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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

A High-Current, Stable Nonaqueous Organic Redox Flow Battery

Nonaqueous redox flow batteries are promising in pursuit of high-energy storage systems owing to the broad voltage window, but currently are facing key challenges such as poor cycling stability and lack of suitable membranes. Here we report a new nonaqueous all-organic flow chemistry that demonstrates an outstanding cell cycling stability primarily because of high chemical persistency of the organic radical redox species and their good compatibility with the supporting electrolyte. A feasibility study shows that Daramic® and Celgard® porous separators can lead to high cell conductivity in flow cells thus producing remarkable cell efficiency and material utilization even at high current operations. This result suggests that the thickness and pore size are the key performance-determining factors for porous separators. With the greatly improved flow cell performance, this new flow system largely addresses the above mentioned challenges and the findings may greatly expedite the development of durable nonaqueous flow batteries.

Wei, Xiaoliang↗

Abstract for CRADA among NETL, Ohio University, and MetalKraft Technologies, LLC

The electrical grid faces challenges for meeting accelerated electricity demand arising from the electrification of building and transportation sectors. According to the DOE Grid Development Office, 70% of transmission lines are approaching the end of their lifecycle. The aging grid and insufficient transmission capacity necessitate the development of new technologies to improve overall grid performance. The conventional conductors used for electrical transmission lines suffer from substantial energy losses, high costs and low durability. These inefficiencies result in higher operational costs, increased energy waste, and difficulties in managing power flow. Improving the grid will require metals and composites with higher electrical conductivity and strength than the materials currently used. This CRADA will develop technologies to improve the grid by fabricating carbon metal composites with improved electrical, structural, and mechanical properties in comparison to metals that do not contain carbon additives. The composites will be made by incorporating carbon materials (graphite, graphene) into aluminum, copper, and other metals. The work will focus primarily on improving material properties that enhance the performance of these materials in electrical conductor applications.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Assimilation of Sentinel 1 and SMAP – Based Satellite Soil Moisture Retrievals into SWAT Hydrological Model: the Impact of Satellite Revisit Time and Product Spatial Resolution on Flood Simulations in Small Basins

In runoff generation process, soil moisture plays an important role as it controls the magnitude of the flood events to the rainfall inputs. In this study, we investigated the ability of a new era of satellite soil moisture retrievals to improve the Soil & Water Assessment Tool (SWAT) daily discharge simulations via soil moisture data assimilation for two small (< 500 km2) and hydrologically different catchments located in Central Italy. We ingested 1) the Soil Moisture Active and Passive (SMAP) Enhanced L3 Radiometer Global Daily 9 km EASE-Grid soil moisture, 2) the Advanced SCATterometer (ASCAT) H113 soil moisture product released within the EUMETSAT Satellite Application Facility on Support to Operational Hydrology and Water Management (H-SAF) which has a nearly daily temporal resolution and sampling of 12.5 km, and 3) a fused ASCAT/Sentinel-1 (S1) satellite soil moisture product named SCATSAR-SWI with temporal and spatial sampling of 1 day and 1 km, respectively into SWAT hydrological model via Ensemble Kalman Filter (EnKF). Different configurations were tested with the aim of exploring the effect of the hydrological regime, the land use conditions, the spatial sampling and the revisit time of the products (which controls the amount of available data to be potentially ingested). Results show a general improvement of SWAT discharge simulations for all products in terms of error and Nash Sutcliffe efficiency index. In particular, we found a relatively good behavior of both the active and the passive products in terms of low flows improvement especially for the catchment characterized by a higher baseflow component. The benefit of the higher spatial resolution of SCATSAR obtained via S1 over ASCAT was small likely due to very challenging areas for S1 retrieval. Eventually, better performances were obtained for the passive product in the more forested catchment. With the aim of exploring the benefit of having more frequent satellite soil moisture observations to be ingested, we tested the performance of the ASCAT product with a reduced temporal sampling obtained by temporally matching ASCAT observations to that of SMAP. The results show a significant reduction of the performance of ASCAT, suggesting that the correction frequency (due to the higher number of observations available) for small catchments is an important aspect for improving flood forecasting as it helps to adjust more frequently the soil moisture pre-storm conditions.

