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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Development of a Power Metallurgy Superalloy for Use at 1800-2000 F (980-1090 C)

A program was conducted to develop a powder metallurgy nickel-base superalloy for 1800-2000 F (980-1090 C) temperature applications. The feasibility of a unique concept for alloying carbon into a superalloy powder matrix and achieving both grain growth and a discrete particle grain boundary carbide precipitation was demonstrated. The process consisted of blending metastable carbides with a carbon free base alloy and consolidating this blend by hot extrusion. This was followed by heat treatment to grow a desired ASTM No. 2-3 grain size and to solution the metastable carbides to allow precipitation of discrete particle grain boundary carbides during subsequent aging heat treatments. The best alloy developed during this program was hydrogen-atomized, thermal-mechanically processed, modified MAR-M246 base alloy plus VC (0.28 w/o C). Although below those for cast MAR-M246, the mechanical properties exhibited by this alloy represent the best combination offered by conventional powder metallurgy processing to date.

Kortovich, C. S.↗
NASA NTRS1987

Observations of 1.3 millimeter continuum emission from the centers of galaxies

A search for 1.3 mm continuum emission from the centers of eight galaxies has been conducted, and three sources of emission, all apparently arising from cold dust, have been detected. The gas mass associated with this dust is calculated. A rough correlation found between the J = 1-0 CO emission and the millimeter continuum flux, as well as a fair agreement between the masses determined from the two types of observation, support the view that the cool dust is mixed with the molecular material in the program objects. Atomic hydrogen masses estimated for the same cources from 21 cm line observations show that there is little H I in the objects. Most of the objects form stars at about the same efficiency as does the Galaxy.

Thronson, Harley A., Jr.↗
NASA NTRS1996

Air Force NiH2 IPV storage testing

USAF Phillips Laboratory Nickel Hydrogen IPV storage test, performed at the Naval Surface Warfare Center (NSWC) at Crane Indiana, is discussed. The storage tests is just one component of the USAF Phillips Laboratory Nickel Hydrogen IPV Test Program. The plan was to store cells for a defined period and cycle matching cells to determine the effect on cycle life. The storage period was completed in April 95 and the cycling cells have achieved five years of real time LEO cycling. The two main objectives of the storage test are: to investigate various methods on NiH2 cells by using two different manufacturers and two different storage methods or conditions, and to determine the effect of storage method on cycle performance and cycle life by using matching cells cycling at 25% depth of discharge. The comparisons between individual cycle performance as well as cycle life are also reported. During the test the following variables has been considered: constant potential, cell current, open circuit voltage, and temperature. The results of the test are also discussed using charts and tables.

Smellie, Shawn↗
NASA NTRSDate not supplied

Development of a Portable Stand-Alone 20 K Brayton Cycle Helium Refrigeration System

From 2012 to 2015, NASA funded development of the Ground Operations Demonstration Unit for Liquid Hydrogen (GODU-LH2) at Kennedy Space Center that scaled up and matured Integrated Refrigeration and Storage (IRAS) technology. IRAS involves the integration of an external helium refrigeration system with a cryogenic storage tank via an internal heat exchanger and allows advanced operations such as zero boiloff and densification of the liquid. The refrigeration system employed for GODU-LH2 was a Linde LR1620 piston-Brayton cycle machine with an RSX helium compressor. The GODU-LH2 system was installed in two separate shipping containers—one housing the cold-box, compressor, and gas management hardware, and the other the water chiller unit—with 480 VAC and 120 VAC electrical power fed from external hardware at the test site, and data capture and controls achieved using four different, independent software packages. From 2017 to 2019, in support of a densified hydrogen loading test program, the entire system was repackaged into a single, 40’ (12 m) shipping container, including the refrigeration system, water chiller, and electrical power distribution hardware, and controls were consolidated into a single Allen Bradley PanelView. Details regarding the design, build-out, and testing of the system will be presented and discussed.

