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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Self-healing polymers

A three dimensional structure fabricated from a self-healing polymeric material, comprising poly(ester amides) obtained from ethylene glycol, azelaic acid and 1,1-aminoundecanoic acid, wherein polymeric material has a melt index above 2.5 g/10 min. as determined by ASTM D1238 at 190.degree. C. and 2.16kg, impact resistance and ductility sufficient to resist cracking and brittle fracture upon impact by a 9 mm bullet fired at a temperature of about 29.degree. C. at subsonic speed in a range from about 800 feet/sec to about 1000 feet/sec. It has been determined that the important factors necessary for self-healing behavior of polymers include sufficient impact strength, control of the degree of crystallinity, low melting point and the ability to instantly melt at impacted area.

Klein, Daniel J.↗
NASA NTRS2003

Structural Fluctuations and Thermophysical Properties of Molten II-VI Compounds

The objectives of the project are to conduct ground-based experimental and theoretical research on the structural fluctuations and thermophysical properties of molten II-VI compounds to enhance the basic understanding of the existing flight experiments in microgravity materials science programs as well as to study the fundamental heterophase fluctuation phenomena in these melts by: 1) conducting neutron scattering analysis and measuring quantitatively the relevant thermophysical properties of the II-VI melts (such as viscosity, electrical conductivity, thermal diffusivity and density) as well as the relaxation characteristics of these properties to advance the understanding of the structural properties and the relaxation phenomena in these melts and 2) performing theoretical analyses on the melt systems to interpret the experimental results. All the facilities required for the experimental measurements have been procured, installed and tested. It has long been recognized that liquid Te presents a unique case having properties between those of metals and semiconductors. The electrical conductivity for Te melt increases rapidly at melting point, indicating a semiconductor-metal transition. Te melts comprise two features, which are usually considered to be incompatible with each other: covalently bound atoms and metallic-like behavior. Why do Te liquids show metallic behavior? is one of the long-standing issues in liquid metal physics. Since thermophysical properties are very sensitive to the structural variations of a melt, we have conducted extensive thermophysical measurements on Te melt.

Su, Ching-Hua↗
NASA NTRS2003

Succinonitrile Purification Facility

The Succinonitrile (SCN) Purification Facility provides succinonitrile and succinonitrile alloys to several NRA selected investigations for flight and ground research at various levels of purity. The purification process employed includes both distillation and zone refining. Once the appropriate purification process is completed, samples are characterized to determine the liquidus and/or solidus temperature, which is then related to sample purity. The lab has various methods for measuring these temperatures with accuracies in the milliKelvin to tenths of milliKelvin range. The ultra-pure SCN produced in our facility is indistinguishable from the standard material provided by NIST to well within the stated +/- 1.5mK of the NIST triple point cells. In addition to delivering material to various investigations, our current activities include process improvement, characterization of impurities and triple point cell design and development. The purification process is being evaluated for each of the four vendors to determine the efficacy of each purification step. We are also collecting samples of the remainder from distillation and zone refining for analysis of the constituent impurities. The large triple point cells developed will contain SCN with a melting point of 58.0642 C +/- 1.5mK for use as a calibration standard for Standard Platinum Resistance Thermometers (SPRTs).

Source record↗
NASA NTRS2016

Self-Healing Composite of Thermoset Polymer and Programmed Super Contraction Fibers

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and a thermoplastic polymer for molecular scale healing is disclosed; the composition has the ability to resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer serves to bring surfaces of a structural defect into approximation, whereafter use of the thermoplastic polymer for molecular scale healing allowed for movement of the thermoplastic polymer into the defect and thus obtain molecular scale healing. The thermoplastic can be fibers, particles or spheres which are used by heating to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. Compositions of the invention have the ability to not only close macroscopic defects, but also to do so repeatedly even if another wound/damage occurs in a previously healed/repaired area.

Li, Guoqiang↗
NASA NTRS2019

New Estimates of Ice and Oxygen Fluxes Across the Entire Lid of Lake Vostok From Observations of Englacial Radio Wave Attenuation

