Hardness of Five Borides at 1625 Deg C
Borides of transition metals, hafnium, zirconium, niobium, lanthanum and holmium tested for hardness at high temperature
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Borides of transition metals, hafnium, zirconium, niobium, lanthanum and holmium tested for hardness at high temperature
Growth parameters for hafnium carbide/tantalum carbide single crystals
Neutron activation procedure to simultaneously detect cesium, hafnium, and tantalum in tektites
Creep strength test for strips of high strength refractory alloy composed of tantalum, tungsten, and hafnium
This is the Monthly Letter Progress Report for the eighth month of a twelve month technical study directed toward the following objectives: A. Determining analytically and experimentally the feasibility and attractiveness of using free-standing pyrolytic graphite for a radiation cooled liquid rocket thrust chamber and exit nozzle for space application. B. Establishing through analysis and experimental demonstration, a set of design principles to facilitate the design of a reliable pyrolytic graphite thrust chamber assembly for a specific range of operating conditions. C. Demonstrate by means of test firings of complete thrust chamber assemblies, the validity of the design data and principles developed during the program. Preparations have been completed for test firing the two 100 lb. thrust Boron Pyralloy chambers at Marquardt during the first week in March 1962. These two chambers will first be static pressure checked with water to a pressure of 135 psig. The chambers will then be test fired with N204/N2H4-MMH propellants . Test samples of eleven different pyrolytic carbide and nitride materials have been ordered for high temperature oxidation tests and should be delivered by the end of March for evaluation in the plasma torch facility. The specific materials ordered in free- standing condition in thicknesses from 0.030 inch to 0.065 inch were as follows: (a) Pyrolytic graphite (on hand) (b) Pyrolytic graphite-boron alloy (on hand) (c) Pyrolytic graphite-tungsten alloy (d)Boron nitride (e) Titanium nitride (f) Silicon carbide (g) Titanium carbide (h) Zirconium carbide (i) Hafnium carbide (j) Niobium carbide (k) Tantalum carbide (l) High density (1 1-90) graphite (m) High density graphite (heat treated) These materials were ordered from Raytheon, HTM, and American Meta 1 Products . A summary of the available data on the oxidation rates of pyrolytic materials under slow air and rocket motor conditions is shown in Figure 1. High Temperature Materials, Inc. has been contacted relative to providing Pyrographite thrust chambers with extra-thick walls . They believe they can deliver chambers with substantially thicker walls than were possible a short time ago. Such a configuration, with acceptable residual stresses, would provide a longer firing life since it is ultimately limited by the oxidation rate of the chamber wall material. Stress and structural studies have continued. The analytical stress studies point out some of the problems associated with the experimental determination of the elastic constants of this highly anisotropic material. Further analysis may shed light on improved techniques for making these experimental determinations. The large potential weight saving available with the use of pyrolytic graphite as a thrust chamber wall material in a radiation cooled rocket motor has been calculated and is shown graphically in Figure 2. Figure A presents the program progress schedule and the actual expenditures as of 7 February 1962.
Protective coating containing a plasma arc sprayed mixture of hafnium oxide and zirconium diboride will withstand high temperatures in an oxygen rich atmosphere. Used on a homogeneous tungsten thermocouple, it does not flake or crack on subsequent cooling and reheating, and does not degrade the thermocouple response time.
Tungsten-hafnium-carbon alloy has tensile strengths of 88,200 psi at 3000 deg F and 62,500 psi at 3500 deg F. Possible industrial applications for this alloy would include electrical components such as switches and spark plugs, die materials for die casting steels, and heating elements.
Graphite-metal composites - hot pressing equipment modifications, hot pressing of calcined petroleum coke, and heterogeneity in density of niobium, hafnium, and molybdenum-graphites
Graphite effect on molybdenum-carbide composite properties and tungsten, vanadium, hafnium, tantalum, niobium, and zirconium metal systems
Solid solution and carbide strengthened arc melted alloys of hafnium with tungsten and ternary alloys of tantalum, columbium, rhenium and carbon
Alloy combines superior strength at elevated temperatures with improved ductility at lower temperatures relative to unalloyed tungsten. Composed of tungsten, rhenium, hafnium, and carbon, the alloy is prepared by consumable electrode vacuum arc-melting and can be fabricated into rod, plate, and sheet.
Hall effect and electric resistance of zirconium carbide niobium carbide and tantalum carbide hafnium carbide alloys
Emittance properties of hafnium oxide, cerium oxide, and iron titanate coatings on platinum rhodium alloy substrates
Iron-base and nickel-base alloys exhibit good oxidation resistance and improved ductility with addition of small amounts of yttrium, tantalum /or hafnium/, and thorium. They can be used in applications above the operating temperatures of the superalloys, if high strength materials are not required.
Various refractory coating systems were evaluated for rocket nozzle applications by actual rocket test firings. A reference is noted which identifies failure mechanisms and gives results of the firing tests for 18 coating systems. Iridium, iridium-rhenium, and hafnium oxide-zirconium oxide coatings show most promising results.
Knudsen flow mass spectrometry, thermodynamics, and chemical bonding of titanium, zirconium, hafnium, and thorium carbides during high temperature vaporization
Oxidation resistance and high temperature tests of rhenium, tungsten, hafnium, and tantalum matrix composites with iridium in oxygen, fluorine, and boron atmospheres for liquid propellant engines
Molybdenum and tungsten alloys, detailing strengthening with hafnium carbide