Thermodynamics of crystalline linear high polymers. V - Extended-chain copolymers of polyethylene.
Superheating crystallization of ethylene- propylene and ethylene-butene-1 copolymers and extended chain morphology
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Superheating crystallization of ethylene- propylene and ethylene-butene-1 copolymers and extended chain morphology
Melting point, melting range, and crystallinity of extended-chain copolymer crystals
Photographic spectra of ablating plastics in thermodynamic environments related to species and temperatures in boundary layers
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Photographic spectra of ablating plastics in thermodynamic environments related to species and temperatures in boundary layers
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Models of diffusion across an inert membrane have been studied using the computer program CINDA. The models were constructed to simulate various conditions obtained in the consideration of the diffusion of Ag (OH)2 ions in the AgO-Zn battery. The effects on concentrations across the membrane at the steady state and on the fluxout as a function of time were used to examine the consequences of stepwise reducing the number of sources of ions, of stepwise blocking the source and sink surfaces, of varying the magnitude of the diffusion coefficient for a uniform membrane, of varying the diffusion coefficient across the membrane, and of excluding volumes to diffusion.
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The design of a materials-science, educational experiment is presented. The student should understand the fundamentals of polymer processing and mechanical property testing of materials. The ability to use American Society for Testing and Materials (ASTM) standards is also necessary for designing material test specimens and testing procedures. The objectives of the experiment are (1) to understand the concept of laminated composite materials, processing, testing, and quality assurance of thermoplastic composites and (2) to observe an application example of recycled plastics.
Characterization of a 2-dimensional material constitutive model in the practical biaxial state for engineering utility of balloon envelope structural analysis is achievable with laboratory cylinder tests. Hoop (circumferential, and longitudinal strains are time-wise measured on axially loaded pressurized cylinders. Pre-programmed ramped loading changes as well as precise long term pressure control are achieved through cascaded proportional, integral derivative (PID) flow control loops that are part of an integrated data acquisition and process control system. Real time data reduction and analysis allow monitoring of unattended tests that have durations of up to a month. Measured and controlled parameters and variables are discussed; date analysis techniques are reviewed.
The introduction of polythylene -2, 6-Naphthalate (PEN) semicrystalline film with thicknesses of 0.9mu, 1.5mu, 4.0Mu and community. Its unique chemical and high temparterure stability, as well as superior thermo-mechanical properties allow ultra thin ( 2mu) PEN film to be processed into miniature multilayer chip capacitors for surface mount technology (SMT) application that can be used with standard soldering techniques.
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To determine whether sputter etching may provide substantial polymer surface texturing with insignificant changes in chemical and mechanical properties, an 8 cm beam diameter, electron bombardment, argon ion source was used to sputter etch (ion-texture process) nine biomedical polymers. The materials included silicone rubber, 32% carbon impregnated polyolefin, polyoxymethylene, polytetrafluoroethylene, ultrahigh molecular weight (UHMW) polyethylene, UHMW polyethylene with carbon fibers (10%), and several polyurethanes (bioelectric, segmented, and cross linked). Ion textured microtensile specimens of each material except UHMW polyethylene and UHMW polyethylene with 10% carbon fibers were used to determine the effect of ion texturing on tensile properties. Scanning electron microscopy was used to determine surface morphology changes, and electron spectroscopy for chemical analysis was used to analyze the near surface chemical changes that result from ion texturing. Ion energies of 500 eV with beam current densities ranging from 0.08 to 0.19 mA/sq cm were used to ion texture the various materials. Standard microtensile specimens of seven polymers were exposed to a saline environment for 24 hours prior to and during the tensile testing. The surface chemical changes resulting from sputter etching are minimal in spite of the often significant changes in the surface morphology.