W F Reaves↗
NASA NTRS2013

Internship at NASA Kennedy Space Center's Cryogenic Test laboratory

NASA's Kennedy Space Center (KSC) is known for hosting all of the United States manned rocket launches as well as many unmanned launches at low inclinations. Even though the Space Shuttle recently retired, they are continuing to support unmanned launches and modifying manned launch facilities. Before a rocket can be launched, it has to go through months of preparation, called processing. Pieces of a rocket and its payload may come in from anywhere in the nation or even the world. The facilities all around the center help integrate the rocket and prepare it for launch. As NASA prepares for the Space Launch System, a rocket designed to take astronauts beyond Low Earth Orbit throughout the solar system, technology development is crucial for enhancing launch capabilities at the KSC. The Cryogenics Test Laboratory at Kennedy Space Center greatly contributes to cryogenic research and technology development. The engineers and technicians that work there come up with new ways to efficiently store and transfer liquid cryogens. NASA has a great need for this research and technology development as it deals with cryogenic liquid hydrogen and liquid oxygen for rocket fuel, as well as long term space flight applications. Additionally, in this new era of space exploration, the Cryogenics Test Laboratory works with the commercial sector. One technology development project is the Liquid Hydrogen (LH2) Ground Operations Demonstration Unit (GODU). LH2 GODU intends to demonstrate increased efficiency in storing and transferring liquid hydrogen during processing, loading, launch and spaceflight of a spacecraft. During the Shuttle Program, only 55% of hydrogen purchased was used by the Space Shuttle Main Engines. GODU's goal is to demonstrate that this percentage can be increased to 75%. Figure 2 shows the GODU layout when I concluded my internship. The site will include a 33,000 gallon hydrogen tank (shown in cyan) with a heat exchanger inside the hydrogen tank attached to a refrigerator capable of removing 850 Watts at 20 Kelvin (shown in green). The refrigerator and most of its supporting equipment will be kept in a standard shipping container (shown in pink). Currently, GODU is in the fabrication process and some of the large components have already been purchased.

Holland, Katherine↗
NASA NTRS1994

An investigation of the effect of surface impurities on the adsorption kinetics of hydrogen chemisorbed onto iron

The goal of this program has been to develop an understanding of heterogeneous kinetic processes for those molecular species which produce gaseous hydrogen degradation of the mechanical properties of metallic structural materials. During the present program, the interaction of hydrogen with the surfaces of alpha-2 (Ti3Al) titanium aluminide, gamma (TiAl) titanium aluminide, and beryllium were studied. The interaction of low pressure hydrogen with gamma titanium aluminide and beryllium was found to be relatively weak. Weak in the sense that adsorption leads to a low surface concentration of dissociated hydrogen, i.e., the chemisorption process is reversible at room temperature (300 K) for gamma titanium aluminide and the sticking coefficient for chemisorption is extremely small for beryllium. Hydrogen was found to interact readily with alpha-2 titanium aluminide to form a stable surface hydride at 300 K. These results correlate well with other recent studies which show that the mechanical properties for alpha-2 titanium aluminide are readily degraded in hydrogen while gamma titanium aluminide exhibits less degradation and beryllium essentially no degradation. The interaction of oxygen with the surface of several of these materials was studied. More recently, preliminary hydrogen permeation studies were completed for three high temperature alloys, Incoloy 909, Mo-47.5Re (wt. %), and this past year, Haynes 188.

Shanabarger, Mickey R.↗
NASA NTRS1986

Modeling the temporal and spatial variations of the vertical structure of Jupiter's atmosphere using observations of the 3-0 hydrogen quadrupole lines

An observational program was established in 1983 to monitor the spatial and temporal variations in the Jovian atmosphere over short and long time scales. The program involves tracking several different longitudes as they rotate around the planet from one limb to another. This tracking experiment was done at many different wavelengths including the 3-0 S(1) and S(0) hydrogen quadrupole lines as well as several broad band methane absorptions. The June 1983 hydrogen quadrupole data was reduced and equivalent widths were measured for approximately 25 east-west positions across the planet at 7 different latitudes for both wavelengths. The data for the South Tropical Zone (20 deg. S) was modeled extensively and the effects of the various model parameters on the value of the calculated equivalent widths of both lines was measured as a longitude rotated from the east (or morning) limb to the west (or evening) limb. The value of the equivalent width is also quite sensitive to the height of the NH3 cloud top and to the value used for the single scattering albedo. A combination of these parameters changing on a diurnal time scale could also explain these observations. This gradual increase from one limb to the other appears in the data for both the North and South Equatorial Belts as well as the equatorial region and the North Tropical Zone. Models that used only normal hydrogen and models that used only equilibrium hydrogen were studied.

Cunningham, C. C.↗
NASA NTRS1977

Program Documentation for Elapsed Time to Oxygen and Hydrogen Caution and Warning System for Captive/active 1 and 3 Flights

High pressure gas storage simulation runs were made to compute the elapsed time from T-O disconnect (transfer to onboard reactant) to the caution and warning pressures for the primary oxygen (O2) and hydrogen (H2) systems of Orbiter Vehicle (OV) 101. The simulation runs were made for approach and landing test flights Captive/Active 1 and Captive/Active 3.

