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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Synthetic Pathways to gamma-Graphyne and Related Allotropes of Carbon

Graphynes, two-dimensional carbon lattices combining sp 1 and sp 2 hybridized atoms, were predicted theoretically more than three decades ago, but few structures have been realized to date. These carbons are believed to possess remarkable mechanical and electronic properties, including high charge carrier mobilities comparable to those in graphene (10 4 to 10 5 cm 2 V -1 s -1 ). Unlike graphene, certain graphynes are predicted to be intrinsic semiconductors. Among these intriguing structures, γ-graphyne stands out as the structurally simplest and most symmetric sp 1 /sp 2 lattice. γ-Graphyne was first theorized in 1987. In contrast with graphene, γ-graphyne will be a semiconductor with a small band gap suitable for fabrication of electronic devices. This solves one of the fundamental problems of carbon-based electronics, the necessity for inducing a band gap in graphene. γ-Graphyne has the potential to form the basis for the next generation of carbon-based electronics operating at speeds unattainable by traditional silicon chips. Unlike silicon, γ-graphyne is a direct band gap semiconductor, and it will feature exceptional strength comparable to that of other 2D carbon allotropes. Such combination of properties may enable a new generation of highly efficient, ultra-light and flexible solar cells. Despite being a potentially “magical” material, γ-graphyne remained synthetically elusive for over three decades. The primary goals of this project were: (1) Synthesis of bulk γ-graphyne phases through solution-phase 2D polymerizations; (2) Experimental exploration of the physical and chemical properties of γ-graphyne; and (3) Mechanistic and theoretical studies of the novel chemical transformations developed in Goal 1. Common pyrolytic and vapor-deposition methodologies used for the synthesis of graphitic allotropes are unsuitable for graphyne and other sp 1 -contaning structures, as acetylenes readily convert to graphene and amorphous carbon at high temperatures. In contrast, this proposal is based on solution-based 2D polymerization. The major advantages of this approach over the traditional high temperature techniques are the potential to adjust the structure of the material with atomic precision, and the possibility of using structurally complex and relatively fragile repeat units. The outcomes of this research can revolutionize carbon nanotechnology, expanding the field’s structural toolbox beyond primarily graphitic and benzenoid structures. Understanding the chemistry of sp 1 carbon allotropes can lead to entirely new classes of structures with unique properties, including graphyne ribbons, nanotubes, quantum dots, and heterostructures with other 2D materials. Furthermore, the development of reliable and robust synthetic pathways towards periodic covalent molecular sheets with atomically precise structures shall have a profound impact on chemistry and materials science.

2D polymerization↗
DOE OSTI2022

Research on oxygen solubility in aqueous amine solvents with common additives used for CO 2 chemical absorption

Oxidative degradation in amine based post-combustion carbon capture (PCCC) leads to solvent losses and decreased solvent performance. Oxygen (O 2 ) in the flue gas is dissolved into the aqueous solvent and can reactively degrade the amine component. Advanced aqueous amine solvents are designed to contain additional surfactant and anti-foam additives as well as two types of corrosion inhibitors. These additives contribute to improve the solvent performance while reducing foaming and corrosion of expensive equipment. This work examines the impact of these additives on oxygen solubility (or dissolved oxygen - DO) in various aqueous amines used in PCCC including ethanolamine (MEA), 1-amino-2-propanol (A2P), 2-amino-1-propanol (2A1P), 2-(methylamino)-ethanol (NMEA), 2-(ethylamine)-ethanol (2EAE), diethanolamine (DEA), methyl-diethanolamine (MDEA), dimethylethanolamine (DMEA), piperazine (PZ), 1,2-ethyldiamine (EDA), and 1,6 hexadiamine (HDA). Further, the impact of carbon loading on oxygen solubility with and without these additives was also examined. The surfactant and anti-foam additives had minimal impact on DO for all the solvents investigated. The two anticorrosion additives had opposite effects in the measured DO, 2- mercaptobenzothiazole (MBT) decreased the DO concentration, and sodium metavanadate showed an increase. These results indicate that several of these common additives can be expected to minimally affect DO related oxidative degradation in these advance amine solvents.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2026

