the threats and vulnerabilities and how would they apply to both the current and future transportation systems in Part-II of this report.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Four-Stage Multi-Physics Simulations to Assist Temperature Sensor Design for Industrial-Scale Coal-Fired Boiler

The growth of renewable energy sources presents a pressing challenge to the operation and maintenance of existing fossil fuel power plants, given that fossil fuel remains the predominant fuel source, responsible for over 60% of electricity generation in the United States. One of the main concerns within these fossil fuel power plants is the unpredictable failure of boiler tubes, resulting in emergency maintenance with significant economic and societal consequences. A reliable high-temperature sensor is necessary for in situ monitoring of boiler tubes and the safety of fossil fuel power plants. In this study, a comprehensive four-stage multi-physics computational framework is developed to assist the design, optimization installation, and operation of the high-temperature stainless-steel and quartz coaxial cable sensor (SSQ-CCS) for coal-fired boiler applications. With the consideration of various operation conditions, we predict the distributions of flue gas temperatures within coal-fired boilers, the temperature correlation between the boiler tube and SSQ-CCS, and the safety of SSQ-CCS. With the simulation-guided sensor installation plan, the newly designed SSQ-CCSs have been employed for field testing for more than 430 days. The computational framework developed in this work can guide the future operation of coal-fired plants and other power plants for the safety prediction of boiler operations.

42 ENGINEERING↗
DOE OSTI2026

Investigation of O( 3 P) Initiated Oxidation Products of 2,3-Dimethylfuran Using Synchrotron Photoionization

Biofuels are an appealing alternative to augment conventional fossil fuels, given that traditional fossil fuels are finite in nature despite being the highest-consumed energy source. Furans have been studied as potential biofuels due to their renewability, high energy density, and ability to both blend with existing fossil fuels and serve as a stand-alone fuel. Although promising, more research efforts on the combustion of furan-based biofuels are needed. Here, in this study, the oxidation of 2,3-dimethylfuran (2,3-DMF) initiated by O( 3 P) was investigated using vacuum-ultraviolet synchrotron radiation from the Advanced Light Source at the Lawrence Berkeley National Laboratory. The reaction was studied at 550 K and 7 Torr. Major reaction products include 3-methyl-3-buten-2-one, 4,5-dimethyl-3(2H)-furanone, and 3-methyl-4-oxo-2(Z)-pentenal, with 3-methyl-3-buten-2-one being the most abundant.

CBS-QB3↗
DOE OSTI2014

Greenhouse gas emissions from production chain of a cigarette manufacturing industry in Pakistan

This study quantified greenhouse gas (GHG) emissions from the Pakistan Tobacco Company (PTC) production using a life cycle approach. The PTC production chain comprises of two phases: agricultural activities (Phase I) and industrial activities (Phase II). Data related to agricultural and industrial activities of PTC production chain were collected through questionnaire survey from tobacco growers and records from PTC manufacturing units. The results showed that total GHG emissions from PTC production chain were 44,965, 42,875, and 43,839 tCO{sub 2}e respectively in 2009, 2010, and 2011. Among the agricultural activities, firewood burning for tobacco curing accounted for about 3117, 3565, and 3264 tCO{sub 2}e, fertilizer application accounted for 754, 3251, and 4761 tCO{sub 2}e in 2009, 2010, and 2011, respectively. Among the industrial activities, fossil fuels consumption in stationary sources accounted for 15,582, 12,733, and 13,203 tCO{sub 2}e, fossil fuels used in mobile sources contributed to 2693, 3038, and 3260 tCO{sub 2}e, and purchased electricity consumed resulted in 15,177, 13,556, and 11,380 tCO{sub 2}e in 2009, 2010, and 2011, respectively. The GHG emissions related to the transportation of raw materials and processed tobacco amounted to 6800, 6301, and 7317 respectively in 2009, 2010, and 2011. GHG emissions from energy use in the industrial activities constituted the largest emissions (i.e., over 80%) of GHG emissions as PTC relies on fossil fuels and fossil fuel based electrical power in industrial processes. The total emissions of carbon footprint (CFP) from PTC production were 0.647 tCO{sub 2}e per million cigarettes produced in 2009, 0.675 tCO{sub 2}e per million cigarettes in 2010 and 0.59 tCO{sub 2}e per million cigarettes in 2011. Potential strategies for GHG emissions reductions for PTC production chain include energy efficiency, reducing reliance on fossil fuels in non-mobile sources, adoption of renewable fuels including solar energy, energy from crop residues, and promotion of organic fertilizers. - Highlights: • We quantified greenhouse gas (GHG) emissions from the Pakistan Tobacco Company (PTC). • PTC production chain comprises of two phases: agricultural and industrial activities. • GHG emissions accounts to 44,965, 42,875 and 43,839 tCO{sub 2}e in 2009, 2010, and 2011, respectively. • GHG emissions from energy use in the industrial activities constituted the largest emissions i.e. 80%. • Implications for GHG emissions mitigation strategies for PTC are also discussed in detail.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Montana BioDiesel Initiative

