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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

The mineralogy and the isotopic composition of sulfur in hydrothermal sulfide/sulfate deposits on the East Pacific Rise, 21 deg N latitude

The mineralogy and isotopic composition of sulfur found in hydrothermal deposits associated with five groups of vents along the ridge axis of the East Pacific Rise near 21 deg N latitude are investigated. Solid samples of mixed sulfides and sulfates from mounds, chimneys and the surrounding sediment as well as fresh basaltic glass were examined with a portable X-ray fluorescence spectrometer and by scanning electron microscopy, X-ray diffractometry, and electron microprobe analysis. For the three vents of exit temperature close to 350 C, the chimneys are found to be rich in copper sulfides, while for those of temperatures around 300 C, zinc sulfide is found to predominate. The major sulfides found in the chimneys include wurtzite, chalcopyrite, pyrite and cubanite, with anhydrite the dominant sulfate. Significant mineralogical differences are found between active and inactive vents. The isotopic composition of sulfur in anhydrites from active vents is observed to be close to that of sea water and consistent with a derivation from sea water sulfate. The isotopic composition of sulfur in the sulfide minerals is explained in terms of precipitation from solutions with reduced sulfur derived from basalts or basaltic magmas, and sea water sulfate. Finally, the deposits are interpreted as the results of the mixing of H2S-dominated hydrothermal fluids with cold sea water near the sea floor.

Styrt, M. M.↗
NASA NTRS1982

Spectral characteristics of the iron oxides with application to the Martian bright region mineralogy

Reflectance spectra of eight polymorphs of FeOOH and Fe2O3 are determined in order to clarify the nature and significance of the iron oxide mineralogy on Mars. The effect of other components that might interfere with iron oxide absorption features is qualitatively constrained through the use of the Kebulka-Munk theory. It is found that the effect of temperature complicates the identification of a given Fe(3+) phase based on the position of the 6A1-4T1 absorption feature. While the Fe(3+) crystal field transitions are spin forbidden, most of the iron oxide polymorphs exhibit anomalously intense crystal field absorption features due to magnetic coupling between adjacent FeO6 octahedra. It is suggested that the resulting deviations from observed remotely sensed reflectance spectra of Mars may provide a basis for the exclusion of many iron oxide phases as significant components of the Martian Fe(3+) mineralogy. A comparison of these results with the visible region spectra of Martian bright regions indicates that the predominant Fe(3+)-bearing phase may be a magnetically disordered material, such as amorphous gels, some ferric sulphates, and other minerals in which Fe(3+) ions in the crystal structure are not magnetically coupled.

Sherman, D. M.↗
NASA NTRS1986

Mineralogy of interplanetary dust particles from the 'olivine' infrared class

Analytical electron microscopy observations establish that olivine is abundant and the predominant silicate phase in three interplanetary dust particles (IDPs) from the 'olivine' infrared spectra category. Two of the particles have microstructures resembling those of most nonhydrous chondritic IDPs, consisting of micron to submicron grains together with a matrix composed of amorphous carbonaceous material and sub-500 A grains. In addition to olivine these particles respectively contain enstatite and magnetite, and pentlandite plus Ca-rich clinopyroxene. The third IDP consists mostly of olivine and pyrrhotite with little or no matrix material. Olivine grains in this particle contain prominent solar-flare ion tracks with densities corresponding to a space-exposure age between 1000 to 100,000 years. Although the three particles have olivine-rich mineralogies in common, other aspects of their mineralogies and microstructures suggest that they experienced different formation histories. The differences between the particles indicate that the olivine infrared spectral category is a diverse collection of IDPs that probably incorporates several genetic groups.

Christoffersen, R.↗
NASA NTRS1987

Mineralogy of a basaltic clast in lunar highland regolith breccia 60019

Mineralogy of a basaltic clast, Ba-2, found on the cut surface of a new slab of lunar highland regolith breccia 60019 was studied and compared with that of lunar meteorites ALHA81005 and Y791197. The coarse-grained Ba-2 clast consists of Na-bearing plagioclase, high-Ca clinopyroxene, ilmenite, silica, and mesostasis. The mineralogy and chemical zoning trends in the Ba-2 clast suggest that this basalt is similar to the 60639,1 basalt in the Apollo 16 rake samples, and to Luna 16 high-alumina moderate-TiO2 mare basalts; however, olivine is not present in Ba-2. On the basis of these and other findings, and assuming the early formation of the Apollo 16 regolith breccia (as proposed by McKay et al., 1986), it is suggested that B-2 could represent a post-Nectaris lava flow older than the formation of 60019.