Small basins↗

Assimilation of Sentinel 1 and SMAP–based satellite soil moisture retrievals into SWAT hydrological model: the impact of satellite revisit time and product spatial resolution on flood simulations in small basins

In runoff generation process, soil moisture plays an important role as it controls the magnitude of the flood events in response to the rainfall inputs. In this study, we investigated the ability of a new era of satellite soil moisture retrievals to improve the Soil & Water Assessment Tool (SWAT) daily discharge simulations via soil moisture data assimilation for two small (< 500 km2) and hydrologically different catchments located in Central Italy. We ingested 1) the Soil Moisture Active and Passive (SMAP) Enhanced L3 Radiometer Global Daily 9 km EASE-Grid soil moisture, 2) the Advanced SCATterometer (ASCAT) H113 soil moisture product released within the EUMETSAT Satellite Application Facility on Support to Operational Hydrology and Water Management (HSAF) which has a nearly daily temporal resolution and sampling of 12.5 km, and 3) a fused ASCAT/Sentinel-1 (S1) satellite soil moisture product named SCATSAR-SWI with temporal and spatial sampling of 1 day and 1 km, respectively into SWAT hydrological model via the Ensemble Kalman Filter (EnKF). Different configurations were tested with the aim of exploring the effect of the hydrological regime, the land use conditions, the spatial sampling and the revisit time of the products (which controls the amount of available data to be potentially ingested). Results show a general improvement of SWAT discharge simulations for all products in terms of error and Nash Sutcliffe efficiency index. In particular, we found a relatively good behavior of both the active and the passive products in terms of low flows improvement especially for the catchment characterized by a higher baseflow component. The benefit of the higher spatial resolution of SCATSAR-SWI obtained via S1 over ASCAT was small, likely due to very challenging areas for the S1 retrieval. Eventually, better performances were obtained for the passive product in the more forested catchment. With the aim of exploring the benefit of having more frequent satellite soil moisture observations to be ingested, we tested the performance of the ASCAT product with a reduced temporal sampling obtained by temporally matching ASCAT observations to that of SMAP. The results show a significant reduction of the performance of ASCAT, suggesting that the correction frequency (due to the higher number of observations available) for small catchments is an important aspect for improving flood forecasting as it helps to adjust more frequently the pre-storm soil moisture conditions.

Shima Azimi↗

An Exact Dual Adjoint Solution Method for Turbulent Flows on Unstructured Grids

An algorithm for solving the discrete adjoint system based on an unstructured-grid discretization of the Navier-Stokes equations is presented. The method is constructed such that an adjoint solution exactly dual to a direct differentiation approach is recovered at each time step, yielding a convergence rate which is asymptotically equivalent to that of the primal system. The new approach is implemented within a three-dimensional unstructured-grid framework and results are presented for inviscid, laminar, and turbulent flows. Improvements to the baseline solution algorithm, such as line-implicit relaxation and a tight coupling of the turbulence model, are also presented. By storing nearest-neighbor terms in the residual computation, the dual scheme is computationally efficient, while requiring twice the memory of the flow solution. The scheme is expected to have a broad impact on computational problems related to design optimization as well as error estimation and grid adaptation efforts.

Nielsen, Eric J.↗

An analytical study of reduced-gravity propellant settling

Full-scale propellant reorientation flow dynamics for the Centaur D-1T fuel tank were analyzed. A computer code using the simplified marker and cell technique was modified to include the capability for a variable-grid mesh configuration. Use of smaller cells near the boundary, near baffles, and in corners provides improved flow resolution. Two drop tower model cases were simulated to verify program validity: one case without baffles, the other with baffles and geometry identical to Centaur D-1T. Flow phenomena using the new code successfully modeled drop tower data. Baffles are a positive factor in the settling flow. Two full-scale Centaur D-1T cases were simulated using parameters based on the Titan/Centaur proof flight. These flow simulations indicated the time to clear the vent area and an indication of time to orient and collect the propellant. The results further indicated the complexity of the reorientation flow and the long time period required for settling.