Multi-omic characterization of a soil microbial consortium reveals critical role of succinate and glutamate metabolism during calcium carbonate precipitation

Microbially induced calcium carbonate precipitation (MICP) holds potential for use in soil stabilization and carbon sequestration, with the overall efficiency of the process being a major determinant for use in many environmental and civil engineering applications. While the biogeochemical pathways and enzymes driving MICP are known, the microbial metabolic networks and community dynamics underlying such precipitation remain poorly characterized. To address this gap, we developed a four-member consortium of soil bacteria (Curtobacterium flaccumfaciens, Rhodococcus qingshengii, Microbacterium sp., and Bacillus toyonensis), termed carbon storing consortium - A (CSC-A), that is capable of MICP. Prior work shows that MICP production is higher in CSC-A compared to the sum of carbonate produced by each member, suggesting carbonate production is driven by consortium dynamics. To that end we used a multi-omic integration approach of genomics, transcriptomics, and metabolomics to investigate potential inter-species interactions that may influence the MICP phenotype. Genomic life history characterizations identified evidence of niche specialization by B. toyonensis and Microbacterium, while metatranscriptomic analysis suggests R. qingshengii is a keystone species during growth in urea. By comparing individual species’ metabolomes to the metabolic profile of a shared well of precipitated metabolites, we identified over 200 metabolites predicted to be produced or consumed by CSC-A members. Integrating both data types to search the KEGG reactome highlighted a network centered around glutamine metabolism and branched chain amino acid biosynthesis under regulation during CSC-A growth in urea. Succinate metabolism was also a major node in this network and laboratory assays confirmed that increasing the amount of succinate in the growth medium leads to increased carbonate precipitation by CSC-A, a critical confirmation of our modeling approach. By isolating and identifying the interconnected metabolic components underlying MICP in CSC-A, we identified keystone taxa, metabolites, and pathways important for future optimization of the application of this consortia to carbonate precipitation.

carbon storing consortium - A (CSC-A)↗
DOE OSTI2025

Growth–Mortality Coordination Differs Among Xerophytic Versus Mesophytic Tree Species During Severe Drought

ABSTRACT Forest composition is changing, yet the consequences for terrestrial carbon cycling are unclear. In the eastern United States, water‐demanding “mesophytic” tree species are replacing “xerophytic” oaks (Quercusspp.) and hickories (Caryaspp.), raising concerns that forest productivity will become increasingly sensitive to more frequent and severe drought conditions predicted for the region. However, we have a limited understanding of the extent to which the mortality risk of xerophytes versus mesophytes is coordinated with their growth sensitivity during drought. Here, we evaluated growth and mortality dynamics for 20 abundant eastern United States tree species following a severe drought in the summer of 2012. We synthesized data from ~4500 forest inventory plots and used an approach that quantified relative drought responses between co‐located trees to minimize impacts from environmental heterogeneity. We found that mesophytes were just as likely to perish as co‐occurring xerophytes but were more sensitive to drought in terms of diminished growth. These findings suggest that xerophytic decline is likely to lead to reduced carbon uptake during drought and that management efforts to conserve oak‐hickory stands will be decisive to sustain the carbon mitigation potential of these forests. However, we also found that growth‐mortality relationships differed between functional groups. Among xerophytes, growth and survival during drought were decoupled. Among mesophytes, there was a high degree of coordination, where species that experienced greater mortality also experienced greater growth reductions. Therefore, mesophytes with high growth sensitivity to water deficits are likely to be the most vulnerable to drought‐driven die‐off events moving forward.