Hurst, J. E.↗
NASA NTRSDate not supplied

Exploring the Potential of Hydrogen as a Lift Gas for Nasa’s Scientific Balloon Program

The United States National Aeronautics and Space Administration (NASA) Balloon Program has a rich history of conducting scientific research in the stratosphere, offering a unique platform for experiments in the near-space environment. One critical component of these high-altitude balloons is the choice of lift gas, which is pivotal to achieving the desired altitude and, thus, mission objectives. Traditionally, helium has been the preferred lift gas due to its inert properties and safety considerations. However, the increasing demand and limited global helium reserves have prompted NASA to explore alternative lift gases, with hydrogen emerging as the most logical choice. Hydrogen boasts several advantages, including its abundant availability, cost-effectiveness, and enhanced lift capability compared to helium. Moreover, it can support a wide range of scientific payloads, enabling extended mission durations and increased payload capacities, ultimately strengthening the program’s scientific potential. However, adopting hydrogen as a lift gas is not without challenges. Safety concerns, especially during the launch and recovery phases, are paramount. NASA and the other major players in the scientific ballooning community have been developing stringent safety protocols and engineering solutions to mitigate these risks. This development includes specialized support systems, leak detection mechanisms, and enhanced launch and recovery procedures. Additionally, environmental considerations must be carefully evaluated. Hydrogen release has the potential to increase concentrations of various greenhouse gases, and its usage must be balanced against the benefits it offers to scientific research and exploration. This paper delves into the ongoing research and development efforts to ensure balloon-based research’s long-term sustainability and its ability to continue pushing the boundaries of scientific discovery. This research demonstrates NASA’s commitment to innovation, safety, and environmental responsibility while maintaining its mission to advance our understanding of the Earth and the cosmos.

balloon↗
NASA NTRS1990

Hydrogen environment effects on beryllium and titanium aluminides

The NASP program has intensively studied the hydrogen-environment embrittlement (HEE) susceptibility of Be, alpha(2)-Ti3Al, and gamma-TiAl. Tensile tests are being conducted on candidate aerospace structure and propulsion candidate materials from each of the three groups, at temperatures in the -130 to +204 C range, in both 0.1 MPa and 13.8 MPa He and H2 environments, using SEM and TEM to discern the details of environmental effects. It has been established that while alpha(2) Ti3Al is HEE-susceptible even in the room-temperature and 13.8 MPa environment, neither Be nor gamma-TiAl are susceptible, even at the highest temperature tested.

Fritzemeier, L. G.↗
NASA NTRS2015

Color Changing Hydrogen Sensors

During the Space Shuttle Program, one of the most hazardous operation that occurred was the loading of liquid hydrogen (LH2) during fueling operations of the spacecraft. Due to hydrogen's low explosive limit, any amount leaked could lead to catastrophic event. Hydrogen's chemical properties make it ideal as a rocket fuel; however, the fuel is deemed unsafe for most commercial use because of the inability to easily detect the gas leaking. The increased use of hydrogen over traditional fossil fuels would reduce greenhouse gases and America's dependency on foreign oil. Therefore a technology that would improve safety at NASA and in the commercial sector while creating a new economic sector would have a huge impact to NASA's mission. The Chemochromic Detector for sensing hydrogen gas leakage is a color-changing detector that is useful in any application where it is important to know not only the presence but also the location of the hydrogen gas leak. This technology utilizes a chemochromicpigment and polymer matrix that can be molded or spun into rigid or pliable shapes useable in variable temperature environments including atmospheres of inert gas, hydrogen gas, or mixtures of gases. A change in color of the detector material indicates where gaseous hydrogen leaks are occurring. The irreversible sensor has a dramatic color change from beige to dark grey and remains dark grey after exposure. A reversible pigment changes from white to blue in the presence of hydrogen and reverts back to white in the presence of oxygen. Both versions of the sensor's pigments were comprised of a mixture of a metal oxide substrate and a hydro-chromic compound (i.e., the compound that changed color in the presence of hydrogen) and immediately notified the operator of the presence of low levels of hydrogen. The detector can be used in a variety of formats including paint, tape, caulking, injection molded parts, textiles and fabrics, composites, and films. This technology brings numerous benefits over the traditional hydrogen sensors: The technology has excellent temperature stability (4K to 373 K), it can be used in cryogenic fluid applications, it is easy to apply and remove; it requires no power to operate; it has a quick response time; the leak points can be detected visually or electronically; it is nonhazardous, thus environmentally friendly; it can be reversible or irreversible; it does not require on-site monitoring; has a long shelf life; the detector is very durable; and the technology is inexpensive to manufacture.

Chemochromic sensor↗
NASA NTRS1985

Adsorption and recombination of hydrogen atoms on a model graphite surface

The adsorption and recombination of atomic hydrogen on a model graphite grain have been examined in a series of calculations in which a modified, iterative, extended Hueckel program was used. The hydrogen atom is found to be chemisorbed at a site with a zero-point binding energy of 0.7 eV and at an equilibrium distance of 2.25 A above the site. Despite a barrier of about 0.4 eV between adjacent sites, calculations suggest that at temperatures as low as 10 K, an H atom will tunnel through to adjacent sites in less than one nanosecond. However, a potential barrier to the recombination of two hydrogen atoms has been found which displays high sensitivity to the mutual arrangement of the two hydrogen atoms with respect to the graphite surface. Results show that at very low temperatures, recombinations can occur only by tunneling. Consistent with experiment, the region in which H2 begins to form exhibits a repulsive potential with respect to possible chemisorption of the incipient H2 entity.