Over deep Antarctic subglacial lakes, spatially varying ice thickness and the pressure‐dependent melting point of ice result in distinct areas of melting and freeze‐on at the ice‐water interface, that is, at the lake lid. These ice mass fluxes drive lake circulation and, because basal Antarctic ice contains air clathrate, affect the input of oxygen to the lake, with implications for subglacial life. Inferences of rates of melting and freeze‐on, that is, accretion rates, from radar layer tracking and geodesy are limited in spatial coverage and resolution. Here we develop a new method to estimate accretion rate, and the resulting oxygen input at a lake lid, using airborne radar data over Lake Vostok together with ice‐temperature and chemistry data from the Vostok ice core. Because the lake lid is a coherent reflector of known reflectivity (at our radar frequency), we can infer depth‐averaged radio wave attenuation in the ice, with a spatial resolution of ~1 km along flight lines. Spatial variation in attenuation depends mostly on variation in ice temperature near the lid, which in turn varies strongly with ice mass flux at the lid. We model ice temperature versus depth with ice mass flux as a parameter, thus linking that flux to observed depth‐averaged attenuation. The resulting map of melt and accretion rates independently reproduces features known from earlier studies but now covers the entire lid. We find that freeze‐on is dominant when integrated over the lid, with an ice imbalance of 0.05 to 0.07 cu.km/year, which is robust against uncertainties.

Dale P. Winebrenner↗
NASA NTRS1980

Low cost Czochralski crystal growing technology. Near implementation of the flat plate photovoltaic cost reduction of the low cost solar array project

Equipment developed for the manufacture of over 100 kg of silicon ingot from one crucible by rechanging from another crucible is described. Attempts were made to eliminate the cost of raising the furnace temperature to 250 C above the melting point of silicon by using an RF coil to melt polycrystalline silicon rod as a means of rechanging the crucible. Microprocessor control of the straight growth process was developed and domonstrated for both 4 inch and 6 inch diameter. Both meltdown and melt stabilization processes were achieved using operator prompting through the microprocessor. The use of the RF work coil in poly rod melting as a heat sink in the accelerated growth process was unsuccessful. The total design concept for fabrication and interfacing of the total cold crucible system was completed.

Roberts, E. G.↗
NASA NTRS1991

The composition of meteoroids impacting LDEF

So far we have completed an initial scanning electron microscopy (SEM) survey of craters on the exterior of the Long Duration Exposure Facility (LDEF) in the 100 micron to 1mm size range and done some quantitative analysis. In typical craters, the residue appears to be a mixture of glass and FeNi and sulfide beads with an overall chondritic elemental composition. In less than 10 percent of the craters, there is a substantial amount of meteoroid debris that also contains unmelted mineral grains. The relatively high abundance of forsterite and enststite among these irregular grains suggests that a high melting point probably plays a role in surviving impact without melting.

Brownlee, D. E.↗
NASA NTRS1996

High-Temperature Magnetic Bearings for Gas Turbine Engines

Magnetic bearings are the subject of a new NASA Lewis Research Center and U.S. Army thrust with significant industry participation, and coordination with other Government agencies. The NASA/Army emphasis is on high-temperature applications for future gas turbine engines. Magnetic bearings could increase the reliability and reduce the weight of these engines by eliminating the lubrication system. They could also increase the DN (diameter of the bearing times rpm) limit on engine speed and allow active vibration cancellation systems to be used--resulting in a more efficient, "more electric" engine. Finally, the Integrated High-Performance Turbine Engine Technology (IHPTET) Program, a joint Department of Defense/industry program, identified a need for a hightemperature (as high as 1200 F) magnetic bearing that could be demonstrated in a phase III engine. This magnetic bearing is similar to an electric motor. It has a laminated rotor and stator made of cobalt steel. Wound around the stator are a series of electrical wire coils that form a series of electric magnets around the circumference. The magnets exert a force on the rotor. A probe senses the position of the rotor, and a feedback controller keeps it in the center of the cavity. The engine rotor, bearings, and case form a flexible structure that contains a large number of modes. The bearing feedback controller, which could cause some of these modes to become unstable, could be adapted to varying flight conditions to minimize seal clearances and monitor the health of the system. Cobalt steel has a curie point greater than 1700 F, and copper wire has a melting point beyond that. Therefore, practical limitations associated with the maximum magnetic field strength in the cobalt steel and the stress in the rotating components limit the temperature to about 1200 F. The objective of this effort is to determine the limits in temperature and speed of a magnetic bearing operating in an engine. Our approach is to use our in-house experience in magnets, mechanical components, high-temperature materials, and surface lubrication to build and test a magnetic bearing in both a rig and an engine. Testing will be done at Lewis or through cooperative programs in industrial facilities.