Biodiversity & Conservation↗
DOE OSTI2023

Enhancing CO 2 Transport Across a PEEK‐Ionene Membrane and Water‐Lean Solvent Interface

Abstract Efficient direct air capture (DAC) of CO 2 will require strategies to deal with the relatively low concentration in the atmosphere. One such strategy is to employ the combination of a CO 2 ‐selective membrane coupled with a CO 2 capture solvent acting as a draw solution. Here, the interactions between a leading water‐lean carbon‐capture solvent, a polyether ether ketone (PEEK)‐ionene membrane, CO 2 , and combinations were probed using advanced NMR techniques coupled with advanced simulations. We identify the speciation and dynamics of the solvent, membrane, and CO 2 , presenting spectroscopic evidence of CO 2 diffusion through benzylic regions within the PEEK‐ionene membrane, not spaces in the ionic lattice as expected. Our results demonstrate that water‐lean capture solvents provide a thermodynamic and kinetic funnel to draw CO 2 from the air through the membrane and into the bulk solvent, thus enhancing the performance of the membrane. The reaction between the carbon‐capture solvent and CO 2 produces carbamic acid, disrupting interactions between the imidazolium (Im + ) cations and the bistriflimide anions within the PEEK‐ionene membrane, thereby creating structural changes through which CO 2 can diffuse more readily. Consequently, this restructuring results in CO 2 diffusion at the interface that is faster than CO 2 diffusion in the bulk carbon‐capture solvent.

Walter, Eric D.↗
DOE OSTI2025

OR-AGENT framework – Architecting electrified heavy-duty drayage applications

The widespread adoption of zero-emission vehicles in heavy-duty (HD) commercial freight transportation faces considerable technoeconomic challenges. For heavy-duty trucks, ensuring high uptime, cost parity with diesel, and safety standards is especially critical as these vehicles operate over long distances with heavy loads, where any downtime or off-nominal behaviors significantly impacts logistics, productivity, and the total cost of ownership. Unlike traditional diesel refueling, BEV charging infrastructure must be co-optimized with vehicle deployment, operational demands, and grid capacity to ensure cost-effective and reliable freight operations. However, the lack of a standardized ownership and service model has led to a fragmented approach—where commercial vehicle operators may invest in, own, and maintain both vehicle/batteries and charging/energy infrastructure. This disconnect may exclude energy service providers from the equation, forcing fleet operators to explore ‘behind-the-fence’ energy solutions that increase capital investment, operational downtime, overhead costs, and, in some cases, net carbon emissions. To address these issues, this study introduces OR-AGENT (Optimal Regional Architecture Generation for Efficient National Transport), a comprehensive modeling framework that integrates powertrain architectures, charging infrastructures, and energy backbone systems into a cohesive strategy. In this paper, OR-AGENT is applied to develop an interconnected systems architecture for energy efficiency and resiliency enhancement of heavy-duty drayage vehicles at the Port of Savannah, GA. This framework showcases an interconnected systems approach to electrifying heavy-duty drayage vehicles at the Port of Savannah, GA. The study assessed BEVs with 400–1200 kWh battery capacities, accounting for seasonal variations in weather and freight routing. A diverse charging mix (150 kW–1250 kW) was evaluated alongside grid capacity constraints, cost, and carbon intensity analysis, leading to the development of a strategic microgrid/Distributed Energy Resources (DER) deployment architecture to ensure a reliable and sustainable transition. However, the findings also highlight the need for alternative zero-emission solutions for remaining trips, such as larger batteries, electrified roadways, hydrogen powertrains, or net-zero emission fuels. In conclusion, the findings are incorporated into a Total Cost of Ownership (TCO) model to identify optimal architectures for an interconnected electrified ecosystem.

Commercial vehicles↗
DOE OSTI2022

Plastic waste upgrade to olefins via mild slurry microwave pyrolysis over solid acids

Chemical upcycling technologies are emerging as the most viable to combat plastic waste accumulation. Among them, catalytic pyrolysis is very promising as it is feedstock agnostic. However, the high energy demand associated with pyrolysis can lead to significant carbon dioxide production. In this work, we demonstrate that coupling microwave heating with suitable solid acid promoters in a slurry reactor coupled with a distillation unit can overcome the energy-related challenge of conventional pyrolysis, by operating at modest temperatures (350–375 °C), enhancing transport, and furnishing high yields of olefins (~88 %) in seconds, with medium-sized olefins (>75 %) composing a significant fraction. Reduced thermal gradients minimize coke formation, further improving the performance. Techno-economic analysis and life cycle assessment indicate the potential of the technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Probing oil recovery in shale nanopores with small-angle and ultra-small-angle neutron scattering

