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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Magnetism and fermiology of kagome magnet YMn 6 Sn 4 Ge 2

Kagome lattice magnets are an interesting class of materials as they can host topological properties in their magnetic and electronic structures. YMn 6 Sn 6 is one such compound in which various exotic magnetic and electronic topological properties have been realized. Here, by means of a partial substitution of Sn with an isovalent and slightly smaller atom Ge, we demonstrate the sensitivity of such chemical substitution on the magnetic structure and its influence in the electronic properties. Magnetic structure of YMn 6 Sn 4 Ge 2 determined by neutron diffraction reveals an incommensurate staggered magnetic spiral with a slightly larger spiral pitch than in YMn 6 Sn 6 . This change in magnetic structure influences the Fermi surface enhancing the out-of-plane conductivity. Such a sensitivity to the partial chemical substitution provides a great potential for engineering the magnetic phases and associated electronic properties not only in YMn 6 Sn 6 , but also in the large family of 166 rare-earth kagome magnet.

36 MATERIALS SCIENCE↗

Easy axis anisotropy creating high contrast magnetic zones on magnetic tunnel junctions based molecular spintronics devices (MTJMSD)

Abstract Magnetic tunnel junction-based molecular spintronics device (MTJMSD) may enable novel magnetic metamaterials by chemically bonding magnetic molecules and ferromagnets (FM) with a vast range of magnetic anisotropy. MTJMSD have experimentally shown intriguing microscopic phenomenon such as the development of highly contrasting magnetic phases on a ferromagnetic electrode at room temperature. This paper focuses on Monte Carlo Simulations (MCS) on MTJMSD to understand the potential mechanism and explore fundamental knowledge about the impact of magnetic anisotropy. The selection of MCS is based on our prior study showing the potential of MCS in explaining experimental results (Tyagi et al. in Nanotechnology 26:305602, 2015). In this paper, MCS is carried out on the 3D Heisenberg model of cross-junction-shaped MTJMSDs. Our research represents the experimentally studied cross-junction-shaped MTJMSD where paramagnetic molecules are covalently bonded between two FM electrodes along the exposed side edges of the magnetic tunnel junction (MTJ). We have studied atomistic MTJMSDs properties by simulating a wide range of easy-axis anisotropy for the case of experimentally observed predominant molecule-induced strong antiferromagnetic coupling. Our study focused on understanding the effect of anisotropy of the FM electrodes on the overall MTJMSDs at various temperatures. This study shows that the multiple domains of opposite spins start to appear on an FM electrode as the easy-axis anisotropy increases. Interestingly, MCS results resembled the experimentally observed highly contrasted magnetic zones on the ferromagnetic electrodes of MTJMSD. The magnetic phases with starkly different spins were observed around the molecular junction on the FM electrode with high anisotropy.

36 MATERIALS SCIENCE↗

Magnetic molecules lose identity when connected to different combinations of magnetic metal electrodes in MTJ-based molecular spintronics devices (MTJMSD)

Abstract Understanding the magnetic molecules’ interaction with different combinations of metal electrodes is vital to advancing the molecular spintronics field. This paper describes experimental and theoretical understanding showing how paramagnetic single-molecule magnet (SMM) catalyzes long-range effects on metal electrodes and, in that process, loses its basic magnetic properties. For the first time, our Monte Carlo simulations, verified for consistency with regards to experimental studies, discuss the properties of the whole device and a generic paramagnetic molecule analog (GPMA) connected to the combinations of ferromagnet-ferromagnet, ferromagnet-paramagnet, and ferromagnet-antiferromagnet metal electrodes. We studied the magnetic moment vs. magnetic field of GPMA exchange coupled between two metal electrodes along the exposed side edge of cross junction-shaped magnetic tunnel junction (MTJ). We also studied GPMA-metal electrode interfaces’ magnetic moment vs. magnetic field response. We have also found that the MTJ dimension impacted the molecule response. This study suggests that SMM spin at the MTJ exposed sides offers a unique and high-yield method of connecting molecules to virtually endless magnetic and nonmagnetic electrodes and observing unprecedented phenomena in the molecular spintronics field.

