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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Study Program to Develop and Evaluate Die and Container Materials for the Growth of Silicon Ribbons

The completion of a major hardware delivery milestone was accomplished with the delivery of three CNTD Si3N4 coated hot pressed Si3N4 crucibles. A limited characterization of the coating was performed at MRL prior to delivery. The coatings were fine grained alpha - Si3N4. It was determined that a two piece die design is required. The importance of the role of oxygen in influencing the attack of the CNTD materials by molten silicon was demonstrated. The stability is greatly enhanced by maintaining the oxygen partial pressure near or below the Si + O2 = SiO2 equilibrium.

Ounby, P. D.↗
NASA NTRS1980

Method of growing a ribbon crystal particularly suited for facilitating automated control of ribbon width

A method of growing a ribbon crystal is described wherein a meniscus of molten semiconductor material attached to vertical movable seed is lifted at a rate substantially equal to the rate at which the meniscus freezes. The method is characterized by the steps of continuously sensing the brightness of the growth region of the ribbon in selected areas across the ribbon width for detecting changes in the intensity of the brightness of the selected areas, and modifying the temperature of the meniscus and pulling speed in response to changes detected in the intensity for controlling the geometry of the ribbon.

Ciszek, T. F.↗
NASA NTRS1980

Method for horizontally growing ribbon crystal

A high speed method for forming ribbon crystal of desired width and thickness is characterized by drawing out the ribbon through a space whose distance is 5.7 times that of the thickness of the grown ribbon. The ribbon is drawn out between the molten body of the lower surface and the tip of the upper surface of the seed crystal and growing crystal. The ribbon growing at the tip of the seed crystal is drawn out horizontally and centrifugally by controlling the amount of cooling and heating. The temperature is maintained about equal to the upper surface of the outlets from which the molten substance is drawn, at least in certain portions of the crucible rim, the rim is elevated to prevent dropping of the molten raw material.

Kudo, B.↗
NASA NTRS1982

The nature and origin of type B1 and B2 Ca-Al-rich inclusions in the Allende meteorite

The Type B Ca-Al-rich inclusions in the Allende carbonaceous chondrite form a continuous range from the mineralogically concentrically zoned B1 subtype to the unzoned B2 subtype. These subtypes differ in (1) structure, texture, grain size and shape, (2) mineralogical proportions and compositions, (3) accessory mineralogy, (4) relative abundance of spinel framboids, (5) rim layering, (6) major element chemistry, and (7) degree of secondary alteration. These differences, together with observations on the crystallization of synthetic melts, suggest that the B1 inclusions crystallized relatively rapidly from molten parental material while B2 types crystallized relatively slowly close to the solidus from material that had not been completely melted. The same data are used to construct an evaporative residue model for the origin of the parental Type B materials. In the model, dust in the protosolar nebula was heated with removal of more volatile elements, leaving completely melted (Type B1) residues at the highest temperatures and incompletely melted, less highly evaporated (Type B2) residues at lower temperatures.

Wark, D. A.↗
NASA NTRS1985

Removal of glass adhered to sintered ceramics in hot isostatic pressing

In the hot isostatic pressing of ceramic materials in molten glass using an inert gas as a pressing medium, glass adhered to the sintered ceramics is heated to convert it to a porous glass and removed. Thus, Si3N4 powder was compacted at 5000 kg/sq cm, coated with a 0.5 mm thick BN, embedded in Pyrex glass in a graphite crucible, put inside a hot isostatic press containing Argon, hot pressed at 1750 C and 100 kg/sq cm; cooled, taken out from the crucible, heated at 1100 C for 30 minutes, cooled, and then glass adhered to the sintered body was removed.

Source record↗
NASA NTRS1987

Growing II/VI Semiconductors With Double Decantation

Concept for growing single crystals combines sheet solidification with controlled cooling. Proposed method for II/VI semiconductor compounds cools newly solidified crystal gradually and nearly isothermally so few defects formed. Method obtains maximum amount of crystal from minimum amount of melt. Double decantation causes sheet crystal to cool first in liquid, then in gas. Vessel tilted to pour off molten semiconductor material. Second tilt, in opposite direction, pours off encapsulant.

