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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Electrical Devices and Circuits for Low Temperature Space Applications

The environmental temperature in many NASA missions, such as deep space probes and outer planetary exploration, is significantly below the range for which conventional commercial-off-the-shelf electronics is designed. Presently, spacecraft operating in the cold environment of such deep space missions carry a large number of radioisotope or other heating units in order to maintain the surrounding temperature of the on-board electronics at approximately 20 C. Electronic devices and circuits capable of operation at cryogenic temperatures will not only tolerate the harsh environment of deep space but also will reduce system size and weight by eliminating or reducing the heating units and their associate structures; thereby reducing system development cost as well as launch costs. In addition, power electronic circuits designed for operation at low temperatures are expected to result in more efficient systems than those at room temperature. This improvement results from better behavior in the electrical and thermal properties of some semiconductor and dielectric materials at low temperatures. An on-going research and development program on low temperature electronics at the NASA Glenn Research Center focuses on the development of efficient electrical systems and circuits capable of surviving and exploiting the advantages of low temperature environments. An overview of the program will be presented in this paper. A description of the low temperature test facilities along with selected data obtained from in-house component testing will also be discussed. On-going research activities that are being performed in collaboration with various organizations will also be presented.

Patterson, R. L.↗
NASA NTRS2009

Li/CFx Cells Optimized for Low-Temperature Operation

Some developments reported in prior NASA Tech Briefs articles on primary electrochemical power cells containing lithium anodes and fluorinated carbonaceous (CFx) cathodes have been combined to yield a product line of cells optimized for relatively-high-current operation at low temperatures at which commercial lithium-based cells become useless. These developments have involved modifications of the chemistry of commercial Li/CFx cells and batteries, which are not suitable for high-current and low-temperature applications because they are current-limited and their maximum discharge rates decrease with decreasing temperature. One of two developments that constitute the present combination is, itself, a combination of developments: (1) the use of sub-fluorinated carbonaceous (CFx wherein x<1) cathode material, (2) making the cathodes thinner than in most commercial units, and (3) using non-aqueous electrolytes formulated especially to enhance low-temperature performance. This combination of developments was described in more detail in High-Energy-Density, Low- Temperature Li/CFx Primary Cells (NPO-43219), NASA Tech Briefs, Vol. 31, No. 7 (July 2007), page 43. The other development included in the present combination is the use of an anion receptor as an electrolyte additive, as described in the immediately preceding article, "Additive for Low-Temperature Operation of Li-(CF)n Cells" (NPO- 43579). A typical cell according to the present combination of developments contains an anion-receptor additive solvated in an electrolyte that comprises LiBF4 dissolved at a concentration of 0.5 M in a mixture of four volume parts of 1,2 dimethoxyethane with one volume part of propylene carbonate. The proportion, x, of fluorine in the cathode in such a cell lies between 0.5 and 0.9. The best of such cells fabricated to date have exhibited discharge capacities as large as 0.6 A h per gram at a temperature of 50 C when discharged at a rate of C/5 (where C is the magnitude of the current, integrated for one hour, that would amount to the nominal charge capacity of a cell).

Smart, Marshall C.↗
NASA NTRS2019

Preparation, Identification, and Low-Temperature Infrared Spectra of Two Elusive Crystalline Nitrile Ices

Infrared (IR) spectra of the alkyl nitrile ices CH3CN and CH3CH2CN are relevant to the study of the low- temperature chemistry of objects within and beyond the Solar System, but the thermodynamically favored low-temperature crystalline phases of these compounds have not been presented and identified in the planetary- sciences literature. Moreover, there is a large variation in the published IR spectra of these two icy solids, including spectra that are used for the analyses of spacecraft data from the Voyager and Cassini missions. Here the IR spectra of the low-temperature crystalline forms of CH3CN and CH3CH2CN, which are the thermodynamically stable phases at Titan temperatures, are presented for the first time with all samples being made by vapor-phase deposition. Conditions are described for producing these ice phases for both compounds, and new measurements are reported of ice density and refractive index, quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, nitrile abundances in extraterrestrial environments. Comparisons are drawn between CH3CN and CH3CH2CN, an earlier prediction on their similar crystallization behaviors is verified, and previous work is examined in light of these new results, including a counterintuitive observation in which the low-temperature phase of an ice is made by heating a high-temperature phase. Applications and extensions are described.