Increasing oil production from unconventional shale reservoirs is crucial to meet growing energy demands while achieving lower carbon emission than conventional crude oil. Enhanced oil recovery (EOR) has been proposed to improve hydrocarbon recovery rates through the injection of a fluid into the reservoir to facilitate residual oil release from the shale formation. However, economical and sustainable implementation of EOR requires advanced knowledge of fluid behavior in nano-sized pore spaces in shale. In this study, we utilize small-angle neutron scattering (SANS) and ultra-small-angle neutron scattering (USANS) as experimental probes to examine decane removal from a shale nano- to micro-porous matrix, utilizing methane as the injectant. The extent of decane saturation and recovery post-methane pressurization is quantified for clay-rich and carbonate-rich shale samples. A key finding is that extraction of decane by methane on depressurization is related to the methane-decane critical point. Furthermore, we found that although clay-rich shale had a much higher porosity of 5.6%, compared with 1.2% for carbonate-rich shale, decane was more easily removed from the carbonate-rich matrix, leading to similar hydrocarbon yields. These promising results demonstrate the ability of SANS and USANS to provide key insights into oil recovery from nano- to micron-sized pores in shale matrices. Combined with effects of various fractures on fluid behavior in shale, this experimental technique can be used to assess the viability of EOR injectants.

04 OIL SHALES AND TAR SANDS↗
DOE OSTI2026

First study of the nuclear response to fast hadrons via angular correlations between pions and slow protons in electron-nucleus scattering

We report on the first measurement of angular correlations between high-energy pions and slow protons in electron-nucleus (eA) scattering, providing a new probe of how a nucleus responds to a fast-moving quark. The experiment employed the CLAS detector with a 5-GeV electron beam incident on deuterium, carbon, iron, and lead targets. For heavier nuclei, the pion-proton correlation function is more spread-out in azimuth than for lighter ones, and this effect is more pronounced in the πp channel than in earlier ππ studies. The proton-to-pion yield ratio likewise rises with nuclear mass, although the increase appears to saturate for the heaviest targets. These trends are qualitatively reproduced by state-of-the-art eA event generators, including BeAGLE, eHIJING, and GiBUU, indicating that current descriptions of target fragmentation rest on sound theoretical footing. At the same time, the precision of our data exposes model-dependent discrepancies, delineating a clear path for future improvements in the treatment of cold-nuclear matter effects in eA scattering.

Correlations↗
DOE OSTI2021

Theoretical Study of the Reaction of the Methylidyne Radical (CH; X 2 Π) with 1-Butyne (CH 3 CH 2 CCH; X 1 A')

In this study, ab initio CCSD(T)-F12/cc-pVTZ-f12//ωB97X-D/6-311G(d,p) + ZPE(ωB97X-D/6-311G(d,p)) calculations were carried out to unravel the area of the C 5 H 7 potential energy surface accessed by the reaction of the methylidyne radical with 1-butyne. The results were utilized in Rice-Ramsperger-Kassel-Marcus calculations of the product branching ratios at the zero pressure limit. The preferable reaction mechanism has been shown to involve (nearly) instantaneous decomposition of the initial reaction adducts, whose structures are controlled by the isomeric form of the C 4 H 6 reactant. If CH adds to the triple CΞC bond in the entrance reaction channel, the reaction is predicted to predominantly form the methylenecyclopropene + methyl (CH 3 ) and cyclopropenylidene + ethyl (C 2 H 5 ) products roughly in a 2:1 ratio. CH insertion into a C-H bond in the methyl group of 1-butyne is anticipated to preferentially form ethylene + propargyl (C 3 H 3 ) by the C-C bond β-scission in the initial complex, whereas CH insertion into C-H of the CH 2 group would predominantly produce vinylacetylene + methyl (CH 3 ) also by the C-C bond β-scission in the adduct. The barrierless and highly exoergic CH + 1-butyne reaction, facile in cold molecular clouds, is not likely to lead to the carbon skeleton molecular growth but generates C 4 H 4 isomers methylenecyclopropene, vinylacetylene, and 1,2,3-butatriene and smaller C 2 and C 3 hydrocarbons such as methyl, ethyl, and propargyl radicals, ethylene, and cyclopropenylidene.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Improving photovoltaic hosting capacity of distribution networks with coordinated inverter control: A case study of the EPRI J1 feeder