Morrison, Andrew D.↗
NASA NTRS1987

Experimental constraints on heating and cooling rates of refractory inclusions in the early solar system

The refractory inclusions in carbonaceous chondrites were the subject of considerable interest since their discovery. These inclusions contain minerals that are predicted to be some of the earliest condensates from the solar nebula, and contain a plethora of isotopic anomalies of unknown origin. Of particular interest are those coarse-grained inclusions that contain refractory metal particles (Fe, Ni, Pt, Ru, Os Ir). Experimental studies of these inclusions in terrestrial laboratories are, however, complicated because the dense particles tend to settle out of a molten or partially molten silicate material. Heating experiments in the Space Station technology and microgravity in order to observe the effects of metal nuggets (which may act as heterogeneous nucleation sites) on nucleation rates in silicate systems and to measure simultaneously the relative volatilization rate of siderophile and lithophile species. Neither experiment is possible in the terrestrial environment.

Boynton, W. V.↗
NASA NTRS1994

Wire Insulation Flammability Experiment: USML-1 One Year Post Mission Summary

Herein we report the results from the Wire Insulation Flammability (WIF) Experiment performed in the Glovebox Facility on the USML-1 mission. This experiment explored various aspects of electrically induced fire scenarios in a reduced gravity environment. Under quiescent microgravity conditions, heat and mass transfer are dominated by diffusive and radiative transport; while in normal-gravity buoyancy induced convection often dominates. Of considerable scientific and practical interest is the intermediate situation of combustion occurring in the presence of imposed gas flows, with lower characteristic velocities than those induced by buoyancy in noma1 gravity. Two distinct cases naturally arise: flow direction opposed to, or concurrent with, the flame spread direction. Two tests of each kind were conducted in the WIF experiment, providing the first controlled demonstration of flame spreading in forced convection ever conducted in space. Four test modules were flown. The wire insulation, 1.5 mm in diameter, was polyethylene, extruded onto nichrome wire. Temperatures of the wh3 cores and insulation heated in quiescent and flowing environments were measured. Video and still-camera images of the samples, burning in air flowing at approximately 10 cm/sec, were recorded to obtain flame characteristics including spread rate, structure and temperature. Flame spread rates in concurrent flow were approximately twice those in opposed flow. In concurrent and opposed flow regimes, the spreading flames stabilized around a bead of molten insulation material, within which bubble nucleation was observed. An ignition attempt without flow mated a quiescent cloud of vaporized fuel which ignited dramatically yet failed to sustain normal flame spread. Finally, all tests produced substantial soot agglomerates, particularly the concurrent flow tests; and the collected soot has a morphology very distinct from soot formed in normal gravity flames. Several unexpected and unique microgravity combustion phenomena were observed.

Greenberg, Paul S.↗
NASA NTRS1991

Method and apparatus for producing microshells

A method is described for forming hollow particles, or shells, of extremely small size. The shell material is heated to a molten temperature in the presence of a gas that is at least moderately soluble in the shell material, to form a solution of the molten shell material and the soluble gas. The solution is atomized to form a multiplicity of separate droplets that are cooled while in free fall. Cooling of a droplet from the outside traps the desolved gas and forces it to form a gas bubble at the center of the droplet which now forms a gas filled shell. The shell is reheated and then cooled in free fall, in an environment having a lower pressure than the gas pressure in the shell. This causes expansion of the shell and the formation of a shell having a small wall thickness compared to its diameter.

Lee, Mark C.↗
NASA NTRS1979

Development and evaluation of die and container materials. Low cost silicon solar array project

Specific compositions of high purity silicon aluminum oxynitride (Sialon) and silicon beryllium oxynitride (Sibeon) solid solutions were shown to be promising refractory materials for handling and manipulating solar grade silicon into silicon ribbon. Evaulation of the interaction of these materials in contact with molten silicon indicated that solid solutions based upon beta-Si3N4 were more stable than those based on Si2N2O. Sibeon was more resistant to molten silicon attack than Sialon. Both materials should preferably be used in an inert atmosphere rather than under vacuum conditions because removal of oxygen from the silicon melt occurs as SiO enhances the dissolution of aluminum and beryllium. The wetting angles of these materials were low enough for these materials to be considered as both die and container materials.

Wills, R. R.↗
NASA NTRS1985

Containerless Manufacture of Glass Optical Fibers

Contamination and crystallization reduced in proposed process. Solid optical fiber drawn from an acoustically levitated lump of molten glass. New material added in solid form, melted and then moved into main body of molten glass. Single axis acoustic levitation furnances levitate glass melts at temperature up to about 700 degrees C. Processing in unit limited to low-melting temperature glasses.

