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Small concentrations of selected gases measured automatically. Proposed multiple-laser-diode spectrometer part of system for measuring automatically concentrations of selected gases at part-per-billion level. Array of laser/photodetector pairs measure infrared absorption spectrum of atmosphere along probing laser beams. Adaptable to terrestrial uses as monitoring pollution or control of industrial processes.
A variety of protective or reactive environmental gases have recently gained growing attention in laser-based metal additive manufacturing (AM) technologies due to their unique thermophysical properties and the potential improvements they can bring to the build processes. However, much remains unclear regarding the effects of different gas environments on critical phenomena in laser AM, such as rapid cooling, energy coupling, and defect generation. Through simultaneous high-speed synchrotron x-ray imaging and thermal imaging, we identify distinct effects of two environmental gases in laser AM and gained a deeper understanding of the underlying mechanisms. Compared to the commonly used protective gas, argon, it is found that helium has a negligible effect on cooling the part. However, helium can suppress unstable keyholes by decreasing effective energy absorption, thus mitigating keyhole porosity generation and reducing pore size under certain processing conditions. In conclusion, these observations provide guidelines for the strategic use of environmental gases in laser AM to produce parts with improved quality.
Low noise amplifiers, laser radar optics, gas lasers and holography, and microminiaturized solid state devices for radio electronics
Diffused optical waveguides are studied using the modal and the ray tracing approach, with an emphasis on the case of a hollow waveguide with diffuse cladding. The properties of the guided modes are investigated in detail. The applications of these structures to optical circuits, integrated optics lasers and capillary gas lasers are discussed.
Papers from the conference are presented, and the topics covered include the following: x-ray lasers, excimer lasers, chemical lasers, high power lasers, blue-green lasers, dye lasers, solid state lasers, semiconductor lasers, gas and discharge lasers, carbon dioxide lasers, ultrafast phenomena, nonlinear optics, quantum optics, dynamic gratings and wave mixing, laser radar, lasers in medicine, optical filters and laser communication, optical techniques and instruments, laser material interaction, and industrial and manufacturing applications.
Iterative technique using continuous gas laser for alignment of Mach-Zehnder interferometer for monochromatic and white light fringes
Q-switching of carbon dioxide and nitrous oxide gas laser transitions
Development of a theory of electron cascade which takes explicitly into account the electron energy distribution. For the particular case of a Boltzmann distribution, it is shown that the monoenergetic approximation is valid, except for low flux densities (less than 20 MW per sq cm) of the laser beam. It is emphasized that the equilibrium temperature can be calculated easily. When electron-ion inverse bremsstrahlung comes into play, this approximation becomes invalid; there is a pressure below which the cascade cannot develop. Numerical results are presented for model calculations of helium and argon.
Review of the techniques and applications of holographic interferometry. The recording of a 'reflected-light' hologram with a gas laser is described in order to illustrate the unique optical properties of a hologram. Special types of interferometric measurement, such as stored-beam holographic interferometry and double-exposure holographic interferometry, are then discussed. Applications of gas-laser holographic interferometry to the detection of internal flaws in steel tubing are cited, as well as applications involving the testing of aircraft and automotive tires and aircraft honeycomb composites for bond integrity and the prediction of failure in mechanical components. Finally, applications of the pulsed solid-state ruby laser in holographic interferometry are considered.
NMR images of laser polarized 3He gas were obtained at 21 G using a simple, homebuilt instrument. At such low fields magnetic resonance imaging (MRI) of thermally polarized samples (e.g., water) is not practical. Low-field noble gas MRI has novel scientific, engineering, and medical applications. Examples include portable systems for diagnosis of lung disease, as well as imaging of voids in porous media and within metallic systems.
A progress report of scaling studies of solar pumped lasers is presented. Conversion of blackbody radiation into laser light has been demonstrated in this study. Parametric studies of the variation of laser mixture composition and laser gas temperature were carried out for CO2 and N2O gases. Theoretical analysis and modeling of the system have been performed. Reasonable agreement between predictions in the parameter variation and the experimental results have been obtained. Almost 200 mW of laser output at 10.6 micron was achieved by placing a small sapphire laser tube inside an oven at 1500 K the tube was filled with CO2 laser gas mixture and cooled by longitudinal nitrogen gas flow.
