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At least 109 records · Page 6

Particle track record in Apollo 15 deep core from 54 to 80 cm depths.

Particle track measurements have been made in nearly 500 individual grains from 13 levels in the 54-80 cm depth range of the Apollo 15 deep core. They reveal a wide range of track densities at all depths and some systematic variations within layers, indicating that both predepositional mixing and subsequent layering are present and that separate sublayers exist within larger regions where no sublayers are visible. Minimum track densities are inferred to be useful measures of maximum residence times for undisturbed layers. Using the observed minimum track densities, we conclude that the average deposition rate in this section of soil column was greater than 0.4 cm/million years.

Fleischer, R. L.↗

Mixing of the lunar regolith

A probabilistic model for mixing and turnover rates for the lunar regolith due to meteoritic impact is presented and evaluated using results from laboratory impact experiments and estimated meteoritic fluxes. The upper millimeter of the lunar surface is shown to be the primary mixing zone in the regolith and an important source for impact melts and vapors. Below this 'mixing layer' the rate of mixing and turnover decreases very rapidly with increasing depth, consistent with well-preserved stratigraphy and resident times deduced from deep drill core tube samples.

Gault, D. E.↗

Patterns of Canopy and Surface Layer Consumption in a Boreal Forest Fire from Repeat Airborne Lidar

Fire in the boreal region is the dominant agent of forest disturbance with direct impacts on ecosystem structure, carbon cycling, and global climate. Global and biome-scale impacts are mediated by burn severity, measured as loss of forest canopy and consumption of the soil organic layer. To date, knowledge of the spatial variability in burn severity has been limited by sparse field sampling and moderate resolution satellite data. Here, we used pre- and post-fire airborne lidar data to directly estimate changes in canopy vertical structure and surface elevation for a 2005 boreal forest fire on Alaskas Kenai Peninsula. We found that both canopy and surface losses were strongly linked to pre-fire species composition and exhibited important fine-scale spatial variability at sub-30m resolution. The fractional reduction in canopy volume ranged from 0.61 in lowland black spruce stands to 0.27 in mixed white spruce and broad leaf forest. Residual structure largely reflects standing dead trees, highlighting the influence of pre-fire forest structure on delayed carbon losses from above ground biomass, post-fire albedo, and variability in understory light environments. Median loss of surface elevation was highest in lowland black spruce stands (0.18 m) but much lower in mixed stands (0.02 m), consistent with differences in pre-fire organic layer accumulation. Spatially continuous depth-of-burn estimates from repeat lidar measurements provide novel information to constrain carbon emissions from the surface organic layer and may inform related research on post-fire successional trajectories. Spectral measures of burn severity from Landsat were correlated with canopy (r = 0.76) and surface (r = -0.71) removal in black spruce stands but captured less of the spatial variability in fire effects for mixed stands (canopy r = 0.56, surface r = -0.26), underscoring the difficulty in capturing fire effects in heterogeneous boreal forest landscapes using proxy measures of burn severity from Landsat.

Alonzo, Michael↗

The Detection of Change in the Arctic Using Satellite and Buoy Data

The decade of the 1990s is the warmest decade of the last century while the year 1998 is the warmest year ever observed by modern techniques with 9 out of 12 months of the year being the warmest month. Since the Arctic is expected to provide early signals of a possible warming scenario, detailed examination of changes in the Arctic environment is important. In this study, we examined available satellite ice cover and surface temperature data, wind and pressure data, and ocean hydrographic data to gain insights into the warming phenomenon. The areas of open water in both western and eastern regions of the Arctic were found to follow a cyclical pattern with approximately decadal period but with a lag of about three years between the two regions. The pattern was interrupted by unusually large anomalies in open water area in the western region in 1993 and 1998 and in the eastern region in 1995. The big 1998 open water anomaly occurred at the same time when a large surface temperature anomaly was also occurring in the area and adjacent regions. The infrared temperature data show for the first time the complete spatial scope of the warming anomalies and it is apparent that despite the magnitude of the 1998 anomaly, it is basically confined to North America and the Western Arctic. The large increases in open water areas in the Western Sector form 1996 to 1998 were observed to be coherent with changing wind directions which was predominantly cyclonic in 1996 and anti-cyclonic in 1997 and 1998. Detailed hydrography measurements up to 500 m depth over the same general area in April 1996 and April 1997 also indicate significant freshening and warming in the upper part of the mixed layer suggesting increases in ice melt. Continuous ocean temperature and salinity data from ocean buoys confirm this result and show significant seasonal changes from 1996 to 1998, at depths of 8 m, 45 m, and 75 m. Long data records of temperature and hydrography were also examined and the potential impact of a warming, freshening, and the presence of abnormally large open areas on the state of the Arctic climate system are discussed.

