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All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Ozone Contamination in Aircraft Cabins. Appendix B: Overview papers. In-flight measurements

The NASA Global Atmospheric Sampling Program ozone measurements were obtained to establish to characteristics of the ambient ozone concentration during routine operations and to determine the attenuation of ambient concentrations of cabin air systems from simultaneous ambient and in cabin measurements. The characteristics of ambient ozone include: (1) maximum concentration; (2) duration of ozone encounters; (3) frequency of ozone during a flight; (4) variability of ozone during a flight; (5) in relation to routes, altitude, and meteorological conditions.

Perkins, P. J.↗
NASA NTRS1977

Comparison of ozone measurement techniques using aircraft, balloon, and ground-based measurements

In order to verify the ultraviolet absorption technique used in the Global Atmospheric Sampling Program, two flight experiments were conducted employing several techniques, both in situ and remote, for measuring atmospheric ozone. The first experiment used the NASA CV-990 equipped with an ultraviolet absorption ozone monitor and an ultraviolet spectrophotometer, a balloon ozonesonde, and a Dobson station for determining and comparing the ozone concentration data. A second experiment compared ozone data from an automated sampling system aboard a B-747 with data from a manned system installed on the NASA CV-990 during a cross-country flight with both aircraft following the same flight path separated by 32 kilometers.

Briehl, D.↗
NASA NTRS2017

Stratospheric Intrusion-Influenced Ozone Air Quality Exceedences Investigated in MERRA-2

Ozone near the surface is harmful to human health and is a result of the photochemical reaction with both man-made and natural precursor pollutant sources. Therefore, in order to reduce near surface ozone concentrations, communities must reduce anthropogenic pollution sources. However, the injection of stratospheric ozone into the troposphere, known as a stratospheric intrusion, can also lead to concentrations of ground-level ozone exceeding air quality standards. Stratospheric intrusions are dynamical atmospheric features, however, these intrusions have been misrepresented in models and reanalyses until recently, as the features of a stratospheric intrusion are best identified in horizontal resolutions of approximately 50 km or smaller. NASA's Modern-Era Retrospective Analysis for Research and Applications Version-2 (MERRA-2) reanalysis is a publicly-available high-resolution dataset (~50 km) with assimilated ozone that characterizes stratospheric ozone on the same spatiotemporal resolution as the meteorology. We show that stratospheric intrusions that impact surface air quality are well represented in the MERRA-2 reanalysis. This is demonstrated through a case study analysis of stratospheric intrusion events which were identified by the United States Environmental Protection Agency (EPA) to impact surface ozone air quality in spring 2012 in Colorado. The stratospheric intrusions are identified in MERRA-2 by the folding of the dynamical tropopause under the jet stream and subsequent isentropic descent of dry, O3-rich stratospheric air towards the surface where ozone air quality exceedences were observed. The MERRA-2 reanalysis can support air quality agencies for more rapid identification of the impact of stratospheric air on ground-level ozone.

Knowland, K. Emma↗
NASA NTRS2013

Inverse Modeling of Texas NOx Emissions Using Space-Based and Ground-Based NO2 Observations

Inverse modeling of nitrogen oxide (NOx) emissions using satellite-based NO2 observations has become more prevalent in recent years, but has rarely been applied to regulatory modeling at regional scales. In this study, OMI satellite observations of NO2 column densities are used to conduct inverse modeling of NOx emission inventories for two Texas State Implementation Plan (SIP) modeling episodes. Addition of lightning, aircraft, and soil NOx emissions to the regulatory inventory narrowed but did not close the gap between modeled and satellite observed NO2 over rural regions. Satellitebased top-down emission inventories are created with the regional Comprehensive Air Quality Model with extensions (CAMx) using two techniques: the direct scaling method and discrete Kalman filter (DKF) with Decoupled Direct Method (DDM) sensitivity analysis. The simulations with satellite-inverted inventories are compared to the modeling results using the a priori inventory as well as an inventory created by a ground-level NO2 based DKF inversion. The DKF inversions yield conflicting results: the satellite based inversion scales up the a priori NOx emissions in most regions by factors of 1.02 to 1.84, leading to 3-55% increase in modeled NO2 column densities and 1-7 ppb increase in ground 8 h ozone concentrations, while the ground-based inversion indicates the a priori NOx emissions should be scaled by factors of 0.34 to 0.57 in each region. However, none of the inversions improve the model performance in simulating aircraft-observed NO2 or ground-level ozone (O3) concentrations.