In many applications, it is highly desirable to operate a CO2 laser in a sealed condition, for in an open system the laser requires a continuous flow of laser gas to remove the dissociation products that occur in the discharge zone of the laser, in order to maintain a stable power output. This adds to the operating cost of the laser, and in airborne or space applications, it also adds to the weight penalty of the laser. In a sealed CO2 laser, a small amount of CO2 gas is decomposed in the electrical discharge zone into corresponding quantities of CO and O2. As the laser continues to operate, the concentration of CO2 decreases, while the concentrations of CO and O2 correspondingly increase. The increasing concentration of O2 reduces laser power, because O2 scavenges electrons in the electrical discharge, thereby causing arcing in the electric discharge and a loss of the energetic electrons required to boost CO2 molecules to lasing energy levels. As a result, laser power decreases rapidly. The primary object of this invention is to provide a catalyst that, by composition of matter alone, contains chemisorbed water within and upon its structure. Such bound moisture renders the catalyst highly active and very long-lived, such that only a small quantity of it needs to be used with a CO2 laser under ambient operating conditions. This object is achieved by a catalyst that consists essentially of about 1 to 40 percent by weight of one or more platinum group metals (Pt, Pd, Rh, Ir, Ru, Os, Pt being preferred); about 1 to 90 percent by weight of one or more oxides of reducible metals having multiple valence states (such as Sn, Ti, Mn, Cu, and Ce, with SnO2 being preferred); and about 1 to 90 percent by weight of a compound that can bind water to its structure (such as silica gel, calcium chloride, magnesium sulfate, hydrated alumina, and magnesium perchlorate, with silica gel being preferred). Especially beneficial results are obtained when platinum is present in the catalyst composition in an amount of about 5 to 25 (especially 7) percent by weight, SnO2 is present in an amount of about 30 to 40 (especially 40) percent by weight, and silica gel is present in an amount of 45 to 55 (especially 50) percent by weight. The composition of this catalyst was suggested by preliminary experiments in which a Pt/SnO2 catalyst was needed for bound water to enhance its activity. These experimental results suggested that if the water were bound to the surface, this water would enhance and prolong catalyst activity for long time periods. Because the catalyst is to be exposed to a laser gas mixture, and because a CO2 laser can tolerate only a very small amount of moisture, a hygroscopic support for the catalyst would provide the needed H2O into the gas. Silica gel is considered to be superior because of its property to chemisorb water on its surface over a wide range of moisture content.
Hydrocarbon gas detection using He-Ne laser radiation absorption, discussing detector electronics
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Chemical mixing laser investigations were conducted (1) to investigate the properties of a bimolecular exchange laser system pumped by the H + Cl2 yields HCl(v) + Cl reaction, initiated by arc-dissociated H2, with lasing occurring between wavelengths of 3.4 and 4.0 microns, and (2) to establish the feasibility of an atom recombination-transfer laser employing recombination of arc-dissociated nitrogen with subsequent transfer of vibrational energy to CO2 for lasing at 10.6 microns. One-dimensional analytical results indicate higher results should be obtained with up to v = 3 to 2 transitions participating. Diagnostic and analytical results show that the reaction mechanism during mixing, a back reaction of HCl(v) with H atoms, reaction of Cl with H2(v), moderately fast V-V, V-T processes, and possible HCl(o) initial contaminant level may explain the low performance. N2-CO2 thermal mixing laser studies were extended to measure the efficiency of transfer of recombination energy in such a nonequilibrium N2 source to 10.6 microns optical energy. The low level of efficiency suggests that V-T decay processes may prevent vibrational energy freezing until much lower temperatures are achieved and that trapping of energy in long-lived electronic excitation of N2 may be a factor.
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Sudden-freeze approximation is applied to the flow of a CO2-N2-He mixture in wedge-type nozzles. This approximation permits rapid estimation of the freezing temperature of the upper laser level as a function of the stagnation pressure and the nozzle geometry. The stagnation temperature and the composition of the mixture appear as parameters. Gain and power output may then be estimated and calculations are presented for two cases.
Electron energy spectra in gas laser discharges and investigation of new discharge configurations