Comiso, Josefino C.↗

Southern Ocean Heat Storage, Reemergence, and Winter Sea Ice Decline Induced by Summertime Winds

The observational record shows a substantial 40-yr upward trend in summertime westerly winds over the Southern Ocean, as characterized by the southern annular mode (SAM) index. Enhanced summertime westerly winds have been linked to cold summertime sea surface temperature (SST) anomalies. Previous studies have suggested that Ekman transport or upwelling is responsible for this seasonal cooling. Here, another process is presented in which enhanced vertical mixing, driven by summertime wind anomalies, moves heat downward, cooling the sea surface and simultaneously warming the subsurface waters. The anomalously cold SSTs draw heat from the atmosphere into the ocean, leading to increased depth-integrated ocean heat content. The subsurface heat is returned to the surface mixed layer during the autumn and winter as the mixed layer deepens, leading to anomalously warm SSTs and potentially reducing sea ice cover. Observational analyses and numerical experiments support our proposed mechanism, showing that enhanced vertical mixing produces subsurface warming and cools the surface mixed layer. Nevertheless, the dominant driver of surface cooling remains uncertain; the relative importance of advective and mixing contributions to the surface cooling is model dependent. Modeling results suggest that sea ice volume is more sensitive to summertime winds than sea ice extent, implying that enhanced summertime westerly winds may lead to thinner sea ice in the following winter, if not lesser ice extent. Thus, strong summertime winds could precondition the sea ice cover for a rapid retreat in the following melt season.

Southern Ocean↗

SO2 on Venus: A final cross-calibration with Pioneer Venus

In our previous report, we noted that we had successfully completed all of the IUE observations which were proposed. A total of 7 Venus spectra were obtained. In the present reporting period, essentially all of the associated data reduction and analysis activities were completed, and Drs. Stern, Barker, and Na met to collaborate on data interpretation. The model atmosphere used in this analysis is similar to the one used in the analysis of the Pioneer Venus observations (Esposito, et al. 1979, 1988) and the previous IUE observations (Na, et al. 1990). In this model, sulfuric acid aerosols with a radius of about 1 micron are mixed uniformly with Rayleigh scattering gases throughout the cloud layer. There are two wavelength-independent absorbers. First, the aerosols are assumed to have a single scattering albedo of 0.98, and second a pure absorbing layer with an optical depth of 0.2 is added at an altitude of 75 mbar. The variable parameters in this model are the mixing ratios of SO2 at the cloud top (40 mbar level), and the scale height of SO2 at the same altitude. Model spectra were calculated using a radiative transfer code utilizing a Markov Chain method. Each model calculation takes into account the multiple scattering and the vertical inhomogeneity of the atmosphere. We reported those initial results at the 1992 meeting of the AAS Division of Planetary Sciences (Barker, Stern, and Na 1992) The important finding we have reached is that the 1991 IUE observations indicate that the long-term decline in Venus SO2 abundance has either halted or reversed. Our simultaneous groundbased measurements made on the McDonald Observatory 2.7 m corroborate this result. We are now preparing a paper describing these IUE results for publication in Icarus. With the IUE results reduced, we are also beginning a project to compare the 1991 IUE results to Pioneer Venus UV spectra made on the same dates.

