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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
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NASA NTRS2017

Chemical Complexity Induced by Efficient Ice Evaporation in the Barnard 5 Molecular Cloud

Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water are consistent with a transient non-thermal evaporation process only affecting the outermost ice mantle layers, possibly triggering a more complex chemistry. Here we present the detection of the complex organic molecules (COMs) acetaldehyde (CH3CHO) and methyl formate (CH3OCHO), as well as formic acid (HCOOH) and ketene (CH2CO), and the tentative detection of di-methyl ether (CH3OCH3) towards the ''methanol hotspot'' of Barnard 5 located between two dense cores using the single dish OSO 20 m, IRAM 30 m, and NRO 45 m telescopes. The high energy cis-conformer of formic acid is detected, suggesting that formic acid is mostly formed at the surface of interstellar grains and then evaporated. The detection of multiple transitions for each species allows us to constrain their abundances through LTE and non-LTE methods. All the considered COMs show similar abundances between approx. 1 and approx. 10% relative to methanol depending on the assumed excitation temperature. The non-detection of glycolaldehyde, an isomer of methyl formate, with a [glycolaldehyde]/[methyl formate] abundance ratio lower than 6%, favours gas phase formation pathways triggered by methanol evaporation. According to their excitation temperatures derived in massive hot cores, formic acid, ketene, and acetaldehyde have been designated as ''lukewarm'' COMs whereas methyl formate and di-methyl ether were defined as ''warm'' species. Comparison with previous observations of other types of sources confirms that lukewarm and warm COMs show similar abundances in low-density cold gas whereas the warm COMs tend to be more abundant than the lukewarm species in warm protostellar cores. This abundance evolution suggests either that warm COMs are indeed mostly formed in protostellar environments and/or that lukewarm COMs are efficiently depleted by increased hydrogenation efficiency around protostars.

ISM: molecules↗
NASA NTRS2017

Chemical Complexity Induced by Efficient Ice Evaporation in the Barnard 5 Molecular Cloud

Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water are consistent with a transient non-thermal evaporation process only affecting the outermost ice mantle layers, possibly triggering a more complex chemistry. Here we present the detection of the complex organic molecules (COMs) acetaldehyde (CH3CHO) and methyl formate (CH3OCHO), as well as formic acid (HCOOH) and ketene (CH2CO), and the tentative detection of di-methyl ether (CH3OCH3) towards the ‘methanol hotspot’ of Barnard 5 located between two dense cores using the single dish OSO 20m, IRAM 30m, and NRO 45m telescopes. The high energy cis- conformer of formic acid is detected, suggesting that formic acid is mostly formed at the surface of interstellar grains and then evaporated. The detection of multiple transitions for each species allows us to constrain their abundances through LTE and non-LTE methods. All the considered COMs show similar abundances between ∼ 1 and ∼ 10 % relative to methanol depending on the assumed excitation temperature. The non-detection of glycolaldehyde, an isomer of methyl formate, with a [glycolaldehyde]/[methyl formate] abundance ratio lower than 6 %, favours gas phase formation pathways triggered by methanol evaporation. According to their excitation temperatures derived in massive hot cores, formic acid, ketene, and acetaldehyde have been designated as ‘lukewarm’ COMs whereas methyl formate and di-methyl ether were defined as ‘warm’ species. Comparison with previous observations of other types of sources confirms that lukewarm and warm COMs show similar abundances in low-density cold gas whereas the warm COMs tend to be more abundant than the lukewarm species in warm protostellar cores. This abundance evolution suggests either that warm COMs are indeed mostly formed in protostellar environments and/or that lukewarm COMs are efficiently depleted by increased hydrogenation efficiency around protostars.

astrochemistry – ISM: abundances – ISM: clouds – I↗
NASA NTRS1991

New photoionization models of intergalactic clouds

New photoionization models of optically thin low-density intergalactic gas at constant pressure, photoionized by QSOs, are presented. All ion stages of H, He, C, N, O, Si, and Fe, plus H2 are modeled, and the column density ratios of clouds at specified values of the ionization parameter of n sub gamma/n sub H and cloud metallicity are predicted. If Ly-alpha clouds are much cooler than the previously assumed value, 30,000 K, the ionization parameter must be very low, even with the cooling contribution of a trace component of molecules. If the clouds cool below 6000 K, their final equilibrium must be below 3000 K, owing to the lack of a stable phase between 6000 and 3000 K. If it is assumed that the clouds are being irradiated by an EUV power-law continuum typical of WSOs, with J0 = 10 exp -21 ergs/s sq cm Hz, typical cloud thicknesses along the line of sight that are much smaller than would be expected from shocks, thermal instabilities, or gravitational collapse are derived.

Donahue, Megan↗
NASA NTRS1995

Importance of real gas effects in entry technology

Critical issues concerning real gas effects in hypervelocity flows where the thermochemical nonequilibrium effects are pronounced, are described. Emphasis is on the development and validation of benchmark analysis tools. Approaches to develop and/or enhance phenomenological models, including test techniques to acquire databases, and incorporate them into computational flow field simulation codes are described. The performance characteristics of shock tubes, ballistic ranges and arc heated wind tunnels, state of the art diagnostics are included. The following aerothermodynamic phenomena are discussed: aerodynamic parameters, viscous interactions, turbulent transition, forebody heating/heat transfer, radiative heating, Lee-Base flows and low density real gas.