Hudson, Reggie L.↗
NASA NTRS2019

Preparation, Identification, and Low-Temperature Infrared Spectra of Two Elusive Crystalline Nitrile Ices

Infrared (IR) spectra of the alkyl nitrile ices CH3CN and CH3CH2CN are relevant to the study of the low- temperature chemistry of objects within and beyond the Solar System, but the thermodynamically favored low-temperature crystalline phases of these compounds have not been presented and identified in the planetary- sciences literature. Moreover, there is a large variation in the published IR spectra of these two icy solids, including spectra that are used for the analyses of spacecraft data from the Voyager and Cassini missions. Here the IR spectra of the low-temperature crystalline forms of CH3CN and CH3CH2CN, which are the thermody-namically stable phases at Titan temperatures, are presented for the first time with all samples being made by vapor-phase deposition. Conditions are described for producing these ice phases for both compounds, and new measurements are reported of ice density and refractive index, quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, nitrile abundances in extraterrestrial environments. Comparisons are drawn between CH3CN and CH3CH2CN, an earlier prediction on their similar crystallization behaviors is verified, and previous work is examined in light of these new results, including a counter- intuitive observation in which the low-temperature phase of an ice is made by heating a high-temperature phase. Applications and extensions are described.

Hudson, Reggie L.↗
NASA NTRS1967

Development of low temperature battery

Self-contained low temperature battery system consisting of a magnesium anode, potassium thiocyanate-ammonia electrolyte and a cathode composed of a mixture of sulfur, carbon, and mercuric sulfate operates for at least seventy-two hours within a discharge temperature range of plus 20 degrees C to minus 90 degrees C.

Armstrong, G. M.↗
NASA NTRS1977

Low-temperature coal desulfurization

Economical, low-temperature chlorinolysis converts sulfur to water-soluble sulfates. Sulfates are removed by washing. Subsequent steps dry coal and remove chlorine. Chlorine and solvents can be reused.

Ganguli, P. S.↗
NASA NTRS2019

Preparation, Identification, and Low-Temperature Infrared Spectra of Two Elusive Crystalline Nitrile Ices

Infrared (IR) spectra of the alkyl nitrile ices CH3CN and CH3CH2CN are relevant to the study of the low-temperature chemistry of objects within and beyond the Solar System, but the thermodynamically favored low-temperature crystalline phases of these compounds have not been presented and identified in the planetary-sciences literature. Moreover, there is a large variation in the published IR spectra of these two icy solids, including spectra that are used for the analyses of spacecraft data from the Voyager and Cassini missions. Here the IR spectra of the low-temperature crystalline forms of CH3CN and CH3CH2CN, which are the thermodynamically stable phases at Titan temperatures, are presented for the first time with all samples being made by vapor-phase deposition. Conditions are described for producing these ice phases for both compounds, and new measurements are reported of ice density and refractive index, quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, nitrile abundances in extraterrestrial environments. Comparisons are drawn between CH3CN and CH3CH2CN, an earlier prediction on their similar crystallization behaviors is verified, and previous work is examined in light of these new results, including a counter-intuitive observation in which the low-temperature phase of an ice is made by heating a high-temperature phase. Applications and extensions are described.

Reggie L Hudson↗
NASA NTRS2019

Preparation, Identification, and Low-Temperature Infrared Spectra of Two Elusive Crystalline Nitrile Ices

Infrared (IR) spectra of the alkyl nitrile ices CH3CN and CH3CH2CN are relevant to the study of the low-temperature chemistry of objects within and beyond the Solar System, but the thermodynamically favored low-temperature crystalline phases of these compounds have not been presented and identified in the planetary-sciences literature. Moreover, there is a large variation in the published IR spectra of these two icy solids, including spectra that are used for the analyses of spacecraft data from the Voyager and Cassini missions. Here the IR spectra of the low-temperature crystalline forms of CH3CN and CH3CH2CN, which are the thermodynamically stable phases at Titan temperatures, are presented for the first time with all samples being made by vapor-phase deposition. Conditions are described for producing these ice phases for both compounds, and new measurements are reported of ice density and refractive index, quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, nitrile abundances in extraterrestrial environments. Comparisons are drawn between CH3CN and CH3CH2CN, an earlier prediction on their similar crystallization behaviors is verified, and previous work is examined in light of these new results, including a counter-intuitive observation in which the low-temperature phase of an ice is made by heating a high-temperature phase. Applications and extensions are described.