Bradshaw, R. D.↗

Simulation of powered-lift flows

The primary objective is to expose government, industry, and academic scientists to work underway at NASA-Ames towards the application of CFD to the powered lift area. One goal is to produce the technologies which will be required in the application of numerical techniques to, for example, the Supersonic STOVL program. The progress to date on the following specific projects is presented: Jet in ground effect with crossflow; Jet in a crossflow; Delta planform with multiple jets in ground effect; Integration of CFD with thermal and acoustic analyses; Improved flow visualization techniques for unsteady flows; YAV-8B Harrier simulation program; and E-7 simulation program.

Vandalsem, William R.↗

NASA's Role in Aeronautics: A Workshop. Volume 4: General aviation

A substantially improved flow of new technology is imperative if the general aviation industry is to maintain a strong world position. Although NASA is the most eminently suited entity available to carry out the necessary research and technology development effort because of its facilities, expertise, and endorsement by the aircraft industry, less than 3% of its aeronautical R&T budget is devoted to general aviation aeronautics. It is recommended that (1) a technology program, particularly one that focuses on improving fuel efficienty and safety, be aggressively pursued by NASA; (2) NASA be assigned the role of leading basic research technology effort in general aviation up through technology demonstration; (3) a strategic plan be developed by NASA, in cooperation with the industry, and implemented in time for the 1982 budget cycle; and (4) a NASA R&T budget be allocated for general aviation adequate to support the proposed plan.

Source record↗

NREL's HydroGEN Photoreactor Platform Design and Characterization

This technical report details the design, fabrication, and construction of a flow-through photoreactor developed at The National Renewable Energy Laboratory (NREL). The photoreactor is designed to facilitate indoor or outdoor testing on photoelectrochemical or integrated solar water splitting devices. The photoreactor design described here is based on a previous demonstration. The photoreactor version described herein contains several advanced design features that include: 1) Chassis-chuck two-part design, 2) Separable counter electrode compartments (here, the counter electrodes are anodes), 3) Reduced electrode separation to reduce electrolyte resistance, 4) Improved flow pattern for bubble removal, 5) Mounting for spectroradiometer receptor, 6) Fresnel lens and collimating tube attachments. The photoreactor presented here was designed primarily to accommodate photocathode materials in an illuminated compartment and a dark anode as the oxygen evolution catalyst. The build materials were thus chosen to for acid electrolyte compatibility. Other embodiments could accommodate a photoanode with dark hydrogen evolution catalyst and other build materials for alkaline compatibility.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Computational Analysis on the Effects of High-lift Propellers and Wingtip Cruise Propellers on X-57 Airplane

This study presents the computational study of the effects of high-lift system and wingtip-mounted cruise propellers on the flow physics and forces and moments of the X-57 Mod III/Mod IV configuration. Results were compared against previously published data on the powered-off configuration to determine the performance benefit. Simulations were performed using four different computational fluid dynamics solvers: STAR-CCM+, Launch Ascent Vehicle Aerodynamics, Kestrel, and USM3D. The high-lift system was shown to increase lift and lift-curve slope of the airplane. Additionally, the high-lift system was shown to increase the maximum lift coefficient and improve flow separation behavior at high anglesof-attack. Wingtip-mounted cruise propellers were shown to decrease the drag of the airplane. Simulation results showed that the drag decreased with increased thrust generated by the wingtip cruise propellers. The primary factor of the decrease in drag was a result of reduction in pressure drag of the wing. At the thrust setting of 230.1 lbf, results showed a reduction of 49-drag counts.