This initiative funding helped put Montana State University (MSU) in a position to help lead in the development of biodiesel production strategies. Recent shortages in electrical power and rising gasoline prices have focused much attention on the development of alternative energy sources that will end our dependence on fossil fuels. In addition, as the concern for environmental impact of utilizing fossil fuels increases, effective strategies must be implemented to reduce emissions or the increased regulations imposed on fossil fuel production will cause economic barriers for their use to continue to increase. Biodiesel has been repeatedly promoted as a more environmentally sound and renewable source of fuel and may prove to be a highly viable solution to provide, at the least, a proportion of our energy needs. Currently there are both practical and economic barriers to the implementation of alternative energy however the advent of these technologies is inevitable. Since many of the same strategies for the storage, transport, and utilization of biodiesel are common with that of fossil fuels, the practical barriers for biodiesel are comparatively minimal. Strategies were developed to harness the CO 2 as feedstock to support the growth of biodiesel producing algae. The initiative funding led to the successful funding of highly rated projects in competitive national grant programs in the National Science Foundation and the Department of Energy. This funding put MSU in a key position to develop technologies to utilize the CO 2 rich emissions produced in fossil fuel utilization and assembled world experts concerning the growth characteristics of photosynthetic microorganisms capable of producing biodiesel.

09 BIOMASS FUELS↗
DOE OSTI2016

Effect of Aging and Demand for Reliability Analysis of Degrading Components

According to the U.S Energy Information Administration (EIA), the U.S fossil fuel share of energy consumption in 2015 was 67%. Furthermore, the Ecotricity UK report based on the CIA World Factbook states that with the current rate of consumption of fossil fuels, petroleum would run out by 2052, natural gas by 2060, and coal by 2088. No fossil fuel will remain by the next century. Besides the limited reserves of fossil fuel, massive consumption of fossil fuel also raises concerns about global warming and pollution. Therefore, there has been a growing interest in reducing fossil fuel consumption in the energy structure and in increasing the proportion of clean energy. Renewable energy (e.g. wind, solar) has the potential for distributed generation. However, the availability for renewable energy fluctuates and is uncontrollable. Therefore, additional energy sources need to be coupled with renewable energy to produce a stable electricity generation profile. Nuclear energy can serve this purpose as it is a clean energy source, has low greenhouse gas emission and possesses high power density and baseload power supply with low fuel cost. It is desirable to develop a hybrid energy system that combines both renewable energy and nuclear energy to meet low carbon emission goals and to utilize renewable energy. Such a nuclear hybrid energy system, consisting of different energy subsystems such as nuclear, solar, and wind, involves frequent switching between different energy subsystems. Since the primary loop in a nuclear power plant generates constant heat, the turbine bypass line in the secondary loop is required to switch frequently to meet the gap in the energy demand and that generated by the renewables. The increased usage of the turbine bypass system is considered to be the major difference between a nuclear hybrid energy system and a traditional nuclear power plant. Reliability analysis for designing such a complex system involves both high level fault propagation analysis at the conceptual design stage and low level failure prediction for specific components. The main focus of this summary to derive a degradation model of hardware components which can later help in the high level fault propagation analysis. The degradation model is a low level failure mode model that combines the effects of natural aging and frequent switching. The model can be used for predicting components' failure due to specific failure modes. The results can serve as indicators for conducting repair actions and maintenance to minimize Operation and Maintenance (O and M) costs. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2018

