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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
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NASA NTRS1982

The scattering phase function of interstellar grains - The case of the reflection nebula NGC 7023

IUE observations of the reflection nebula NGC 7023 and the illuminating star, HD 200775, in the spectral range from 1300 to 3100 A are combined with ground-based measurements of the nebular brightness distribution at 3500, 4100, 4700, and 5500 A to determine the scattering properties of the nebular dust grains. Total nebular fluxes are derived from existing data obtained by satellite and ground-based observations. The relevance of far-IR fluxes from the nebula is considered, and models are derived that are applicable to NGC 7023 both with respect to the ratio of nebular to stellar fluxes and with respect to the nebular surface brightness distribution. It is shown that the average grain albedo in the UV is about 0.54 and that the albedo increases to a level of about 0.6 at 1400 A after reaching a minimum of approximately 0.4 near 2200 A. The results suggest that isotropically scattering particles of high albedo make a significant contribution to interstellar scattering in the far-UV.

Witt, A. N.↗
NASA NTRS1999

An infrared spectral match between GEMS and interstellar grains

Infrared spectral properties of silicate grains in interplanetary dust particles (IDPs) were compared with those of astronomical silicates. The approximately 10-micrometer silicon-oxygen stretch bands of IDPs containing enstatite (MgSiO3), forsterite (Mg2SiO4), and glass with embedded metal and sulfides (GEMS) exhibit fine structure and bandwidths similar to those of solar system comets and some pre-main sequence Herbig Ae/Be stars. Some GEMS exhibit a broad, featureless silicon-oxygen stretch band similar to those observed in interstellar molecular clouds and young stellar objects. These GEMS provide a spectral match to astronomical "amorphous" silicates, one of the fundamental building blocks from which the solar system is presumed to have formed.

NASA Discipline Exobiology↗
NASA NTRS1984

Relic interstellar grains in Murchison meteorite

It is shown that, in the Murchison meteorite, the D/H ratios of hydrogen are unusually high in several separates and in one case up to 30 times the cosmic value of 2 x 10 to the -5th. Many phases show high C-13/C-12 ratios, up to 2.5 times the terrestrial value of 0.011. These C-13-rich and D-rich components of the two chemical elements are not correlated. They are heterogeneously distributed, suggesting that different components in the meteorite originated from different astrophysical sites and at different times. The D-rich hydrogen in the meteorite is probably due to molecules formed by ion-molecule reactions in interstellar clouds while the tiny amount of C-13-rich carbon is probably due to nucleosynthesis in red giant stars as suggested by Swart et al. (1983). Both of these heavy-isotope enriched components survived homogenization in the accumulation and subsequent history of the meteorites.

Yang, J.↗
NASA NTRS1978

Interplanetary dust - Possible implications for comets and presolar interstellar grains

Interplanetary dust is important to studies of the origin of the solar system because it is material from comets and asteroids, the smallest surviving bodies from the early solar system. The fact that comets are the major suppliers of the millimeter meteoroids which produce optical meteors suggests that a significant fraction of the submillimeter portion of the meteoroid complex is also cometary material. While comets are probably the major source, it is important to remember that the dust presently impacting the earth was probably generated by a number of different parent bodies. The collection of interplanetary dust is considered and a description is presented of the physical properties of interplanetary dust, taking into account the structure, elemental composition, and mineralogy.

Brownlee, D. E.↗
NASA NTRS1980

Behavior of molecules on interstellar grains - Application of the Langevin equation and iterative extended Hueckel

The Langevin equation was used to explore an adsorbate desorption mechanism. Calculations were performed using iterative extended Hueckel on a silica model site with various small adsorbates, e.g., H, CH, OH, NO, CO. It was found that barriers to free traversal from one site to another are substantial (about 3-10 eV). A bootstrap desorption mechanism for some molecules in the process of forming at a site also became apparent from the calculations. The desorption mechanisms appear to be somewhat balanced by a counterforce - the attraction of sites for the newly desorbed molecule. The order of attraction to a silica grain site for the diatomic molecules considered was OH greater than CH greater than CO greater than NO, when these entities were sufficiently distant. The nature of the silica grain and that of the 'cold' desorption mechanism, when considered together, suggest that the abundance of very small grains might be less common than anticipated.

Aronowitz, S.↗
NASA NTRS1983

A note on the composition and structure of interstellar grains

The plausibility of relatively pure diatomic oxide crystals forming in the expanding atmospheres of cool stars is commented on, and the likelihood of SiO grains condensing is discussed on the basis of laboratory nucleation experiments. Results of annealing experiments are used to consider the further evolution of silicon oxide and silicate grains. The evidence shows that SiO solids form only when SiO condenses directly onto surfaces, and that the probability of pure crystalline SiO grains forming is rather small.