Nitrogen dioxide↗
DOE OSTI2024

Assessment of Long-Term Degradation of Adsorbents for Direct Air Capture by Ozonolysis

Porous adsorbents are a promising class of materials for the direct air capture of CO 2 (DAC). Practical implementation of adsorption-based DAC requires adsorbents that can be used for thousands of adsorption–desorption cycles without significant degradation. We examined the potential degradation of adsorbents by a mechanism that appears to have not been considered previously, namely, ozonolysis by trace levels of ozone from ambient air. We focused on amine-appended metal–organic frameworks, specifically amine-functionalized Mg 2 (dobpdc), as a representative DAC adsorbent. Estimates based on the number of amine sites in these adsorbents and the ozone concentration in air suggest that degradation by ozone may be relevant over thousands of adsorption–desorption cycles if reactions with adsorbed ozone are fast. We used density functional theory calculations to estimate reaction rates for amine groups and carbon–carbon double bonds in amine-functionalized Mg 2 (dobpdc).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1991

Nonlocal thermodynamic equilibrium processes in ozone - Implications for the energy budget of the mesosphere and lower thermosphere

The conversion of chemical potential energy and infrared radiative energy to kinetic energy by non-LTE processes involving ozone is a potentially significant source of heat in the terrestrial upper mesosphere and lower thermosphere. Heating rates are calculated and compared using two different statistical equilibrium models previously applied in the analysis of measurements of limb emission from ozone. The calculated heating depends strongly on the assumed distribution and relaxation of energy in the quasi-nascent ozone molecule. Finally, in the absence of a detailed data base of rate coefficients it may be possible to estimate the heating rate due to non-LTE processes in ozone from appropriate satellite measurements of the ozone concentration and of the infrared emission from ozone in the 9-12 micron spectral interval.

Milynczak, Martin G.↗
NASA NTRS1991

Cloud condensation nuclei near marine stratus

Extensive airborne measurements of cloud condensation nucleus (CCN) spectra and concentrations of total particles, or condensation nuclei (CN), below, in, and above the stratus cloud decks off the southern California coast point to important aerosol-cloud interactions. Consistently low CCN concentrations below cloud appear to be due to cloud scavenging processes which include Brownian coagulation, nucleation, coalescence, and drizzle. The higher CCN and CN concentrations above cloud are associated with ambient ozone concentrations which suggest a link with continental, probably anthropogenic, sources, even at distances of 500 km from the California coast.

Hudson, James G.↗
NASA NTRS2012

Modeling and Observations of the Response of Tropical Tropospheric Ozone to ENSO

The El Nino-Southern Oscillation (ENSO) is the dominant mode of tropical variability on interannual time scales. ENSO appears to extend its influence into the chemical composition of the tropical troposphere, Recent results have revealed an ENSO induced wave-1 anomaly in observed tropical tropospheric column ozone, This results in a dipole over the western and eastern tropical Pacific, whereby differencing the two regions produces an ozone anomaly with an extremely high correlation to the Nino 3.4 Index. We have successfully reproduced this result using the Goddard Earth Observing System Version 5 (GEOS-5) general circulation model coupled to a comprehensive stratospheric and tropospheric chemical mechanism forced with observed sea surface temperatures over the past 25 years, An examination of the modeled ozone field reveals the vertical contributions of tropospheric ozone to the column over the western and eastern Pacific region, We will show targeted comparisons with SHADOZ ozonesondes over these regions to provide insight into the vertical structure. Also, comparisons with NASA's Aura satellite Microwave Limb Sounder (MLS) and Tropospheric Emissions Spectrometer (TES) instruments and other appropriate data sets will be shown. In addition, the water vapor response to ENSO will be compared to help illuminate its role relative to dynamics in impacting ozone concentrations. These results indicate that the tropospheric ozone response to ENSO is potentially a very useful chemistry-climate diagnostic and should be considered in future modeling assessments.

