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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

The Effect of Clouds on Water Vapor Profiling from the Millimeter-Wave Radiometric Measurements

Simultaneous measurements with the millimeter-wave imaging radiometer (MIR), cloud lidar system (CLS), and the MODIS airborne simulator (MAS) were made aboard the NASA ER-2 aircraft over the western Pacific Ocean on 17-18 January 1993. These measurements were used to study the effects of clouds on water vapor profile retrievals based on millimeter-wave radiometer measurements. The CLS backscatter measurements (at 0.532 and 1.064 am) provided information on the heights and a detailed structure of cloud layers; the types of clouds could be positively identified. All 12 MAS channels (0.6-13 Am) essentially respond to all types of clouds, while the six MIR channels (89-220 GHz) show little sensitivity to cirrus clouds. The radiances from the 12-/Am and 0.875-gm channels of the MAS and the 89-GHz channel of the MIR were used to gauge the performance of the retrieval of water vapor profiles from the MIR observations under cloudy conditions. It was found that, for cirrus and absorptive (liquid) clouds, better than 80% of the retrieval was convergent when one of the three criteria was satisfied; that is, the radiance at 0.875 Am is less than 100 W/cm.sr, or the brightness at 12 Am is greater than 260 K, or brightness at 89 GHz is less than 270 K (equivalent to cloud liquid water of less than 0.04 g/cm). The range of these radiances for convergent retrieval increases markedly when the condition for convergent retrieval was somewhat relaxed. The algorithm of water vapor profiling from the MIR measurements could not perform adequately over the areas of storm-related clouds that scatter radiation at millimeter wavelengths.

Wang, J. R.↗
NASA NTRS2003

Derivation of Aerosol Columnar Mass from MODIS Optical Depth

In order to verify performance, aerosol transport models (ATM) compare aerosol columnar mass (ACM) with those derived from satellite measurements. The comparison is inherently indirect since satellites derive optical depths and they use a proportionality constant to derive the ACM. Analogously, ATMs output a four dimensional ACM distribution and the optical depth is linearly derived. In both cases, the proportionality constant requires a direct intervention of the user by prescribing the aerosol composition and size distribution. This study introduces a method that minimizes the direct user intervention by making use of the new aerosol products of MODIS. A parameterization is introduced for the derivation of columnar aerosol mass (AMC) and CCN concentration (CCNC) and comparisons between sunphotometer, MODIS Airborne Simulator (MAS) and in-measurements are shown. The method still relies on the scaling between AMC and optical depth but the proportionality constant is dependent on the MODIS derived r$_{eff}$,\eta (contribution of the accumulation mode radiance to the total radiance), ambient RH and an assumed constant aerosol composition. The CCNC is derived fkom a recent parameterization of CCNC as a function of the retrieved aerosol volume. By comparing with in-situ data (ACE-2 and TARFOX campaigns), it is shown that retrievals in dry ambient conditions (dust) are improved when using a proportionality constant dependent on r$ {eff}$ and \eta derived in the same pixel. In high humidity environments, the improvement inthe new method is inconclusive because of the difficulty in accounting for the uneven vertical distribution of relative humidity. Additionally, two detailed comparisons of AMC and CCNC retrieved by the MAS algorithm and the new method are shown. The new method and MAS retrievals of AMC are within the same order of magnitude with respect to the in-situ measurements of aerosol mass. However, the proposed method is closer to the in-situ measurements than the MODIS retrievals. The retrievals of CCNC are also within the same order of magnitude for both methods. The new method is applied to an actual MODIS retrieval and although no in-situ data is available to compare, it is shown that the proposed method yields more credible values than the MODIS retrievals. In addition, recent data available from the PRIDE (Puerto Rico Dust Experiment, July 2000) will be shown by comparing sunphotometer, MODIS and in-situ data.