Takeda, Hiroshi↗
NASA NTRS1987

Mineralogy of chondritic interplanetary dust particles

This paper presents a synopsis of current investigations on the mineralogy of chondritic micrometeorites obtained from the lower stratosphere using flat-plate collection surfaces attached to high-flying aircraft. A compilation of detailed mineralogical analyses for 30 documented chondritic interplanetary dust particles indicates a wide variety of minerals present in assemblages which, as yet, are poorly defined. Two possible assemblages are: (1) carbonaceous phases and layer silicates and (2) carbonaceous and chain silicates or nesosilicates. Particles with both types of silicate assemblages are also observed.

Mackinnon, Ian D. R.↗
NASA NTRS1989

Mineralogy and composition of Archean Crust, Greenland: A pilot study

The Portable Instant Display and Analysis Spectrometer (PIDAS) was taken to southwestern Greenland to investigate in situ the potential application of AVIRIS to estimate the mineralogy and composition of rocks exposed in Archean terranes. The goal was to determine the feasibility of using a high spectral resolution scanner to find and study pristine rocks, those that have not been altered by subsequent deformation and metamorphism. The application of AVIRIS data to the problems in Greenland is logical. However, before a costly deployment of the U-2 aircraft to Greenland is proposed, this study was undertaken to acquire the spectral data necessary to verify that mineralogical mapping in the environmental conditions found there is possible. Although field conditions were far from favorable, all of the major objectives of the study were addressed. One of the major concerns was that lichens would obscure the rock surfaces. It was found that the spectral signature of the lichens was distinct from the underlying rocks. Thus, a spectrum of a rock outcrop, with its partial cover of lichens, can be un-mixed into rock and lichen components. The data acquired during the course of this study supports the conclusion that areas of pristine Archean crust can be differentiated from that which has experienced low grade alteration associated with Proterizoic faulting.

Goetz, Alexander F. H.↗
NASA NTRS1988

In situ mineralogical-chemical analysis of Martian materials at landing/roving sites by active and passive remote sensing methods

Remote sensing of the Martian surface from the ground and from orbiting spacecraft has provided some first-order insight into the mineralogical-chemical composition and the weathering state of Martian surface materials. Much more detailed information can be gathered from performing such measurements in situ at the landing sites or from a rover in combination with analogous measurements from orbit. Measurements in the wavelength range of approximately 0.3 to 12.0 micrometers appear to be suitable to characterize much of the physical, mineralogical, petrological, and chemical properties of Martian surface materials and the weathering and other alteration processes that have acted on them. It is of particular importance to carry out measurements at the same time over a broad wavelength range since the reflectance signatures are caused by different effects and hence give different and complementing information. It appears particularly useful to employ a combination of active and passive methods because the use of active laser spectroscopy allows the obtaining of specific information on thermal infrared reflectance of surface materials. It seems to be evident that a spectrometric survey of Martian materials has to be focused on the analysis of altered and fresh mafic materials and rocks, water-bearing silicates, and possibly carbonates.

Neukum, G.↗
NASA NTRS1988

Mineralogical and geochemical anomalous data of the K-T boundary samples

Cretaceous-Tertiary boundary problem has been discussed previously from the geological research, mainly by fossil changes. Although geochemical bulk data of Ir anomaly suggest the extraterrestrial origin of the K-T boundary, the exact formation process discussed mainly by mineralogical and geochemical study has been started recently, together with noble gas contents. The K-T boundary sample at Kawaruppu River, Hokkaido was collected, in order to compare with the typical K-T boundary samples of Bubbio, Italy, Stevns Klint, Denmark, and El Kef, Tunisia. The experimental data of the silicas and calcites in these K-T boundary samples were obtained from the X-ray unit-cell dimension (i.e., density), ESR signal and total linear absorption coefficient, as well as He and Ne contents. The K-T boundary samples are usually complex mixture of the terrestrial activities after the K-T boundary event. The mineralogical and geochemical anomalous data indicate special terrestrial atmosphere at the K-T boundary formation probably induced by asteroid impact, followed the many various terrestrial activities (especially the strong role of sea-water mixture, compared with terrestrial highland impact and impact craters in the other earth-type planetary bodies).

