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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Advanced data analysis in inertial confinement fusion and high energy density physics

Bayesian analysis enables flexible and rigorous definition of statistical model assumptions with well-characterized propagation of uncertainties and resulting inferences for single-shot, repeated, or even cross-platform data. This approach has a strong history of application to a variety of problems in physical sciences ranging from inference of particle mass from multi-source high-energy particle data to analysis of black-hole characteristics from gravitational wave observations. The recent adoption of Bayesian statistics for analysis and design of high-energy density physics (HEDP) and inertial confinement fusion (ICF) experiments has provided invaluable gains in expert understanding and experiment performance. In this Review, we discuss the basic theory and practical application of the Bayesian statistics framework. We highlight a variety of studies from the HEDP and ICF literature, demonstrating the power of this technique. Due to the computational complexity of multi-physics models needed to analyze HEDP and ICF experiments, Bayesian inference is often not computationally tractable. Two sections are devoted to a review of statistical approximations, efficient inference algorithms, and data-driven methods, such as deep-learning and dimensionality reduction, which play a significant role in enabling use of the Bayesian framework. We provide additional discussion of various applications of Bayesian and machine learning methods that appear to be sparse in the HEDP and ICF literature constituting possible next steps for the community. We conclude by highlighting community needs, the resolution of which will improve trust in data-driven methods that have proven critical for accelerating the design and discovery cycle in many application areas.

47 OTHER INSTRUMENTATION↗

Proton deflectometry with in situ x-ray reference for absolute measurement of electromagnetic fields in high-energy-density plasmas

In this work, we report a technique of proton deflectometry that uses a grid and an in situ reference x-ray grid image for precise measurements of magnetic fields in high-energy-density plasmas. A D 3 He fusion implosion provides a bright point source of both protons and x-rays, which is split into beamlets by a grid. The protons undergo deflections as they propagate through the plasma region of interest, whereas the x-rays travel along straight lines. The x-ray image, therefore, provides a zero-deflection reference image. The line-integrated magnetic fields are inferred from the shifts of beamlets between the deflected (proton) and reference (x-ray) images. We developed a system for analysis of these data, including automatic algorithms to find beamlet locations and to calculate their deflections from the reference image. The technique is verified in an experiment performed at OMEGA to measure a nonuniform magnetic field in vacuum and then applied to observe the interaction of an expanding plasma plume with the magnetic field.

47 OTHER INSTRUMENTATION↗

Designing a hybrid electrode toward high energy density with a staged Li + and PF 6 - deintercalation/intercalation mechanism

Existing lithium-ion battery technology is struggling to meet our increasing requirements for high energy density, long lifetime, and low-cost energy storage. Here, a hybrid electrode design is developed by a straightforward reengineering of commercial electrode materials, which has revolutionized the “rocking chair” mechanism by unlocking the role of anions in the electrolyte. Our proof-of-concept hybrid LiFePO 4 (LFP)/graphite electrode works with a staged deintercalation/intercalation mechanism of Li + cations and PF 6 - anions in a broadened voltage range, which was thoroughly studied by ex situ X-ray diffraction, ex situ Raman spectroscopy, and operando neutron powder diffraction. Introducing graphite into the hybrid electrode accelerates its conductivity, facilitating the rapid extraction/insertion of Li + from/into the LFP phase in 2.5 to 4.0 V. This charge/discharge process, in turn, triggers the in situ formation of the cathode/electrolyte interphase (CEI) layer, reinforcing the structural integrity of the whole electrode at high voltage. Consequently, this hybrid LFP/graphite-20% electrode displays a high capacity and long-term cycling stability over 3,500 cycles at 10 C, superior to LFP and graphite cathodes. Importantly, the broadened voltage range and high capacity of the hybrid electrode enhance its energy density, which is leveraged further in a full-cell configuration.

25 ENERGY STORAGE↗

Recognition of V3+/V4+/V5+ Multielectron Reactions in Na3V(PO4)2: A Potential High Energy Density Cathode for Sodium-Ion Batteries

Na3V(PO4)2 was reported recently as a novel cathode material with high theoretical energy density for Sodium-ion batteries (SIBs). However, whether V3+/V4+/V5+ multielectron reactions can be realized during the charging process is still an open question. In this work, Na3V(PO4)2 is synthesized by using a solid-state method. Its atomic composition and crystal structure are verified by X-ray diffraction (XRD) and neutron diffraction (ND) joint refinement. The electrochemical performance of Na3V(PO4)2 is evaluated in two different voltage windows, namely 2.5–3.8 and 2.5–4.3 V. 51V solid-state NMR (ssNMR) results disclose the presence of V5+ in Na2-xV(PO4)2 when charging Na3V(PO4)2 to 4.3 V, confirming Na3V(PO4)2 is a potential high energy density cathode through realization of V3+/V4+/V5+ multielectron reactions.