42 ENGINEERING↗

Effect of oxygen stoichiometry on the magnetization profiles and negative magnetization in LSMO thin films

The depth-dependent magnetization in thin film oxygen stoichiometric and oxygen-deficient La 0.7 Sr 0.3 MnO 3 is investigated by using polarized neutron reflectivity and DC bulk magnetometry. The polarized neutron reflectivity results reveal that the stoichiometric sample shows enhanced interfacial magnetization relative to the rest of the film. The oxygen-deficient sample exhibits a reduced average magnetization from the optimized recipe. Both films show regions of suppressed magnetization at the surface regardless of the growth pressure. The oxygen stoichiometric film does not show an interfacial dead layer, whereas the oxygen-deficient film exhibits a dead layer whose thickness changes with temperature. At a low applied field, we observe striking differences in the depth dependence of the magnetic ordering, with the oxygen-deficient film exhibiting exchange spring behavior, while the stoichiometric film shows a constant magnetization direction across the film. Furthermore, these results suggest that the incorporation of oxygen vacancies during growth leads to an accumulation of vacancies at the interface, which is enhanced at higher temperature due to increased oxygen mobility, creating a region of reduced magnetism that couples to the rest of the film. These results offer insight into the complex behavior and role of oxygen vacancies in the magnetism of these systems. Additionally, the study reveals further details of the negative magnetization in La 0.7 Sr 0.3 MnO 3 reported in previous studies, which are discussed here.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Deep-learning-enabled Bayesian inference of fuel magnetization in magnetized liner inertial fusion

Fuel magnetization in magneto-inertial fusion (MIF) experiments improves charged burn product confinement, reducing requirements on fuel areal density and pressure to achieve self-heating. By elongating the path length of 1.01 MeV tritons produced in a pure deuterium fusion plasma, magnetization enhances the probability for deuterium–tritium reactions producing 11.8-17.1 MeV neutrons. Nuclear diagnostics thus enable a sensitive probe of magnetization. Characterization of magnetization, including uncertainty quantification, is crucial for understanding the physics governing target performance in MIF platforms, such as magnetized liner inertial fusion (MagLIF) experiments conducted at Sandia National Laboratories, Z-facility. We demonstrate a deep-learned surrogate of a physics-based model of nuclear measurements. A single model evaluation is reduced from O ( 10 – 100 ) (10–100) CPU hours on a high-performance computing cluster down to O ( 10 – 100 ) (10) ms on a laptop. This enables a Bayesian inference of magnetization, rigorously accounting for uncertainties from surrogate modeling and noisy nuclear measurements. The approach is validated by testing on synthetic data and comparing with a previous study. We analyze a series of MagLIF experiments systematically varying preheat, resulting in the first ever systematic experimental study of magnetic confinement properties of the fuel plasma as a function of fundamental inputs on any neutron-producing MIF platform. We demonstrate that magnetization decreases from B R ∼ 0.2 ~0.5 to B R ∼ 0.2 ~0.2 MG cm as laser preheat energy deposited increases from E preheat ∼ 460 ~460 J to E preheat ∼ 460 ~1.4 kJ. This trend is consistent with 2D LASNEX simulations showing Nernst advection of the magnetic field out of the hot fuel and diffusion into the target liner.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Magnetic Field Mapping of a 2.5 T Fixed-Field HTS Gantry Magnet for Proton Therapy

We present results from testing a high-temperature superconducting (HTS) magnet prototype for proton therapy. This magnet is specifically designed for a novel rotating gantry capable of delivering the entire proton beam energy range (70225 MeV) while maintaining a fixed magnetic field in the superconducting magnets. The gantry layout simplifies the magnet design, enabling the use of straight, flat racetrack Bi-2223 (DI-BSCCO) coil technology and operation at higher temperatures (1015 K). The magnet has a non-linear field distribution for bending and focusing the proton beams. To validate this feature, we developed a system for measuring the magnetic field distribution in the magnet aperture. We present the design of this hall probe array and experimental results from two different magnet tests at 4.2 K in a liquid helium bath. These results are compared with the simulated field distribution and discussed in the context of the required field quality for the application.