Aronowitz, S.↗
NASA NTRSDate not supplied

Modeling of Cryogenic Heated-Tube Flow Boiling Experiments of Hydrogen and Helium With the Generalized Fluid System Simulation Program

Accurate modeling of cryogenic boiling heat transfer is vital for the development of extended-duration space missions. Such missions may require the transfer of cryogenic propellants from in-space storage depots or the cooling of nuclear reactors. Purdue University in collaboration with NASA has assembled a database of cryogenic flow boiling data points from heated-tube experiments dating back to 1959, which has been used to develop new flow boiling correlations specifically for cryogens. Computational models of several of these experiments have been constructed in the Generalized Fluid System Simulation Program (GFSSP), a network flow code developed at NASA’s Marshall Space Flight Center. The new Purdue-developed universal correlations cover the full boiling curve: onset of nucleate boiling, nucleate boiling, critical heat flux, and film boiling. These correlations have been coded into GFSSP user subroutines. The fluids modeled in this study are liquid hydrogen and liquid helium. Predictions of local wall temperature and pressure drop are presented and compared to the test data.

multi-phase flow↗
NASA NTRS1985

Fuel-rich catalytic combustion: A soot-free technique for in situ hydrogen-like enrichment

An experimental program on the catalytic oxidation of iso-octane demonstrated the feasibility of the two-stage combustion system for reducing particulate emissions. With a fuel-rich (phi = 4.8 to 7.8) catalytic combustion preburner as the first stage the combustion process was soot free at reactor outlet temperatures of 1200 K or less. Although soot was not measured directly, its absence was indicated. Reaction products collected at two positions downstream of the catalyst bed were analyzed on a gas chromatograph. Comparison of these products indicated that pyrolysis of the larger molecules continued along the drift tube and that benzene formation was a gas-phase reaction. The effective hydrogen-carbon ratio calculated from the reaction products increased by 20 to 68 percent over the range of equivalence ratios tested. The catalytic partial oxidation process also yielded a large number of smaller-containing molecules. The fraction of fuel carbon in compounds having two or fewer carbon atoms ranged from 30 percent at 1100 K to 80 percent at 1200 K.

Brabbs, T. A.↗
NASA NTRS1999

Methane Pyrolysis and Disposing Off Resulting Carbon

Sabatier/Electrolysis (S/E) is a leading process for producing methane and oxygen for application to Mars ISPP. One significant problem with this process is that it produces an excess of methane for combustion with the amount of oxygen that is produced. Therefore, one must discard roughly half of the methane to obtain the proper stoichiometric methane/oxygen mixture for ascent from Mars. This is a waste of hydrogen, which must be brought from Earth and is difficult to transport to Mars and store on Mars. To reduce the problem of transporting hydrogen to Mars, the S/E process can be augmented by another process which reduces overall hydrogen requirement. Three conceptual approaches for doing this are (i) recover hydrogen from the excess methane produced by the S/E process, (ii) convert the methane to a higher hydrocarbon or other organic with a lower H/C ratio than methane, and (iii) use a separate process (such as zirconia or reverse water gas shift reaction) to produce additional oxygen, thus utilizing all the methane produced by the Sabatier process. We report our results here on recovering hydrogen from the excess methane using pyrolysis of methane. Pyrolysis has the advantage that it produces almost pure hydrogen, and any unreacted methane can pass through the S/E process reactor. It has the disadvantage that disposing of the carbon produced by pyrolysis presents difficulties. The goals of a research program on recovery of hydrogen from methane are (in descending priority order): 1) Study the kinetics of pyrolysis to arrive at a pyrolysis reactor design that produces high yields in a confined volume at the lowest possible operating temperature; 2) Study the kinetics of carbon burnoff to determine whether high yields can be obtained in a confined volume at acceptable operating temperatures; and 3) Investigate catalytic techniques for depositing carbon as a fine soot which can be physically separated from the reactor. In the JPL program, we have made significant measurements in regard to goal 1, cursory measurements in regard to goal 2, and would plan to pursue goal 3 if additional resources are secured.

Sharma, P. K.↗
NASA NTRS1978

Computer model for refinery operations with emphasis on jet fuel production. Volume 3: Detailed systems and programming documentation

The FORTRAN computing program predicts flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuels of varying end point and hydrogen content specifications. The program has a provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case.

Dunbar, D. N.↗