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At least 109 records · Page 6

CsPbI 3 Nanocrystals Go with the Flow: From Formation Mechanism to Continuous Nanomanufacturing

Despite the groundbreaking advancements in the synthesis of inorganic lead halide perovskite (LHP) nanocrystals (NCs), stimulated from their intriguing size-, composition-, and morphology-dependent optical and optoelectronic properties, their formation mechanism through the hot-injection (HI) synthetic route is not well-understood. Here in this work, for the first time, in-flow HI synthesis of cesium lead iodide (CsPbI 3 ) NCs is introduced and a comprehensive understanding of the interdependent competing reaction parameters controlling the NC morphology (nanocube vs nanoplatelet) and properties is provided. Utilizing the developed flow synthesis strategy, a change in the CsPbI 3 NC formation mechanism at temperatures higher than 150 °C, resulting in different CsPbI 3 morphologies is revealed. Through comparison of the flow- versus flask-based synthesis, deficiencies of batch reactors in reproducible and scalable synthesis of CsPbI 3 NCs with fast formation kinetics are demonstrated. The developed modular flow chemistry route provides a new frontier for high-temperature studies of solution-processed LHP NCs and enables their consistent and reliable continuous nanomanufacturing for next-generation energy technologies.

36 MATERIALS SCIENCE↗

Probing signals of self-interacting dark matter core collapse in H I -rich galaxies

Here, we analyze rotation curves of five Hi-rich galaxies recently discovered with MeerKAT. These galaxies exhibit sharply rising rotation curves, while their baryonic components are not dynamically dominant, suggesting that their dark matter halos have high inner densities. When fitting the standard Navarro–Frenk–White (NFW) halo model, four galaxies require extremely high halo concentrations, exceeding the cosmological median by 5σ. In contrast, self-interacting dark matter (SIDM) halos in the core-collapse phase naturally account for the high densities in these galaxies. For halos with masses around 10 11 M ⊙ , those in cosmic filaments exhibit concentrations consistent with the cosmological average, while halos in cosmic nodes show relatively higher concentrations that align with the SIDM fits but remain insufficient for the NFW fits. Our analysis indicates that these Hi-rich galaxies may have formed in cosmic nodes of dark matter with significant self-interactions.

dark matter↗

Analysis of ultrafast magnetization switching dynamics in exchange-coupled ferromagnet–ferrimagnet heterostructures

Magnetization switching in ferromagnets has so far been limited to the current-induced spin–orbit–torque effects. Recent observation of helicity-independent all-optical magnetization switching (HI-AOS) in an exchange-coupled ferromagnet–ferrimagnet (FM-FEM) heterostructures expanded the range and applicability of such ultrafast heat-driven magnetization switching. Here we report the element-resolved HI-AOS dynamics of such an exchange-coupled system, using a modified microscopic three-temperature model. We have studied the effect of (i) the Curie temperature of the FM, (ii) FEM composition, (iii) the long-range Ruderman–Kittel–Kasuya–Yosida (RKKY) exchange-coupling strength, and (iv) the absorbed optical energy on the element-specific time-resolved magnetization dynamics. The phase-space of magnetization illustrates how the RKKY coupling strength and the absorbed optical energy influence the switching time. Our analysis demonstrates that the threshold switching energy depends on the composition of the FEM and the switching time depends on the Curie temperature of the FM as well as RKKY coupling strength. Importantly, this simulation anticipates new insights into developing faster and more energy-efficient spintronics devices.

36 MATERIALS SCIENCE↗

Consequences of 131 I Transmutation in Gas Phase Radioiodine Molecules and Adsorbed on Graphite Surface

In the case of nuclear power plant accidents, several radionuclides are being dispersed into the environment. In particular, the release of radioiodine 131 I represents a major health concern because of its absorption by the thyroid gland. To reduce the release of 131 I into the environment, capture materials, such as activated carbon, provide a mean to efficiently retain radioiodine-bound molecular species. Here, we use ab initio molecular dynamic calculations to investigate the effects of 131 I radioactive decay on the molecular stability of I 2 , acid iodine (HI, HIO, HIO 2 , and HIO 3 ), and methyl-iodine species in both gas phase and adsorbed on graphite. In gas phase, we found that I 2 is the least resistant to 131 I transmutation, followed by the HIO x family of molecules, then HI and CH 3 I which are the most resistant. However, the graphite surface is found to greatly favorize the fragmentation of adsorbed molecular species. While the identification of gas phase fragments can offer new chemical route to consider in chemical kinetics models, the formation reactive fragment products at the graphite surface can favorize their reaction with surface carbon atoms which overtime could reduce the number of adsorption sites of capture materials available, and hence, impacting their capture capability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Evolving Distribution of Relative Humidity Conditional Upon Daily Maximum Temperature in a Warming Climate

