The investigation of flame spreading over the surface of igniting solid propellants Final summary report
Flame spreading over surface of igniting solid propellants in different gas mixtures at various pressures
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Flame spreading over surface of igniting solid propellants in different gas mixtures at various pressures
Microgravity experiments on flame spread over thermally thick fuels were conducted using foam fuels to obtain low density and thermal conductivity, and thus large spread rate (Sf) compared to dense fuels such as PMMA. This scheme enabled meaningful results to lie obtained even in 2.2 second drop tower experiments. It was found that, in contrast conventional understanding; steady spread can occur over thick fuels in quiescent microgravity environments, especially when a radiatively active diluent gas such as CO2 is employed. This is proposed to be due to radiative transfer from the flame to the fuel surface. Additionally, the transition from thermally thick to thermally thin behavior with decreasing bed thickness is demonstrated.
Flame spreading over igniting surface of double base propellants in high pressure quiescent environment
Flame spreading over igniting solid propellant surface in high pressure oxygen-inert environment
Mechanism by which flame spreads over surface of condensed-phase material in quiescent gaseous environment
Flame spreading over surface of igniting solid rocket propellants at different pressures, and oxygen-nitrogen mixtures
Surface flame spreading characteristics of ICRPG reference composite propellant composed of ammonium perchlorate with polyurethane binder
The present numerical solution for the de Ris (1969) problem of flame-spread over thin condensed fuel in an opposed-flow environment is obtained by reformulating the problem in terms of four nondimensional parameters, while retaining all assumptions of the original theory. While the de Ris theory sees the location of the leading edge and the eigenlocation of the onset of evaporation as identical, this analysis treats the leading edge as part of the solution; the location of the flame leading edge is in this way established to be upstream of the eigenlocation, with significant consequences for the spread rate formula.
The gas-phase combustion of a vertical fuel slab pyrolyzing at a finite rate under downward flame spread conditions is investigated theoretically. The backward boundary layer character of the flow is exploited, and a transformation that shifts the singularity associated with boundary-layer equations to a location, upstream of flame lift-off, where the surface temperature is nearly ambient, is employed. The boundary-layer flow is matched asymptotically for large Grashof number to a potential flow that allows the flow induced by the flame and along the upstream surface of the fuel bed to be calculated. Gas-phase temperature and velocity predictions are compared to experiment, and although analysis of the gas phase is emphasized, an approximate spread rate, based on a solid-phase energy balance, is calculated.
Comparison of flame spreading over thin flat surfaces in normal gravity and weightlessness in oxygen environment
The heat transfer rate to a thin solid combustible from an attached diffusion flame, spreading across the surface of the combustible in a quiescent, microgravity environment, was determined from measurements made in the drop tower facility at NASA-Lewis Research Center. With first-order Arrhenius pyrolysis kinetics, the solid-phase mass and energy equations along with the measured spread rate and surface temperature profiles were used to calculate the net heat flux to the surface. Results of the measurements are compared to the numerical solution of the complete set of coupled differential equations that describes the temperature, species, and velocity fields in the gas and solid phases. The theory and experiment agree on the major qualitative features of the heat transfer. Some fundamental differences are attributed to the neglect of radiation in the theoretical model.
The purpose of this project is to examine in detail the influence of the triple flame structure on the flame spread problem. It is with an eye to the practical implications that this fundamental research project must be carried out. The microgravity configuration is preferable because buoyancy-induced stratification and vorticity generation are suppressed. A more convincing case can be made for comparing our predictions, which are zero-g, and any projected experiments. Our research into the basic aspects will employ two models. In one, flows of fuel and oxidizer from the lower wall are not considered. In the other, a convective flow is allowed. The non-flow model allows us to develop combined analytical and numerical solution methods that may be used in the more complicated convective-flow model.
The effects of gravity on the spreading of a flame over a solid combustible surface were determined. Flame propagation rates were measured from specimens of thin cellulose acetate sheets burning in both normal gravity (1 g) and reduced gravity (0 g) environments; the specimens were burned in various quiescent mixtures of oxygen, helium, argon, and nitrogen. A correlation for normal gravity and reduced gravity burning was obtained based on theoretical models of previous investigators.
A three-dimensional, time-dependent model is developed describing ignition and subsequent transition to flame spread over a thermally thin cellulosic sheet heated by external radiation in a microgravity environment. A low Mach number approximation to the Navier Stokes equations with global reaction rate equations describing combustion in the gas phase and the condensed phase is numerically solved. The effects of a slow external wind (1-20 cm/s) on flame transition are studied in an atmosphere of 35% oxygen concentration. The ignition is initiated at the center part of the sample by generating a line-shape flame along the width of the sample. The calculated results are compared with data obtained in the 10s drop tower. Numerical results exhibit flame quenching at a wind speed of 1.0 cm/s, two localized flames propagating upstream along the sample edges at 1.5 cm/s, a single line-shape flame front at 5.0 cm/s, three flames structure observed at 10.0 cm/s (consisting of a single line-shape flame propagating upstream and two localized flames propagating downstream along sample edges) and followed by two line-shape flames (one propagating upstream and another propagating downstream) at 20.0 cm/s. These observations qualitatively compare with experimental data. Three-dimensional visualization of the observed flame complex, fuel concentration contours, oxygen and reaction rate isosurfaces, convective and diffusive mass flux are used to obtain a detailed understanding of the controlling mechanism, Physical arguments based on lateral diffusive flux of oxygen, fuel depletion, oxygen shadow of the flame and heat release rate are constructed to explain the various observed flame shapes.
A solid-phase conduction problem that is a modified version of one that has been treated previously in the literature and is applicable to flame spreading over a pyrolyzing fuel is solved using a boundary integral equation (BIE) method. Results are compared to surface temperature measurements that can be found in the literature. In addition, the heat conducted through the solid forward of the flame, the heat transfer responsible for sustaining the flame, is also computed in terms of the Peclet number based on a heated layer depth using the BIE method and approximate methods based on asymptotic expansions. Agreement between computed and experimental results is quite good as is agreement between the BIE and the approximate results.
Excerpts from a paper describing the numerical examination of concurrent-flow flame spread over a thin solid in purely forced flow with gas-phase radiation are presented. The computational model solves the two-dimensional, elliptic, steady, and laminar conservation equations for mass, momentum, energy, and chemical species. Gas-phase combustion is modeled via a one-step, second order finite rate Arrhenius reaction. Gas-phase radiation considering gray non-scattering medium is solved by a S-N discrete ordinates method. A simplified solid phase treatment assumes a zeroth order pyrolysis relation and includes radiative interaction between the surface and the gas phase.
The effect of radiative heat loss from the surface of a solid material burning in a zero gravity environment in an opposed flow is studied through the use of a numerical model. Radiative heat loss is found to decrease the flame spread rate, the boundary layer thickness, and pyrolysis lengths. Blowoff extinction is predicted to occur at slower opposesd flow velocities than would occur if the radiative loss is not present. The radiative heat fluxes are comparable to the conduction fluxes, indicating the significance of the surface energy loss.
The effort described here is a reflight of the Solid Surface Combustion Experiment (SSCE), with extension of the flight matrix first and then experiment modification. The objectives of the reflight are to extend the understanding of the interplay of the radiative processes that affect the flame spread mechanisms.