Gasso, Santiago↗
NASA NTRS2004

Product Distribution Theory and Semi-Coordinate Transformations

Product Distribution (PD) theory is a new framework for doing distributed adaptive control of a multiagent system (MAS). We introduce the technique of "coordinate transformations" in PD theory gradient descent. These transformations selectively couple a few agents with each other into "meta-agents". Intuitively, this can be viewed as a generalization of forming binding contracts between those agents. Doing this sacrifices a bit of the distributed nature of the MAS, in that there must now be communication from multiple agents in determining what joint-move is finally implemented However, as we demonstrate in computer experiments, these transformations improve the performance of the MAS.

Airiau, Stephane↗
NASA NTRS2004

Product Distribution Theory for Control of Multi-Agent Systems

Product Distribution (PD) theory is a new framework for controlling Multi-Agent Systems (MAS's). First we review one motivation of PD theory, as the information-theoretic extension of conventional full-rationality game theory to the case of bounded rational agents. In this extension the equilibrium of the game is the optimizer of a Lagrangian of the (probability distribution of) the joint stare of the agents. Accordingly we can consider a team game in which the shared utility is a performance measure of the behavior of the MAS. For such a scenario the game is at equilibrium - the Lagrangian is optimized - when the joint distribution of the agents optimizes the system's expected performance. One common way to find that equilibrium is to have each agent run a reinforcement learning algorithm. Here we investigate the alternative of exploiting PD theory to run gradient descent on the Lagrangian. We present computer experiments validating some of the predictions of PD theory for how best to do that gradient descent. We also demonstrate how PD theory can improve performance even when we are not allowed to rerun the MAS from different initial conditions, a requirement implicit in some previous work.

Lee, Chia Fan↗
NASA NTRS2004

Facilitating the Specification Capture and Transformation Process in the Development of Multi-Agent Systems

To support the development of flexible and reusable MAS, we have built a framework designated MAS-CF. MAS-CF is a component framework that implements a layered architecture based on contextual composition. Interaction rules, controlled by architecture mechanisms, ensure very low coupling, making possible the sharing of distributed services in a transparent, dynamic and independent way. These properties propitiate large-scale reuse, since organizational abstractions can be reused and propagated to all instances created from a framework. The objective is to reduce complexity and development time of multi-agent systems through the reuse of generic organizational abstractions.

Filho, Aluzio Haendehen↗
NASA NTRS2006

Solid State NMR Studies of the Aluminum Hydride Phases

Several solid state NMR techniques including magic-angle-spinning (MAS) and multiple-quantum (MQ) MAS experiments have been used to characterize various AlH3 samples. MAS-NMR spectra for the 1H and 27Al nuclei have been obtained on a variety of AlH3 samples that include the (beta)- and (gamma)- phases as well as the most stable (alpha)-phase. While the dominant components in these NMR spectra correspond to the aluminum hydride phases, other species were found that include Al metal, molecular hydrogen (H2), as well as peaks that can be assigned to Al-O species in different configurations. The occurrence and concentration of these extraneous components are dependent upon the initial AlH3 phase composition and preparation procedures. Both the (beta)-AlH3 and (gamma)-AlH3 phases were found to generate substantial amounts of Al metal when the materials were stored at room temperature while the (alpha)-phase materials do not exhibit these changes.

phase compositions↗
NASA NTRS2007

Validation of the Lockheed Martin Morphing Concept with Wind Tunnel Testing

The Morphing Aircraft Structures (MAS) program is a Defense Advanced Research Projects Agency (DARPA) led effort to develop morphing flight vehicles capable of radical shape change in flight. Two performance parameters of interest are loiter time and dash speed as these define the persistence and responsiveness of an aircraft. The geometrical characteristics that optimize loiter time and dash speed require different geometrical planforms. Therefore, radical shape change, usually involving wing area and sweep, allows vehicle optimization across many flight regimes. The second phase of the MAS program consisted of wind tunnel tests conducted at the NASA Langley Transonic Dynamics Tunnel to demonstrate two morphing concepts and their enabling technologies with large-scale semi-span models. This paper will focus upon one of those wind tunnel tests that utilized a model developed by Lockheed Martin Aeronautics Company (LM). Wind tunnel success criteria were developed by NASA to support the DARPA program objectives. The primary focus of this paper will be the demonstration of the DARPA objectives by systematic evaluation of the wind tunnel model performance relative to the defined success criteria. This paper will also provide a description of the LM model and instrumentation, and document pertinent lessons learned. Finally, as part of the success criteria, aeroelastic characteristics of the LM derived MAS vehicle are also addressed. Evaluation of aeroelastic characteristics is the most detailed criterion investigated in this paper. While no aeroelastic instabilities were encountered as a direct result of the morphing design or components, several interesting and unexpected aeroelastic phenomenon arose during testing.