Stern, S. Alan↗

HST-STIS Spectra of Saturn's Rings and Implications for Their Reddening Agent

We obtained HST-STIS spectra of Saturn's main rings in May 2011, using the G230L (and G430L) gratings, with final averaged radial resolution of 160 (and 330) km/pixel. The dataset filled a previous 200-330nm "spectral gap" between Cassini and ground-based spectra. The data provide radial profiles as a function of wavelength, but our most basic product at this point is a set of very low-noise spectra, radially averaged over broad regions of the rings (A, B, C, and Cassini Division). The raw spectra required special processing to remove artifacts due to extended-source grating scatter. We have modeled the spectra using a new particle surface model, which corrects for on-surface shadowing due to the likely very rough ring particle surfaces, and avoids overestimation of intra-mixed "neutral absorber". We correct for non-classical layer effects and finite ring optical depth, and relate our observed reflectivities to the spherical albedos of individual smooth particles. We model these smooth particle albedos using standard Hapke theory for regolith grain mixtures that are either homogeneous and "intramixed" (nonicy absorbers dispersed in water ice regolith grains) or heterogeneous "intimate" mixtures. As candidates for the nonicy contaminants we have considered amorphous carbon, aromatic-rich and aliphatic-rich organic tholins, silicates, hematite and iron metal. For the A and B rings, we find that iron metal (including a new theoretical estimate of the refractive indices of nanometer-sized grains of iron) is not spectrally steep enough in the 200-300nm range, and that aliphatic-rich tholins are either too steep at short wavelengths or too flat at long wavelengths. However, less than 1% by mass of aromatic-rich tholins provides a very good fit across the entire spectral range with no gratuitous "neutral absorber" needed, and a minimum of additional free parameters. The best fits require forward-scattering regolith grains. For the C Ring and Cassini Division, additional absorbers are needed (updated results will be given).

Saturn's Rings↗

Mechanisms Controlling the Interannual Variation of Mixed Layer Temperature Averaged over the Nino-3 Region

The present study examines processes governing the interannual variation of MLT in the eastern equatorial Pacific.Processes controlling the interannual variation of mixed layer temperature (MLT) averaged over the Nino-3 domain (5 deg N-5 deg S, 150 deg-90 deg W) are studied using an ocean data assimilation product that covers the period of 1993-2003. The overall balance is such that surface heat flux opposes the MLT change but horizontal advection and subsurface processes assist the change. Advective tendencies are estimated here as the temperature fluxes through the domain's boundaries, with the boundary temperature referenced to the domain-averaged temperature to remove the dependence on temperature scale. This allows the authors to characterize external advective processes that warm or cool the water within the domain as a whole. The zonal advective tendency is caused primarily by large-scale advection of warm-pool water through the western boundary of the domain. The meridional advective tendency is contributed to mostly by Ekman current advecting large-scale temperature anomalies through the southern boundary of the domain. Unlike many previous studies, the subsurface processes that consist of vertical mixing and entrainment are explicitly evaluated. In particular, a rigorous method to estimate entrainment allows an exact budget closure. The vertical mixing across the mixed layer (ML) base has a contribution in phase with the MLT change. The entrainment tendency due to the temporal change in ML depth is negligible compared to other subsurface processes. The entrainment tendency by vertical advection across the ML base is dominated by large-scale changes in upwelling and the temperature of upwelling water. Tropical instability waves (TIWs) result in smaller-scale vertical advection that warms the domain during La Nina cooling events. However, such a warming tendency is overwhelmed by the cooling tendency associated with the large-scale upwelling by a factor of 2. In summary, all the balance terms are important in the MLT budget except the entrainment due to lateral induction and temporal variation in ML depth. All three advective tendencies are primarily caused by large-scale and low-frequency processes, and they assist the Nino-3 MLT change.

eastern equatorial Pacific↗

Mixed Layer Drift Revealed by Satellite Data

For the first time we are able to derive ocean currents using the wavelet algorithm for feature tracking from two different sensors (MODIS and SeaWiFS) on different satellites. Satellite ocean color data provide an important insight to the marine biosphere because of their capability to quantify certain fundamental properties (such as phytoplankton pigment concentration, marine primary production, etc.) on a global basis. The mixed layer drift can be derived because the ocean color signal bears information from a much larger depth (10 to 30 meters) as compared with the sea surface temperature data. Although the drifter data are very limited in the study area, the comparison shows a general agreement between drifter data and satellite tracking results, especially for the cases near the Gulf Stream boundary.