Abstract The impacts of heat waves in a warming climate depend not only on changing temperatures but also on changing humidity. Using 35 simulations from the Community Earth System Model Large Ensemble (CESM LENS), we investigate the long‐term evolution of the joint distribution of summer relative humidity (RH) and daily maximum temperature ( Tmax ) near four U.S. cities (New York City, Chicago, Phoenix, and New Orleans) under the high‐emissions Representative Concentration Pathway (RCP) 8.5. We estimate the conditional quantiles of RH given Tmax with quantile regression models, using functions of temperature for each city in July for three time periods (1990–2005, 2026–2035, and 2071–2080). Quality‐of‐fit diagnostics indicate that these models accurately estimate conditional quantiles for each city. As expected, each quantile of Tmax increases from 1990–2005 to 2071–2080, while mean RH decreases modestly. Conditional upon a fixed quantile of Tmax , the median and high quantiles of RH decrease, while those of the Heat Index (HI) and dew point both increase. This result suggests that, despite a modest decrease in median relative humidity, heat stress measured by metrics considering both humidity and temperature in a warming climate will increase faster than that measured by temperatures alone would indicate. For a fixed Tmax , the high quantiles of RH (and thus of HI and dew point) increase from 1990–2005 to 2071–2080 in all four cities. This result suggests that the heat stress of a day at a given Tmax will increase in a warming climate due to the increase of RH.

Yuan, Jiacan↗

Finite Element Modeling of Diffusion in Fractured Porous Media by Using Hierarchical Material Properties

Abstract Fractured porous media challenge modeling approaches due to high computational costs and excessive mesh refinement imposed by the extreme scale variability of fractures and the heterogeneity of the surrounding porous rock. To overcome such difficulties, we utilize the hierarchical finite element method ( Hi ‐FEM) that has been developed previously to simulate the electrical potential distribution in complex geologic environments. The method employs the hierarchical basis functions in classical finite element analysis to enable representation of material properties on each dimensional component of a given 3D unstructured finite element, thereby inherently allowing for interactions at the boundary between fracture and a host rock. In this study, we extend its application to transient fluid flow and heat conduction in the Laplace domain. Time‐domain flow solutions are obtained by numerical inverse Laplace transform. We evaluate the accuracy of the method using different flow models and demonstrate its robustness for large‐scale, rock mass models featuring complex fracture networks. Moreover, for the computation of nodal Darcian velocity fields in fractured porous media where the fractures are represented as 2D features, a new approach that employs the Yeh's Galerkin model for both volume and facet elements is proposed. Results show that Hi ‐FEM can produce accurate flow solutions for fractured porous media without any need of coupling or transfer mechanism while still being computationally economical and numerically robust, even for large‐scale simulations.

Beskardes, G. D.↗

Probing the Magnetosheath Boundaries Using Interstellar Boundary Explorer (IBEX) Orbital Encounters

Inside the magnetosheath, the IBEX-Hi energetic neutral atom (ENA) imager measures a distinct background count rate that is more than 10 times the typical heliospheric ENA emissions observed when IBEX is outside the magnetosheath. The source of this enhancement is magnetosheath ions of solar wind (SW) origin that deflect around the Earth's magnetopause (MP), scatter and neutralize from the anti-sunward part of the IBEX-Hi sunshade, and continue into the instrument as neutral atoms, behaving indistinguishably from ENAs emitted from distant plasma sources. While this background pollutes observations of outer heliospheric ENAs, it provides a clear signature of IBEX crossings over the magnetospheric boundaries. In this study, we investigate IBEX encounters with the magnetosheath boundaries using ~8 yr of orbital data, and we determine the MP and bow shock (BS) locations derived from this background signal. We find 280 BS crossings from X GSE ~ 11 R e to X GSE ~ –36 R e and 241 MP crossings from X GSE ~ 6 R e to X GSE ~ –48 R e . We compare IBEX BS and MP crossing locations to those from IMP-8, Geotail, Cluster, Magion-4, ISEE, and Magnetospheric Multiscale Mission, and we find that IBEX crossing locations overlap with the BS and MP locations inferred from these other data sets. In this paper, we demonstrate how IBEX can be used to identify magnetosheath crossings, and extend boundary observations well past the terminator, thus further constraining future models of magnetosheath boundaries. Furthermore, we use the IBEX data set to show observational evidence of near-Earth magnetotail squeezing during periods of strong interplanetary magnetic field B y .

