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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Cali Urban Development: Using NASA Earth Observations to Assess Wetlands and Land Reclamation in Cali, Colombia

Recent research has documented the global decline of wetlands, largely attributed to increased urbanization and agriculture. This NASA DEVELOP study partnered with two local environmental entities in Cali, Colombia: The Fundación Dinamizadores Ambientales and the Departamento Administrativo de Gestión del Medio Ambiente. The team utilized Earth observations to evaluate trends in wetland extent, potential, and land cover in Cali between 2002 and 2023. A supervised classifier was generated within Google Earth Engine to create land use analyses of the region using Landsat 5 TM, Landsat 8 OLI, and Landsat 9 OLI-2 imagery. To identify locations of wetland potential within the study area, wetland probability was assessed by inputting PlanetScope, Sentinel-2 MSI, and partner-provided datasets into the Wetland Intrinsic Potential Tool in ArcGIS Pro and R. Data from Sentinel-1 C-SAR, Sentinel 2-MSI, and Suomi-NPP VIIRS were used to evaluate wetland extent using the Wetland Extent 3.0 Tool in3 Python. Overall, results indicated high wetland potential, particularly in the southeast region where agricultural areas were previously wetlands. Outputs also suggest a vast network of riparian wetlands in Cali. This study did not investigate socioeconomic data as it relates to wetlands, which is an avenue for future research. This project supplemented research into links between land use change, wetland extent, and wetland potential, and provided partner organizations with an objective foundation from which they can identify at-risk wetlands and develop community initiatives for management, conservation, and education.

Cali↗

Hawaiʻi Urban Development: Mapping Urban Infrastructure and Linkages to Wastewater Impacts across Hawaiʻi

Coastal ecosystems and human health across the Hawaiʻian islands are under threat from cesspools and other unpermitted wastewater infrastructure. Cesspools, or home sewage systems that hold wastewater effluent in porous concrete containers underground, discharge raw, untreated sewage directly into waterways. In fact, it is estimated that approximately 88,000 cesspools release 55 million gallons of raw sewage into Hawaiʻi’s waterways each day. Our partners, The Nature Conservancy, Hawaiʻi Regional Office (TNC) and University of Hawaiʻi, Mānoa (UHM), are heavily involved with the implementation and impact of Act 125, which was passed in 2017 by Hawaiʻi State Legislature to help combat these effects. This requires the conversion of cesspools to be upgraded and either converted to approved onsite disposal systems or connected to a sewer system so that the wastewater may be treated and to avoid leaching into the groundwater. Thus, identifying and locating cesspool and other unpermitted wastewater infrastructure is key to state and partner goals. Utilizing NASA Earth observations including Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI), and Landsat 9 OLI-2 imagery, as well as pre-classified Sentinel-2 Multispectral Instrument (MSI) imagery in Esri’s Living Atlas, our team showcased the various perspectives that wastewater pollution research can use to assist in identifying and tracking urban development and concrete condition. This process was demonstrated by utilizing supervised object-based classification models, calculating various urban indices, and finding building size estimates to calculate effluent levels. Additionally, providing our partners with a GIS Methodology that can be built on to reach their future needs.

urban classification↗

Cali Urban Development II: Investigating the Impacts of Land Use Change on Urban Heat and Social Vulnerability in Cali, Colombia

The surface urban heat island (SUHI) effect is an environmental phenomenon resulting in cities with higher temperatures than rural areas due to increased pavement and decreased cooling from vegetation. The city of Santiago de Cali in Colombia faces SUHI challenges exacerbated by land use change. The Cali municipal government agency, Departamento Administrativo de Gestión del Medio Ambiente, and the community organization Fundacion Dinamizadores Ambientales partnered with NASA DEVELOP to evaluate communities in Cali most vulnerable to urban heat. This project illustrated the utility of using NASA Earth observations to evaluate the relationship between land use, temperature, and social factors in Cali, Colombia between 2013 and 2023. The team used Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS), and Landsat 9 OLI-2/TIRS-2 to generate land surface temperature (LST) maps in Google Earth Engine through NASA DEVELOP’s Urban Heat Exposure Assessment Tempe 2.0 tool. Cloud cover limited the project feasibility, but it improved with Landsat 9 data. In ArcGIS Pro, the team found that LST was significantly higher in urban areas than in wetlands or forests. Using R Studio, the team ran a principal component analysis and found that health care and green space access were negatively correlated, and Afro-Colombian ethnicity was positively correlated with LST. With knowledge of the most impacted and vulnerable regions, the partner organizations can prioritize establishing healthcare facilities and green spaces in those areas to reduce the impacts of urban heat.