Oman, L. D.↗
NASA NTRS2016

Nitrous Oxides Ozone Destructiveness Under Different Climate Scenarios

Nitrous oxide (N2O) is an important greenhouse gas and ozone depleting substance as well as a key component of the nitrogen cascade. While emissions scenarios indicating the range of N2O's potential future contributions to radiative forcing are widely available, the impact of these emissions scenarios on future stratospheric ozone depletion is less clear. This is because N2O's ozone destructiveness is partially dependent on tropospheric warming, which affects ozone depletion rates in the stratosphere. Consequently, in order to understand the possible range of stratospheric ozone depletion that N2O could cause over the 21st century, it is important to decouple the greenhouse gas emissions scenarios and compare different emissions trajectories for individual substances (e.g. business-as-usual carbon dioxide (CO2) emissions versus low emissions of N2O). This study is the first to follow such an approach, running a series of experiments using the NASA Goddard Institute for Space Sciences ModelE2 atmospheric sub-model. We anticipate our results to show that stratospheric ozone depletion will be highest in a scenario where CO2 emissions reductions are prioritized over N2O reductions, as this would constrain ozone recovery while doing little to limit stratospheric NOx levels (the breakdown product of N2O that destroys stratospheric ozone). This could not only delay the recovery of the stratospheric ozone layer, but might also prevent a return to pre-1980 global average ozone concentrations, a key goal of the international ozone regime. Accordingly, we think this will highlight the importance of reducing emissions of all major greenhouse gas emissions, including N2O, and not just a singular policy focus on CO2.

stratospheric ozone depletion↗
NASA NTRS2016

Tropospheric Ozone Change from 1980 to 2010 Dominated by Equatorward Redistribution of Emissions

Ozone is an important air pollutant at the surface, and the third most important anthropogenic greenhouse gas in the troposphere. Since 1980, anthropogenic emissions of ozone precursors methane, non-methane volatile organic compounds, carbon monoxide and nitrogen oxides (NOx) have shifted from developed to developing regions. Emissions have thereby been redistributed equatorwards, where they are expected to have a stronger effect on the tropospheric ozone burden due to greater convection, reaction rates and NOx sensitivity. Here we use a global chemical transport model to simulate changes in tropospheric ozone concentrations from 1980 to 2010, and to separate the influences of changes in the spatial distribution of global anthropogenic emissions of short-lived pollutants, the magnitude of these emissions, and the global atmospheric methane concentration. We estimate that the increase in ozone burden due to the spatial distribution change slightly exceeds the combined influences of the increased emission magnitude and global methane. Emission increases in Southeast, East and South Asia may be most important for the ozone change, supported by an analysis of statistically significant increases in observed ozone above these regions. The spatial distribution of emissions dominates global tropospheric ozone, suggesting that the future ozone burden will be determined mainly by emissions from low latitudes.

Zhang, Yuqiang↗
NASA NTRS2010

Contributions to Future Stratospheric Climate Change: An Idealized Chemistry-Climate Model Sensitivity Study

Within the framework of an idealized model sensitivity study, three of the main contributors to future stratospheric climate change are evaluated: increases in greenhouse gas concentrations, ozone recovery, and changing sea surface temperatures (SSTs). These three contributors are explored in combination and separately, to test the interactions between ozone and climate; the linearity of their contributions to stratospheric climate change is also assessed. In a simplified chemistry-climate model, stratospheric global mean temperature is most sensitive to CO2 doubling, followed by ozone depletion, then by increased SSTs. At polar latitudes, the Northern Hemisphere (NH) stratosphere is more sensitive to changes in CO2, SSTs and O3 than is the Southern Hemisphere (SH); the opposing responses to ozone depletion under low or high background CO2 concentrations, as seen with present-day SSTs, are much weaker and are not statistically significant under enhanced SSTs. Consistent with previous studies, the strength of the Brewer-Dobson circulation is found to increase in an idealized future climate; SSTs contribute most to this increase in the upper troposphere/lower stratosphere (UT/LS) region, while CO2 and ozone changes contribute most in the stratosphere and mesosphere.

Hurwitz, M. M.↗
NASA NTRS1977

Reaction rates for O3 + HCl yielding O + O2 + HCl, Cl + O3 yielding ClO + O2, and HCl + O yielding OH + Cl at elevated temperatures

Ozone and a much greater quantity of hydrogen chloride, slightly diluted by oxygen and argon, were heated by a shock wave process to temperatures in the range 480-1300 K at pressures from four to eight atmospheres. From variations in ozone concentration, determined by the attentuation of 2537-A radiation, the rate coefficient for the reaction O3 + HCl yielding O + O2 + HCl was determined to be k1 = (4.0 plus or minus 1.5) x 10 to the minus 10 exp(-10,408/T)cm3/s for temperatures of 480-720 K. From the concentration of ClO remaining at the end of ozone decomposition the rate coefficients for the reactions Cl + O3 yielding ClO + O2 and HCl + O yielding OH + Cl were also deduced for a temperature of about 1100 K.