Technoeconomic Evaluation of MEA versus Mixed Amines and a Catalyst System for CO 2 Removal at Near-Commercial Scale at Duke Energy Gibson 3 Plant and Duke Energy Buck NGCC Plant

Carbon emissions in the power sector remains an important goal for both US and Chinese decision makers and industrial leaders. To deeply reduce their greenhouse gas emissions, many utilities are considering carbon capture, utilization, and sequestration (CCUS). CCUS can enable the current fossil fuel infrastructure to be utilized while non-fossil fuel based energy supplies evolve to replace fossil fuels.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2018

Impacts of air pollutants from fire and non-fire emissions on the regional air quality in Southeast Asia

Abstract. Severe haze events in Southeast Asia caused by particulate pollution have become more intense and frequent in recent years. Widespread biomass burning occurrences and particulate pollutants from human activities other than biomass burning play important roles in degrading air quality in Southeast Asia. In this study, numerical simulations have been conducted using the Weather Research and Forecasting (WRF) model coupled with a chemistry component (WRF-Chem) to quantitatively examine the contributions of aerosols emitted from fire (i.e., biomass burning) versus non-fire (including fossil fuel combustion, and road dust, etc.) sources to the degradation of air quality and visibility over Southeast Asia. These simulations cover a time period from 2002 to 2008 and are driven by emissions from (a) fossil fuel burning only, (b) biomass burning only, and (c) both fossil fuel and biomass burning. The model results reveal that 39 % of observed low-visibility days (LVDs) can be explained by either fossil fuel burning or biomass burning emissions alone, a further 20 % by fossil fuel burning alone, a further 8 % by biomass burning alone, and a further 5 % by a combination of fossil fuel burning and biomass burning. Analysis of an 24 h PM 2.5 air quality index (AQI) indicates that the case with coexisting fire and non-fire PM 2.5 can substantially increase the chance of AQI being in the moderate or unhealthy pollution level from 23 to 34 %. The premature mortality in major Southeast Asian cities due to degradation of air quality by particulate pollutants is estimated to increase from ∼ 4110 per year in 2002 to ∼ 6540 per year in 2008. In addition, we demonstrate the importance of certain missing non-fire anthropogenic aerosol sources including anthropogenic fugitive and industrial dusts in causing urban air quality degradation. An experiment of using machine learning algorithms to forecast the occurrence of haze events in Singapore is also explored in this study. All of these results suggest that besides minimizing biomass burning activities, an effective air pollution mitigation policy for Southeast Asia needs to consider controlling emissions from non-fire anthropogenic sources.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Center for Bio-Inspired Solar Fuel Production (BISfuel)

The vast majority of the country’s energy needs are met with fossil fuels in the form of natural gas, coal and oil. The use of these fossil fuels contributes to climate change, the unequal distribution of fossil fuel deposits in the earth leads to geopolitical and economic problems, and eventually, fossil fuels will be exhausted. Thus, a renewable, widely distributed, environmentally benign, and inexpensive substitute large enough to meet the needs of society is required. Solar energy meets these criteria. Solar energy may be converted to electricity by photovoltaics, but the need for a continuous energy supply and high-density energy requirements for transportation necessitate technology for storage of energy from sunlight in a fuel. Cost-effective technologies for solar fuel production do not exist, prompting the need for new fundamental science.