25 ENERGY STORAGE↗

Measurements of electron temperature in high-energy-density plasmas using gated x-ray pinhole imaging

We present measurements of spatially and temporally resolved electron temperature in high-energy-density plasmas using gated x-ray pinhole imagers. A 2D image of bremsstrahlung x-ray self-emission from laser-driven plasma plumes is detected at the same time through two pinholes covered with different filter materials. By comparing the attenuated signal through each filter, a spatially resolved electron temperature as low as 0.1 keV can be estimated. Measurements of the plasma plume taken from different directions indicate that imaging through extended plasmas has a negligible effect on the temperature estimates. Methods for estimating the expected signal, selecting filters, and incorporating the response of the detector are discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Time-of-flight vs time-of-arrival in neutron spectroscopic measurements for high energy density plasmas

The neutron time-of-flight (nToF) diagnostic technique has a lengthy history in Inertial Confinement Fusion (ICF) and High Energy Density (HED) Science experiments. Its initial utility resulted from the simple relationship between the full width half maximum of the fusion peak signal in a distant detector and the burn averaged conditions of an ideal plasma producing the flux [Lehner and Pohl, Z. Phys. 207, 83–104 (1967)]. More recent precision measurements [Gatu-Johnson et al., Phys. Rev. E 94(8), 021202 (2016)] and theoretical studies [Munro, Nucl. Fusion 56, 035001 (2016)] have shown the spectrum to be more subtle and complicated, driving the desire for an absolute calibration of the spectrum to disambiguate plasma dynamics from the conditions producing thermonuclear reactions. In experiments where the neutron production history is not well measured, but the neutron signal is preceded by a concomitant flux of photons, the spectrum can be in situ calibrated using a set of collinear detectors to obtain a true “time-of-flight” measurement. This article presents the motivation and overview of this technique along with estimates of the experimental precision needed to make useful measurements in existing and future nToF systems such as the pulsed power Z-machine located in Albuquerque, NM, at Sandia National Laboratories.

Fusion experiments↗

An Extensible High Energy Density Modeling Tool for Extreme Regimes

The overreaching goal of the project is to develop a simulation capability to model an entire High Energy Density (HED) target heated by an X-ray Free Electron Laser (XFEL) beam including the surrounding material with a focus on target material associated with subsequent shots. Our primary objective is to study target fratricide problems, where radiation/debris from the current shot degrade the target for subsequent shots. This work will have a large impact on research being conducted at HED facilities where the quality of data is directly related to the effective repetition rate of the driver, which is often limited by target fratricide problems. This project focuses on a stream of closely spaced droplet targets that are appropriate for new very high repetition rate sources such as the ~1 MHz LCLS-II upgraded XFEL. The capability of the PISALE (Pacific Island Structured-AMR with ALE) code is extended to model this class of problems. We summarize the capability and improvements made to the HED branch of the PISALE code. We discuss our simulations of target fratricide for small (5 micron) hydrogen droplets heated by an XFEL beam at SLAC. We also compare simulations of the initial dynamics of larger (50 micron) water droplets, heated by the same XFEL beam, with experimental data. We briefly discuss training, dissemination, and related activities associated with this project.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Physics of Ultra-High Energy Density Relativistic Plasmas from Ordered Nanostructures

This award funded a four-year program at Colorado State University on the physics of ultra-high energy density plasmas generated by focusing femtosecond, >1021 Wcm-2 laser pulses onto ordered nanowire arrays. We used the ALEPH petawatt-class Ti:Sa laser with its high contrast 400 nm second harmonic beamline to irradiate arrays of Ni and TiO2 nanowires made by template assisted electrodeposition and atomic layer deposition over a wide range of average densities. We met two of the three original project goals: radial ion acceleration via doppler shifted K shell emission, and time and spectrally resolved K shell measurements. The main experimental advance was integrating the Lawrence Livermore National Laboratory (LLNL) TREX ultrafast x-ray streak camera with a suite of spherically bent quartz Bragg crystal spectrometers built using Princeton Plasma Physics Laboratory (PPPL) methodology. This is the first TREX-on-bent-quartz setup fielded at a femtosecond, >1021 Wcm-2 facility. It is now a permanent diagnostic at ALEPH and is offered to the LaserNetUS user community. The program produced three peer reviewed journal articles that acknowledge this award. The platform will continue at the upgraded CSU ATLAS facility, where the ALEPH laser is being upgraded to 2 PW.