vegetation loss↗

Hilo Bay Water Resources: Monitoring Water Quality in Hilo Bay, Hawaii to Support Future Community Planning

Designated as an impaired body of water by both state and federal water quality standards, Hilo Bay, Hawaiʻi is highly susceptible to brown water, a condition where the water becomes murky and is associated with excess levels of bacteria, contaminants, and nutrients. A breakwater in Hilo Bay, which was established to protect Hilo town from tsunamis, interferes with water circulation and prolongs the presence of brown water in the bay. The State of Hawaiʻi issues brown water advisories (BWAs) following flash flood warnings, sewage spills, and other events to indicate a public health concern for those who use Hilo Bay for recreation, cultural purposes, and fishing. Due to the elevated public health risk and ecosystem disturbance that brown water poses to Hilo Bay, we partnered with the Hawaiʻi County Office of Sustainability, Climate, Equity, and Resilience (OSCER) to examine the feasibility of using Earth observations (EO) to monitor water quality in the Hilo Bay region. We leveraged data from Sentinel-2 Multispectral Instrument (MSI), Landsat 8 Operational Land Imager (OLI), Landsat 9 OLI-2, and Aqua and Terra Moderate Resolution Imagine Spectroradiometer (MODIS) instruments to identify and assess spatial and temporal patterns of two main water quality parameters, turbidity and chlorophyll-a, during BWAs. We used the Optical Reef and Coastal Area Assessment (ORCAA) tool in Google Earth Engine to process EO data and generate water quality maps and time series. Our study found that increased turbidity levels can be identified by EO data during BWAs. In addition, our map products indicated the presence of several turbidity plumes along the coast, with the highest concentration of turbidity found within Hilo Bay. While chlorophyll-a levels were relatively flat within our study region during BWAs, we found that regional chlorophyll-a patterns could be derived from MODIS chlorophyll-a data in NASA Worldview. Our study’s multi-sensor approach provided valuable insights for how water quality in the Hilo Bay region can be monitored in the future.

remote sensing↗

Jemez Pueblo Agriculture: Monitoring Rangeland Conditions to Inform Drought and Land Management in New Mexico

The Jemez Pueblo, a community located in the semi-arid high desert region of northcentral New Mexico, faces challenges with drought mitigation and livestock management. NASA DEVELOP partnered with the Pueblo of Jemez Natural Resources Department and The Nature Conservancy to provide recent and historical rangeland conditions to aid present decision-making, which relies on cultural practices, site familiarity, available resources, and physical data. This partnership offers the opportunity to support management practices by leveraging remote sensing and virtual fencing technologies. Our project explored Rangeland Analysis Platform (RAP) products incorporating NASA Earth observation Landsat 5 TM, Landsat 7 ETM+, Landsat 8 OLI, and Landsat 9 OLI-2 remote-sensed imagery as an agricultural land management tool. We performed linear regression analysis to evaluate RAP data to field data and explored RAP annual herbaceous biomass, ground cover trends, and climatic factors at the pasture level. We then computed study area summary statistics, performed pixel-by-pixel trend analysis across the study period, and evaluated ground cover trends near water sources. Based on available data, RAP was poorly correlated to bare ground and herbaceous biomass, generally underestimating the former and overestimating the latter. To improve the evaluation of RAP products, we suggest increasing the spatiotemporal distribution of the field dataset. According to RAP, from 1986 to 2023, the site became hotter and drier, bare ground increased, and annual forbs and grasses increased while perennials decreased. RAP products did not agree with field-collected data; however, the trends over time may be useful for informing rangeland management actions.

