Search NASA⌕ Search

SEARCH · Search NASA

Results for “GUM”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Fabrication of lignocellulosic biomass paper containing nanofibrillated biomass

Fibrillated cellulose has been frequently used for making nanopapers and thin films. However, limited work has been carried out in the construction of such materials using native lignocellulosic biomass. Making papers from fibrillated biomass allows complete utilization of whole plant material and may reduce chemical and energy consumption. Ultra-friction grinding was used to directly fibrillate knife-milled poplar into micro- to nano-sized biomass fibers. Papers were made using the fibrillated biomass containing nanofibrillated biomass and their mechanical properties were tested. Biomass papers made via press-drying had higher tensile strength than papers made by air-drying. A higher press-drying temperature of 180 °C produced stronger papers than at 150 °C. Guar gum substantially increased the strength of the press-dried papers in comparison to cationic starch. Press-drying increased the thermogravimetric peak decomposition temperature by 13 °C in comparison to air-drying.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

AmeriFlux US-TLR Timberlake Observatory for Wetland Restoration (TOWeR)

This is the AmeriFlux version of the carbon flux data for the site US-TLR Timberlake Observatory for Wetland Restoration (TOWeR). Site Description - This tower is located in Timberlake Forest, a restored forested wetland located 4 km from Albermarle Sound on the North Carolina coast. The forest to the south of the tower had historically been ditched, drained and converted to agricultural land, and subsequently reforested with Black Gum and Cypress trees and naturally re-wetted in 2006. This southern region has a bottomland forest ecosystem which saw a large-scale succession event of pine trees following the reforestation efforts. The northern part of the forest had been ditched, but never drained or converted for other land uses. It is much wetter and more sparsely vegetated when compared to the southern region, and has a mixed bottomland forest and swamp ecosystem.

Rey-Sanchez, Camilo [North Carolina State Universi↗
DOE OSTI2026

AmeriFlux FLUXNET-1F US-TLR Timberlake Observatory for Wetland Restoration (TOWeR)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-TLR Timberlake Observatory for Wetland Restoration (TOWeR). This is the FLUXNET version of the carbon flux data for the site US-TLR Timberlake Observatory for Wetland Restoration (TOWeR) produced by applying the standard ONEFlux (1F) software. Site Description - This tower is located in Timberlake Forest, a restored forested wetland located 4 km from Albermarle Sound on the North Carolina coast. The forest to the south of the tower had historically been ditched, drained and converted to agricultural land, and subsequently reforested with Black Gum and Cypress trees and naturally re-wetted in 2006. This southern region has a bottomland forest ecosystem which saw a large-scale succession event of pine trees following the reforestation efforts. The northern part of the forest had been ditched, but never drained or converted for other land uses. It is much wetter and more sparsely vegetated when compared to the southern region, and has a mixed bottomland forest and swamp ecosystem.

Rey-Sanchez, Camilo [North Carolina State Universi↗
DOE OSTI2023

Measurement of Plutonium Ratios for CRM 137A Recertification

This report documents the analytical methodologies used by the Chemical and Isotopics Mass Spectrometry (CIMS) Group at the US Department of Energy’s Oak Ridge National Laboratory (ORNL) for plutonium isotopic ratio characterizations on purified ~1 mg units prepared by Lawrence Livermore National Laboratory (LLNL) from a mother solution created from an existing 250 mg unit of certified reference material (CRM) 137. The analytical processes described are designed to maintain traceability of the final certified attributes and to eliminate sources of systematic bias for the measurements described. The measurands for certification are the plutonium isotope ratios: 238 Pu/ 239 Pu, 240 Pu/ 239 Pu, 241 Pu/ 239 Pu, and 242 Pu/ 239 Pu. The preparation and analytical process included the following activities: Preparation of reference materials to be used as calibrants to establish traceability to the SI unit of mass for the isotopic analyses and quality controls. For the plutonium isotopic analyses, CRM 128 (a CRM comprising equal atoms of 239 Pu and 242 Pu) was used as the primary calibrant; Each CRM 137A unit was reconstituted using dilute high-purity HNO3. From each, seven replicates were distributed for the isotopic characterizations by thermal ionization mass spectrometry (TIMS) using the total evaporation (TE) method for isotope ratio measurements and MC-ICP-MS using a dynamic peak hooping method for secondary isotope ratio measurements; Due to time delay in the analyses from the last purification of the original CRM 137 mother solution by LLNL, an aliquot of the three provided plutonium units was purified using Eichrom TEVA separation methods to remove americium in-growth and uranium impurities; Minimally corrected data were reported from each analysis using reporting templates provided by the New Brunswick Laboratory Program Office (NBL PO) for the specific methods used for isotopic measurements. In addition, a copy of the instrument exports, Excel templates for isotopic data corrections, and the uncertainty budgets completed with the GUM Workbench software package were submitted to NBL PO.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2024