Liu, Antony K.↗

Validation of Saharan Dust Layer Characteristics with Lidar Observations

Lidar backscattering profiles available from the LITE data set have been used to estimate the optical depths of the Saharan dust layer over West Africa and E. Atlantic regions, in the context of validating the 3-D conceptual model of the Saharan dust plume proposed by Karyampudi and Carlson. The aerosol extinction profiles and optical depths were retrieved from LITE using the Fernald et al. (1972) method. An extinction-to-backscattering ratio, S(sub a), of 25 was selected for optical depth calculations. The spatial analysis of total column and Saharan dust layer optical depths show higher optical depths over W. Africa that decrease westward over E. Atlantic. The higher optical depths over W. Africa, in general, are associated with heavy dust being raised from the surface in dust source regions. Rapid depletion of these heavy dust particles, perhaps due to sedimentation, appear to decrease the dust loading within the dust layer as the plume leaves the west African continent. Higher optical depths are generally confined to the southern edge of the dust layer, where the middle level jet appears to transport the heavy dust concentrations that tend to mix downward from vertical mixing associated with the strong vertical shears underneath the middle jet. Thus, LITE measurements although, in general, validate the Saharan dust plume conceptual model, show maximum values of optical depths near the southern edge of the dust plume over the E. Atlantic region instead of near the center of the dust plume as described in the conceptual model.

Karyampudi, V. Mohan↗

Entrainment into a stratocumulus layer with distributed radiative cooling

It is shown that the radiative cooling of a cloud layer strongly influences the turbulent flux profiles and the entrainment rate, and that the radiative cooling should be modeled as acting inside the turbulent layer. Numerical experiments demonstrate that a cloud-topped mixed-layer model, similar to that of Lilly (1968), is quite sensitive to delta (p) sub R, the depth of the radiatively cooled layer near cloud top. As delta (p) sub R increases, the model's sensitivity to the entrainment assumption is markedly heightened; for large delta (p) sub R the cloud top and cloud base rise as the entrainment parameter k is increased, while for small delta (p) sub R an increase in k has almost no effect. The model is most sensitive to delta (p) sub R for the cold-water, strong-divergence regime of greatest interest.

Randall, D. A.↗

Regional Characteristics of the Relationship Between Columnar AOD and Surface PM2.5: Application of Lidar Aerosol Extinction Profiles over Baltimore-Washington Corridor During DISCOVER-AQ

The first field campaign of DISCOVER-AQ (Deriving Information on Surface conditions from COlumn and VERtically resolved observations relevant to Air Quality) took place in July 2011 over Baltimore-Washington Corridor (BWC). A suite of airborne remote sensing and in-situ sensors was deployed along with ground networks for mapping vertical and horizontal distribution of aerosols. Previous researches were based on a single lidar station because of the lack of regional coverage. This study uses the unique airborne HSRL (High Spectral Resolution Lidar) data to baseline PM2.5 (particulate matter of aerodynamic diameter less than 2.5 μm) estimates and applies to regional air quality with satellite AOD (Aerosol Optical Depth) retrievals over BWC (∼6500 sq. km). The linear approximation takes into account aerosols aloft above AML (Aerosol Mixing Layer) by normalizing AOD with haze layer height (i.e., AOD/HLH). The estimated PM2.5 mass concentrations by HSRL AOD/HLH are shown within 2 RMSE (Root Mean Square Error ∼9.6 μg/cu. m) with correlation ∼0.88 with the observed over BWC. Similar statistics are shown when applying HLH data from a single location over the distance of 100 km. In other words, a single lidar is feasible to cover the range of 100 km with expected uncertainties. The employment of MPLNET-AERONET (MicroPulse Lidar NETwork - AErosol RObotic NETwork) measurements at NASA GSFC produces similar statistics of PM2.5 estimates as those derived by HSRL. The synergy of active and passive remote sensing aerosol measurements provides the foundation for satellite application of air quality on a daily basis. For the optimal range of 10 km, the MODIS-estimated PM2.5 values are found satisfactory at 27 (out of 36) sunphotometer locations with mean RMSE of 1.6-3.3 μg/cu. m relative to PM2.5 estimated by sunphotometers. The remaining 6 of 8 marginal sites are found in the coastal zone, for which associated large RMSE values ∼4.5-7.8 μg/cu. m are most likely due to overestimated AOD because of water-contaminated pixels.