Mosat, M↗

Permanent Magnets for the CEBAF 24GeV Upgrade

An upgrade of the CEBAF facility to double its present energy of 12GeV has been proposed. To provide double the number of linac passes using the existing five stacked arc beamlines, some beamlines are replaced by fixed-field accelerator (FFA) arcs, allowing multiple energies to pass through the same magnets. A solution is presented in which two of the existing electromagnetic beamlines are replaced with permanent magnet non-scaling FFA arcs, as demonstrated at CBETA. The two-stage design reduces peak magnetic field and synchrotron radiation loss compared to using a single stage. FFAs do not pulse their magnets, making permanent magnets a promising and power-efficient technology option. However, the magnetic field requirements are still at the high end of accelerator permanent magnets produced thus far (1.6T peak on beam), while the magnets must also be combined-function, having a gradient with a dipole offset. Designs using a novel oval aperture and open midplane within an adapted Halbach magnet are presented.

Brooks, S. J.↗

Magnetic Avalanche Detector using Single-Molecule Magnets

Here we discuss the results of the 9 month add-on project: “Magnetic Avalanche Detector using Single-Molecule Magnets”. The key point of the projects was to design a cryogenic system that is capable of applying magnetic fields high enough to magnetize the Single-Molecule Magnets (SMMs), maintain temperatures below 1K, and be able to detect magnetic avalanches of the SMM domains. We were able to achieve these goals. Our system was able to magnetize and sense the magnetization of SMM crystals. Moreover, we were able to detect avalanche demagnetization events caused by an alpha particle interacting with a magnetized SMM.

47 OTHER INSTRUMENTATION↗

Magnetic monopole plasma oscillations and the survival of Galactic magnetic fields

This paper explores the general nature of magnetic-monopole plasma oscillations as a theoretical possibility for the observed Galactic magnetic field in the presence of a high abundance of magnetic monopoles. The modification of the hydromagnetic induction equation by the monopole oscillations produces the half-velocity effect, in which the magnetic field is transported bodily with a velocity midway between the motion of the conducting fluid and the monopole plasma. Observational studies of the magnetic field in the Galaxy, and in other galaxies, exclude the half-velocity effect, indicating that the magnetic fields is not associated with monopole oscillations. In any case the phase mixing would destroy the oscillations in less than 100 Myr. The conclusion is that magnetic monopole oscillations do not play a significant role in the galactic magnetic fields. Hence the existence of galactic magnetic fields places a low limit on the monopole flux, so that their detection - if they exist at all - requires a collecting area at least as large as a football field.

Parker, E. N.↗

On turbulent diffusion of magnetic fields and the loss of magnetic flux from stars

The turbulent diffusion of magnetic fields in astrophysical objects, and the processes leading to magnetic field flux loss from such objects are discussed with attention to the suppression of turbulent diffusion by back-reaction of magnetic fields on small spatial scales, and on the constraint imposed on magnetic flux loss by flux-freezing within stars. Turbulent magnetic diffusion can be suppressed even for very weak large-scale magnetic fields, so that 'standard' turbulent diffusion is incapable of significant magnetic flux destruction within a star. Finally, magnetic flux loss via winds is shown to be generally ineffective, no matter what the value of the effective magnetic Reynolds number is.

Vainshtein, Samuel I.↗

Optimization of the Magnetic Field Topology in the Hall Effect Rocket with Magnetic Shielding

NASA's Hall Effect Rocket with Magnetic Shielding (HERMeS) 12.5 kilowatt Technology Demonstration Unit-1 (TDU-1) has been the subject of extensive technology maturation in preparation for flight system development. The TDU-1 thruster implements a magnetically shielded field topology and has demonstrated the elimination of the discharge channel erosion. Extensive wear testing of the TDU Hall thrusters has identified the thruster front pole covers as the next life limiting component. This effort aims to explore and investigate alternate magnetic field topologies to assess whether reductions in the front pole cover erosion can be attained while still maintaining very low erosion rates on the discharge channel walls. NASA GRC (Glenn Research Center) and JPL (Jet Propulsion Laboratory) have begun a magnetic field topology characterization and optimization study by designing four candidate magnetic field topologies that reduce the effectiveness of the shielding along the discharge channel walls with the intent to also reduce the erosion rates along the pole covers. Three of the four candidate magnetic field topologies have been manufactured subjected to an extensive test campaign that includes performance, plume, and stability characterization. In the Phase I test segment, the thruster's oscillation magnitude and laser-induced fluorescence (LIF) measurements of the plasma plume were performed for the three candidate topologies. In Phase I, the thruster's oscillation magnitude and LIF measurements were performed for the three candidate topologies. Phase I test results found that the B1 configuration attained lower oscillation levels than the baseline topology (B0). Additionally, laser induced fluorescence measurements along the discharge chamber centerline found that upstream retraction of the thruster’s peak magnetic field does result in an upstream shift of the acceleration zone but the magnitude of the shift does not correspond one-to-one to the shift in the location of the peak radial magnetic field magnitude. Phase II test segment will include performing performance, stability, plume, and erosion measurements for the various candidate magnetic field topologies..