Ices, IR spectroscopy, Titan, organic chemistry, i↗
NASA NTRS2016

The Effect of Electrolyte Composition on Lithium Plating During Low Temperature Charging of Li-Ion Cells

In the present work, a number of additives have been investigated for their effect on the charge characteristics of cells containing low temperature, high ester content electrolytes (1.0 M LiPF6 in ethylene carbonate (EC) + ethyl methyl carbonate (EMC) + methyl propionate (MP) 20:20:60 vol % + X additive). These experimental three-electrode cells are composed of graphite anodes, LiNiCoAlO2 cathodes, and a lithium metal reference electrode. Cells were first subjected to electrochemical characterization at various temperatures, consisting of performing Electrochemical Impedance Spectroscopy (EIS), linear micropolarization and Tafel polarization measurement to determine the kinetic parameters for both the anodes and cathodes. Following electrochemical characterization, the cells were subjected to charging at decreasing temperatures using C/5 rates to 4.10V, with a constant potential C/50 current taper. Analysis of the C/20 discharge following the charge at low temperature revealed either the presence or absence of a high voltage plateau during the initial stages of the discharge. This plateau has been linked to the presence of lithium metal on the anode previously and was used as a measure for the extent of lithium plating in the cell. Differential analysis (dV/dQ) was applied as well to more clearly visualize the position of the high voltage plateau and use the peak position (x-axis) in the dV/dQ plot as a gauge for the amount of plating which took place in the cell on the prior charge. Most additives investigated increased the resistance of the anode and decreased the resistance of the cathode, thereby leading to an overall increase in plating observed at low temperature. One additive, LiFSI, was found to be beneficial during low temperature charging, however studies of electrode kinetics from the cell containing LiFSI did not reveal significant improvements compared to the baseline.

Jones, John-Paul↗
NASA NTRS2000

The Development of the Low Temperature Microgravity Physics Facility

We describe the design and development of the Low Temperature Microgravity Physics Facility, which is intended to provide long duration (4.5 months) low temperature (1.4K) and microgravity conditions for scientists to perform breakthrough investigations on board the International Space Station.

Low Temperature Fundamental Physics Microgravity P↗
NASA NTRS2011

Substituted Quaternary Ammonium Salts Improve Low-Temperature Performance of Double-Layer Capacitors