DISCOVER-AQ↗

New Insights on the 7[superscript]Be Cycle in the Ocean

The cosmogenic radionuclide 7[superscript]Be has been applied as a tracer of dynamical processes in the upper ocean and of atmospheric deposition of trace elements at the sea surface. These applications usually assume that 7[superscript]Be is entirely in the dissolved form, and that scavenging and downward export of 7[superscript]Be by settling particles can be neglected. In this work, we explore these assumptions and more generally assess the significance of the 7[superscript]Be activity in the particulate fraction, through the generation of vertical profiles of particulate 7[superscript]Be in the open ocean. From detailed measurements obtained from low-background gamma spectrometers placed in underground facilities, we report vertical profiles of 7[superscript]Be activity in suspended particles (7[superscript]Bep[subscript]) collected in various oceanic regions: the Mediterranean Sea (DYFAMED station), the Indian Sector of the Southern Ocean (station A3-2 from the KEOPS2 cruise), the Sargasso Sea (OFP station), and the subpolar North Atlantic Ocean (GEOVIDE cruise). We find that, in each oceanic region, 7[superscript]Bep[subscript] activities are generally higher in the mixed layer than in the thermocline. They vary in the mixed layer from 3.0 dpm/m3 at DYFAMED to 33.1dpm/m3 at GEOVIDE cross-over station 51/60, i.e., within a range consistent with previous 7[superscript]Bep[subscript] measurements for the open ocean. For the GEOVIDE cruise, the 7[superscript]Bep[subscript] activities measured on different filter types at different depths are corrected for filter offsets derived from multiple 7[superscript]Bep[subscript] measurements at a near-coastal station in the western Mediterranean Sea. We then combine measurements of total 7[superscript]Be activity (Shelley et al., 2017) with our measurements of 7[superscript]Bep[subscript] activity to estimate the solid/solution partitioning of 7[superscript]Be. On average, the particulate fraction would represent 6% of total 7[superscript]Be activity at 5-m water depth (n = 6), 22% at 20 m (n = 2) and 9% at 70 m (n = 3). At GEOVIDE stations, 7[superscript]Bep[subscript] inventories range from 5% to 19% of the total 7[superscript]Be inventories. In the Labrador Sea, the measured 7[superscript]Bep[subscript] inventories are lower than the dry 7[superscript]Be deposition fluxes estimated from aerosol samples collected during GEOVIDE, suggesting that a significant portion of 7[superscript]Bep[subscript] may be removed by sinking particles. The distribution coefficient Kd for 7Be increases with depth, with log10Kd averaging 5.2 ± 0.1 at 5 m to 6.1 ± 0.1 between 70 and 150 m, suggesting that scavenging of dissolved 7[superscript]Be by particles is more pronounced in the thermocline than in the mixed layer when differences in particle concentrations are taken into account. Overall, our study suggests that, at least in some oceanic regions, the removal of 7[superscript]Be by marine particles may be significant and that it may need to be considered in applications of 7[superscript]Be as a tracer of oceanic processes and atmospheric deposition.

Beryllium-7↗

The Two-Column Aerosol Project: Phase I - Overview and Impact of Elevated Aerosol Layers on Aerosol Optical Depth