Seung Y. Yoo↗

Geometry effects on STOL engine-over-the-wing acoustics with 5:1 slot nozzles

The correspondence of far field acoustic trend with changes in the characteristics of the flow field at the wing trailing edge caused by alterations in the nozzle-wing geometry were determined at model scale with a 5:1 slot nozzle for several STOL-OTW configurations. Nozzle roof angles of 10 to 40 deg were tested with and without cutback of the nozzle sidewalls. With increasing wing size, representing several airframe/engine installations, the jet noise shielding benefits increased. With increasing nozzle roof angle, the jet velocity at the trailing edge was decreased, causing a decrease in trailing-edge and fluctuating lift noise. Cutback of the nozzle sides improved flow attachment and reduced far-field noise. The best flow attachment and least trailing-edge noise generally were obtained with a 40-deg external deflector configuration and a cutback nozzle with a 40-deg roof angle.

Von Glahn, U.↗

Geometry effects on STOL engine-over-the-wing acoustics with 5.1 slot nozzles

The correspondence of far field acoustic trends with changes in the characteristics of the flow field at the wing trailing edge caused by alterations in the nozzle-wing geometry were determined for several STOL-OTW configurations. Nozzle roof angles of 10 to 40 deg were tested with and without cutback of the nozzle sidewalls. Three wing chord sizes were used: baseline (33 cm with flaps retracted), 2/3-baseline, and 3/2-baseline. Flap deflection angles of 20 and 60 deg were used. The nozzle locations were at 21 and 46-percent of chord. With increasing wing size the jet noise shielding benefits increased. With increasing nozzle roof angle, the jet velocity at the trailing edge was decreased, causing a decrease in trailing-edge and fluctuating lift noise. Cutback of the nozzle sides improved flow attachment and reduced far-field noise. The best flow attachment and least trailing-edge noise generally were obtained with a 40 deg external deflector configuration and a cutback nozzle with a 40 deg roof angle.

Vonglahn, U.↗

Improved Safety Injection Flow Map Associated with Target RCS Depressurization to Maintain Core Coolability of OPR1000

In Korea, Severe Accident Management Guidance (SAMG) for Optimized Power Reactor (OPR1000) has been developed through the research results related to the WOG SAMG, in which the operation phase shifts from the Emergency Operation Procedure (EOP) to the SAMG when the Core Exit Temperature (CET) reaches 923 K. Among 7 mitigation strategies envisioned, the third management strategy, injecting coolant into Reactor Coolant System (RCS) by depressurizing the RCS is one of the key strategies to fortify the in-vessel retention capability. As an aid to such mitigation strategy, a safety injection (SI) flow map has been developed by Lee et al. for predicting required flow rate associated with target RCS depressurization to recover in-vessel coolability. The mechanistic SI flow map used the CET increase rate and core water level decrease rate obtained from MELCOR code simulation. It should be noted that during the severe accident, the total heat generated is sum of the decay heat and the oxidation heat. Thus, it is necessary to consider additional heat sources by oxidation reaction between cladding, structure, control rod, and hot steam prior to the injection of coolant. It was believed that the SI model estimated required flow rate rather conservatively by considering the expected amount decay heat and the accumulated heat in the core based on the RCS pressure. However, it was confirmed that the SI model developed by Lee et al. could not represent the total heat removal especially since start of oxidation. Under transient conditions, the heat sources accumulated in the heat structures (fuel, cladding, supporting structures) should be embarked in the model for accurate contribution of the total heat source to the required flow rate. Therefore, the objective of this study is to improve the previous SI flow map predicting the injection flow rate associated with target RCS depressurization to satisfy the in-vessel coolability during severe accidents. Additional terms were developed to reflect accurate heat accumulating and included in the existing model. Resulting SI flow map includes the target RCS depressurization, which enables discharge of the required flow rate by utilizing the flow rate-pressure curve with operation of two high pressure safety injections (HPSIs). Also recent MELCOR simulation result of a postulated steam generator tube rupture (SGTR) accident verified the accuracy of the improved map.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An Improved Design and Versatile New Lamination Fabrication Method for Twin Electrode Thin Layer Cells Utilizing Track‐etch Membranes