Double-layer capacitors are unique energy storage devices, capable of supporting large current pulses as well as a very high number of charging and discharging cycles. The performance of doublelayer capacitors is highly dependent on the nature of the electrolyte system used. Many applications, including for electric and fuel cell vehicles, back-up diesel generators, wind generator pitch control back-up power systems, environmental and structural distributed sensors, and spacecraft avionics, can potentially benefit from the use of double-layer capacitors with lower equivalent series resistances (ESRs) over wider temperature limits. Higher ESRs result in decreased power output, which is a particular problem at lower temperatures. Commercially available cells are typically rated for operation down to only 40 C. Previous briefs [for example, Low Temperature Supercapacitors (NPO-44386), NASA Tech Briefs, Vol. 32, No. 7 (July 2008), p. 32, and Supercapacitor Electrolyte Solvents With Liquid Range Below 80 C (NPO-44855), NASA Tech Briefs, Vol. 34, No. 1 (January 2010), p. 44] discussed the use of electrolytes that employed low-melting-point co-solvents to depress the freezing point of traditional acetonitrile-based electrolytes. Using these modified electrolyte formulations can extend the low-temperature operational limit of double-layer capacitors beyond that of commercially available cells. This previous work has shown that although the measured capacitance is relatively insensitive to temperature, the ESR can rise rapidly at low temperatures, due to decreased electrolyte conductance within the pores of the high surface- area carbon electrodes. Most of these advanced electrolyte systems featured tetraethylammonium tetrafluoroborate (TEATFB) as the salt. More recent work at JPL indicates the use of the asymmetric quaternary ammonium salt triethylmethylammonium tetrafluoroborate (TEMATFB) or spiro-(l,l')-bipyrrolidium tetrafluoroborate (SBPBF4) in a 1:1 by volume solvent mixture of acetonitrile (AN) and methyl formate (MF) enables double-layer capacitor cells to operate well below -40 C with a relatively low ESR. Typically, a less than twofold increase in ESR is observed at -65 C relative to room-temperature values, when these modified electrolyte blends are used in prototype cells. Double-layer capacitor coin cells filled with these electrolytes have displayed the lowest measured ESR for an organic electrolyte to date at low temperature (based on a wide range of electrolyte screening studies at JPL). The cells featured high-surface-area (approximately equal to 2,500 m/g) carbon electrodes that were 0.50 mm thick and 1.6 cm in diameter, and coated with a thin layer of platinum to reduce cell resistance. A polyethylene separator was used to electrically isolate the electrodes.

Brandon, Erik J.↗
NASA NTRS2005

Evolvable hardware system at extreme low temperatures

This paper describes circuit evolutionary experiments at extreme low temperatures, including the test of all system components at this extreme environment (EE). In addition to hardening-by-process and hardening-by-design, 'hardening-by-reconfiguration ', when applicable, could be used to mitigate drifts, degradation, or damage on electronic devices (chips) in EE, by using re-configurable devices and an adaptive selfreconfiguration of their circuit topology. Conventional circuit design exploits device characteristics within a certain temperature/radiation range; when that is exceeded, the circuit function degrades. On a reconfigurable device, although component parameters change in EE, a new circuit design, suitable for new parameter values, may be mapped into the reconfigurable structure to recover the initial circuit function. This paper demonstrates this technique for circuit evolution and recovery at liquid nitrogen temperatures (-196.6 (deg)C). In addition, preliminary tests are performed to assess the survivability limitations of the evolutionary processor at extreme low temperatures.

evolvable harware↗
NASA NTRS2003

The Low Temperature Microgravity Physics Facility: Progress and Status

The Jet Propulsion Laboratory (JPL) is developing the Low Temperature Microgravity Physics Facility (LTMPF). The LTMPF is a multiple user and multiple flight facility that will provide a long duration low temperature environment for performing state of the art experiments at the International Space Station (ISS). During each mission, two distinct primary experiments will be accommodated. Secondary experiments utilizing the hardware built for the primary experiments will also be accommodated during each mission. Over the past year, much progress has occurred on the LTMPF as the flight hardware has started to be built. Also, many changes have occurred. Last summer, the initial flight of the LTMPF was delayed until early 2008 by a 2-year slip in the delivery of the Japanese Experiment Module (KIBO) Exposed Facility of the ISS, where the LTMPF will be attached when it flies. Finally, the experiments that will fly as part of the first mission have been changed so that one Gravitational and Relativistic experiment and one Low Temperature Condensed Matter experiment will fly on each flight of the LTMPF. Therefore, the experiments that will fly on the initial mission of the LTMPF will be DYNAMX and the Superconducting Microwave Oscillator Experiment (SUMO).

Larson, Melora↗
NASA NTRS1992

Long Duration Exposure Facility (LDEF) low temperature heat pipe experiment package (HEPP) flight results

The Low Temperature Heat Pipe Flight Experiment (HEPP) is a fairly complicated thermal control experiment that was designed to evaluate the performance of two different low temperature ethan heat pipes. A total of 388 days of continuous operation with an axially grooved aluminum transporter heat pipe and an axially grooved stainless steel heat pipe diode was demonstrated before the EPDS batteries lost power. Preliminary postflight tests showed that the heat pipes are still functioning. A summary of the flight data analysis for the heat pipes and the related support systems is presented.

Mcintosh, Roy↗