cattle grazing management↗

Assessing the Feasibility of Using Various Earth Observations to Monitor Environmental Trends Associated with River Flow Impediments Near Energy Intake Structures

Grassing events, characterized by the release of river vegetation in large quantities, are often responsible for major flow impediments surrounding industrial water intake structures. These sudden flow impediments halt critical municipal functions, such as cooling at energy generating facilities, leading to widespread energy disruptions for surrounding communities. Because the origin and cause of grassing events in rivers are largely unknown, employees at these facilities can only reactively respond after they occur by pausing energy generation to manually remove the accumulation of aquatic vegetation. In 2023, the Dresden Generating Station, in collaboration with the United States Geological Survey, began looking into using remote sensing methodologies to locate floating aquatic vegetation surrounding their intake structure located along the Kankakee River in northern Illinois. This project contributed to this effort by conducting a case study that compared the performance, practicality, and feasibility of using various Earth observations (Landsat 9 OLI-2, Landsat 8 OLI, Sentinel-2 MSI, and DOVE PlanetScope) and vegetation indices (NDVI, EVI, SAVI, and GCI) to monitor aquatic vegetation in the Kankakee River. Additionally, this study incorporated several environmental metrics to identify potential triggers for grassing events. Results from this project found that while Landsat sensors provide a lower spatial resolution than commercial satellite Earth observations, areas of aquatic vegetation were similarly identified; therefore, it may not be necessary to acquire expensive, high-resolution datasets for continued monitoring. Finally, preliminary correlation analyses showed a potential negative relationship between the river discharge and the presence of aquatic vegetation (-0.875 correlation coefficient), suggesting that periods of low flow could lead to large releases in aquatic vegetation.

Marisa Smedsrud↗

Investigating the Impacts of Land Use Change on Urban Heat and Vulnerability in Cali, Columbia

The urban heat island effect (UHI) is an environmental phenomenon where cities experience higher temperatures than rural areas due to increased pavement and decreased cooling from vegetation. Approximately 76% of people in Colombia live in urban areas, and the city of Santiago de Cali is facing UHI challenges exacerbated by land use change. Wetlands and forests formerly surrounded the city but were replaced by development and agriculture. The Colombian municipal government agency Departamento Administrativo de Gestión del Medio Ambiente and the community organization Fundacion Dinamizadores Ambientales partnered with NASA DEVELOP to evaluate communities in Cali most vulnerable to urban heat. This project illustrated the utility of using NASA Earth observations to evaluate the relationship between land use, temperature, and social factors in Cali, Colombia between 2013 and 2023. The team used Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS), and Landsat 9 OLI-2/TIRS-2 to generate land surface temperature (LST), normalized difference vegetation index (NDVI), and albedo maps in Google Earth Engine. Heavy cloud cover limited the accuracy of the LST but incorporating up to three satellites for a median image reduced potential errors. Through further analysis in ArcGIS Pro, the team classified land use change using a deep learning model and found that LST was significantly higher in urban areas than in wetlands or forests. Using R studio, the team ran a principal component analysis to determine which social factors had the strongest correlation with LST. The team found that health care and green space access were negatively correlated, and Afro-Colombian ethnicity was positively correlated with LST. With awareness of the most impacted and vulnerable regions, the partner organizations can work to prioritize green space establishment in those areas to reduce the impacts of urban heat. Addressing the urban heat island effect will reduce environmental justice concerns within the city and improve overall health, air, and water quality for those who live there.

Brenna Bruffey↗

Using NASA Earth Observations to Identify Trends in Harmful Algal Blooms in Narragansett Bay

Narragansett Bay in Rhode Island is known for its quahog, or hard-shell clam, shellfisheries. However, increased levels in harmful algal blooms (HABs) have posed threats to quahog populations and raised public health concerns due to shellfishery closures resulting from contamination with neurotoxins released by phytoplankton. NASA DEVELOP partnered with the Environmental Protection Agency’s National Health and Environmental Effects Research Laboratory and Rhode Island’s Department of Environmental Management to use Earth observations and the partners’ in-situ data to visualize phytoplankton bloom events within the bay. The team used Sentinel-3 Ocean and Land Color Instrument (OLCI), Landsat 8 Operational Land Imager (OLI), and Landsat 9 OLI-2 to track proposed proxies for phytoplankton from June 2016 to October 2023. Multiple sensors and datasets were employed for more accurate results due to the small spatial extent of Narragansett Bay. Chlorophyll-a and total suspended solids were determined to be accurate parameters to monitor HAB events. Although complications could arise due to the relatively small size of the bay and small-scale of the bloom events, which may be difficult to visualize via remote sensing, Earth observations have proven to help strengthen HAB research, monitoring, and prediction and will complement the extensive in-situ data in Narragansett Bay.