79 ASTRONOMY AND ASTROPHYSICS↗

Adsorption and exchange reactions of iodine molecules at the alumina surface: modelling alumina-iodine reaction mechanisms

Harnessing aluminum oxidation energy requires navigating the particle's passivation shell composed of alumina. The shell is a barrier to aluminum oxidation but can also exothermically react with halogenated species and therefore contribute to the overall energy generated during aluminum particle combustion. Fluorination reactions with alumina have been studied because fluorine is abundant in binder formulations that commonly surround aluminum particles in an energetic mixture. However, iodine has emerged as an alternative halogenated-based binder or oxidizer because iodine gas provides ancillary benefits such as chemical neutralization of biological agents or sterilization of contaminated environments. Furthermore, this study used density functional theory (DFT) calculations to evaluate potential reaction pathways for aluminum–iodine combustion. Relative to fluorinated fragments such as HF and F – , the adsorption energies associated with HI and I– are nearly triple the exchange reaction energy available from fluorination reactions with alumina (–189 and –278 kJ mol –1 for HI and I – , respectively). However, exchange reactions between iodinated species and the alumina surface are energetically unfavorable. These results explain that through adsorption, alumina surface exothermic reactions with iodine are more energetic than with fluorine fragments. Experiments performed with differential scanning calorimetry (DSC) confirm the higher magnitude of energy generated for iodination compared with fluorination reactions with alumina. Additionally, strong adsorption energies can promote synthesis of new shell chemistries. Adsorption in solution will promote alumina dissolution and iodine precipitation reactions to produce hydroxyl complexes and iodinated species synthesized on the surface of the particle, thereby replacing alumina with alternative passivation shell chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Modeling of the high column density systems in the Lyman-Alpha forest

The Lyman-α forests observed in the spectra of high-redshift quasars can be used as a tracer of the cosmological matter density to study baryon acoustic oscillations (BAO) and the Alcock-Paczynski effect. Extraction of cosmological information from these studies requires modeling of the forest correlations. While the models depend most importantly on the bias parameters of the intergalactic medium (IGM), they also depend on the numbers and characteristics of high-column-density systems (HCDs) ranging from Lyman-limit systems with column densities log N HI /1cm -2 > 17 to damped Lyman-α systems (DLAs) with log N HI /1cm -2 > 20.2. These HCDs introduce broad damped absorption characteristic of a Voigt profile. Consequently they imprint a component on the power spectrum whose modes in the radial direction are suppressed, leading to a scale-dependent bias. Using mock data sets of known HCD content, we test a model that describes this effect in terms of the distribution of column densities of HCDs, the Fourier transforms of their Voigt profiles and the bias of the halos containing the HCDs. Our results show that this physically well-motivated model describes the effects of HCDs with an accuracy comparable to that of the ad-hoc models used in published forest analyses. We also discuss the problems of applying the model to real data, where the HCD content and their bias is uncertain.

Lyman alpha forest↗

Performance of the ATLAS muon triggers in Run 2

The performance of the ATLAS muon trigger system is evaluated with proton-proton ( pp ) and heavy-ion (HI) collision data collected in Run 2 during 2015–2018 at the Large Hadron Collider. It is primarily evaluated using events containing a pair of muons from the decay of Z bosons to cover the intermediate momentum range between 26 GeV and 100 GeV. Overall, the efficiency of the single-muon triggers is about 68% in the barrel region and 85% in the endcap region. The p T range for efficiency determination is extended by using muons from decays of J ψ mesons, W bosons, and top quarks. The performance in HI collision data is measured and shows good agreement with the results obtained in pp collisions. The muon trigger shows uniform and stable performance in good agreement with the prediction of a detailed simulation. Dedicated multi-muon triggers with kinematic selections provide the backbone to beauty, quarkonia, and low-mass physics studies. The design, evolution and performance of these triggers are discussed in detail.