Naumann, R. J.↗
NASA NTRS2018

Systems and Methods for Fabricating Structures Including Metallic Glass-Based Materials Using Low Pressure Casting

Systems and methods to fabricate objects including metallic glass-based materials using low-pressure casting techniques are described. In one embodiment, a method of fabricating an object that includes a metallic glass-based material includes: introducing molten alloy into a mold cavity defined by a mold using a low enough pressure such that the molten alloy does not conform to features of the mold cavity that are smaller than 100 microns; and cooling the molten alloy such that it solidifies, the solid including a metallic glass-based material.

Hofmann, Douglas C.↗
NASA NTRS1971

Preparation of homogeneous vitreous materials for electronic and optical devices

Vitreous material builds up as series of solidified layers on inside walls of sealed quartz ampoule containing molten constituents of material, and forms well defined shapes to close dimensional tolerances. Ampoules are made of material which does not react with melt and has lower thermal expansion coefficient than solidified layer.

Gatos, H. C.↗
NASA NTRS2008

Evaluation of Sulfur 'Concrete' for Use as a Construction Material on the Lunar Surface

Combining molten sulfur with any number of aggregate materials forms, when solid, a mixture having attributes similar, if not better, to conventional water-based concrete. As a result the use of sulfur "concrete" on Earth is well established, particularly in corrosive environments. Consequently, discovery of troilite (FeS) on the lunar surface prompted numerous scenarios about its reduction to elemental sulfur for use, in combination with lunar regolith, as a potential construction material; not requiring water, a precious resource, for its manufacture is an obvious advantage. However, little is known about the viability of sulfur concrete in an environment typified by extreme temperatures and essentially no atmosphere. The experimental work presented here evaluates the response of pure sulfur and sulfur concrete subjected to laboratory conditions that approach those expected on the lunar surface, the results suggesting a narrow window of application.

Grugel, R. N.↗
NASA NTRS2017

Height Control and Deposition Measurement for the Electron Beam Free Form Fabrication (EBF3) Process

A method of controlling a height of an electron beam gun and wire feeder during an electron freeform fabrication process includes utilizing a camera to generate an image of the molten pool of material. The image generated by the camera is utilized to determine a measured height of the electron beam gun relative to the surface of the molten pool. The method further includes ensuring that the measured height is within the range of acceptable heights of the electron beam gun relative to the surface of the molten pool. The present invention also provides for measuring a height of a solid metal deposit formed upon cooling of a molten pool. The height of a single point can be measured, or a plurality of points can be measured to provide 2D or 3D surface height measurements.

Seufzer, William J.↗
NASA NTRS1990

Multi-element spherical shell generation

A nozzle assembly in a multi-element spherical shell generation system includes first and second side-by-side spaced apart nozzles and a web portion extending between and connecting the nozzles. The first nozzle has an inner orifice adapted to discharge a first filler material and an outer annular orifice separated from and defined in concentric relation about the inner orifice and adapted to discharge a first shell material. The second nozzle has an inner orifice adapted to discharge a second filler material and an outer annular orifice separated from and defined in concentric relation about the inner orifice and adapted to discharge a second shell material. A multi-element spherical shell can be formed through employment of the nozzle assembly by merger with one another after discharge from the outer orifices of the nozzles of a pair of adjacent annular streams of liquid or molten shell wall material of different compositions and encapsulation by the mixed shell wall materials of a common encapsulated core fluids also simultaneously discharged by the inner orifices nozzles. On the other hand, the pair of encapsulating streams of shell wall material can be of the same materials which merge together and encapsulate core fluids of different compositions which will merge together after discharge from the nozzles.

Morrison, Andrew D.↗
NASA NTRS1990

Hot filament technique for measuring the thermal conductivity of molten lithium fluoride

Molten salts, such as lithium fluoride, are attractive candidates for thermal energy storage in solar dynamic space power systems because of their high latent heat of fusion. However, these same salts have poor thermal conductivities which inhibit the transfer of heat into the solid phase and out of the liquid phase. One concept for improving the thermal conductivity of the thermal energy storage system is to add a conductive filler material to the molten salt. High thermal conductivity pitch-based graphite fibers are being considered for this application. Although there is some information available on the thermal conductivity of lithium fluoride solid, there is very little information on lithium fluoride liquid, and no information on molten salt graphite fiber composites. This paper describes a hot filament technique for determining the thermal conductivity of molten salts. The hot filament technique was used to find the thermal conductivity of molten lithium fluoride at 930 C, and the thermal conductivity values ranged from 1.2 to 1.6 W/mK. These values are comparable to the slightly larger value of 5.0 W/mK for lithium fluoride solid. In addition, two molten salt graphite fiber composites were characterized with the hot filament technique and these results are also presented.

Jaworske, Donald A.↗