Isabella Giordano↗

Pennsylvania Department of Environmental Protection (PA DEP) 26r Detailed Produced Water Compositions (version 1.0)

A database of geochemical compositions of aqueous species in produced water reported to the PA DEP. Samples were collected between mid-2012 to early-2020. Data from publicly-available PA DEP 26r reports were scraped from pdf files and cumulated into tabular spreadsheet format for >1000 produced water streams from Marcellus wells in Pennsylvania. In addition to providing the original values, the NETL NEWTS team has reformatted the dataset to allow sample streams to be easily copied into OLI Studio and Geochemist WorkBench (GWB) software for modeling the geochemistry and the recovery of critical minerals, such as lithium, from these produced water streams. In addition, a version of the dataset has been included with predictions for some missing values in the original dataset using machine learning techniques within CoDaRT software, a public ML software developed by the Nation Energy Technology Laboratory. We have made the Input into CoDaRT and one example output from CoDaRT available in this dataset.

Aqueous Chemistry↗

Pennsylvania Department of Environmental Protection (PA DEP) 26r Detailed Produced Water Compositions (version 2.0)

A database of geochemical compositions of aqueous species in produced water reported to the PA Department of Environmental Protection (PA DEP). Samples were collected between late-2010 to late-2024. Data from publicly available PA DEP 26r reports were scraped from pdf files and cumulated into tabular spreadsheet format for >3,000 produced water streams from Marcellus Shale wells in Pennsylvania. In addition to providing the original values, the NETL NEWTS team has reformatted the dataset to allow sample streams to be easily copied into OLI Studio and Geochemist WorkBench (GWB) software for modeling the geochemistry and the recovery of critical minerals, such as lithium, from these produced water streams. ***This dataset is an updated version of the PA DEP 26r Detailed Produced Water Compositions (version 1.0) dataset, providing expanded spatial and temporal coverage.***

Aqueous Chemistry↗

Keweenaw Bay Water Resources: Turbidity Data Decision Support for Shoreline Assessment and Management in Lake Superior'S Keweenaw Bay

The Keweenaw Bay Indian Community (KBIC) has shoreline along the south of Lake Superior that is contaminated with copper stamp sands from legacy mining. The stamp sands have been capped with sandy-loam soils and restored native species, but erosion and flooding threaten to re-deposit these stamp sands onto wetlands and into the bay. Erosion and flooding also threaten loss of beaches and shoreline, infrastructure, wetland restoration projects, and coastal highways, which has driven shoreline armoring. However, while shoreline armoring can be effective in protecting the intended areas, it can also exacerbate erosion in nearby unarmored areas, so its net impact on the shoreline is yet to be quantified. The DEVELOP team partnered with KBIC and the Environmental Protection Agency (EPA) to utilize imagery from Landsat 8 Operational Land Imager (OLI) and Sentinel-2 Multispectral Instrument (MSI) in order to analyze turbidity proxies. The results from these analyses showed that seasonal variation in study area was greatest during the season dominated by rain, but spatial variability across our study period did not show a clear trend. These results will be used to better inform future shoreline management efforts and support resilience in the face of more coastal erosion.

remote sensing↗

Incorporating corrosion design constraints in desalination process optimization: A case study in mechanical vapor compression

