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At least 109 records · Page 6

Thermodynamic limits to the conversion of blackbody radiation by quantum systems

Using general thermodynamic arguments, we analyze the conversion of the energy contained in the radiation from a blackbody to useful work by a quantum system. We show that the energy available for conversion is bounded above by the change in free energy in the incident and reradiated fields and that this free energy change depends upon the temperature of the receiving device. Universal efficiency curves giving the ultimate thermodynamic conversion efficiency of the quantum system are presented in terms of the blackbody temperature and the temperature and threshold energy of the quantum system. Application of these results is made to a variety of systems including biological photosynthetic, photovoltaic, and photoelectrochemical systems.

Buoncristiani, A. M.↗

Stress versus temperature dependent activation energies in creep

The activation energy for creep at low stresses and elevated temperatures is lattice diffusion, where the rate controlling mechanism for deformation is dislocation climb. At higher stresses and intermediate temperatures, the rate controlling mechanism changes from that of dislocation climb to one of obstacle-controlled dislocation glide. Along with this change, there occurs a change in the activation energy. It is shown that a temperature-dependent Gibbs free energy does a good job of correlating steady-state creep data, while a stress-dependent Gibbs free energy does a less desirable job of correlating the same data. Applications are made to copper and a LiF-22 mol. percent CaF2 hypereutectic salt.

Freed, A. D.↗

Observations from Hinode and SDO of a Twisting and Writhing Start to a Solar-filament-eruption Cascade

Active region eruption of 1 June 2011. Ejective eruption. GOES class C4.1 flare. SDO/AIA, various filters (94, 131, 171, 193, 211, 304, 335 Ang.) High time cadence (24 s) and high spatial resolution (0 .6 pixels). SDO/HMI line-of-sight magnetograms. Hinode observed the onset, and the later decay phase. There are two filament eruptions (filament 1 and filament 2). Filament 1 has slow rise with steps, as in several previous cases. GOES "episodes" play role of "microflares" in other events; that is, filament jumps <=> intensity peaks. Episode 1 brightening: Accompanied by filament 1 s initial motions. (Rest of talk.) Filament 1 becomes unstable, and.. Episode 2 brightening: Flare ribbons following filament 1 s fast liftoff. This destabilizes neighboring filament 2, and... Episode 3 brightening: Flare ribbons of whole system following filament 2 s eruption.Something leads to reconnection; not totally clear what. Reconnection -> twisted flux rope in approx.20 min; episode 1 microflare (flare ribbons; TC) and filament jump. Twist -> writhe, via kink instability; filament-trajectory plateau, approx. 20 min. Writhe -> jump and eruption of filament 1, via instability; episode 2 microflare (flare ribbons; TC). (E.g., Williams et al.) First eruption -> second filament eruption (episode 3 flare ribbons; TC). (E.g., Sterling, Moore; Liu et al.; Torok et al.; Schrijver & Title.). Estimate amount of free energy in newly-twisted field (cf. Moore 1988): where we have taken L and r = 50, 3 arcsec. Energy of the total system is likely 1030 ergs or more. So "no" is answer to question. Additional energy comes from remainder of sheared large loop, shear (free energy) of second filament, etc. (Normally assumed situation.) Some history of twist-induced instability in filament eruptions: e.g., Sakurai, Torok & Kliem, Fan & Gibson, Gilbert et al., van Driel-Gesztelyi et al. Criterion : Kink instability for line-tied tube (Hood & Priest): 2.5pi; for Titov & Demoulin loop (Torok et al): approx.3.5pi We observe here: approx.1.5 turns (3.0pi) over ~50. => consistent with kink instability acting. (Cf. Srivastava et al. (2010): Small flare seen in TRACE and Hinode: approx.6.0pi)

Sterling, Alphonse C.↗

Coronal heating by stochastic magnetic pumping

Recent observational data cast serious doubt on the widely held view that the Sun's corona is heated by traveling waves (acoustic or magnetohydrodynamic). It is proposed that the energy responsible for heating the corona is derived from the free energy of the coronal magnetic field derived from motion of the 'feet' of magnetic field lines in the photosphere. Stochastic motion of the feet of magnetic field lines leads, on the average, to a linear increase of magnetic free energy with time. This rate of energy input is calculated for a simple model of a single thin flux tube. The model appears to agree well with observational data if the magnetic flux originates in small regions of high magnetic field strength. On combining this energy input with estimates of energy loss by radiation and of energy redistribution by thermal conduction, we obtain scaling laws for density and temperature in terms of length and coronal magnetic field strength.