Investigating Material Properties of Subsurface Rock Formations Modified by Engineering Mineral Precipitation (Final Scientific and Technical Report)

Montana State University’s (MSU) Energy Research Institute (ERI), in collaboration with the Center for Biofilm Engineering (CBE) and the Department of Civil Engineering (CE), has conducted a long‐term research program aimed at developing a novel cementing agent to address wellbore integrity and reduce the unwanted upward migration of fluids and greenhouse gases from the subsurface. The primary technology developed through this research program is known as ureolysis‐induced calcite precipitation (UICP), which harnesses bio‐chemical processes to precipitate calcium carbonate (CaCO 3 ). The same general process can also be called microbially-induced calcium carbonate precipitation (MICP) when microbes provide the process-catalyzing urease enzyme. Both terms are used in this report. Results have conclusively demonstrated that, if properly controlled, UICP can successfully seal fractures, high permeability zones, and compromised cement in the vicinity of wellbores and in nearby caprock. This technology has been successfully deployed to mitigate annular leakage in two test wells and over sixty commercial wells with a 100% success rate. This success in downhole deployment generates consideration of other subsurface applications where UICP could provide benefit to the energy sector, such as shale property modification for unconventional oil and gas recovery. The focus of this research project was to investigate fundamental material and mechanical properties of select shale cores and analyze how these properties change due to engineered mineral precipitation with the intent to control these properties to achieve a range of engineering objectives. Ultimately, the project aim was to identify valuable new areas where application of UICP might contribute to national energy security and environmental protection. The research workplan coupled UICP treatment of core samples, nuclear magnetic resonance (NMR) characterization, and mechanical strength testing at MSU with advanced X‐Ray micro-computed tomography (μCT) imaging and numerical modeling performed by collaborators at two national laboratories, the National Energy Technology Laboratory (NETL) and Lawrence Berkeley National Laboratory (LBNL). Experimental results are useful to inform geo-mechanical models which could be applied to predict mineralized rock formation behavior at field scale. Our findings suggest that NMR and μCT methods to detect and quantify biomineral formation in shale fractures are complementary and consistent with each other. Either could be used to estimate the volume of new mineral formed by UICP in shale fractures. The use of surfactants and guar gum to enhance biomineral precipitation in shale fractures merits further research. UICP can, under some conditions, increase the tensile strength of sealed shale fractures beyond that of the intact shale. These findings demonstrate that continued research in this area may be valuable to understanding and improving shale resource recovery techniques.

58 GEOSCIENCES↗
DOE OSTI2025

Assessment and Simulation of Particulate Transport for Delivery of Solid Amendments into the Subsurface: FY25 Status Report