Nuth, J. A.↗
NASA NTRS1988

A comparison of Halley dust with meteorites, interplanetary dust and interstellar grains

The variability of the mineral forming elements in the submicron Halley grains provides a powerful basis for comparison of Halley with the different classes of meteoritic materials that have been studied in the lab. The degree of variability in the Halley samples is larger than that seen in chondrites implying that Halley is more heterogeneous at the submicron scale. A critical distinction is that Halley contains abundant pure Mg silicates at the size scale while the carbon rich meteorites do not. The submicron dispersion composition seen in Halley is dramatically different from the narrowly constrained compositions seen in CI and CM (type 1 and 2) carbonaceous chondrites. These meteorites are carbon rich but are dominated by a hydrated silicate with a very narrow range of Mg/Si ratio. The Halley results are also unlike the composition variations seen in most of interplanetary dust types that are dominated by hydrated materials. The only known class of meteoritic material that appear to closely resemble the Halley data is a class of cosmic dust composed entirely of anhydrous minerals. The composition implies that Halley is dominated by olivine, pyroxene, iron sulfide, glass and amorphous carbonaceous matter.

Brownlee, D. E.↗
NASA NTRS1988

The condensation and vaporization behavior of H2O:CO ices and implications for interstellar grains and cometary activity

IR spectroscopy has been used to ascertain several parameters associated with CO, H2O, and H2O:CO ices' physical behavior. Since CO is noted to be capable of condensing into H2O-rich ices at temperatures that are twice as high as those required for condensation in pure CO, CO is able to condense onto H2O-rich ice grains at temperatures of up to 50 K. CO's presence in H2O ice modestly enhances the effective volatility of the H2O. Attention is given to the implications of these results for cometary models generally and the question of cometary formation specifically.

Sandford, Scott A.↗
NASA NTRS1988

On PAHs as interstellar grains - Infrared absorption coefficients

Consideration is given to the proposal that PAHs are the source of IR continuum and emission features and the visible diffuse bands. Absolute IR cross-sections have been obtained for eight PAHs. The results show that a thermal continuum is not consistent with the spectra obtained, and that an array of normal molecules shows a spectrum that is more complex than the observed spectrum. The cross-sections of the UV spectra are 2-3 orders of magnitude larger than those of the IR spectra. It is suggested that, to account for these observations, structure must be produced in the UV extinction curve.

Salisbury, D. W.↗
NASA NTRS1991

The SiH vibrational stretch as an indicator of the chemical state of interstellar grains

The infrared spectra of amorphous silicate grains and films formed in a variety of laboratory experiments have been measured. It is found that the frequency of the SiH fundamental stretch is extremely sensitive to the chemical environment of the grain in which the silicon is bound and varies from 2270/cm in oxidized grains to 2110/cm in a reducing environment. It is proposed that features previously observed in W33A could be due to -SiH groups in amorphous silica, partially reduced silica, silicon nitride or slightly oxidized silicon carbide. It is predicted that observations at 2270/cm will reveal a feature due to -SiH groups in highly oxidized interstelar and circumstellar grains. Such a feature might also appear in the spectra of comets.

Moore, Marla H.↗
NASA NTRS1991

X-ray irradiation of interstellar grains in active galaxies - Evaporation and infrared spectra

A fundamental physical study of grains heated transiently by X-rays is presented. The X-ray photoionization cross sections used to determine the rate of energy deposition into the grains are given. A grain model is constructed and the radiative and evaporative responses of grains into X-ray absorption are described. The basic theory of stochastic grain heating is outlined, and analytical expressions for the temperature distributions of flickering grains are provided. The resulting IR spectra due to X-ray illumination are given, and the relevance of the present work to the IR continua of active galaxies is discussed. The present model provides two observational predictions: the infrared spectra of grains, even if they are superheated, should show a cutoff between 1 and 3 microns; and X-ray-illuminated environments should exhibit no PAH emissions.

Voit, G. M.↗
NASA NTRS1995

High-Density Amorphous Ice, the Frost on Interstellar Grains

Most water ice in the universe is in a form which does not occur naturally on Earth and of which only minimal amounts have been made in the laboratory. We have encountered this 'high-density amorphous ice' in electron diffraction experiments of low-temperature (T less than 30 K) vapor-deposited water and have subsequently modeled its structure using molecular dynamics simulations. The characteristic feature of high-density amorphous ice is the presence of 'interstitial' oxygen pair distances between 3 and 4 A. However, we find that the structure is best described as a collapsed lattice of the more familiar low-density amorphous form. These distortions are frozen in at temperatures below 38 K because, we propose, it requires the breaking of one hydrogen bond, on average, per molecule to relieve the strain and to restructure the lattice to that of low-density amorphous ice. Several features of astrophysical ice analogs studied in laboratory experiments are readily explained by the structural transition from high-density amorphous ice into low-density amorphous ice. Changes in the shape of the 3.07 gm water band, trapping efficiency of CO, CO loss, changes in the CO band structure, and the recombination of radicals induced by low-temperature UV photolysis all covary with structural changes that occur in the ice during this amorphous to amorphous transition. While the 3.07 micrometers ice band in various astronomical environments can be modeled with spectra of simple mixtures of amorphous and crystalline forms, the contribution of the high-density amorphous form nearly always dominates.

Jenniskens, P.↗