14 SOLAR ENERGY↗
DOE OSTI2017

Impacts of air pollutants from fire and non-fire emissions on the regional air quality in Southeast Asia

Severe haze events in Southeast Asia caused by particulate pollution have become more intense and frequent in recent years, degrading air quality, threatening human health, and interrupting economic and societal activities. Widespread biomass burning activities are a major source of severe haze events in Southeast Asia. On the other hand, particulate pollutants from human activities other than biomass burning also play an important role in degrading air quality in Southeast Asia. In this study, numerical simulations have been conducted using the Weather Research and Forecasting (WRF) model coupled with a chemistry component (WRF-Chem) to quantitatively examine the contributions of aerosols emitted from fire (i.e., biomass burning) versus non-fire (including fossil fuel combustion, road and industrial dust, land use, and land change, etc.) sources to the degradation of air quality and visibility over Southeast Asia. These simulations cover a time period from 2002 to 2008 and were respectively driven by emissions from: (a) fossil fuel burning only, (b) biomass burning only, and (c) both fossil fuel and biomass burning. Across ASEAN 50 cities, these model results reveal that 39 % of observed low visibility days can be explained by either fossil fuel burning or biomass burning emissions alone, a further 20 % by fossil fuel burning alone, a further 8 % by biomass burning alone, and a further 5 % by a combination of fossil fuel burning and biomass burning. The remaining 28 % of observed low visibility days remain unexplained, likely due to emissions sources that have not been accounted for. Further analysis of 24-hr PM 2.5 Air Quality Index (AQI) indicates that comparing to the simulated result of the case with stand-alone non-fire emissions, the case with coexisting fire and non-fire PM 2.5 can substantially increase the chance of AQI being in the moderate or unhealthy pollution level from 23 % to 34 %. The premature mortality among major Southeast Asian cities due to degradation of air quality by particulate pollutants is estimated to increase from ~ 4110 per year in 2002 to ~ 6540 per year in 2008. In addition, we demonstrate the importance of certain missing non-fire anthropogenic aerosol sources including anthropogenic fugitive and industrial dusts in causing urban air quality degradation. An exploratory experiment of using machine learning algorithms to forecasting the occurrence of haze events in Singapore is also demonstrated in this study. All these results suggest that besides minimizing biomass burning activities, an effective air pollution mitigation policy for Southeast Asia needs to consider controlling emissions from non-fire anthropogenic sources.

Lee, Hsiang-He (ORCID:0000000251407324)↗
DOE OSTI2018

The Economic Impacts of High Wind Penetration Scenarios in the United States

The U.S. electric sector is experiencing rapid increases in renewable generation with an expectation of continued growth. We examine the impacts of increased wind electricity on the U.S. economy using a hybrid model that links a detailed electric sector model (the National Renewable Energy Laboratory's Regional Energy Deployment System [ReEDS]) with a computable general equilibrium model of the U.S. economy (the Massachusetts Institute of Technology's U.S. Regional Energy Policy [USREP] model). Increasing wind capacity displaces fossil fuels for electricity generation, which depresses fossil fuel prices and reduces economy-wide CO 2 emissions. Competitive wind deployment in the reference scenario achieves these outcomes with lower electricity prices than a scenario with wind capacity fixed at 2016 levels. Lower fossil fuel and electricity prices benefit low-income households, but the dominant economic impacts are driven by increased electric sector investment and capital returns, which primarily benefit those with higher incomes. Overall, cost-competitive wind provides benefits to the U.S. economy that are initially low but rise beyond 2030 to achieve cumulative welfare and GDP improvements of $110 and $111 billion through 2050. Prescribing additional wind deployment (meeting 35% of demand by 2050) increases post-2030 electricity prices but not more so than keeping wind capacity fixed at 2016 levels. The negative effect of higher prices on welfare, however, is outweighed by higher returns from the additional wind investment. While these changes favor higher income classes, we find economy-wide benefits through 2040. These benefits diminish by 2050, but the cumulative additional gains through 2050, beyond the reference case, are $192 billion in welfare and $150 billion in GDP.

17 WIND ENERGY↗