Hollinger, Reed [Colorado State University]↗

Self-Forming Thin Interphases and Electrodes Enabling 3-D Structured High Energy Density Batteries

An electrolytically in-situ formed fluoride/lithium based battery has been developed to offer a pathway to scalable reconfigurable solid state batteries of high energy density. Research into the development of novel in-situ formed chemistries encompassing the negative and positive reactive current collectors, and the bi-ion glass conductor along with electrode structure was accomplished with a focused attention on transport. The solid state in-situ batteries were fabricated with a maskless scalable patterning technique to offer a pathway to high throughput, low material loss and fabrication of complex architectures. Such development and integration enabled to achieve the 12 V bipolar batteries at > 1000 Wh/L energy density based on electrode pairs and current collectors.

25 ENERGY STORAGE↗

Advancing our understanding of instabilities in high-energy-density systems through the study of benchmark datasets with advanced modeling tools

Numerous types of pulsed power driven inertial confinement fusion (ICF) and high energy density (HED) systems rely on implosion stability to achieve desired temperatures, pressures, and densities. Sandia National Laboratories Pulsed Power Sciences Center’s main ICF platform, Magnetized Liner Inertial Fusion (MagLIF), suffers from implosion instabilities which limit attainable fuel conditions and can compromise fuel confinement. This Truman Fellowship research primarily focused on computationally exploring (a) methods for improving our understanding of hydrodynamic and magnetohydrodynamic instabilities that form during cylindrical liner implosions, (b) methods for mitigating implosion instabilities, particularly those that degrade performance of MagLIF targets, and (c) novel MagLIF target designs intended to improve target performance primarily via enhanced implosion stability. Several multi-dimensional computational tools were used, including the magnetohydrodynamics code ALEGRA, the radiation-magnetohydrodynamics code HYDRA, and the magnetohydrodynamics code KRAKEN. This research succeeded in executing and analyzing simulations of automagnetizing liner implosions, shockless MagLIF implosions, dynamic screw pinch driven cylindrical liner implosions, and cylindrically convergent HED instability studies. The methods and tools explored and developed in this Truman Fellowship research have been published in several peer-reviewed journal articles and will serve as useful contributions to the fields of pulsed power science and engineering, particularly pertaining to pulsed power ICF and HED science.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

High Energy Density Physics of Inertial Confinement Fusion Ablator Materials (Final Technical Report)

The goal of this project was to conduct dynamic compression experiments and predictive simulations to reveal the fundamental high-energy-density (HED) physics of amorphous carbon. These results are essential for assessing amorphous carbon as a potential ablator material for next generation of inertial confinement fusion (ICF) capsules. We made significant progress in exploring the HED properties of amorphous carbon through experiments at Omega EP Laser and the European XFEL, in addition to billion-atom, quantum-accurate molecular dynamics (MD) simulations. Through our joint experimental and simulation program, we mapped the phase diagram of amorphous carbon, uncovering its range of metastability and identifying phase transitions to diamond and liquid carbon along the Hugoniot and at higher pressures using double shock compression pathways. Our findings indicate that amorphous carbon melts at significantly lower shock pressures than high-density carbon (diamond). However, nanocrystalline diamond nucleates across a broad range of pressures and temperatures. This emergence of the nanocrystalline microstructure during compression can negatively impact the planarity of the shock front and potentially trigger ablator/fuel mixing during Inertial Fusion Energy (IFE) applications.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Advancing sustainable aviation fuel with high-energy-density bicycloalkanes production from corn stover mixed sugars

Bicycloalkanes stand out as a replacement for aromatics from conventional jet fuel (CJF) because of their high energy density and lower freezing point. Most reports to date have focused on synthesizing bicycloalkanes using model compounds or single sugar components of lignocellulose. Here, we utilize all lignocellulosic sugars of corn stover (CS) to produce bicycloalkanes. First, furfural (FFR) and 5-hydroxymethyl furfural (5-HMF) are produced via acid-catalyzed dehydration, achieving combined FFRs molar yields ranging from 65% to 73%, respectively. The resulting FFRs are converted to cyclopentanones with molar yields within the range of 57%–63% via hydrogenation and Piancatelli rearrangement. Further aldol condensation of cyclopentanones yields C 10 -C 12 oxygenates with 80 mol %. Lastly, these oxygenates are directly hydrodeoxygenated to bicycloalkanes in a yield of 83.8 mol %. The resulting bicycloalkanes exhibit tier α fuel properties consistent with Jet A fuel (CJF) specifications and blend compatibility with CJF at a 37% volumetric ratio.