Miura, Y.↗
NASA NTRS1989

Chemical, isotopic and mineralogical evidence for the origin of matrix in ordinary chondrites

Results are presented of a combined chemical, isotopic, and mineralogical study of fine-grained opaque matrix material from a type-3 ordinary chondrite Allan Hills A77299. It was found that the matrix of this chondrite (in contrast to chondrules) shows no siderophile element depletions and is remarkably unfractionated relative to CI chondrites. It was also found that the matrix lump has a unique oxygen isotopic composition which lies below the terrestrial fractionation line and differs markedly from the composition of fine-grained matrix lumps and chondrule rims from Semarkona chondrules (Grossman and Wasson, 1987; Grossman et al., 1987); the mineralogy and textures of the matrix lump (which consists of rare angular grains of pyroxene and olivine embedded within a ground-mass of rounded fine-grained olivines), as well as its major element composition, are typical of matrix material of other type-3 chondrites studied. It is concluded that the matrix lump in these chondrites consists largely of material that formed by annealing of amorphous presolar dust or nebular condensates.

Brearley, Adrian J.↗
NASA NTRS1989

Reflectance spectroscopy and asteroid surface mineralogy

Information available from reflectance spectroscopy on the surface mineralogy of asteroids is discussed. Current spectral interpretive procedures used in the investigations of asteroid mineralogy are described. Present understanding of the nature and history of asteroids is discussed together with some still unresolved issues such as the source of ordinary chondrites.

Gaffey, Michael J.↗
NASA NTRS1990

Mineralogical comparison of the Y86032-type lunar meteorites to feldspathic fragmental breccia 67016

Mineralogical characteristics of lunar meteorites Y82193 and Y86032 were compared to those of Apollo-16 fieldspathic fragmental breccia 67016, using results from electron microprobe analysis and TEM. It was found that the pyroxene mineralogy and chemistry of granulitic clasts in 67016 breccia and the Y86032-type lunar meteorites were much alike, suggesting that the formation processes of the fieldspathic fragmental breccias are also important in the genesis of lunar meteorites. There were differences in matrix microtextures, however, implying that 67016 and Y86032-type breccia formation temperatures were different.

Takeda, H.↗
NASA NTRS1990

Iron mineralogy of a Hawaiian palagonitic soil with Mars-like spectral and magnetic properties

Visible and near-IR spectral data for some palagonitic soils from Mauna Kea, Hawaii, are similar to corresponding spectral data for Mars. It is important to understand the composition, distribution, and mineralogy of the ferric-bearing phases for the best spectral analogues because the correspondence in spectral properties implies that the nature of their ferric-bearing phases may be similar to those on Mars. In order to constrain interpretations of the Martian data, a variety of palagonitic soils should be studied in order to establish to what extent differences in their spectral data correspond to differences in the mineralogy of their ferric-bearing phases. Spectral (350-2100 nm), Mossbauer, magnetic, and some compositional data for one of a suite of Hawaiian palagonitic soils are presented. The soil (HWMK1) was collected below the biologically active zone from the sides of a gully cut at 9000 ft elevation on Mauna Kea. The soil was wet sieved with freon into seven size fractions less than 1 mm.

Morris, Richard V.↗
NASA NTRS1991

The mineralogy of ordinary chondrites and implications for asteroid spectrophotometry

Published data from bulk chemical analyses of 94 ordinary chondrites are compiled in a table of normative mineralogy and discussed in detail. Significant variations in olivine, pyroxene, and metal abundance ratios are found within each chondrite class and attributed to redox processes superimposed on initial differences in metal/silicate ratios. The use of the diagrams constructed here to predict the mineralogic characteristics of asteroids on the basis of spectrophotometric observations is suggested.