For particulate-based amendments to be viable for field-scale remediation at the Hanford Site (e.g., the 200 DV-1 Operable Unit), amendment particles need to be delivered a reasonable distance away from an injection well to provide cost effective in situ treatment. Field-scale particle transport models can estimate spatial deposition of amendment particles in the subsurface, which is critical for developing an overall remediation strategy. However, field-scale particle simulations are currently limited due to insufficient simulation capability and a lack of experimental data to validate and parameterize particle transport models. During this fiscal year, the following progress has been made toward a field-scale particle transport modeling evaluation: (1) in addition to the two particle transport models implemented last FY, four additional particle transport models have been implemented within PFLOTRAN; (2) a Python-based pre-screening tool was finalized, enabling users to quickly estimate the particle radius of influence (ROI) for any given particle-amendment system; and (3) an initial compatibility assessment was completed using both particle transport simulations deployed through the pre-screening tool, in conjunction with general guidelines to (a) identify the most suitable amendment particle sizes for various Hanford sediments and (b) evaluate amendment-delivery fluid compatibility. The preliminary compatibility assessment revealed that for amendment delivery success to the various Hanford target formations, amendment particle sizes will likely need to be smaller than the amendment sizes tested in the DV-1 treatability study. It is recommended that amendment particles be decreased in size, or alternative smaller size amendments be obtained from the manufacture, prior to any further experimental testing. Also, preliminary testing suggests that xanthan gum may be the most broadly compatible delivery fluid. Planned laboratory experiments will be instrumental in validating and refining the PFLOTRAN particulate transport model formulations, ultimately enabling predictive capabilities to facilitate the design of field-scale amendment delivery systems. This work consists of acquiring new theoretical or experimental knowledge. The information associated with this report should not be used as design input or operating parameters without additional qualification.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Simulation of Particulate Transport for Delivery of Solid Amendments into the Subsurface: FY24 Status Report

For particulate-based amendments to be viable for field-scale remediation at the Hanford Site (e.g., 200 DV-1 Operable Unit), particles need to be delivered a sufficient radial distance from an injection well and retained at concentrations high enough for effective treatment. An accurate description of the particle radius of influence (ROI) is critical for developing an overall remediation strategy. However, field-scale particle simulations are currently limited due to insufficient simulation capabilities and a lack of experimental data to validate and parameterize particle transport models. To help build toward field-scale deployment, this fiscal year (FY) we have (1) developed a pre screening tool to estimate particle transport, (2) implemented particle transport models within PFLOTRAN, and (3) conducted preliminary estimations of particle ROI. While field-scale numerical simulations will ultimately be necessary before remedy design and field implementation, we have developed a pre-screening tool that offers valuable estimations of expected particle injectability and ROI in a 1-D system. The advantage of the tool is that it does not require extensive laboratory experiments and instead makes predictions based solely on routine laboratory measurements. This tool can assist in down-selection and decision-making by identifying which particle amendment systems are worth pursuing in future laboratory experiments, such as 1-D column tests and beyond. With any system, scaling up from the lab to the field presents challenges. Currently, there is no field data available for model calibration or validation. However, the theoretical particle models being developed herein are the best tools available to guide progress toward field deployment. To help bridge this gap and verify model predictions, larger-scale lab experiments are being proposed. To advance simulation capabilities, six particle transport models are being integrated into the reactive transport simulator PFLOTRAN. These include colloid filtration theory (CFT) and five additional particle transport models (M1-M5). Each model, from M1 to M5, progressively incorporates additional particle transport and retention processes. Ultimately, the simplest model capable of accurately describing 1-D column data will be selected and parameterized. During FY24, the CFT and M1 model have been fully implemented within PFLOTRAN. Using an existing 1 D column experiment, the two currently implemented particle transport models (CFT and M1), and associated parameters, were fit to this experiment. While simpler model formulations are helpful for estimations, these formulations could not fully describe particle transport and retention behavior in the previous 1-D column experiment. Thus, additional complexities will need to be considered, which will be accounted for in the M2-M5 model formulations. Additionally, because a viscous, shear thinning fluid was required to keep particles in suspension, considerations for flow will also need to also be accounted for. Therefore, a new immiscible two-phase flow mode is currently being implemented in PFLOTRAN. With some modifications, this new flow module could also support simulation of non-Newtonian liquid amendments, foams, and emulsions. We also estimated the expected ROI of solid amendments using 1-D simulations. The average predicted ROI was approximately 15 ft for micron-sized zero valent iron (mZVI) suspended in xanthan gum (XG). Using the pre screening tool and ROI estimates, additional amendment-delivery laboratory characterization and experiments are proposed. The results from additional experiments can be used to validate and parametrize particulate transport model formulations, which will ultimately provide predictive capabilities for field amendment-delivery systems.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