Kamhawi, Hani↗

Optimization of the Magnetic Field Topology in the Hall Effect Rocket with Magnetic Shielding

NASA's Hall Effect Rocket with Magnetic Shielding (HERMeS) 12.5kW Technology Demonstration Unit-1 (TDU-1) has been the subject of extensive technology maturation in preparation for flight system development. The TDU-1 thruster implements a magnetically shielded field topology and has demonstrated the elimination of the discharge channel erosion. Extensive wear testing the TDU Hall thrusters has identified the thruster front pole covers as the next life limiting component. This effort aims to explore and investigate alternate magnetic field topologies to assess whether reductions in the front pole cover erosion can be attained while still maintaining very low erosion rates on the discharge channel walls. NASA GRC and JPL have begun a magnetic field topology characterization and optimization study by designing four candidate magnetic field topologies that reduce the effectiveness of the shielding along the discharge channel walls with the intent to also reduce the erosion rates along the pole covers. Three of the four candidate magnetic field topologies have been manufactured subjected to an extensive test campaign that includes performance, plume, and stability characterization. In Phase I of the testing campaign, the thruster's oscillation magnitude and Laser Induced fluorescence (LIF) measurements of the plasma plume were performed for the three candidate topologies. In Phase I, the thruster's oscillation magnitude and LIF measurements were performed for the three candidate topologies. Phase I test results found that the B1 configuration attained lower oscillation levels than B0. Additionally, LIF measurements along the discharge chamber centerline found that upstream retraction of the thruster's peak magnetic field does result in an upstream shift of the acceleration zone but the magnitude of the shift does not correspond one-to-one to the shift in the location of the peak radial magnetic field magnitude. Phase II test segment will include performing performance, stability, plume, and erosion measurements for the various candidate magnetic field topologies.

Kamhawi, Hani↗

Coexistence of Magnetic Orders in Two-Dimensional Magnet CrI3

The magnetic properties in two-dimensional van der Waals materials depend sensitively on structure. CrI 3 , as an example, has been recently demonstrated to exhibit distinct magnetic properties depending on the layer thickness and stacking order. Bulk CrI 3 is ferromagnetic (FM) with a Curie temperature of 61 K and a rhombohedral layer stacking, whereas few-layer CrI 3 has a layered antiferromagnetic (AFM) phase with a lower ordering temperature of 45 K and a monoclinic stacking. In this work, we use cryogenic magnetic force microscopy to investigate CrI 3 flakes in the intermediate thickness range (25–200 nm) and find that the two types of magnetic orders, hence the stacking orders, can coexist in the same flake with a layer of ~13 nm at each surface being in the layered AFM phase similar to few-layer CrI 3 and the rest in the bulk FM phase. The switching of the bulk moment proceeds through a remnant state with nearly compensated magnetic moment along the c-axis, indicating formation of c-axis domains allowed by a weak interlayer coupling strength in the rhombohedral phase. Our research provides a comprehensive picture on the magnetism in CrI 3 and point to the possibility of engineering magnetic heterostructures within the same material.