Ivanco, Thomas G.↗
NASA NTRS2000

Extending the ICRF into the Infrared: 2MASS - UCAC Astrometry

An external comparison between the infrared 2MASS and the optical UCAC positions was performed, both being on the same system, the ICRS. About 48 million sources in common were identified. Random errors of the 2MASS catalog positions are about 60 to 70 mas per coordinate for the Ks = 4 to 14 range, increasing to about 100 to 150 mas for saturated and very faint stars. Systematic position differences between the 2 catalogs are very small, about 5 to 10 mas as a function of magnitude and color, with somewhat larger errors as a function of right ascension and declination. The extension of the ICRF into the infrared has become a reality.

USNO CCD Astrograph Catalog (UCAC)↗
NASA NTRS2010

The Position/Structure Stability of Four ICRF2 Sources

Four compact radio sources in the International Celestial Reference Frame (ICRF2) catalog were observed using phase referencing with the VLBA at 43, 23, and 8.6-GHz, and with VERA at 23-GHz over a one-year period. The goal was to determine the stability of the radio cores and to assess structure effects associated with positions in the ICRF2. Conclusions are: (1) 43-GHz VLBI high-resolution observations are often needed to determine the location of the radio core. (2) Over the observing period, the relative positions among the four radio cores were constant to 0.02 mas, suggesting that once the true radio core is identified, it remains stationary in the sky to this accuracy. (3) The emission in 0556+238, one of the four sources investigated and one of the 295 ICRF2 defining sources, was dominated by a strong component near the core and moved 0.1 mas during the year. (4) Comparison of the VLBA images at 43, 23, and 8.6-GHz with the ICRF2 positions suggests that the 8-GHz structure is often dominated by a bright non-core component. The measured ICRF2 position can be displaced more than 0.5 mas from the radio core and partake in the motion of the bright jet component.

Fomalont, Ed↗
NASA NTRS2016

VLTI-AMBER Velocity-Resolved Aperture-Synthesis Imaging of Eta Carinae with a Spectral Resolution of 12 000: Studies of the Primary Star Wind and Innermost Wind-Wind Collision Zone

The mass loss from massive stars is not understood well. Eta Carinae is a unique object for studying the massive stellar wind during the luminous blue variable phase. It is also an eccentric binary with a period of 5.54 yr. The nature of both stars is uncertain, although we know from X-ray studies that there is a wind-wind collision whose properties change with orbital phase. Aims. We want to investigate the structure and kinematics of Car's primary star wind and wind-wind collision zone with a high spatial resolution of approx.6 mas (approx.14 au) and high spectral resolution of R = 12 000. Methods. Observations of Car were carried out with the ESO Very Large Telescope Interferometer (VLTI) and the AMBER instrument between approximately five and seven months before the August 2014 periastron passage. Velocity-resolved aperture-synthesis images were reconstructed from the spectrally dispersed interferograms. Interferometric studies can provide information on the binary orbit, the primary wind, and the wind collision. Results. We present velocity-resolved aperture-synthesis images reconstructed in more than 100 di erent spectral channels distributed across the Br(gamma) 2.166 micron emission line. The intensity distribution of the images strongly depends on wavelength. At wavelengths corresponding to radial velocities of approximately -140 to -376 km/s measured relative to line center, the intensity distribution has a fan-shaped structure. At the velocity of -277 km/s, the position angle of the symmetry axis of the fan is 126. The fan-shaped structure extends approximately 8.0 mas (approx.18:8 au) to the southeast and 5.8 mas (approx.13:6 au) to the northwest, measured along the symmetry axis at the 16% intensity contour. The shape of the intensity distributions suggests that the obtained images are the first direct images of the innermost wind-wind collision zone. Therefore, the observations provide velocity-dependent image structures that can be used to test three-dimensional hydrodynamical, radiative transfer models of the massive interacting winds of Eta Car.