The Two-Column Aerosol Project (TCAP), conducted from June 2012 through June 2013, was a unique study designed to provide a comprehensive data set that can be used to investigate a number of important climate science questions, including those related to aerosol mixing state and aerosol radiative forcing. The study was designed to sample the atmosphere be tween and within two atmospheric columns; one fixed near the coast of North America (over Cape Cod, MA) and a second moveable column over the Atlantic Ocean several hundred kilometers from the coast. The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF) was deployed at the base of the Cape Cod column, and the ARM Aerial Facility was utilized for the summer and winter intensive observation periods. One important finding from TCAP is that four of six nearly cloud-free flight days had aerosol layers aloft in both the Cape Cod and maritime columns that were detected using the nadir pointing second-generation NASA high-spectral resolution lidar (HSRL-2).These layer s contributed up to 60 of the total observed aerosol optical depth (AOD). Many of these layers were also intercepted by the aircraft configured for in situ sampling, and the aerosol in the layers was found to have increased amounts of biomass burning material and nitrate compared to aerosol found near the surface. In addition, while there was a great deal of spatial and day-to-day variability in the aerosol chemical composition and optical properties, no systematic differences between the two columns were observed.

aerosols↗

Maps Suggest Transport and Source Processes of PM2.5 at 1 km x 1 km for the Whole San Joaquin Valley, Winter 2011 (Generalizations from DISCOVER-AQ)

We present interpreted data analysis using MAIAC (Multiangle implementation of Atmospheric Correction) retrievals and appropriate RAPid Update Cycle (RAP) meteorology to map respirable aerosol (PM2.5) for the period January and February, 2011. The San Joaquin Valley is one of the unhealthiest regions in the USA for PM2.5 and related morbidity. The methodology evaluated can be used for the entire moderate-resolution imaging spectrometer (MODIS, VIIRS) data record. Other difficult areas of the West: Riverside, CA, Salt Lake City, UT, and Doa Ana County, NM share similar difficulties and solutions. The maps of boundary layer depth for 1116 hr local time from RAP allows us to interpret aerosol optical thickness as a concentration of particles in a nearly well-mixed box capped by clean air. That mixing is demonstrated by DISCOVER-AQ data and afternoon samples from the airborne measurements, P3B (on-board) and B200 (HSRL2 lidar). This data and the PM2.5 gathered at the deployment sites allowed us to estimate and then evaluate consistency and daily variation of the AOT to PM2.5 relationship. Mixed-effects modeling allowed a refinement of that relation from day to day; RAP mixed layers explained the success of previous mixed-effects modeling. Compositional, size-distribution, and MODIS angle-of-regard effects seem to describe the need for residual daily correction beyond ML depth.We report on an extension method to the entire San Joaquin Valley for all days with MODIS imagery using the permanent PM2.5 stations, evaluated for representativeness. Resulting map movies show distinct sources, particularly Interstate-5 (at approx. 1km x 1km resolution) and the broader Bakersfield area. Accompanying winds suggest transport effects and variable pathways of pollution cleanout. Such estimates should allow morbiditymortality studies. They should be also useful for actual model assimilations, where composition and sources are uncertain. We conclude with a description of new work to extend these insights to similar regions, e.g. interior valleys of California, the Po Valley, the Mediterranean litoral, and the Ganges Plain.This work show generalizable use of remote sensing, a major goal of DISCOVER-AQ, Deriving Information on Surface Conditions from COlumn and VERtically Resolved Observations Relevant to Air Quality.

Chatfield, R.↗

A Simple Model of Cirrus Horizontal Inhomogeneity and Cloud Fraction

A simple model of horizontal inhomogeneity and cloud fraction in cirrus clouds has been formulated on the basis that all internal horizontal inhomogeneity in the ice mixing ratio is due to variations in the cloud depth, which are assumed to be Gaussian. The use of such a model was justified by the observed relationship between the normalized variability of the ice water mixing ratio (and extinction) and the normalized variability of cloud depth. Using radar cloud depth data as input, the model reproduced well the in-cloud ice water mixing ratio histograms obtained from horizontal runs during the FIRE2 cirrus campaign. For totally overcast cases the histograms were almost Gaussian, but changed as cloud fraction decreased to exponential distributions which peaked at the lowest nonzero ice value for cloud fractions below 90%. Cloud fractions predicted by the model were always within 28% of the observed value. The predicted average ice water mixing ratios were within 34% of the observed values. This model could be used in a GCM to produce the ice mixing ratio probability distribution function and to estimate cloud fraction. It only requires basic meteorological parameters, the depth of the saturated layer and the standard deviation of cloud depth as input.