47 OTHER INSTRUMENTATION↗

Heat metrics and thresholds reshape population exposure and inequality signals

Extreme heat is intensifying worldwide, yet estimates of heat hazard and exposure inequality depend on both the heat metric and how extreme days are defined. Using summer 2022 across the Mediterranean, we quantify population heat exposure with four metrics—land surface temperature (LST), air temperature (Ta), heat index (HI), and wet-bulb globe temperature (WBGT)—under absolute (fixed-value) and relative (anomaly-based) thresholds. Under absolute thresholds, total heat exposure differs by more than two orders of magnitude across metrics (31.3 billion person-days for Ta vs 0.3 billion for HI). Geographic hotspots also diverge: WBGT concentrates in humid coastal North Africa (e.g. the Nile Delta), whereas Ta and LST are more widespread. Under relative thresholds, exposure totals converge and cross-metric hotspot agreement increases (e.g. Ta–WBGT top-tercile overlap increases from 10.7% to 29.0%), shifting hotspots toward densely populated southern Europe. Crucially, the exposure–deprivation relationship also reverses across threshold frameworks: absolute thresholds concentrate exposure in more deprived North Africa and the Middle East, whereas relative thresholds shift the burden toward less-deprived European cities. This sensitivity is decision-relevant: city rankings based on WBGT exposure duration are almost completely reordered when switching threshold frameworks. Threshold choice therefore systematically reshapes hotspot patterns and inequality signals. Reporting both absolute and relative exposures can reveal hidden hotspots and support more targeted heat-risk monitoring and intervention planning.

Mediterranean↗

Post-starburst properties of post-merger galaxies

Post-starburst galaxies (PSBs) are transition galaxies showing evidence of recent rapid star formation quenching. To understand the role of galaxy mergers in triggering quenching, we investigate the incidence of PSBs and resolved PSB properties in post-merger galaxies using both SDSS single-fibre spectra and MaNGA resolved IFU spectra. We find post-mergers have a PSB excess of 10–20 times that relative to their control galaxies using single-fibre PSB diagnostics. A similar excess of ∼ 19 times is also found in the fraction of central (C)PSBs and ring-like (R)PSBs in post-mergers using the resolved PSB diagnostic. However, 60 per cent of the CPSBs + RPSBs in both post-mergers and control galaxies are missed by the single-fibre data. By visually inspecting the resolved PSB distribution, we find that the fraction of outside-in quenching is seven times higher than inside-out quenching in PSBs in post-mergers while PSBs in control galaxies do not show large differences in these quenching directions. In addition, we find a marginal deficit of HI gas in PSBs relative to non-PSBs in post-mergers using the MaNGA-HI data. The excesses of PSBs in post-mergers suggest that mergers play an important role in triggering quenching. Resolved IFU spectra are important to recover the PSBs missed by single-fibre spectra. The excess of outside-in quenching relative to inside-out quenching in post-mergers suggests that AGNs are not the dominant quenching mechanism in these galaxies, but that processes from the disc (gas inflows/consumption and stellar feedback) play a more important role.

79 ASTRONOMY AND ASTROPHYSICS↗

A comparison of the baryonic Tully–Fisher relation in MaNGA and IllustrisTNG

We compare an observed baryonic Tully–Fisher relation (BTFR) from the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) and HI-MaNGA surveys to a simulated BTFR from the cosmological magnetohydrodynamical simulation, IllustrisTNG. To do so, we calibrate the BTFR of the local universe using 377 galaxies from the MaNGA and HI-MaNGA surveys, and perform mock 21 cm observations of matching galaxies from IllustrisTNG. The mock observations are used to ensure that the comparison with the observed galaxies is fair since it has identical measurement algorithms, observational limitations, biases, and uncertainties. For comparison, we also calculate the BTFR for the simulation without mock observations and demonstrate how mock observations are necessary to fairly and consistently compare between observational and theoretical data. We report a MaNGA BTFR of log$_{10} (M_{ \rm Bary}/M_\odot)= (2.97 \pm 0.18)$ log$_{10} V_{ \rm Rot} + (4.04 \pm 0.41)\, \log _{10}{M_{\odot }}$ and an IllustrisTNG BTFR of log$_{10} (M_{ \rm Bary}/M_\odot) = (2.94 \pm 0.23$) log$_{10} V_{ \rm Rot} + (4.15 \pm 0.44)\, \log _{10}{M_{\odot }}$. Thus, MaNGA and IllustrisTNG produce BTFRs that agree within uncertainties, demonstrating that IllustrisTNG has created a galaxy population that obeys the observed relationship between mass and rotation velocity in the observed universe.