Sturrock, P. A.↗

Coronal heating by stochastic magnetic pumping

Recent observational data cast serious doubt on the widely held view that the sun's corona is heated by traveling waves (acoustic or magnetohydrodynamic). It is here proposed that the energy responsible for heating the corona is derived from the free energy of the coronal magnetic field derived from motion of the 'feet' of magnetic field lines in the photosphere. Stochastic motion of the feet of magnetic field lines leads, on the average, to a linear increase of magnetic free energy with time. This rate of energy input is calculated for a simple model of a single thin flux tube. The model appears to agree well with observational data if the magnetic flux originates in small regions of high magnetic field strength as proposed by Tarbell et al. (1979). On combining this energy input with estimates of energy loss by radiation and of energy redistribution by thermal conduction, scaling laws are obtained for density and temperature in terms of length and coronal magnetic field strength.

Sturrock, P. A.↗

Thermodynamic properties of liquid Si and Ge

Thermodynamic properties of liquid Si and Ge are calculated using standard variational techniques, with the hard-sphere system as a reference system. Third-order electron-ion pseudopotential contributions are included nonvariationally and are shown to have little effect on the free energy, although a larger one on the derivatives of the free energy. Two different model pseudopotentials are used and give similar results in good agreement with experiment.

Shih, W.-H.↗

Thermodynamic limits to the efficiency of solar energy conversion by quantum devices

The second law of thermodynamics imposes a strict limitation to the energy converted from direct solar radiation to useful work by a quantum device. This limitation requires that the amount of energy converted to useful work (energy in any form other than heat) can be no greater than the change in free energy of the radiation fields. Futhermore, in any real energy conversion device, not all of this available free energy in the radiation field can be converted to work because of basic limitations inherent in the device itself. A thermodynamic analysis of solar energy conversion by a completely general prototypical quantum device is presented. This device is completely described by two parameters, its operating temperature T sub R and the energy threshold of its absorption spectrum. An expression for the maximum thermodynamic efficiency of a quantum solar converter was derived in terms of these two parameters and the incident radiation spectrum. Efficiency curves for assumed solar spectral irradiance corresponding to air mass zero and air mass 1.5 are presented.

Buoncristiani, A. M.↗

Small particle melting of pure metals

Submicron-sized crystallites of lead, tin, indium and bismuth were melted in situ in the modified specimen chamber of a Siemens transmission e lectron microscope. Melting point and size determinations were made directly from the dark field images of the crystallites. Particles exhibited melting points that decreased with decreasing particle size. A near-linear relationship was observed for the melting point as a function of the reciprocal of the radius. Thermodynamnic expressions based on the significant contributions of the surface energy to the free energy of the system also suggest a linear relation. Other factors, such as shape and surface contamination, were also observed to affect the size-dependent melting of particles. Crystallites of extended platelet shape did not exhibit a significant depression in melting point. Elevated residual gas pressures were found to lessen the melting point depression of spherical particles.