Deiwert, George S.↗
NASA NTRS1986

Milky Way halo gas kinematics

Measurements of high resolution, short wavelength absorption data taken by IUE toward high latitude O and B stars are presented in a discussion of the large scale kinematic properties of Milky Way Halo gas. An analysis of these data demonstrates that: (1) the obsrved absorption widths (FWHM) of Si II are very large, ranging up to 150 Km/s for the most distant halo star; this is much larger than is generally appreciated from optical data; (2) the absorption is observed to be systematically negative in radial velocity, indicating that cool material is, on the whole, flowing toward the disk of the galaxy; (3) there is some evidence for asymmetry between the northern and southern galactic hemispheres, in accordance with the HI 21 cm data toward the galactic poles; (4) low column density gas with highly negative radial LSR velocity (V less than -70 km/s) can be found toward stars beyond 1-3 kpc in the northern galactic hemisphere in all four quadrants of galactic longitude; and (5) only the profiles toward stars in the direction of known high velocity HI features show a clear two component structure.

Danly, L.↗
NASA NTRS1974

Simultaneous Raman and laser velocimeter measurements

The feasibility of performing Raman and laser velocimeter measurements simultaneously is demonstrated, and it is shown that the background radiation associated with the Mie scattering and large particulate concentrations does not saturate or distort the relatively weak rotational Raman signals. Under stringent conditions of low static gas densities and large particulate concentrations, Raman density and temperature measurements agree to within plus or minus 5% of the calculated values.

Hillard, M. E., Jr.↗
NASA NTRS1986

Theoretical study of the X-ray emission from astrophysical shock waves

Theoretical X-ray emission spectra are needed to interpret the X-ray emission observed by many low and moderate resolution X-ray instruments, and to provide diagnosis of physical conditions for high resolution spectra. Over the past decade, a set of model codes which compute the X-ray and XUV emission for a wide set of physical conditions, including high or low densities, photoionized gas, and time-dependent ionization balance was developed. In the past year, the atomic rate coefficients in the code was improved. Further capabilities were added, and applied to several astrophysical problems.

Raymond, J.↗
NASA NTRS1987

On the redistribution of OB star luminosity and the warming of nearby molecular clouds

Infrared Astronomy Satellite (IRAS) observations of the neighborhoods of six outer-Galaxy HII regions were combined with CO observations to show that most of the far infrared (FIR) luminosity from within approximately 25 to 75 pc of the ionizing stars is contributed by dust in molecular clouds, not by dust in the low-density ionized gas. Dust associated with the clouds is warmed by absorption of UV and visible light from the cluster of stars responsible for the ionization. Most of the OB cluster starlight is not absorbed locally. A fraction of the order of 10% of the OB cluster luminosity is absorbed by nearby molecular clouds and reradiated as FIR light. The luminosity per unit mass for the heated clouds is approximately 3 to 13 solar luminosity/solar mass, approximately one order of magnitude greater than the corresponding ratio for clouds found near clusters without O stars, and two orders of magnitude greater than the ratio for dark clouds heated primarily by the interstellar radiation field. If the observations of clouds near outer-Galaxy HII regions are used to characterize the molecular clouds heated by HII regions in the inner-Galaxy, then at most 30% of the Galaxy's molecular cloud mass is actively engaged in the formation of massive stars at the present time.

Leisawitz, D.↗
NASA NTRS1988

On the nearest molecular clouds. II - MBM 12 and 16

The paper presents echelle spectra recorded at the D lines of Na I for three stars projected on the high-latitude molecular cloud MBM 16 at l = 172 deg, b = -38 deg. The A stars HD 21142 at about 95 pc and HD 21134 at about 240 pc show strong D-line absorption at the same velocities as the CO emission observed at these positions. The distance to MBM 16 therefore is in the range of 60 to 95 pc. MBM 16 is only 11 deg away from MBM 12, previously placed by the same method at distance of about 65 pc. Consideration is given to the relationship between clouds 12 and 16 and the local hot low-density interstellar gas.

Hobbs, L. M.↗
NASA NTRS1989

Narrow ultraviolet emission lines from SN 1987A - Evidence for CNO processing in the progenitor

Results from UV observations of SN 1987A with the IUE satellite are presented, showing that emission lines of He II, C III, N III, N IV, N V, and O III increase in strength with time after May 24, 1987. It is found that increased emission originated in a photoionized low-density circumstellar gas, lost by the progenitor in its red supergiant phase. A nebular analysis reveals a large nitrogen overabundance, indicating that the gas has undergone substantial CNO processing. This suggests that the progenitor of SN 1987A lost much of its hydrogen envelope before the explosion. The findings are consistent with models in which a red supergiant evolves to the blue supergiant stage before exploding.

Fransson, C.↗