2D magnets↗

Magnetic Helicity in a Chiral-Polar Magnet Ni 2 InSbO 6

The class of chiral-polar magnets has recently captured significant interest in scientific study due to their intriguing physical phenomena. Among all the chiral-polar magnets, Ni 2 InSbO 6 stands out because of its unique attributes, such as the emergence of the topological chiral soliton lattice in the presence of an external magnetic field perpendicular to the chiral-polar axis. However, the magnetic structure of Ni 2 InSbO 6 at zero field has not been well understood yet. This work presents an analysis including polarized optical microscopy and polarized neutron diffraction on a carefully chosen Ni 2 InSbO 6 crystal. Here, results confirm the predominance of a single chiral-polar domain within the crystal and indicate the likelihood of cycloidal magnetic ordering under zero magnetic field, alongside the observation of net magnetic helicity. The existence of both a dominant chiral-polar domain and a dominant cycloidal magnetic domain within Ni 2 InSbO 6 provides an excellent platform for further exploration of its unconventional physical attributes.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Mechanically robust high magnetic-performance Sm-Co sintered magnets through microstructure engineering

Samarium-cobalt (Sm-Co) sintered magnets have high magnetic energy densities, great resistance to demagnetization and corrosion, and excellent thermal stability in a wide temperature range (–50–550 °C). However, the utilization of these magnets is restricted by their brittleness. Based on micromechanical and the Zener pinning model, Sm-Co sintered magnets with improved mechanical properties have been designed and fabricated via microstructure engineering. A small amount of fine Sm 2 O 3 particulates (0–3 wt%) has been incorporated into Sm 2 (CoFeCuZr) 17 sintered magnets to refine the grain size by up to approximately 50% (from 45 to 22 µm) and narrow the grain size distribution. Doping with 3 wt% Sm 2 O 3 increased the flexural strength by 62% while maintaining magnetic performance. Both grain-refined unimodal microstructure and heterogeneous laminated coarse/fine grain microstructure were formed by strategically designed assemblies of Sm 2 O 3 -added Sm-Co powder feedstock mixtures. The technology is compatible with existing magnet manufacturing processes. Numerical micromechanics simulation indicates that the fracture is dominated by intragranular mode. The mechanical strength is mainly enhanced by the additive-induced grain refinement, while the small amount of Sm 2 O 3 addition has a small direct positive contribution. Finally, these magnets will be more cost-effective, efficient, and robust for various functional applications.

36 MATERIALS SCIENCE↗

Effects of magnetic field annealing on the hard magnetic properties of milled Nd-Fe-B powders

In this study, we report the effect of magnetic field annealing (MA) in relieving the stress induced during the milling of Nd-Fe-B sintered magnets. The effect of MA processing parameters and particle size on the magnetic properties were investigated. Based on the results, magnetic field annealing is more effective in improving the magnetic properties of larger size particles, compared to finer particles. Our computational study on the role of particle surface defects in bi-modal particle distribution agrees with results obtained experimentally. In conclusion, magnetic field annealed powder has been successfully used to develop 4.6 g.cm -3 density bonded magnets with 75 vol% of magnetic powder and polyamide 12 (nylon 12) polymer binder resulting in 11.3 MGOe energy product.

36 MATERIALS SCIENCE↗

Magnetic force microscopy revealing long range molecule impact on magnetic tunnel junction based molecular spintronics devices

Magnetic force microscopy (MFM) vividly showed that organometallic molecules, when bridged between two ferromagnetic electrodes along the cross-shaped magnetic tunnel junction edges transformed the magnetic electrodes itself. Molecules impacted a large area of ferromagnetic leads around the junction at room temperature and complement the previous magnetic measurements showing molecule effect on pillar form magnetic tunnel junctions. This molecule induced changes in the magnetic electrodes impacted the transport of the magnetic tunnel junction and stabilized as much as seven orders smaller current at room temperature. We have discussed the current suppression phenomenon in the recent publication [Ref. Tyagi et al. Organic Electronics, 2019, Vol. 64, p 188]; however, we did not provide any direct evidence of molecule impact on ferromagnetic electrodes around molecule junction. Our MFM studies in this paper suggests that molecule effect was observable several μm away from the molecule-metal junctions. Furthermore, our study suggests that magnetic tunnel junction based molecular spintronics devices can be a gateway to a vast range of commercially viable and robust futuristic computer devices and highly correlated materials.

42 ENGINEERING↗