Allen, G. L.↗

Homogenous Surface Nucleation of Solid Polar Stratospheric Cloud Particles

A general surface nucleation rate theory is presented for the homogeneous freezing of crystalline germs on the surfaces of aqueous particles. While nucleation rates in a standard classical homogeneous freezing rate theory scale with volume, the rates in a surface-based theory scale with surface area. The theory is used to convert volume-based information on laboratory freezing rates (in units of cu cm, seconds) of nitric acid trihydrate (NAT) and nitric acid dihydrate (NAD) aerosols into surface-based values (in units of sq cm, seconds). We show that a surface-based model is capable of reproducing measured nucleation rates of NAT and NAD aerosols from concentrated aqueous HNO3 solutions in the temperature range of 165 to 205 K. Laboratory measured nucleation rates are used to derive free energies for NAT and NAD germ formation in the stratosphere. NAD germ free energies range from about 23 to 26 kcal mole, allowing for fast and efficient homogeneous NAD particle production in the stratosphere. However, NAT germ formation energies are large (greater than 26 kcal mole) enough to prevent efficient NAT particle production in the stratosphere. We show that the atmospheric NAD particle production rates based on the surface rate theory are roughly 2 orders of magnitude larger than those obtained from a standard volume-based rate theory. Atmospheric volume and surface production of NAD particles will nearly cease in the stratosphere when denitrification in the air exceeds 40 and 78%, respectively. We show that a surface-based (volume-based) homogeneous freezing rate theory gives particle production rates, which are (not) consistent with both laboratory and atmospheric data on the nucleation of solid polar stratospheric cloud particles.

Tabazadeh, A.↗

Global Energetics of Solar Flares. V. Energy Closure in Flares and Coronal Mass Ejections

In this study we synthesize the results of four previous studies on the global energetics of solar flares and associated coronal mass ejections (CMEs), which include magnetic, thermal, nonthermal, and CME energies in 399 solar M and X-class flare events observed during the first 3.5 years of the Solar Dynamics Observatory (SDO) mission. Our findings are: (1) The sum of the mean nonthermal energy of flare-accelerated particles (E(sub nt)), the energy of direct heating (E(sub dir)), and the energy in coronal mass ejections (E(sub CME)), which are the primary energy dissipation processes in a flare, is found to have a ratio of (E(sub nt) + E(sub dir) + E(sub CME))/E(sub mag) = 0.87±0.18, compared with the dissipated magnetic free energy E(sub mag), which confirms energy closure within the measurement uncertainties and corroborates the magnetic origin of flares and CMEs; (2) The energy partition of the dissipated magnetic free energy is: 0.51±0.17 in nonthermal energy of ≥ 6 keV electrons, 0.17± 0.17 in nonthermal ≥ 1 MeV ions, 0.07 ± 0.14 in CMEs, and 0.07 ± 0.17 in direct heating; (3) The thermal energy is almost always less than the nonthermal energy, which is consistent with the thick-target model; (4) The bolometric luminosity in white-light flares is comparable with the thermal energy in soft X-rays (SXR); (5) Solar Energetic Particle (SEP) events carry a fraction ≈ 0.03 of the CME energy, which is consistent with CME-driven shock acceleration; and (6) The warm-target model predicts a lower limit of the low-energy cutoff at e(sub c) ≈ 6 keV, based on the mean differential emission measure (DEM) peak temperature of T(sub e) = 8.6 MK during flares. This work represents the first statistical study that establishes energy closure in solar flare/CME events.

Solar activity↗

Global Energetics of Solar Flares. V. Energy Closure in Flares and Coronal Mass Ejections

In this study we synthesize the results of four previous studies on the global energetics of solar flares and associated coronal mass ejections (CMEs), which include magnetic, thermal, nonthermal, and CME energies in 399 solar M and X-class flare events observed during the first 3.5 years of the Solar Dynamics Observatory (SDO) mission. Our findings are: (1) The sum of the mean nonthermal energy of flare-accelerated particles (E(sub nt)), the energy of direct heating (E(sub dir)), and the energy in coronal mass ejections (E(sub CME)), which are the primary energy dissipation processes in a flare, is found to have a ratio of (E(sub nt)+E(sub dir)+E(sub CME))/E(sub mag) = 0.87±0.18, compared with the dissipated magnetic free energy E(sub mag), which confirms energy closure within the measurement uncertainties and corroborates the magnetic origin of flares and CMEs; (2) The energy partition of the dissipated magnetic free energy is: 0.51±0.17 in nonthermal energy of ≥ 6 keV electrons, 0.17± 0.17 in nonthermal ≥ 1 MeV ions, 0.07 ± 0.14 in CMEs, and 0.07 ± 0.17 in direct heating; (3) The thermal energy is almost always less than the nonthermal energy, which is consistent with the thick-target model; (4) The bolometric luminosity in white-light flares is comparable with the thermal energy in soft X-rays (SXR); (5) Solar Energetic Particle (SEP) events carry a fraction ≈ 0.03 of the CME energy, which is consistent with CME-driven shock acceleration; and (6) The warm-target model predicts a lower limit of the low-energy cutoff at ec ≈ 6 keV, based on the mean differential emission measure (DEM) peak temperature of T(sub e) = 8.6 MK during flares. This work represents the first statistical study that establishes energy closure in solar flare/CME events.