Velocity-resolved aperture-synthesis images↗
NASA NTRS2021

VLTI-MATISSE Chromatic Aperture-Synthesis Imaging of η Carinae’s Stellar Wind Across the Brα Line: Periastron Passage Observations in February 2020

Context: Eta Carinae is a highly eccentric, massive binary system (semimajor axis∼15.5 au) with powerful stellar winds and a phase-dependent wind-wind collision (WWC) zone. The primary star, ηCar A, is a luminous blue variable (LBV); the secondary, η Car B, is a Wolf-Rayet or O star with a faster but less dense wind. Aperture-synthesis imaging allows us to study the mass loss from the enigmatic LBV η Car. Understanding LBVs is a crucial step toward improving our knowledge about massive stars and their evolution. Aims: Our aim is to study the intensity distribution and kinematics of η Car’s WWC zone. Methods: Using the VLTI-MATISSE mid-infrared interferometry instrument, we perform Brα imaging of η Car’s distorted wind. Results: We present the first VLTI-MATISSE aperture-synthesis images of η Car A’s stellar wind in several spectral channels distributed across the Brα 4.052 μm line (spectral resolving power R∼960). Our observations were performed close to periastron passage in February 2020 (orbital phase∼14.0022). The reconstructed iso-velocity images show the dependence of the primary stellar wind on wavelength or line-of-sight (LOS) velocity with a spatial resolution of 6 mas (∼14 au). The radius of the faintest outer wind regions is∼26 mas (∼60 au). At several negative LOS velocities, the primary stellar wind is less extended to the northwest than in other directions. This asymmetry is most likely caused by the WWC. Therefore, we see both the velocity field of the undisturbed primary wind and the WWC cavity. In continuum spectral channels, the primary star wind is more compact than in line channels. A fit of the observed continuum visibilities with the visibilities of a stellar wind CMFGEN model (CMFGEN is an atmosphere code developed to model the spectra of a variety of objects) provides a full width at half maximum fit diameter of the primary stellar wind of 2.84±0.06 mas (6.54±0.14 au). We compare the derived intensity distributions with the CMFGEN stellar wind model and hydrodynamic WWC models.

G Weigelt↗
NASA NTRS2022

Constraining Global Coronal Models with Multiple Independent Observables

Global coronal models seek to produce an accurate physical representation of the Sun's atmosphere that can be used, for example, to drive space-weather models. Assessing their accuracy is a complex task, and there are multiple observational pathways to provide constraints and tune model parameters. Here, we combine several such independent constraints, defining a model-agnostic framework for standardized comparison. We require models to predict the distribution of coronal holes at the photosphere, and neutral line topology at the model's outer boundary. We compare these predictions to extreme-ultraviolet (EUV) observations of coronal hole locations, white-light Carrington maps of the streamer belt, and the magnetic sector structure measured in situ by Parker Solar Probe and 1 au spacecraft. We study these metrics for potential field source surface (PFSS) models as a function of source surface height and magnetogram choice, as well as comparing to the more physical Wang–Sheeley–Arge (WSA) and the Magnetohydrodynamic Algorithm outside a Sphere (MAS) models. We find that simultaneous optimization of PFSS models to all three metrics is not currently possible, implying a trade-off between the quality of representation of coronal holes and streamer belt topology. WSA and MAS results show the additional physics that they include address this by flattening the streamer belt while maintaining coronal hole sizes, with MAS also improving coronal hole representation relative to WSA. We conclude that this framework is highly useful for inter- and intra-model comparisons. Integral to the framework is the standardization of observables required of each model, evaluating different model aspects.