09 BIOMASS FUELS↗

Simulation and flow physics of a shocked and reshocked high-energy-density mixing layer

This work describes a computational investigation of multimode instability growth and multimaterial mixing induced by multiple shock waves in a high-energy-density (HED) environment, where pressures exceed 1 Mbar. The simulations are based on a series of experiments performed at the National Ignition Facility (NIF) and designed as an HED analogue of non-HED shock-tube studies of the Richtmyer–Meshkov instability and turbulent mixing. A three-dimensional computational modelling framework is presented. It treats many complications absent from canonical non-HED shock-tube flows, including distinct ion and free-electron internal energies, non-ideal equations of state, radiation transport and plasma-state mass diffusivities, viscosities and thermal conductivities. The simulations are tuned to the available NIF data, and traditional statistical quantities of turbulence are analysed. Integrated measures of turbulent kinetic energy and enstrophy both increase by over an order of magnitude due to reshock. Large contributions to enstrophy production during reshock are seen from both the baroclinic source and enstrophy–dilatation terms, highlighting the significance of fluid compressibility in the HED regime. Dimensional analysis reveals that Reynolds numbers and diffusive Péclet numbers in the HED flow are similar to those in a canonical non-HED analogue, but conductive Péclet numbers are much smaller in the HED flow due to efficient thermal conduction by free electrons. It is shown that the mechanism of electron thermal conduction significantly softens local spanwise gradients of both temperature and density, which causes a minor but non-negligible decrease in enstrophy production and small-scale mixing relative to a flow without this mechanism.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Characterizing x-ray transmission through filters used in high energy density physics diagnostics

We report on the design and implementation of a new system used to characterize the energy-dependent x-ray transmission curve, Θ(E), through filters used in high-energy density physics diagnostics. Using an Amptek X-123-CdTe x-ray spectrometer together with a partially depleted silicon surface barrier detector, both the energy spectrum and total emission of an x-ray source have been accurately measured. By coupling these detectors with a custom PROTO-XRD x-ray source with interchangeable cathodes, accurate characterizations of Θ(E) for filters of varying materials and thicknesses have been obtained. The validity of the technique has been confirmed by accurately reproducing areal densities for high-purity filters with known x-ray transmission properties. In this paper, the experimental setup is described and the results of absorption calibrations performed on a variety of different filters are presented.

47 OTHER INSTRUMENTATION↗

Exploring high-intensity laser-driven secondary sources via high-order spectral pulse shaping for high-energy-density experiments

We present here the results of an investigation that aims to explore the impact of spectral pulse shaping on the generation of high-energy electrons (>1 MeV) and x rays (∼5–9 keV) using a high-intensity (I∼10 21 W/cm 2 ) laser system. The study involved a systematic scan of a broad parameter space in group delay dispersion and third-order dispersion, with variations up to 4 × 10 3 fs −2 and 6 × 10 4 fs −3 , respectively, to identify optimal conditions for enhancing secondary source yields. Several spectral phase conditions were found to significantly enhance the generation of hot electrons and x rays by amounts reaching up to 50% relative to the transform-limited pulse. The experiment, conducted at the Scarlet laser facility (800 nm, 5 J, 30 fs) at the Ohio State University, highlights the potential of spectral pulse shaping as a powerful tool for tuning secondary laser-driven sources. These findings are particularly relevant for advancing brighter x-ray and electron probes for high-energy-density science.

Physics - Plasma physics↗

Generation and Control of Self-Organized Nonlinear Kinetic Structures in High Energy Density Plasmas in the Presence of Intense Magnetic Fields and Ultrashort Laser Pulses

Goals were to study the interplay between electron plasma waves (EPW), KEEN waves and externally generated magnetic fields. In particular, the Weibel instability B field generation process and its interrelationship with the existence of nonlinear EPWs in high energy density plasmas. We focused on a number of models of how Kinetic, Nonlinear Electron Plasma Waves, KNL-EPW and KEEN waves create anisotropic electron velocity distribution functions, e- VDF, and how these anisotropic e- VDFs in turn drive the Weibel instability and generate B fields. Our goal is to control the SRS and SKEENS processes that generate the KNL-EPW, control the anisotropy, and thus also control the dynamics of the resulting B fields, their influence on the transport coefficients and heat transport that results, their modification of SRS itself and the reinforced anisotropy driven loop gain.

(Kinetic electrostatic electron nonlinear) KEEN wa↗

Unlocking multiphysics design guidelines on Si/C composite nanostructures for high-energy-density and robust lithium-ion battery anode

In general, current material fabrication guidance for novel designs of Si/C composite particle materials focuses on electrochemical behavior and redox reactions at the nano/micro level. However, such guidance cannot provide detailed information for predicting mechanical deformations of the composite particles, especially when the mechanical field coupled with electrochemical and thermal fields. Here, we establish an electro-chemo-mechanical model and implement it to quantitatively analyze the multiphysics behavior of five representative Si/C composite nanostructures. Modeling and computation discover that yolk-shell and dual-shell structures are more robust in terms of particle fractures. When considering electrochemical performance, the yolk-shell structure is the best among the compared five Si/C composites. Finally, we map design guidance to further illustrate quantitative structure-property relationships. This study provides novel insights on Si/C composite nanostructure anode material design and additional powerful design tools for next-generation high-energy-density lithium-ion batteries.

25 ENERGY STORAGE↗