Solar activity↗

Global Energetics of Solar Flares and CMEs: V. Energy Closure

In this study we synthesize the results of four previous studies on the global energetics of solar flares and associated coronal mass ejections (CMEs), which include magnetic, thermal, nonthermal, and CME energies in 399 solar M and X-class flare events observed during the first 3.5 years of the Solar Dynamics Observatory (SDO) mission. Our findings are: (1) The sum of the mean nonthermal energy of flare-accelerated particles (E(sub nt)), the energy of direct heating (E(sub dir)), and the energy in coronal mass ejections (E(sub CME)), which are the primary energy dissipation processes in a flare, is found to have a ratio of (E(sub nt)+E(sub dir)+E(sub CME))/E(sub mag) = 0.87±0.18, compared with the dissipated magnetic free energy E(sub mag), which confirms energy closure within the measurement uncertainties and corroborates the magnetic origin of flares and CMEs; (2) The energy partition of the dissipated magnetic free energy is: 0.51±0.17 in nonthermal energy of ≥ 6 keV electrons, 0.17± 0.17 in nonthermal ≥ 1 MeV ions, 0.07 ± 0.14 in CMEs, and 0.07 ± 0.17 in direct heating; (3) The thermal energy is almost always less than the nonthermal energy, which is consistent with the thick-target model; (4) The bolometric luminosity in white-light flares is comparable with the thermal energy in soft X-rays (SXR); (5) Solar Energetic Particle (SEP) events carry a fraction ≈ 0.03 of the CME energy, which is consistent with CME-driven shock acceleration; and (6) The warm-target model predicts a lower limit of the low-energy cutoff at e(sub c) ≈ 6 keV, based on the mean differential emission measure (DEM) peak temperature of T(sub e) = 8.6 MK during flares. This work represents the first statistical study that establishes energy closure in solar flare/CME events.

Solar activity↗

Stress versus temperature dependence of activation energies for creep

The activation energy for creep at low stresses and elevated temperatures is associated with lattice diffusion, where the rate controlling mechanism for deformation is dislocation climb. At higher stresses and intermediate temperatures, the rate controlling mechanism changes from dislocation climb to obstacle-controlled dislocation glide. Along with this change in deformation mechanism occurs a change in the activation energy. When the rate controlling mechanism for deformation is obstacle-controlled dislocation glide, it is shown that a temperature-dependent Gibbs free energy does better than a stress-dependent Gibbs free energy in correlating steady-state creep data for both copper and LiF-22mol percent CaF2 hypereutectic salt.

Freed, A. D.↗

Energy Requirements of Hydrogen-utilizing Microbes: A Boundary Condition for Subsurface Life