79 ASTRONOMY AND ASTROPHYSICS↗

Impacts of Voltage-Based Grid Support Functions on Energy Production of PV Customers

This paper presents the impact of inverter grid- support functions (GSFs) on photovoltaic (PV) customer energy production on a real distribution feeder in Oahu, HI. These autonomous GSFs based on local voltage measurements are good alternatives to increase PV hosting capacity. However, these functions can result in PV energy curtailment to the customer, and this study addresses the concerns about the impact of inverter GSFs through detailed quasi-static time series (QSTS) simulations. It proposes four metrics: maximum and average GSF curtailment, average increased generation and average net generation change, to assess the impact of a given control on PV systems located on customer sites. It was found that curtailment of PV production is negligible for customers where peak voltage is within ANSI C84.1 range. A reliable relationship between curtailment and peak customer voltage is demonstrated, suggesting that peak voltage could be used as an indicator of customer curtailment.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Characterization of NbTi busbar for HL LHC Interaction Region Quadrupoles

The US Accelerator Upgrade for the HiLumi-LHC (US-HL-LHC AUP) project and CERN are designing and fabricating superconducting quadrupole magnets for the interaction regions of the High Luminosity Large Hadron Collider (HLLHC). The triplet is made of three optical elements: Q1, Q2, and Q3. The Nb3Sn quadrupole magnets operate in superfluid He at 1.9 K with a nominal field gradient of 132.6 T/m. The three inner triplet elements are connected together with superconducting buses. The design and fabrication of the through and local buses is carried out at Applied Physics and Superconducting Technology Division (APS-TD) at Fermilab (FNAL). This paper reports the characterization of the bus-bar thermoelectric properties. The bus was tested with a short Nb3Sn magnet (MQXFS1e) in the vertical test facility of the APS-TD at FNAL. The test demonstrated that the bus design is adequate since no spontaneous quench took place up to 17.87 kA current value. Quench propagation velocities were investigated over a range of currents that is typical for accelerator superconducting magnets. Temperature margins were found above that required for the Hi- Lumi triplet bus. The design guarantees the protection of the bus at operational current value according to the quench detection voltage threshold (100 mV) established for the Hi-Lumi LHC interaction region.

43 PARTICLE ACCELERATORS↗

Antigenic Characterization and Pandemic Risk Assessment of North American H1 Influenza A Viruses Circulating in Swine

The first pandemic of the 21st century was caused by an H1N1 influenza A virus (IAV) introduced from pigs into humans, highlighting the importance of swine as reservoirs for pandemic viruses. Two major lineages of swine H1 circulate in North America: the 1A classical swine lineage (including that of the 2009 H1N1 pandemic) and the 1B human seasonal-like lineage. Here, we investigated the evolution of these H1 IAV lineages in North American swine and their potential pandemic risk. We assessed the antigenic distance between the HA of representative swine H1 and human seasonal vaccine strains (1978 to 2015) in hemagglutination inhibition (HI) assays using a panel of monovalent antisera raised in pigs. Antigenic cross-reactivity varied by strain but was associated with genetic distance. Generally, the swine 1A lineage viruses that seeded the 2009 H1 pandemic were antigenically most similar to the H1 pandemic vaccine strains, with the exception of viruses in the genetic clade 1A.1.1.3, which had a two-amino acid deletion mutation near the receptor-binding site, which dramatically reduced antibody recognition. The swine 1B lineage strains, which arose from previously circulating (pre-2009 pandemic) human seasonal viruses, were more antigenically similar to pre-2009 human seasonal H1 vaccine viruses than post-2009 strains. Human population immunity was measured by cross-reactivity in HI assays to representative swine H1 strains. There was a broad range of titers against each swine strain that was not associated with age, sex, or location. However, there was almost no cross-reactivity in human sera to the 1A.1.1.3 and 1B.2.1 genetic clades of swine viruses, and the 1A.1.1.3 and 1B.2.1 clades were also the most antigenically distant to the human vaccine strains. Our data demonstrate that the antigenic distances of representative swine strains from human vaccine strains represent an important part of the rational assessment of swine IAV for zoonotic risk research and pandemic preparedness prioritization.