Park, C.↗
NASA NTRS2012

Quantifying Interannual Variability of the UTLS Ozone Using Assimilation of Satellite Data

An accurate representation of spatial and temporal variability of the Upper Troposphere Lower Stratosphere (UTLS) ozone is essential for understanding both the tropospheric ozone budget and ozone s contribution to radiative forcing. The complex, dynamically driven structure of trace gas fields in the UTLS presents a challenge to data-based and modelling studies. Small features are not fully resolved in data from limb-sounding instruments such as the Microwave Limb Sounder on EOS-Aura (the EOS-MLS), but are captured in assimilation of those data as vertical structure is added from the assimilated meteorology. This will be demonstrated using a multi-year assimilation of EOS-MLS observations in the Goddard Earth Observing System, Version 5 (GEOS-5) data assimilation system. The results demonstrate the realism of the seasonal and year to year variability of laminar structures in the mid-latitudinal ozone field between years 2005-2007, for which independent validation data are available from the HIRDLS instrument. The analysis is done in the context of the underlying large scale dynamics. The lifetimes of most research instruments are too short for them to be used throughout the duration of long-term (at least 3 decades) reanalyses. For example, the EOS-MLS instrument has operated since mid-2004 until present. By contrast, Solar Backscatter Ultra Violet (SBUV) measurements provide continuous data since late 1978, but their vertical resolution is insufficient to represent the profile shape in the UTLS. Assimilation of these SBUV/2 observations in the GEOS-5 data assimilation system has hitherto not captured a realistic ozone structure in the UTLS, even though transport studies using GEOS-5 wind fields do show such structures. We show that careful construction of the background error covariance structure in GEOS-5 can lead to more realistic UTLS ozone fields when assimilating SBUV/2 observations. The reasoning behind this will be discussed, emphasizing the need to retain the sharp gradient of ozone concentrations across the tropopause. We analyze the UTLS ozone distributions in multi-year SBUV/2 assimilation experiments, comparing the results against the independent HIRDLSdataset and, for a longer period, with the MLS assimilation and discuss the consequences for tropospheric ozone and radiative forcing.

Wargan, K.↗
NASA NTRS2021

Additional Characterization of Dome-C to Improve its Use as an Invariant Visible Calibration Target

Dome-C is a recommended CEOS invariant target that has been utilized by the calibration community for several decades for monitoring onboard sensor calibration systems as well radiometric inter-comparisons. Dome-C is a high-altitude Earth target located on the East Antarctic interior plateau, which has a permanent bright, flat, and homogeneous snow-covered surface with little aerosol, cloud cover, snowfall, and water vapor burden. This paper describes angular directional models for characterizing the Dome-C top-of-atmosphere (TOA)radiances as a function of cosine solar zenith angle for pre-solstice and post-solstice conditions. The 0.86-μm channel Dome-C reflectance decreases over the summer due to snow metamorphosisis not observed by the visible channels. Coinciding Terra and AquaMODIS Dome-C reflectance showed occasional inter-annual anomalies when compared against the deep convective cloud and Libya-4 invariant targets observations. Further characterization of the Dome-C reflectances with the Dome-C surface broadband albedo, Antarctic Oscillation(AAO) index, and ozone concentration values were evaluated. A strong correlation with ozone was found for the 0.55-μm and 0.65-μm MODIS channels. The monthly Dome-C reflectances were linearly regressed with ozone to derive the ozone correction coefficients. The uncertainty in the Aqua-and Terra-MODIS Dome-C trends was reduced by half after applying ozone corrections to both the 0.55-μm and 0.65-μm channelTOA observations.

David R Doelling↗
NASA NTRS1988

The three-dimensional morphology of the Antarctic ozone minimum

The three-dimensional morphology of the Antarctic ozone minimum was obtained by mapping ozone distribution data from Nimbus-7 solar backscatter UV instrument, obtained at different pressure levels, on a south polar projection. These maps show that a clearly defined ozone minimum relative to the local ozone field extends throughout the stratosphere from about 10 km to above 50 km, though the intensity of the ozone decrease becomes less with altitude. The examination of the behavior of the general ozone-hole area suggests the existence of at least three distinct regions: (1) the region below 33 km, where ozone follows the pattern of the ozone hole, exhibiting a strong trend since 1979 and decreasing from late August to a minimum in October; (2) the 33-43 km height region of relatively stable ozone concentration; and (3) the region above 43 km, where ozone is again fluctuating, with a decrease during September to a minimum in October.