Source record↗
NASA NTRS2004

Passive Acoustic Tomography Tested for Measuring Gas Temperatures

The requirements of higher performance, better fuel economy, and lower emissions place an increasing premium on knowing the internal operating parameters of jet engines. One of the most important is the gas temperature in the post combustor section of the engine. Typically the gas temperature is measured with a thermocouple probe or by some optical technique such as Rayleigh scattering. Probes, while providing valuable information, have several limitations. The probe signal must be corrected for radiation and conduction losses, probes provide only a point measurement, and probes must be constructed of materials whose melting points are lower than the temperature of the environment into which they are inserted. Some of the disadvantages of probes are overcome by various optical techniques. Nothing needs to be inserted into the flow, and the temperature can be directly related to the signal by known physical laws. However, optical techniques require optical access (i.e., a window) and a light source (such as a laser), and they are very sensitive to the presence of particles in the flow. To overcome these problems, researchers from the NASA Glenn Research Center and The University of Nevada are developing a technique that uses sound instead of light to measure gas temperature. Like optical techniques, it is nonintrusive--no probe need be exposed to the combustion environment--and the temperature is directly related to a measured quantity--the speed of sound, which is proportional to the square root of the absolute temperature. The temperature profile inside the engine is constructed from the differences in arrival time between correlated signals from an array of microphones placed around the circumference of the engine. In much the same way as a complete picture of the inside of your body can be constructed from an array of x-ray photographs taken at different angles, the temperature profile in the engine is constructed from the angular array of microphones. It is tomography by sound waves. Active acoustic tomography, in which a sound pulse is injected into the flow and the time delays between members of an array of microphones are used to construct the temperature field has been used successfully in the stacks of power plants. However, the flow field inside a jet engine is much too noisy for it to be possible to detect an externally injected sound pulse. Instead we are developing passive acoustic tomography, which uses the sound already present in the flow.

Fralick, Gustave C.↗
NASA NTRS2006

Oceanic Low Blows Hitting Ice Sheets Where It Hurts

The recent acceleration, thinning and retreat of large outlet glaciers in both Antarctica and Greenland is altering the mass balance of these two large ice sheets and increasing their contribution to rising sea level. In this short Perspective solicited by Science for a special March 24th issue on sea level change, I argue that the cause of these bihemispheric changes is that warmer water has gained access to the undersides of these glaciers where they come afloat from the continent. This process is particularly effective at accelerating glaciers because the beds of the large outlet glaciers are well below sea level (1000 meters or more) but "guarded" downstream by a shallow moraine formed when the glacier was more advanced. Once warmer water can breach this moraine, it sinks in the colder, fresh water behind the moraine and reaches the submarine front of the glacier. The pressure melting effect lowers the melting point of this deep ice allowing the warmer water to melt ice at rates of many tens of meters per year. This melting reduces . the frictional hold of the bed on the ice, allowing the ice to accelerate in agreement with the observations, Hansen has discussed the likelihood that approximately half of the Earth's radiation imbalance is manifesting in warmer ocean waters and Levitus et al. have seen warming in ocean temperature measurements at mid and low latitudes. The behavior of these outlet glaciers indicates this ocean warmth is reaching polar waters. The prognosis is for a continuation of this process, more negative ice sheet mass balances and increased rates of sea level rise.

Bindschadler, Robert↗
NASA NTRS2020

Computational Design of Eutectic Molten Salt Mixtures: What Can Thermodynamic Models Do?

In the search for efficient energy storage battery technologies, designing stable electrolytes has been a long-standing challenge. Electrolytes based on molten salt eutectics are known for their stability with minimum parasitic reactions when compared to their widely used organic counterparts. However, the operating temperatures of these molten salt electrolyte-based batteries are dictated by the melting point of the eutectic mixtures. Design and high throughput screening of low melting temperature eutectic molten salt mixtures have been hindered by the lack of computational models. In this work, we develop thermodynamic models to predict the eutectic points of several molten salt mixtures. The framework of the COSMO-SAC model is used for the predictions and is compared with experimental data and other thermodynamic approaches. Rapid thermodynamics-based approaches, as shown in this study, can accelerate the discovery of new materials, complementing experimental techniques.

Ashwin Ravichandran↗
NASA NTRS1984

Electromagnetic containerless undercooling facility and experiments for the Shuttle

An electromagnetic furnace is being prepared for flights aboard the Space Shuttle. This apparatus is capable of melting metals and alloys up to 1400 C melting point by induction heating with subsequent solidification of the freely levitated melt without contact with any container. The solidification can be carried out with greatly reduced fields resulting in minimal heating and stirring of the free melt. Sequential specimens can be processed during flight. Several experiments are planned for a series of flights, beginning in 1985 with an undercooling experiment of NiSn alloys. These will be interspersed with detailed studies of fluid flow caused by low and high field levels in order to quantify the corresponding effect upon the solidification process.