Abstract Adding photovoltaic (PV) systems in distribution networks, while desirable for reducing the carbon footprint, can lead to voltage violations under high solar‐low load conditions. The inability of traditional volt‐VAr control in eliminating all the violations is also well‐known. This article presents a novel coordinated inverter control methodology that leverages system‐wide situational awareness to significantly improve hosting capacity (HC). The methodology employs a real‐time voltage‐reactive power (VQ) sensitivity matrix in an iterative linear optimizer to calculate the minimum reactive power intervention from PV inverters needed for mitigating over‐voltage without resorting to active power curtailing or requiring step voltage regulator setting changes. The algorithm is validated using the EPRI J1 feeder under an extensive set of realistic use cases and is shown to provide 3x improvement in HC under all scenarios.

Dalal, Dhaval [School of Electrical, Computer, and↗
DOE OSTI2022

Modeling ablator grain structure impacts in ICF implosions

High-density carbon is a leading ablator material for inertial confinement fusion (ICF). This and some other ablator materials have grain structure which is believed to introduce very small-scale (~nm) density inhomogeneity. In principle, such inhomogeneity can affect key ICF metrics like fuel compression and yield, by, for example, acting as a seed for instabilities and inducing mix between ablator and fuel. However, assessments of such effects are uncertain due to the difficulty of modeling this small-scale structure in ICF simulations, typically requiring reduced-resolution modeling that scales these features. We present a grain model and show both the impact of de-resolving grains and the complex mixing dynamics such structures can induce. We find that different methods for de-resolving grains can yield both different total deposition of kinetic energy perturbations and different fuel–ablator mixing. We then show a simple-to-implement approach for approximately conserving the deposition of perturbed kinetic energy and demonstrate that, for the present grain model and test cases, this approach yields a reasonably matched time history of mix width between less and more resolved grain models. The simulations here also demonstrate the complex interaction history between grain-induced mixing and instability around the fuel–ablator interface, showing, for example, that the grain-induced perturbations typically trigger instability of conduction-driven density gradients in the DT fuel, enhancing mix penetration early in the acceleration of the shell. Furthermore simulating both microscale and nanoscale grains, we find initial evidence for larger mixing in the microscale case of the present model, despite smaller deposited kinetic energy perturbation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Characterizing impurity sourcing and transport in the high temperature boundary of DIII-D wide pedestal QH-mode plasmas

Wide Pedestal QH-mode (WPQH) plasmas in the DIII-D tokamak show a sheath limited SOL, where electron density and temperature remain nearly constant along field lines from the midplane to the divertor. Consequently, parallel gradients are weak. The first Langmuir probe measurements in this regime point to a high sheath temperature with target electron temperature T e up to ~150 eV, leading to high carbon self-sputtering. Midplane carbon densities from SOLPS-ITER modeling of these plasmas in a double-null configuration fall far below experimental measurements unless full drifts are activated. In the drift-dependent SOLPS-ITER modeling, anomalous poloidally uniform, radially varying transport is adjusted to match measured radial electron temperature and density profiles in the pedestal and SOL region. The resulting carbon density (C6+) matches measured carbon densities just inside the separatrix. The C2+ density near the outer strike point is also consistent with spectroscopic imaging. With the ion B×∇B drift towards the X-point, carbon in the lower divertors is redistributed from the private flux region to the high field side (HFS) and pushed upstream in the SOL by poloidal E×B drifts. The B × ∇B drift dominates the radial flow of carbon as it moves upstream. Simulations with reversed toroidal field (ion B × ∇B drift away from the X-point) show a radically different behavior, where carbon accumulates on the low field side in lower divertors, and is pushed towards the HFS in the upper divertors, indicating a strong effect of particle drifts on impurity distribution. In double-null configurations which are usually used in WPQH plasmas, these drift effects tend to counterbalance, so that the carbon density and Z eff are reduced at the outer mid-plane only modestly, by around 7% in the modeling. Further predictive modeling indicates that the carbon density can be significantly reduced by an order of magnitude by implementing a single-null shape with reversed toroidal field.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Dihadron azimuthal correlations in deep-inelastic scattering off nuclear targets