Abstract Reported here are laminated membrane electrodes, an improved design and more advantageous method of fabrication for previously reported thin layer cell electrode systems developed on track‐etch membranes. The laminated membrane approach potentially further improves flow resistance by dramatically reducing the surface area to volume ratio, but also produces a cohesive device that can be more readily applied to a broad range of applications. In addition, this new fabrication method was implemented in a scalable, commercial process and resulting product demonstrations indicate that volume manufacturing is feasible. Characterization of laminated membrane electrodes reveal redox cycling amplification factors as high as 30 with linear responses to variable concentrations of redox couple. These performance characteristics are shown to be comparable to similar generator‐collector systems fabricated through much more laborious laboratory methods. This combination of added versatility, cost‐reduced fabrication and exceptional performance clearly reveals unrealized potential of track‐etch membrane approaches and boosts their candidacy as powerful new options for generator‐collector electrode systems.

Hauke, Adam↗

Transmission expansion with smart switching under demand uncertainty and line failures

One of the major challenges in deciding where to build new transmission lines is that there is uncertainty regarding future loads, renewal generation output and equipment failures. We propose a robust optimization model whose transmission expansion solutions ensure that demand can be met over a wide range of conditions. Specifically, we require feasible operation for all loads and renewable generation levels within given ranges, and for all single transmission line failures. Furthermore, we consider transmission switching as an allowable recovery action. This relatively inexpensive method of redirecting power flows improves resiliency, but introduces computational challenges. Lastly, we present a novel algorithm to solve this model. Computational results are discussed.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Asphaltene-induced spontaneous emulsification: Effects of interfacial co-adsorption and viscoelasticity

Asphaltenes are a class of high molecular weight aromatic compounds found in crude oil. They adsorb onto toluene-water interfaces and induce a spontaneous emulsification phenomenon, whereby stable water-in-oil emulsions form without the need of an external energy input. This work aims to control and understand the factors affecting spontaneous droplet formation in the presence of asphaltene adsorption. This is particularly useful for crude oil refining, where the presence of a stable emulsion hampers the efficiency of downstream processing operations. We explore the effect of the addition of copolymers designed as crude oil flow improvers as a means to control the extent of emulsion formation. We find that the polymers competitively adsorb onto the toluene-water interface and diminish spontaneous emulsification. Additionally, we conduct fluorescence microscopy experiments and measurements of the interfacial energy to determine the mechanism of spontaneous emulsification in asphaltene systems. We conclude that an emulsion forms via the diffusion of molecular water into the oil phase and subsequent binding with asphaltene aggregates, leading to the nucleation of micrometer-sized water droplets. We find that the polymer forms complexes with the dissolved asphaltenes, possibly hampering the ability of diffused water to bind to the asphaltenes and reducing the extent of spontaneous emulsification. Finally, we investigate the role of interfacial shear and dilatational viscoelasticity to better understand which fundamental interfacial properties are important in the emulsification of asphaltene-laden systems. We find that the rate of formation of an interfacial microstructural network is inversely correlated with the extent and rate of spontaneous emulsification.

42 ENGINEERING↗

Model simulations of Plum Island Ecosystems LTER low marsh site using ELM-PFLOTRAN