Mcsween, Harry Y., Jr.↗
NASA NTRS1991

Mineralogy of Cretaceous/Tertiary boundary clays in the Chicxulub structure in northern Yucatan

The Cretaceous/Tertiary (K/T) boundary clay layer is thought to be derived from ejecta material from meteorite impact, based on the anomalous concentrations of noble metals in the layer. Because of recent findings of a half-meter thick ejecta deposit at the K/T boundary in Haiti, efforts have focused on locating a large impact feature in the Caribbean and the Gulf of Mexico. One of the leading candidates for the site of a large impact is the Chicxulub structure located on the northern Yucatan Peninsula in Mexico. The Chicxulub structure is a subsurface zone of upper Cretaceous igneous rocks, carbonates, and breccias. The structure has been interpreted to be a 200 km diameter; however, there is some question to the size of the structure or to the fact that it even is an impact feature. Little is known about the mineralogy of this structure; the objective of this study was to determine the clay mineralogy of core samples from within the Chicxulub structure.

Ming, D. W.↗
NASA NTRS1991

Mineralogy of an unusual Cr-rich inclusion in the Los Martinez (L6) chrondritic breccia

During the petrological study of the L6 chondritic breccia, Los Martinez, we discovered a large, highly unusual Cr-rich inclusion whose mineralogy appears to be unique in both terrestrial and extraterrestrial occurrences. We carried out electron microprobe, scanning electron microscopy, and transmission electron microscopy investigations of this inclusion in order to determine its composition and mineralogy in detail and to establish its origin and possible relationship to other Cr-rich objects in chondritic meteorites. Details of the chemical composition, origin, and thermal history are given.

Brearley, Adrian J.↗
NASA NTRS1992

Venus surface mineralogy - Observational and theoretical constraints

Earth-based, earth-orbital, and spacecraft observations of the atmosphere and surface of Venus, thermodynamic models of atmosphere-lithosphere interactions, and where available kinetic data on relevant gas-solid reactions to place constraints on the mineralogy of the surface of Venus are used. Which minerals and mineral assemblages are stable on the surface of Venus and which, if any, of these minerals are involved in controlling the abundances of reactive gases in the atmosphere of Venus. It is concluded by identifying key issues facing us today about the mineralogy and geochemistry of the surface of Venus and suggest experimental, observational, and theoretical studies that can improve knowledge of these important questions are discussed.

Fegley, Bruce, Jr.↗
NASA NTRS1992

Mineralogy of 12 large 'chondritic' interplanetary dust particles

Mineralogical analyses of 12 large 'chondritic' interplanetary dust particles (IDPs) are reported. It is found that nine of these particles belong to the smectite class of IDPs, and the remainder to the pyroxene class. In comparing these results to previous studies of generally smaller IDPs, a significantly higher percentage of smectite-class IDPs is found, which may therefore be a size-related phenomenon. The probable origin of these large IDPs is discussed, comparing hydrous to anhydrous particles. On the basis of mineralogical and compositional similarities it is suggested that the bulk (at least) of pyroxene- and smectite-class IDPs have experienced similar or identical parent body processes, and are possibly derived from the same parent bodies. It is noted that it is commonly difficult to classify certain IDPs by the current scheme because of the presence of abundant amorphous materials and coexistence of both hydrous and anhydrous silicates. It is suggested that the degree of compositional heterogeneity exhibited by anhydrous silicates could form the basis of an alternate IDP classification scheme.

Zolensky, Michael E.↗
NASA NTRS1992

The mineralogy and formation processes of Mars soil

The mineralogical nature of Mars soil is far from being understood, nor are the formation time and weathering processes known. Quantitatively, the two major mineral-forming elements in Mars soil are silicon and iron, constituting 44 and 19 percent of the soils as SiO4 and Fe2O3, respectively. The silicate phases have been studied only briefly, mostly because of their limited spectral fingerprinting in the VIS and NIR. Much attention was given to the iron minerals in the soil, due to their pronounced absorption in the VIS and NIR, making them easily detectable by telescopic observations. The available information on Mars soil mineralogy, mostly obtained by remote sensing, is reviewed, and it is hypothesized that it leads to the suggestion that nanophase short-range-order (amorphous) phases of the silicates and iron oxides abound in the soil.

Banin, Amos↗