We measured the nuclear dependence of the di-pion azimuthal correlation function in deepinelastic scattering (DIS) using the CEBAF Large Acceptance Spectrometer (CLAS) and a 5 GeV electron beam. As the nuclear-target size increases, transitioning from deuterium to carbon, iron, and lead, the correlation function broadens monotonically. Its shape exhibits a significant dependence on kinematics, including the transverse momentum of the pions and the difference in their rapidity. None of the various Monte-Carlo event generators we evaluated could fully replicate the observed correlation functions and nuclear effects throughout the entire phase space. As the first study of its kind in DIS experiments, this research provides an important baseline for enhancing our understanding of the interplay between the nuclear medium and the hadronization process in these reactions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Actinide Crystallization and Fission Reactions in Cooling White Dwarf Stars

The first solids that form as a cooling white dwarf (WD) starts to crystallize are expected to be greatly enriched in actinides. This is because the melting points of WD matter scale as Z5/3 and actinides have the largest charge Z. We estimate that the solids may be so enriched in actinides that they could support a fission chain reaction. This reaction could ignite carbon burning and lead to the explosion of an isolated WD in a thermonuclear supernova (SN Ia). Our mechanism could potentially explain SN Ia with sub-Chandrasekhar ejecta masses and short delay times.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Observation of Azimuth-Dependent Suppression of Hadron Pairs in Electron Scattering off Nuclei

Here, we present the first measurement of dihadron angular correlations in electron-nucleus scattering. The data were taken with the CLAS detector and a 5.0 GeV electron beam incident on deuterium, carbon, iron, and lead targets. Relative to deuterium, the nuclear yields of charged-pion pairs show a strong suppression for azimuthally opposite pairs, no suppression for azimuthally nearby pairs, and an enhancement of pairs with large invariant mass. These effects grow with increased nuclear size. The data are qualitatively described by the GIBUU model, which suggests that hadrons form near the nuclear surface and undergo multiple scattering in nuclei. These results show that angular correlation studies can open a new way to elucidate how hadrons form and interact inside nuclei.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

First Measurement of Λ Electroproduction off Nuclei in the Current and Target Fragmentation Regions

Here, we report results of Λ hyperon production in semi-inclusive deep-inelastic scattering off deuterium, carbon, iron, and lead targets obtained with the CLAS detector and the Continuous Electron Beam Accelerator Facility 5.014 GeV electron beam. These results represent the first measurements of the Λ multiplicity ratio and transverse momentum broadening as a function of the energy fraction (z) in the current and target fragmentation regions. The multiplicity ratio exhibits a strong suppression at high z and an enhancement at low z. The measured transverse momentum broadening is an order of magnitude greater than that seen for light mesons. This indicates that the propagating entity interacts very strongly with the nuclear medium, which suggests that propagation of diquark configurations in the nuclear medium takes place at least part of the time, even at high z. The trends of these results are qualitatively described by the Giessen Boltzmann-Uehling-Uhlenbeck transport model, particularly for the multiplicity ratios. These observations will potentially open a new era of studies of the structure of the nucleon as well as of strange baryons.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Modeling of Particle Thermal Energy Reservoir for Solar Industrial Process Heat (Final Technical Report)

Industrial process heat is a leading source of carbon emissions in the United States. To achieve decarbonization goals and reduce costs, solar industrial process heat (SIPH) systems have been investigated as a means of providing a carbon-free heat supply. Particle thermal energy storage (TES) could supplement solar resources (i.e., concentrating solar thermal and photovoltaics) to enable a high capacity factor (> 90%), carbon-free heat source. Particle TES has been considered due to its low-cost storage medium and capability to support a wide range of temperatures. This report provides technical details of developing a component and system modeling tool for a unique particle TES platform to assist the adoption of SIPH technology.

14 SOLAR ENERGY↗