C136A and C138A Report of Analysis

In this work the isotopic ratios and weight percentages of 238 Pu, 239 Pu, 240 Pu, 241 Pu and 242 Pu were determined using Isotope Dilution Mass Spectrometry. Two samples of C136A and C138A were sent to the Analytical Research laboratories by the National Nuclear Security Administration Nuclear Reference Material Program. The four samples were dissolved in concentrated hydrochloric acid. From the parent solutions, eight aliquots were taken, diluted, spiked with 244 Pu and submitted to separations. After the samples were separated, they were analyzed using Multicollector Inductively Coupled Plasma Mass Spectrometry. Along with the samples, two C126A Quality Control Samples were analyzed each day. Mass bias standards were also analyzed at the beginning, during and at the end of the analysis. GUM Workbench Pro software Version 2.4.1.406 was used to calculate the isotopic ratios relative to 239 Pu, and total Pu mass and the correlated expanded uncertainties.

37 - INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL C↗
DOE OSTI2024

Effects of Pectinase on Bacterial Succession during Hemp Retting

Pectinase accelerates hemp retting. An elevated temperature during the enzymatic action is favorable for bacterial colonization. Industrial hemp (Cannabis sativa L.) bast fiber was retted in a 40 °C water bath under four different conditions: water retting, pectinase retting, bacterial retting, and bacterial retting with the presence of pectinase. Bacterial communities were sampled from the retting liquid of each condition at the beginning of retting and on days 1, 3, and 5. The bacterial successions were identified by 16S rRNA gene metagenomic sequencing. The results showed that Bacillaceae dominated the hemp retting conditions containing 1% (m/v) pectinase, suggesting that pectinase can manipulate the bacterial community succession by changing the nutrients available to bacteria through the breakdown of pectin. Micromorphological analysis also observed the degradation of a gum-like substance and the aggregation of bacteria with the addition of pectinase.

Engineering↗
NASA NTRS1969

Quick don-doff electrode pastes

Evaluation of electrode pastes for use in electrocardiographs and electroencephalographs found that the one having the desired don-doff properties had to be water soluble or a water dispersible base. Poly /methyl vinyl ether/maleic anhydride/ or starch gels of the gum drop variety are two such bases.

Mosier, B.↗
NASA NTRS1971

Formation of giant H II regions following supernova explosions

The principal optical properties of type I supernovae are summarized. These include the light curve and the spectrum. The spectra consist of broad bands with very little continuum. According to the theory presented, the observed light is principally fluorescence, excited in the medium surrounding the supernova by ultraviolet radiation originating from the explosion. It is proposed that the spectrum that impinges on the fluorescent medium while emission is taking place must fall abruptly across the Lyman edge of He II. Such a filtering action is plausibly provided by a much denser internal region, rich in helium, immediately surrounding the exploding object. This will form a Stromgren sphere during the time the intense UV pulse is passing through it. The dense region also slows down the photons below the edge by Thomson scattering, thereby spreading out the UV pulse in time. Various proposed mechanisms for the production of ionization in the Gum nebula are discussed.

Sartori, L.↗
NASA NTRS1971

The velocity and composition of supernova ejecta

In case of the Gum nebula, a pulsar - a presumed neutron star - is believed to be a relic of the supernova explosion. Regardless of the mechanism of the explosion, the velocity distribution and composition of the ejected matter will be roughly the same. The reimploding mass fraction is presumed to be neutron rich. The final composition is thought to be roughly 1/3 iron and 2/3 silicon, with many small fractions of elements from helium to iron. The termination of helium shell burning occurs because the shell is expanded and cooled by radiation stress. The mass fraction of the helium burning shell was calculated.