59 BASIC BIOLOGICAL SCIENCES↗

DEEPEN Global Standardized Categorical Exploration Datasets for Magmatic Plays

DEEPEN stands for DE-risking Exploration of geothermal Plays in magmatic ENvironments. As part of the development of the DEEPEN 3D play fairway analysis (PFA) methodology for magmatic plays (conventional hydrothermal, superhot EGS, and supercritical), weights needed to be developed for use in the weighted sum of the different favorability index models produced from geoscientific exploration datasets. This was done using two different approaches: one based on expert opinions, and one based on statistical learning. This GDR submission includes the datasets used to produce the statistical learning-based weights. While expert opinions allow us to include more nuanced information in the weights, expert opinions are subject to human bias. Data-centric or statistical approaches help to overcome these potential human biases by focusing on and drawing conclusions from the data alone. The drawback is that, to apply these types of approaches, a dataset is needed. Therefore, we attempted to build comprehensive standardized datasets mapping anomalies in each exploration dataset to each component of each play. This data was gathered through a literature review focused on magmatic hydrothermal plays along with well-characterized areas where superhot or supercritical conditions are thought to exist. Datasets were assembled for all three play types, but the hydrothermal dataset is the least complete due to its relatively low priority. For each known or assumed resource, the dataset states what anomaly in each exploration dataset is associated with each component of the system. The data is only a semi-quantitative, where values are either high, medium, or low, relative to background levels. In addition, the dataset has significant gaps, as not every possible exploration dataset has been collected and analyzed at every known or suspected geothermal resource area, in the context of all possible play types. The following training sites were used to assemble this dataset: - Conventional magmatic hydrothermal: Akutan (from AK PFA), Oregon Cascades PFA, Glass Buttes OR, Mauna Kea (from HI PFA), Lanai (from HI PFA), Mt St Helens Shear Zone (from WA PFA), Wind River Valley (From WA PFA), Mount Baker (from WA PFA). - Superhot EGS: Newberry (EGS demonstration project), Coso (EGS demonstration project), Geysers (EGS demonstration project), Eastern Snake River Plain (EGS demonstration project), Utah FORGE, Larderello, Kakkonda, Taupo Volcanic Zone, Acoculco, Krafla. - Supercritical: Coso, Geysers, Salton Sea, Larderello, Los Humeros, Taupo Volcanic Zone, Krafla, Reyjanes, Hengill. **Disclaimer: Treat the supercritical fluid anomalies with skepticism. They are based on assumptions due to the general lack of confirmed supercritical fluid encounters and samples at the sites included in this dataset, at the time of assembling the dataset. The main assumption was that the supercritical fluid in a given geothermal system has shared properties with the hydrothermal fluid, which may not be the case in reality. Once the datasets were assembled, principal component analysis (PCA) was applied to each. PCA is an unsupervised statistical learning technique, meaning that labels are not required on the data, that summarized the directions of variance in the data. This approach was chosen because our labels are not certain, i.e., we do not know with 100% confidence that superhot resources exist at all the assumed positive areas. We also do not have data for any known non-geothermal areas, meaning that it would be challenging to apply a supervised learning technique. In order to generate weights from the PCA, an analysis of the PCA loading values was conducted. PCA loading values represent how much a feature is contributing to each principal component, and therefore the overall variance in the data.

15 GEOTHERMAL ENERGY↗

Three-Dimensional Modeling of the Explicit Chemistry of Organic Aerosols: Formation, Removal, and Comparison with Observations

The major goals of the project were to further our understanding of the formation of secondary organic aerosols (SOA) from major anthropogenic and biogenic precursors, and to evaluate the GECKO-A chemistry model in the context of three DOE-led field campaigns (GoAmazon, BBOP, and HI-SCALE) with the long-term objective of improving the treatment of organic gases and particles in three-dimensional regional and global models. The three field campaigns were selected to evaluate and improve specific aspects of GECKO-A: (i) GoAmazon to help quantify interactions of biogenic and anthropogenic emissions; (ii) BBOP to predict the UV-visible absorption properties of biomass burning aerosols (brown carbon) from explicit molecular properties; and (iii) HI-SCALE to evaluate new model components that include aqueous (cloud) processing of organic gases and aerosols.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