S. T. Badman↗
DOE OSTI2022

Advanced Sensor Deployment for Distribution System State Estimation and Fault Identification: Preprint

Distribution systems are currently facing steep operational challenges as a result of the rapidly increasing integration of renewables and other distributed energy resources (DERs)at both the primary and secondary circuit levels. Distribution utilities and system operators have traditionally had some visibility of their primary circuits using low-frequency supervisory control and data acquisition systems, and they have had very poor if not zero visibility of the secondary circuits where the presence of DERs is constantly increasing. Therefore, this paper presents simulation studies to demonstrate the benefits of an advanced, high-fidelity sensor technology, called as the Meta-Alert System (MAS), developed by Electrical Grid Monitoring Ltd. (EGM), on the distribution grid. First, a reliable model of the EGM sensors is developed, and then two use cases - distribution system state estimation (DSSE) and fault identification - are simulated to evaluate the performance of the MAS technology. Simulation results on the Electric Power Research Institute J1feeder demonstrate that the MAS can effectively participate in system-level DSSE programs and can detect and locate faults faster than traditional distribution protection schemes.

distribution system monitoring↗
DOE OSTI2020

Glass formation and structure of melt quenched mixed oxy-sulfide Na 4 P 2 S 7-x O x glasses for 0 ≤ x ≤ 5

The structures of Na 4 P 2 S 7-x O x , 0 ≤ x ≤ 5, glasses were investigated using melt quench (MQ) samples. The short-range order (SRO) structures of these glasses were examined using a combination of Raman, Fourier Transform Infrared (FT-IR), and 31 P Magic Angle Spinning NMR ( 31 P MAS NMR) spectroscopies to determine how oxygen is incorporated into the sulfide structure. Using vibrational spectroscopy, semi-quantitative 31 P MAS NMR, and charge balancing, a complete compositional map of all the SRO structures present in these glasses has been generated. From these findings, full incorporation of the oxygen into the sulfide melt was found to occur across the compositional series through a structural disproportionation reaction where oxygen systematically replaces bridging sulfurs (BSs), before replacing the remaining non-bridging sulfurs (NBSs). Under the melting and quenching conditions used in this study, it was found that the melts crystallize too quickly to form homogeneous crystallite-free glasses for x > 5.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Proton-detected solid-state NMR spectroscopy of spin-1/2 nuclei with large chemical shift anisotropy

Constant-time (CT) dipolar heteronuclear multiple quantum coherence (D-HMQC) has previously been demonstrated as a method for proton detection of high-resolution wideline NMR spectra of spin-1/2 nuclei with large chemical shift anisotropy (CSA). However, 1 H transverse relaxation and t 1 -noise often reduce the sensitivity of D-HMQC experiments, preventing the theoretical gains in sensitivity provided by 1 H detection from being realized. In this paper, we demonstrate a series of improved pulse sequences for 1 H detection of spin-1/2 nuclei under fast MAS, with 195 Pt SSNMR experiments on cisplatin as an example. First, a t 1 -incrementation protocol for D-HMQC dubbed Arbitrary Indirect Dwell (AID) is demonstrated. AID allows the use of arbitrary, rotor asynchronous t 1 -increments, but removes the constant time period from CT D-HMQC, resulting in improved sensitivity by reducing transverse relaxation losses. Next, we show that short high-power adiabatic pulses (SHAPs), which efficiently invert broad MAS sideband manifolds, can be effectively incorporated into 1 H detected symmetry-based resonance echo double resonance (S-REDOR) and t 1 -noise eliminated (TONE) D-HMQC experiments. The S-REDOR experiments with SHAPs provide approximately double the dipolar dephasing, as compared to experiments with rectangular inversion pulses. We lastly show that sensitivity and resolution can be further enhanced with the use of swept excitation pulses as well as adiabatic magic angle turning (aMAT).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Double echo symmetry-based REDOR and RESPDOR pulse sequences for proton detected measurements of heteronuclear dipolar coupling constants