Frost, R. T.↗
NASA NTRS1974

Studies of Martian polar regions

The flow law determined experimentally for solid CO2 establishes that an hypothesis of glacial flow of CO2 at the Martian poles is not physically unrealistic. Compression experiments carried out under 1 atmosphere pressure and constant strain rate conditions demonstrate that the strength of CO2 near its sublimation point is considerably less than the strength of water ice near its melting point. A plausible glacial model for the Martian polar caps was constructed. The CO2 deposited near the pole would have flowed outward laterally to relieve high internal shear stresses. The topography of the polar caps, and the uniform layering and general extent of the layered deposits were explained using this model.

Smith, C. I.↗
NASA NTRS2005

Thermophysical and Optical Properties of Semiconducting Ga2Te3 Melt

The majority of bulk semiconductor single crystals are presently grown from their melts. The thermophysical and optical properties of the melts provide a fundamental understanding of the melt structure and can be used to optimize the growth conditions to obtain higher quality crystals. In this paper, we report several thermophysical and optical properties for Ga2Te3 melts, such as electrical conductivity, viscosity, and optical transmission for temperatures ranging from the melting point up to approximately 990 C. The conductivity and viscosity of the melts are determined using the transient torque technique. The optical transmission of the melts is measured between the wavelengths of 300 and 2000 nm by an dual beam reversed-optics spectrophotometer. The measured properties are in good agreement with the published data. The conductivities indicate that the Ga2Te3 melt is semiconductor-like. The anomalous behavior in the measured properties are used as an indication of a structural transformation in the Ga2Te3 melt and discussed in terms of Eyring's and Bachinskii's predicted behaviors for homogeneous melts.

Li, Chao↗
NASA NTRS2017

Detached Melt and Vapor Growth of InI in SUBSA Furnace

Indium iodide (InI) is a promising wide energy band gap nuclear detector material. It is ideal for space experiments because it is non-toxic and has a relatively low melting point of only 351 degrees Centigrade. However, it has been established that melt-grown crystals contain a large amount of second phase inclusions/precipitates. The typical size of inclusions are 1 to 27 microns in diameter, while the volume fraction of all sizes is 300 to 600 parts per million. The SEM-EDS (Scanning Electron Microscopy / Energy Dispersive X-Ray Spectroscopy) analysis of the inclusions has revealed that they all contain oxygen and some contain carbon. At present, under sponsorship of NASA and CASIS (Center for the Advancement of Science in Space), we are conducting ground-based experiments with InI in preparation for the flight experiments to be conducted in the SUBSA (Solidification Using a Baffle in Sealed Ampoules) furnace in the Microgravity Science Glovebox at the International Space Station, planned for the summer/fall of 2017. Earth-based experiments include melt and vapor growth conducted in the SUBSA ground unit, measurements of the volumetric expansion coefficient of the melt, and measurements of the wetting angle of molten InI. Finite element modeling has been conducted to optimize the design of the flight ampoules. Alloying with Tl and Ga has given promising results.

Ostrogorsky, A. G.↗
NASA NTRS1975

Feasibility investigation of growing gallium arsenide single crystals in ribbon form

Polycrystalline GaAs ribbons have been grown in graphite boats by passage of a wide zone through B2O3 encapsulated feed stock, confined by a quartz cover plate. By controlling the heat flow in the graphite boat and controlling the zoning rate, large grained, single phase polycrystalline samples with directional solidification and good thickness control were achieved. Arsenic vaporization was effectively suppressed at the melting point of GaAs by the B2O3 moat and 3 atmospheres of pressure. A vertical constrained-zone-melting apparatus with a B2O3 moat seal, rf heating, and water cooling on the bottom will be used to control the heat flow and temperature patterns required for growth of single crystal ribbons.

Richardson, D. L.↗
NASA NTRS1978

Early climate on earth-reduced gas models and early climate on Mars-reduced gas and obliquity models

At high obliquity, Martian polar ground temperatures could exceed the melting point of ice for considerable periods of time (approximately 90 Earth days). Under special conditions ice itself might melt. Carbon dioxide adsorbed on the Martian regolith is not expected to buffer the seasonal pressure wave except in the unlikely event that the soil pore size is very large (50 micron). For a basaltic soil composition the maximum CO2 that could be desorbed over obliquity time scales due to thermal forces is a few millibars. At low obliquities the atmospheric pressures may drop, desorbing the soil. The only means to achieve higher CO2 pressures is to have much higher planet-wide temperatures due to some greenhouse effect, or to be at an epoch before the regolith or carbonates formed. The water ice budget between north and south polar caps was considered and summer sublimation rates imply that the ice could be exchanged between the poles during obliquity cycles. A critical factor in the polar cap water budget is the interaction of water and dust. The origin of the Martian polar laminae is probably due to variations in this interaction.