Model simulations using the E3SM Land Model (ELM) coupled to the PFLOTRAN reactive transport model via the Alquimia interface. The simulations were conducted for a tidal salt marsh at the Plum Island Ecosystems LTER near Rowley, Massachusetts, USA. Model simulations were forced using site-specific tidal cycles and salinity, and the simulations used a biogeochemical reaction network including aerobic decomposition, sulfate reduction, iron reduction, and methanogenesis. Model outputs include simulated carbon stocks, carbon dioxide and methane fluxes, and porewater concentrations of key solutes related to sulfur, iron, and carbon cycling. The model simulations included a saline simulation (with tidal sulfate inputs), a fresh simulation (with low salinity and low sulfate inputs), and a saline simulation with lower vegetation productivity to represent the effect of salinity on vegetation. These simulations were conducted to demonstrate that a new model framework incorporating subsurface redox and biogeochemical interactions into a land surface model could reproduce measured surface greenhouse gas fluxes and biogeochemical dynamics in tidal marsh ecosystems, and to test whether including redox interactions in a land surface model would allow the model to resolve contrasts in biogeochemical cycling and greenhouse gas production between saline and freshwater wetlands.The data package includes gzipped tar archives (which can be expanded using standard tar and gzip utilities) of model outputs from three model configurations: saline subsurface and reduced vegetation productivity related to salinity; saline subsurface with vegetation productivity not reduced; and freshwater. Also included are code for the modified E3SM model, Alquimia interface, and PFLOTRAN reactive transport simulator in gzipped tar format; plain text parameter and configuration files; python code files for visualizing model output and defining model configurations; and model output, tide and salinity forcing, and configuration files in netCDF format. See the README.md file in the data package for a detailed description of all files contained in the package. All files are in netCDF (.nc), gzipped tar archive (.tar.gz or .tgz), or text (all other files).Updated: May 13, 2024. Model output, E3SM code, PFLOTRAN input files, and python codes for visualizing results were updated to reflect changes made for the manuscript revision. The updated archive reflects the code and model output from the final accepted manuscript. Changes included updated reaction parameters reflecting improved parameterization and additional comparisons with field measurements. E3SM code changes included better support for multiple grid cells and improved flow and transport parameterization.

54 ENVIRONMENTAL SCIENCES↗

Fluid – Fluid Interfacial Area and Its Impact on Relative Permeability - A Pore Network Modeling Study

Abstract Relative permeability (kr) is commonly modeled as an empirical function of phase saturation. Although current empirical models can provide a good match of one or two measured relative permeabilities using saturation alone, they are unable to predict relative permeabilities well when there is hysteresis or when physical properties such as wettability change. Further, current models often result in relative permeability discontinuities that can cause convergence and accuracy problems in simulation. To overcome these problems, recent research has modeled relative permeability as a state function of both saturation (S) and phase connectivity (X). Pore network modeling (PNM) data, however, shows small differences in relative permeability for the same S-X value when approached from a different flow direction. This paper examines the impact of one additional Minkowski parameter (Mecke and Arns, 2005), the fluid-fluid interfacial area, on relative permeability to identify if that satisfactorily explains this discrepancy. We calculate the total fluid-fluid interfacial areas (IA) during two-phase (oil/water) flow in porous media using pore network modeling. The area is calculated from PNM simulations using the areas associated with corners and throats in pore elements of different shapes. The pore network is modeled after a Bentheimer sandstone, using square, triangular, and circular pore shapes. Simulations were conducted for numerous primary drainage and imbibition cycles at a constant contact angle of 0° for the wetting phase. Simultaneous measurements of capillary pressure, relative permeability, saturation, and phase connectivity are made for each displacement. Fluid-fluid interfacial area is calculated from the PNM capillary pressure, the fluid location in the pore elements, and the pore element dimensional data. The results show that differences in the relative permeability at the same (S,X) point is explained well by differences in the fluid-fluid interfacial area (IA). That is, for a larger change in IA at these intersection points, the permeability difference is greater. That difference in relative permeability approaches zero as the difference in IA approaches zero. This confirms that relative permeability can be modeled better as a unique function of S, X, and IA. The results also show that an increase in IA restricts flow decreasing the nonwetting (oil) phase permeability. This decrease is caused by an increase in the throat area fraction compared to the corner area as the total area IA increases. The wetting phase relative permeability, however, shows the inverse trend, in that its relative permeability is greater when IA becomes larger owing to a greater fraction of the total area associated with the corners. The area IA, however, impacts the nonwetting phase relative permeability more than the wetting phase relative permeability. Corner flow improves the wetting phase relative permeability because the wetting phase is continuous there. Finally, a sensitivity analysis shows that relative permeability a is more sensitive to change in S than they are for IA for the case studied implying that if only two parameters are used to model relative permeability it is better to choose S and X.

Engineering↗