1 H{X} symmetry-based rotational echo double resonance pulse sequences (S-REDOR) and symmetry-based rotational echo saturation pulse double resonance (S-RESPDOR) solid-state NMR experiments have found widespread application for 1 H detected measurements of difference NMR spectra, dipolar coupling constants, and internuclear distances under conditions of fast magic angle spinning (MAS). In these experiments the supercycled $\text{R4}^2_1 (\text{SR4}^2_1)$ symmetry-based recoupling pulse sequence is typically applied to the 1 H spins to reintroduce heteronuclear dipolar couplings. However, the timing of $\text{SR4}^2_1$ and other symmetry-based pulse sequences must be precisely synchronized with the rotation of the sample, otherwise, the evolution of 1 H CSA and other interactions will not be properly refocused. For this reason, significant distortions are often observed in experimental dipolar dephasing difference curves obtained with S-REDOR or S-RESPDOR pulse sequences. Here we introduce a family of double echo (DE) S-REDOR/S-RESPDOR pulse sequences that function in an analogous manner to the recently introduced $t_1$-noise eliminated (TONE) family of dipolar heteronuclear multiple quantum coherence (D-HMQC) pulse sequences. Through numerical simulations and experiments the DE S-REDOR/S-RESPDOR sequences are shown to provide dephasing difference curves similar to those obtained with S-REDOR/S-RESPDOR. However, the DE sequences are more robust to the deviations of the MAS frequency from the ideal value that occurs during typical solid-state NMR experiments. In this work, the DE sequences are shown to provide more reliable 1 H detected dipolar dephasing difference curves for nuclei such as 15 N (with isotopic labelling), 183 W and 35 Cl. The double echo sequences are therefore recommended to be used in place of conventional S-REDOR/S-RESPDOR sequences for measurement of weak dipolar coupling constants and long-range distances.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Current limitations of solid-state NMR in carbohydrate and cell wall research

High-resolution investigation of cell wall materials has emerged as an important application of biomolecular solid-state NMR (ssNMR). Multidimensional correlation experiments have become a standard method for obtaining sufficient spectral resolution to determine the polymorphic structure of carbohydrates and address biochemical questions regarding the supramolecular organization of cell walls. Here, using plant cellulose and matrix polysaccharides as examples, we will review how the multifaceted complexity of polysaccharide structure is impeding the resonance assignment process and assess the available biochemical and spectroscopic approaches that could circumvent this barrier. We will emphasize the ineffectiveness of the current methods in reconciling the ever-growing dataset and deriving structural information. We will evaluate the protocols for achieving efficient and homogeneous hyperpolarization across the cell wall material using magic-angle spinning dynamic nuclear polarization (MAS-DNP). Critical questions regarding the line-broadening effects of cell wall molecules at cryogenic temperature and by paramagnetic biradicals will be considered. Finally, the MAS-DNP method will be placed into a broader context with other structural characterization techniques, such as cryo-electron microscopy, to advance ssNMR research in carbohydrate and cell wall biomaterials.

09 BIOMASS FUELS↗
DOE OSTI2024

Comparison of methods for the NMR measurement of motionally averaged dipolar couplings

Motionally averaged dipolar couplings are an important tool for understanding the complex dynamics of catalysts, polymers, and biomolecules. While there is a plethora of solid-state NMR pulse sequences available for their measurement, in can be difficult to gauge the methods’ strengths and weaknesses. In particular, there has not been a comprehensive comparison of their performance in natural abundance samples, where 1H homonuclear dipolar couplings are important and the use of large MAS rotors may be required for sensitivity reasons. In this work, we directly compared some of the more common methods for measuring C–H dipolar couplings in natural abundance samples using L-alanine (L-Ala) and the N-formyl-L-methionyl-L-leucyl-L-phenylalanine (fMLF) tripeptide as model systems. Here, we evaluated their performance in terms of accuracy, resolution, sensitivity, and ease of implementation. We found that, despite the presence of 1H homonuclear dipolar interactions, all methods, with the exception of REDOR, were able to yield the reasonable dipolar coupling strengths for both mobile and static moieties. Of these methods, PDLF provides the most convenient workflow and precision at the expense of low sensitivity. In low-sensitivity cases, MAS-PISEMA and DIPSHIFT appear to be the better options.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