Aikin, A. C.↗
NASA NTRS2000

Elevated Tropospheric Ozone Over the South Tropical Atlantic in January-February 1999: An Ozone Paradox Due to Interhemispheric Transport, Lightning, or Stratospheric Exchange?

On this first North American to southern African oceanographic cruise with ozonesonde launches (January and February 1999 on board the NOAA Research Vessel Ronald H Brown between Norfolk, VA, and Cape Town, South Africa) we found: (1) high ozone, CO, and aerosols off northern equatorial Africa from biomass burning, but even higher ozone concentrations off southern Africa which was not burning - an "ozone paradox"; (2) TOMS satellite evidence that south Atlantic elevated ozone in January-February 1999 was a regional feature similar in extent to the well-known September-October ozone maximum. Several mechanisms are considered to explain the "ozone paradox." Convection transporting air from the lower troposphere rich in ozone and/or ozone precursors to the upper troposphere through the ITCZ (intertropical Convergence Zone) may lead to cross-hemisphere transport of pollution. This is supported by trajectory linkage of lower-tropospheric ozone maxima with smoke seen by the TOMS satellite. Lightning-generated NO (nitric oxide) leading to ozone peaks of > 100 ppbv observed at 7-10 km altitude is another explanation. The TRMM (Tropical Rainfall Measuring Mission) Lightning Imaging Sounder shows many lightning flashes over southern Africa, which trajectories link to the high-ozone layers south of the ITCZ. The highest ozone peaks in the middle troposphere correspond to very low water vapor, which may point to photochemical destruction of ozone or subsidence from the upper troposphere which had interacted with stratospheric ozone.

Thompson, Anne M.↗
NASA NTRS2002

Urban and Rural Ozone Collect over Lusaka (Zambia, 15.5 S, 28 E) during SAFARI-2000 (September 2000)

In early September, throughout south central Africa, seasonal clearing of dry vegetation and the production of charcoal for cooking leads to intense smoke haze and ozone formation. Ozone soundings made over Lusaka in early September 2000 recorded layers of high ozone (greater than 125 ppbv at 5 km) during two stagnant periods, broken by a frontal passage that reduced boundary layer ozone by 30%. During the 6-day measurement period, surface ozone concentrations ranged from 50-95 ppbv and integrated tropospheric ozone from the soundings was 39-54 Dobson Units (note 1.3 km elevation at the launch site). A stable layer of high ozone at 2-5 km was advected from rural burning regions in western Zambia and neighboring countries, making Lusaka a collection point for transboundary pollution. This is confirmed by trajectories that show ozone leaving Angola, Namibia, Botswana and South Africa before heading toward the Indian Ocean and returning to Lusaka via Mozambique and Zimbabwe. Ozone in the mixed layer at Lusaka is heavily influenced by local sources.

Thompson, Anne M.↗
DOE OSTI2024

Characterizing Overwater High Ozone Events in the Houston–Galveston–Brazoria Region during the 2021 GO3 and TRACER-AQ Campaigns

Photochemical modeling outputs showing high ozone concentrations over the Gulf of Mexico and Galveston Bay during ozone episodes in the Houston–Galveston–Brazoria (HGB) region have not been previously verified using in situ observations. Such data were collected systematically, for the first time, from July to October 2021 from three boats deployed for the Galveston Offshore Ozone Observations (GO3) and Tracking Aerosol Convection Interactions Experiment—Air Quality (TRACER-AQ) field campaigns. A pontoon boat and a commercial vessel operated in Galveston Bay, while another commercial vessel operated in the Gulf of Mexico offshore of Galveston. All three boats had continuously operating sampling systems that included ozone analyzers and weather stations, and the two boats operating in Galveston Bay had a ceilometer. The sampling systems operated autonomously on the two commercial boats as they traveled their daily routes. Thirty-seven ozonesondes were launched over water on forecast high ozone days in Galveston Bay and the Gulf of Mexico. During the campaigns, multiple periods of ozone exceeding 100 ppbv were observed over water in Galveston Bay and the Gulf of Mexico. These events included previously identified conditions for high ozone events in the HGB region, such as the bay/sea-breeze recirculation and postfrontal environments, as well as a localized coastal high ozone event after the passing of a tropical system (Hurricane Nicholas) that was not well forecast.

54 ENVIRONMENTAL SCIENCES↗