Corrosion is an expensive and complex challenge for desalination, yet current design approaches do not explicitly account for corrosion mechanisms in process modeling and technoeconomic analysis. Here, to address this gap, we present a workflow for incorporating corrosion design constraints directly into desalination process optimization models. We develop surrogate models for general and localized corrosion metrics as functions of temperature, pH, salinity, dissolved oxygen, and material using data from OLI Systems’ Corrosion Analyzer. We then integrate these surrogates as corrosion design constraints in a cost-optimization MVC model that minimizes the levelized cost of water (LCOW). For a case study of mechanical vapor compression (MVC) treating seawater across a range of recoveries, we find dissolved oxygen (DO) is the dominant driver of localized corrosion, and thus of cost-optimal material choice and operating conditions. Reducing the DO from 8 mg/L to 0.5 mg/L reduces the LCOW by 15-35%, informing the breakeven costs for implementing DO removal or selecting highly corrosion-resistant alloys. This framework is broadly applicable across corrosion types, materials, and components and enables desalination process design that minimizes capital costs.

36 MATERIALS SCIENCE↗

Structural regulation-induced Li-electron disentanglement for stabilized oxygen redox of Li-excess disordered rock-salt cathode materials

Since the discovery of its electrochemical activity, Li-excess disordered rock-salt (DRX) cathode material has received worldwide attention as it sets up a new way to exploit oxygen redox beyond the conventional layered structure with late-3d transition metals. However, the intricate structure-function relationship in the disordered lattice of the DRX material fogs the researcher's lens on the underlying redox mechanisms. Here, in this study, we employ a synergistic approach combining neutron total scattering with reverse Monte Carlo modeling and density functional theory calculations to unravel the landscape of oxygen redox reactions in DRX. Redox activities are evaluated in diverse oxygen clusters (OLi x TM 6-x ) and the spatial distribution of these clusters in the model DRX structure (Li 1.16 Ti 0.37 Ni 0.37 Nb 0.1 O 2 and Li 1.2 Ti 0.35 Ni 0.35 Nb 0.1 O 1.8 F 0.2 ) is explicitly determined. The results unveil that by regulating the short-range ordering between cations, fluorine atoms can effectively decouple the location of Li extraction and electron depletion. Such disentanglement between the Li reservoir and electron reservoir in the DRX lattice could play a pivotal role in protecting the oxidized oxygen and preserving the lattice framework during cycling. Through a tentatively designed non-fluorinated DRX oxide realizing similar Li-electron decoupling, an obvious enhancement of the cycling capability can be achieved without compromising the capacity release.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NEWTS Argonne Geothermal Geochemical Database with CoDART

A database of geochemical compositions of aqueous species in potential geothermal resources. The NETL NEWTS team has formatted the original Argonne V2 database for Charge Balance, Input into OLI Studio, and Input into GWB. (Geochemist WorkBench) In addition, some missing species in the original database were predicted using machine learning techniques within CoDart software, a public ML software developed by the Nation Energy Technology Laboratory. We have made the Input into CoDart and one example output from CoDart available in this dataset.

Aqueous Chemistry↗

Highly Efficient Regeneration Module for Carbon Capture Systems in NGCC Applications

The objective of this project is to design, fabricate, and test a highly efficient regeneration module capable of providing an ultra-lean absorption solution that is required for capturing CO 2 from dilute sources at 95% or better efficiency. By integrating this advanced regenerator module with SRI International’s Mixed Salt Process (MSP) absorption modules, SRI expects to demonstrate significant progress toward a reduction in cost of capture versus the DOE reference natural gas combined cycle (NGCC) plant with carbon capture. SRI designed, built, and tested an advanced stripper to enhance the performance of SRI’s MSP for CO 2 capture – a transformational ammonia-based solvent technology – for natural gas (NG) power sources. The testing of the advanced stripper for MSP was conducted at an SRI site using a simulated flue gas stream equivalent to about 10 kWe. The research work included modeling of the advanced stripper and integrating it with the MSP absorbers; studying the strategies for producing very highly alkaline lean solvent with minimized emissions; operating the stripper with advanced heat integration to improve process efficiencies; and collecting critically important data for a detailed techno-economic analysis (TEA). The project tasks were designed to address concerns relating to scale-up and integration of the technology to NG power plants—more specifically, to maximize the carbon capture efficiency achievable with MSP and identify pathways to achieve higher capture efficiencies and ultimately zero net carbon emissions. SRI teamed up with a process modeling company (OLI Systems), a process and chemical engineering company (Trimeric Corporation), and a cost-sharing commercial partner (Baker-Hughes – a leading multinational company that designs, manufactures, and services transformative energy technologies) to execute the project. The research findings will accelerate the MSP development and pave the way for the technology to reach the DOE’s goal, and ultimately commercialization of the MSP technology for low-cost CO 2 capture from NGCC flue gas and other dilute CO 2 sources.