Microbial ecosystems based on the energy supplied by water-rock chemistry carry particular significance in the context of geo- and astrobiology. With no direct dependence on solar energy, lithotrophic microbes could conceivably penetrate a planetary crust to a depth limited only by temperature or pressure constraints (several kilometers or more). The deep lithospheric habitat is thereby potentially much greater in volume than its surface counterpart, and in addition offers a stable refuge against inhospitable surface conditions related to climatic or atmospheric evolution (e.g., Mars) or even high-energy impacts (e.g., early in Earth's history). The possibilities for a deep microbial biosphere are, however, greatly constrained by life s need to obtain energy at a certain minimum rate (the maintenance energy requirement) and of a certain minimum magnitude (the energy quantum requirement). The mere existence of these requirements implies that a significant fraction of the chemical free energy available in the subsurface environment cannot be exploited by life. Similar limits may also apply to the usefulness of light energy at very low intensities or long wavelengths. Quantification of these minimum energy requirements in terrestrial microbial ecosystems will help to establish a criterion of energetic habitability that can significantly constrain the prospects for life in Earth's subsurface, or on other bodies in the solar system. Our early work has focused on quantifying the biological energy quantum requirement for methanogenic archaea, as representatives of a plausible subsurface metabolism, in anoxic sediments (where energy availability is among the most limiting factors in microbial population growth). In both field and laboratory experiments utilizing these sediments, methanogens retain a remarkably consistent free energy intake, in the face of fluctuating environmental conditions that affect energy availability. The energy yields apparently required by methanogens in these sediment systems for sustained metabolism are about half that previously thought necessary. Lowered energy requirements would imply that a correspondingly greater proportion of the planetary subsurface could represent viable habitat for microorganisms.

Hoehler, Tori M.↗

Impulsive Reconnection in the Sun's Atmosphere

Recent high-resolution observations from the Hinode mission show dramatically that the Sun's atmosphere is filled with explosive activity ranging from chromospheric explosions that reach heights of Mm, to coronal jets that can extend to solar radii, to giant coronal mass ejections (CME) that reach the edge of the heliosphere. The driver for all this activity is believed to be 3D magnetic reconnection. From the large variation observed in the temporal behavior of solar activity, it is clear that reconnection in the corona must take on a variety of distinct forms. The explosive nature of jets and CMEs requires that the reconnection be impulsive in that it stays off until a substantial store of free energy has been accumulated, but then turns on abruptly and stays on until much of this free energy is released. The key question, therefore, is what determines whether the reconnection is impulsive or not. We present some of the latest observations and numerical models of explosive and non-explosive solar activity. We argue that, in order for the reconnection to be impulsive, it must be driven by a quasi-ideal instability. We discuss the generality of our results for understanding 31) reconnection in other contexts.

Antiochos, Spiro K.↗

A Contemporary Analysis of the O'Neill-Glaser Model for Space-Based Solar Power and Habitat Construction