Toon, O. B.↗
NASA NTRS1999

Effects of Melt Processing on Evolution of Structure in PEEK

We report on the effects of melt processing temperature on structure formation in Poly(ether-ether-ketone), PEEK. Real time Small Angle X-ray Scattering, SAXS, and thermal analysis are used to follow the melting behavior after various stages of processing. Assignment of peaks to structural entities within the material, the relative perfection of the crystals, and the possibility of their reorganization, are all influenced by the melt processing history. With the advent of high intensity synchrotron sources of X-radiation, polymer scientists gain a research tool which, when used along with thermal analysis, provides additional structural information about the crystals during growth and subsequent melting. PEEK is an engineering thermoplastic polymer with a very high glass transition temperature (145 C) and crystal melting point (337 C). PEEK has been the subject of recent studies by X-ray scattering in which melt and cold crystallization were followed in real-time. X-ray scattering and thermal studies have been used to address the formation of dual endothermic response which has been variously ascribed to lamellar insertion, dual crystal populations, or melting followed by re-crystallization. Another important issue is whether all of the amorphous phase is located in interlamellar regions, or alternatively whether some is located in "pockets" away from the crystalline lamellar stacks. The interpretation of scattering from lamellar stacks varies depending upon whether such amorphous pockets are formed. Some groups believe all of the amorphous phase is interlamellar. This leads to selection of a smaller thickness for the crystals. Other groups suggest that most amorphous phase is not interlamellar, and this leads to the suggestion that the crystal thickness is larger than the amorphous layer within the stacks. To investigate these ideas, we used SAXS and Differential Scanning Calorimetry to compare results of single and dual stage melt crystallization of PEEK using a treatment scheme involving annealing/crystallization at T(sub a1) followed by annealing at T(sub a2) where either T(sub a1) < T(sub a2) or T(sub a1) > T(sub a2). We proposed a model to explain multiple melting endotherms in PPS, treated according to one or two-stage melt or cold crystallization. Key features of this model are that multiple endotherms: (1) are due to reorganization/recrystallization after cold crystallization; and, (2) are dominated by crystal morphology after melt crystallization at high T. In other words, multiple distinct crystal populations are formed by the latter treatment, leading to observation of multiple melting. PEEK 45OG pellets (ICI Americas) were the starting material for this study. Films were compression molded at 400 C, then quenched to ice water. Samples were heated to 375 C in a Mettler FP80 hot stage and held for three min. to erase crystal seeds before cooling them to T(sub a1) = 280 C . Samples were held at T(sub a2) for a period of time, then immediately heated to 360 C. In the second treatment samples were held at T(sub a1) = 31 C for different crystallization times t(sub c) then cooled to 295 C and held 15 min. In situ (SAXS) experiments were performed at the Brookhaven National Synchrotron Light Source with the sample located inside the Mettler hot stage. The system was equipped with a two-dimensional position sensitive detector. The sample to detector distance was 172.7 cm and the X-ray wavelength was 1.54 Angstroms. SAXS data were taken continuously during the isothermal periods and during the heating to 360 C at 5 C/min. Each SAXS scan was collected for 30 sec. Since the samples were isotropic, circular integration was used to increase the signal to noise ratio. After dual stage melt crystallization with T(sub a1) < T(sub a2) the lower melting endotherm arises from holding at T(sub a1). During cooling a broad distribution of crystals forms, and the low-melting tail is perfected during T(sub al). Heating to T(sub a2) melts these imperfect crystals and allows others with greater average long spacing to form in their place. After dual stage crystallization with T(sub a1) > T(sub a2), the amount of space remaining for additional growth at T(sub a2) depends upon the holding time at T(sub a1). The long period of crystals formed at T(sub a2) is smaller than that formed at T(sub a1) due to growth in a now-restricted geometry. Perfection of crystals is seen as an increase of the intensity of the population scattering at higher s, while the intensity of the population scattering at lower s stays constant. During heating from below to above the minor endotherm, we see rapid decrease of the intensity of the X-ray scattering corresponding to the population of crystals scattering in the shoulder. Another important observation is that after the sample is annealed at 295 C, the shoulder intensity is restored once again. The population scattering at higher s remains longer before it disappears in the sample treated to the second stage of melt crystallization, compared to the sample crystallized with a single stage. This could be interpreted as an effect of continued perfection of the less perfect population, which is also reflected in the increased melting temperature of the smaller endotherm as the holding time at 295 C increases. In the corresponding DSC scans we see a shift in the area and the peak temperature of the lower melting endotherm with an increase of the annealing time.

Georgiev, Georgi↗