Colgate, S. A.↗
NASA NTRS1971

Three proposed B-associations in the vicinity of zeta puppis

There appear to be three loose B associations in the general vicinity of zeta Puppis, all at distances of approximately 300 to 400 parsecs from the sun. Their diameters, perpendicular to the line of sight, are 20 to 50 parsecs, and their separations are of similar size. All three are situated in bright areas of the Gum nebula. The proposed associations A and C lie in the two brightest parts of the nebula. The three associations are not all of the same age. Association C is about 50 million years old, whereas A and B are decidedly younger. The ages of A and B cannot be determined from the present data, as their color-magnitude diagrams show no clear turnoff from the main sequence. Association A may be young enough to qualify as the birthplace of zeta Puppis. There is no other identifiable association in which zeta Puppis can have originated, unless its age is substantially greater than the 3 million years assumed.

Upton, E. K. L.↗
NASA NTRS1971

A discussion of the H-alpha filamentary nebulae and galactic structure in the Cygnus region

From observation of the galactic structure in Cygnus, the system of filamentary nebulae was found to lie at a distance of roughly 1.5 kpc, in the same region as about half the thermal radio sources in Cygnus X, the supernova remnant near gamma Cygni, and the association Cygnus OB2, in the direction of which the X-ray source Cygnus XR-3 is observed. The source of excitation was probably the pulse of radiation from a supernova explosion, as proposed in the case of Gum nebula. However continuing excitation by early stars in the region of Cygnus X cannot be excluded.

Matthews, T. A.↗
NASA NTRS1971

The difficulty of ultraviolet emssion from supernovae

There are certain conceptual difficulties in the theory of the generation of ultraviolet radiation which is presumed for the creation of the optical fluorescence mechanism of supernova light emission and ionization of a nebula as large as the Gum nebula. Requirements concerning the energy distribution of the ultraviolet photons are: 1) The energy of the greater part of the photons must be sufficient to cause both helium fluorescence and hydrogen ionization. 2) If the photons are emitted in an approximate black body spectrum, the fraction of energy emitted in the optical must be no more than what is already observed. Ultraviolet black body emission depends primarily on the energy source. The probability that the wide mixture of elements present in the interstellar medium and supernova ejecta results in an emission localized in a limited region with less than 0.001 emission in the visible, for either ionization or fluorescence ultraviolet, is remote. Therefore transparent emission must be excluded as unlikely, and black body or at least quasi-black-body emission is more probable.

Colgate, S. A.↗
NASA NTRS1971

The basic assumption

When a supernova occurs, there is a release of sufficient energy to ionize a large amount of the surrounding material. The Gum nebula is an example of this process.

Stecher, T. P.↗
NASA NTRS1971

Fundamental ignition study for material fire safety improvement, part 2

The autoignition behavior of polymeric compositions in oxidizing media was investigated as well as the nature and relative concentration of the volatiles produced during oxidative decomposition culminating in combustion. The materials investigated were Teflon, Fluorel KF-2140 raw gum and its compounded versions Refset and Ladicote, 45B3 intumenscent paint, and Ames isocyanurate foam. The majority of the tests were conducted using a stagnation burner arrangement which provided a laminar gas flow and allowed the sample block and gas temperatures to be varied independently. The oxidizing atmospheres were essentially air and oxygen, although in the case of the Fluorel family of materials, due to partial blockage of the gas inlet system, some tests were performed unintentionally in enriched air (not oxygen). The 45B3 paint was not amenable to sampling in a dynamic system, due to its highly intumescent nature. Consequently, selected experiments were conducted using a sealed tube technique both in air and oxygen media.

Paciorek, K. L.↗
NASA NTRS1972

An investigation of the preparation of high molecular weight perfluorocarbon polyethers

High molecular weight perfluorocarbon polyether gums were obtained by photolysis of perfluorodienes and discyl fluorides containing a perfluorocarbon polyether backbond. The materials obtained are represented by chemical formulas. A method was developed whereby reactive acyl fluoride and trifluorovinyl end groups are converted into inert structures. In order to investigate the possible preparation of difunctional molecules which may be useful in polymer synthesis, the reactions of hexafluoropropene oxide (HFPO) with Grignard and organolithium reagents have been studied. Reactions of various nucleophilic reagents with HFPO were also investigated.

Watts, R. O.↗