In 1975 Gerard O Neill published in the journal Science a model for the construction of solar power satellites. He found that the solar power satellites suggested by Peter Glaser would be too massive to launch economically from Earth, but could be financially viable if the workforce was permanently located in free space habitats and if lunar and asteroid materials were used for construction. All new worldwide electrical generating capacity could be then achieved by solar power satellites. The project would financially break even in about 20 years after which it would generate substantial income selling power below fossil fuel prices. Two NASA / Stanford University led studies at Ames Research center during the summers of 1974 and 1976 found the concept technically sound and developed a detailed financial parametric model. Although the project was not undertaken when suggested in the 1970s, several contemporary issues make pursuing the O Neill -- Glaser concept more compelling today. First, our analysis suggests that if in the first ten years of construction that small habitats (compared to the large vista habitats envisioned by O Neill) supporting approximately 300 people were utilized, development costs of the program and the time for financial break even could be substantially improved. Second, the contemporary consensus is developing that carbon free energy is required to mitigate global climate change. It is estimated that 300 GW of new carbon free energy would be necessary per year to stabilize global atmospheric carbon. This is about 4 times greater energy demand than was considered by the O Neill Glaser model. Our analysis suggests that after the initial investments in lunar mining and space manufacturing and transportation, that the profit margin for producing space solar power is very high (even when selling power below fossil fuel prices). We have investigated the financial scaling of ground launched versus space derived space solar power satellites. We find that for the carbon mitigation case even modernized ground launched space solar power satellites are not financially viable. For space derived solar power satellites, however, the increased demand makes them break even substantially sooner and yield much higher profit. Third, current awareness is increasing about the dangers of humanity remaining a single planet species. Our technological power has been increasing relative to the size of the planet Earth. Since the middle of the 20th century our technological power has grown large relative to our planet's size. This presents a very real potential for human self-extinction. We argue that the potential for human self-extinction is increasing with time in proportion to the exponential growth of our technological power making self-extinction likely within this century if humanity remains a single planet species. The O Neill model of multiple independent free space habitats, it is argued, can protect humanity from extinction in the same way that portfolio diversification protects ones assets from total loss. We show that about 1 million people for the electricity only case, and about 1 billion people for the carbon mitigation case, can be provided with permanent space habitats and transportation from Earth in 30 years and can be funded by the space derived solar power satellite program. 1.2 Scope of this Chapter The goal of this chapter is to illustrate the power and importance of the O'Neill-Glaser concept in the context of human survival and maintaining a healthy planet Earth. We argue that at this point in human history our technological power is too dangerous to our selves and our home planet for us not to expand into space. We show by the models presented in the chapter that the imminent dangers of global warming and human self-extinction mandate that humanity move aggressively into the solar system in this generation. We show that the production of solar power satellites using space resources and with a work foe living in space provides a viable financial model to mitigate CO2 preventing the worst global warming scenarios, and safeguards humanity against self-extinction by providing hundreds of habitats and a billion people living in space within about 35 years. To accomplish this goal we need only consider the classic O'Neill-Glaser model which was parameterized for 1970's technological projections. Only habitat size optimization for the first ten years of production is added. This is a conservative approach since the innovations of the last 30 years will make the financial projections more favorable. However, the classic O'Neill-Glaser model represented a broad technological consensus. The model is well documented in the references and our calculations can be easily reproduced In this chapter the economics of the O Neill - Glaser model is compared with models that rely exclusively on Earth launched materials. Although many studies of Earth launched Solar Power Satellites have been made, we found that the NASA "Fresh Look Study" was the most comprehensive and well documented. It also provided one of the most optimistic Earth launch financial projections. We thus chose it for comparison purposes.

Curreri, Peter A.↗

The Role of Magnetic Helicity in Coronal Heating

One of the greatest challenges in solar physics is understanding the heating of the Sun's corona. Most theories for coronal heating postulate that free energy in the form of magnetic twist/stress is injected by the photosphere into the corona where the free energy is converted into heat either through reconnection or wave dissipation. The magnetic helicity associated with the twist/stress, however, is expected to be conserved and appear in the corona. In previous works, we showed that the helicity associated with the small-scale twists undergoes an inverse cascade via stochastic reconnection in the corona and ends up as the observed large-scale shear of filament channels. Our "helicity condensation" model accounts for both the formation of filament channels and the observed smooth, laminar structure of coronal loops. In this paper, we demonstrate, using helicity- and energy-conserving numerical simulations of a coronal system driven by photospheric motions, that the model also provides a natural mechanism for heating the corona. We show that the heat generated by the reconnection responsible for the helicity condensation process is sufficient to account for the observed coronal heating. We study the role that helicity injection plays in determining coronal heating and find that, crucially, the heating rate is only weakly dependent on the net helicity preference of the photospheric driving. Our calculations demonstrate that motions with 100% helicity preference are least efficient at heating the corona; those with 0% preference are most efficient. We discuss the physical origins of this result and its implications for the observed corona.

Knizhnik, K. J.↗

Particle acceleration and wave emissions associated with the formation of auroral cavities and enhancements

A unified model is presented which interrelates the various processes involved in auroral particle acceleration and the associated wave emissions, and it is shown how energy is coupled from the magnetosphere into the ionosphere. The phenomena in the magnetotail which can provide the source of free energy for the perpendicular electrostatic shocks are identified along with the associated potential structures in the nightside auroral region. The characteristics of the particle acceleration produced by the shock are described, including efficiency and energy transport between magnetospheric and ionospheric plasmas, the properties of the particle distributions throughout the shock region and return current regions, and the associated wave emissions. The source of free energy for the generation of ion conics is identified, as are the signatures for the formation of plasma cavities and/or enhancements.

Winglee, R. M.↗