Smith, Samantha A.↗

High Resolution Aerosol Data from MODIS Satellite for Urban Air Quality Studies

The Moderate Resolution Imaging Spectroradiometer (MODIS) provides daily global coverage, but the 10 km resolution of its aerosol optical depth (AOD) product is not suitable for studying spatial variability of aerosols in urban areas. Recently, a new Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm was developed for MODIS which provides AOD at 1 km resolution. Using MAIAC data, the relationship between MAIAC AOD and PM(sub 2.5) as measured by the 27 EPA ground monitoring stations was investigated. These results were also compared to conventional MODIS 10 km AOD retrievals (MOD04) for the same days and locations. The coefficients of determination for MOD04 and for MAIAC are R(exp 2) =0.45 and 0.50 respectively, suggested that AOD is a reasonably good proxy for PM(sub 2.5) ground concentrations. Finally, we studied the relationship between PM(sub 2.5) and AOD at the intra-urban scale (10 km) in Boston. The fine resolution results indicated spatial variability in particle concentration at a sub-10 kilometer scale. A local analysis for the Boston area showed that the AOD-PM(sub 2.5) relationship does not depend on relative humidity and air temperatures below approximately 7 C. The correlation improves for temperatures above 7 - 16 C. We found no dependence on the boundary layer height except when the former was in the range 250-500 m. Finally, we apply a mixed effects model approach to MAIAC aerosol optical depth (AOD) retrievals from MODIS to predict PM(sub 2.5) concentrations within the greater Boston area. With this approach we can control for the inherent day-to-day variability in the AOD-PM(sub 2.5) relationship, which depends on time-varying parameters such as particle optical properties, vertical and diurnal concentration profiles and ground surface reflectance. Our results show that the model-predicted PM(sub 2.5) mass concentrations are highly correlated with the actual observations (out-of-sample R(exp 2) of 0.86). Therefore, adjustment for the daily variability in the AOD-PM(sub 2.5) relationship provides a means for obtaining spatially-resolved PM(sub 2.5) concentrations.

remote sensing↗

Multilayer Approach for Characterization of Bacterial Diversity in a Marginal Sea: From Surface to Seabed

Bacteria are the most important microorganisms in the world oceans, accounting for up to 75% of the total biomass. They are responsible for fundamental biogeochemical processes and therefore often used as ecological indicators. In this study, bacteria were quantified by flow cytometry and their diversity assessed by High Throughput Sequencing (HTS) in the southern Adriatic Sea. The most abundant bacterial groups were also quantified by qPCR. The samples were collected from the surface to the seabed over a total of 16 different depths at four stations during the late winter BIOTA (BIO-Tracing Adriatic water masses) cruise conducted in March 2016. The investigated area showed unusual water mass properties and was characterized by a shallow mixed layer, which differed from the usual winter convection conditions, typical of middle-altitude ecosystems and important for the seasonal picoplankton dynamics of this area. Heterotrophic bacteria were separated into HNA (relative High Nucleic Acid content) and LNA (Low Nucleic Acid content) subpopulations with abundances up to 1.8×10(exp 5) and 8.8×10(exp 5) cells/mL, respectively. HNA dominated at offshore stations reaching their maximum at depths below the euphotic zone. The bacterial community was dominated by Alphaproteobacteria, accounting for greater than 40% of the total sequence reads and were mainly represented by the SAR11 clade (90.84%), followed by Marinimicrobia (18% of the total sequence reads), mainly represented by clade SAR406 (8.44%). Distinctive bacterial groups were found in the euphotic layer (Bacteroidetes and Actinobacteria) and aphotic layer samples (Deltaproteobacteria, Marinimicrobia, Chloroflexi, Acidobacteria and Planctomycetes). Results of the qPCR analyses further confirmed HTS results with highest abundances obtained for Alphaproteobacteria, followed by Gammaproteobacteria and Bacteroidetes. The adopted multiple approach, combining different molecular tools, critically supported by optics and flow cytometry, reveal changes in the bacterial assemblages during the unusual thermohaline conditions observed in 2016 in the southern Adriatic Sea.

Southern Adriatic Sea↗