03 NATURAL GAS↗

Effect of Anoxic Iron Corrosion on WIPP Brine Geochemistry FY23 Final Report (U)

A 280-day study was completed to evaluate the effect of zero-valent iron (Fe 0 ) on the Waste Isolation Pilot Plant (WIPP) brine geochemistry under anticipated reducing conditions. Hydrogen (H 2 ) gas is expected to be present in the repository after closure due to the anoxic corrosion of a vast quantity of iron contained in the waste forms disposed at WIPP; therefore, a background argon atmosphere containing H 2 was chosen for this study. WIPP groundwater brine pH and E h will impact the mobility and fate of plutonium within the repository. Modeling and laboratory results for Castile WIPP brine indicate that equilibrium E h values relative to the standard hydrogen electrode (SHE) are 40 mV more reducing (i.e., more negative) than those for Salado WIPP brine (-480 mV vs. -440 mV, respectively) because of the higher pH of the Castile brine (pH 9.3 for Castile vs. pH 8.8 for Salado). The E h and pH data were corrected for the effects of high ionic strength. The experimental results for both brines are consistent with thermodynamic predictions using OLI Systems' Mixed Solvent Electrolyte chemical equilibrium model. The measured and corrected pH and E h data from this study are provided in Table ES-1 and Table ES-2, respectively.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

MO/DSD online information server and global information repository access

Often in the past, standards and new technology information have been available only in hardcopy form, with reproduction and mailing costs proving rather significant. In light of NASA's current budget constraints and in the interest of efficient communications, the Mission Operations and Data Systems Directorate (MO&DSD) New Technology and Data Standards Office recognizes the need for an online information server (OLIS). This server would allow: (1) dissemination of standards and new technology information throughout the Directorate more quickly and economically; (2) online browsing and retrieval of documents that have been published for and by MO&DSD; and (3) searching for current and past study activities on related topics within NASA before issuing a task. This paper explores a variety of available information servers and searching tools, their current capabilities and limitations, and the application of these tools to MO&DSD. Most importantly, the discussion focuses on the way this concept could be easily applied toward improving dissemination of standards and new technologies and improving documentation processes.

Nguyen, Diem↗

Kinetic Induction of Oat Shoot Pulvinus Invertase mRNA by Gravistimulation and Partial cDNA Cloning by the Polymerase Chain Reaction

An asymmetric (top vs. bottom halves of pulvini) induction of invertase mRNA by gravistimulation was analyzed in oat shoot pulvini. Total RNA and poly(A)(+) RNA, isolated from oat pulvini, and two oli-gonucleotide primers, corresponding to two conserved amino acid sequences (NDPNG and WECPD) found in invertase from other species, were used for the polymerase chain reaction (PCR). A partial length cDNA (550 bp) was obtained and characterized. A 62% nucleotide sequence homology and 58% deduced amino acid sequence homology, as compared to beta-fructosidase of carrot cell wall, was found. Northern blot analysis showed that there was an obviously transient induction of invertase mRNA by gravistimulation in the oat pulvinus system. The mRNA was rapidly induced to a maximum level at 1 hour after gravistimulation treatment and gradually decreased afterwards. The mRNA level in the bottom half of the oat pulvinus was significantly higher than that in the top half of the pulvinus tissue. The kinetic induction of invertase mRNA was consistent with the transient accumulation of invertase activity during the graviresponse of the pulvinus. This indicates that the expression of the invertase gene(s) could be regulated by gravistimulation at the transcriptional level. Southern blot analysis showed that there were two to three genomic DNA fragments which hybridized with the partial-length invertase cDNA.

Wu, Liu-Lai↗