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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Chronopotentiometry of refractory metals, actinides and oxyanions in molten salts: A review

The applications of chronopotentiometry to the study of electrochemical behavior of three technologically important areas of refractory metals, actinides, and oxyanions in molten salts are critically reviewed. Chronopotentiometry is a very versatile diagnostic tool to understand the reaction mechanism of the electrode processes for the electrochemical reduction/oxidation of these electroactive species in molten salt solutions. Well adherent, compact, and uniformly thick coatings of refractory metals may be electrodeposited from their solutions in molten salts.

Bansal, Narottam P.↗
NASA NTRS1993

Thermal spray forming of refractory sample ampoule cartridges for single crystal growth space furnaces

A thermal spray process is being used to build up refractory metals and ceramics into a containment cartridge for high temperature, single crystal semiconductor growth experiments. This process uses high energy plasma inside a low pressure (100-200 torr) inert environment to apply layers of material onto a removable mandrel. A variety of materials are being characterized and evaluated against a demanding set of requirements, including high service temperature (1700 C), oxidation resistance, and resistance to liquid metal attack. Techniques to spray form refractory metals (tungsten, molybdenum, niobium, tantalum) and ceramics (alumina, boron nitride) are being developed in the Plasma Spray Cell at Marshall Space Flight Center. These plasma spray formed materials have been evaluated for mechanical properties, density, microstructure, and resistance to liquid metal attack. Forming techniques and the resultant mechanical and metallurgical properties will be presented.

Zimmerman, Frank↗
NASA NTRS1993

Thermal spray forming of refractory sample ampoule cartridges for single crystal growth space furnaces

A thermal spray process is being used to build up refractory metals and ceramics into a containment cartridge for high temperature, single crystal semiconductor growth experiments. This process uses high energy plasma inside a low pressure (100-200 torr) inert environment to apply layers of material onto a removable mandrel. A variety of materials are being characterized and evaluated against a demanding set of requirements, including high service temperature (1700 C), oxidation resistance, and resistance to liquid metal attack. Techniques to spray form refractory metals (tungsten, molybdenum, niobium, tantalum) and ceramics (alumina, boron nitride) are being developed in the Plasma Spray Cell at Marshall Space Flight Center. These plasma spray formed materials have been evaluated for mechanical properties, density, microstructure, and resistance to liquid metal attack. Forming techniques and the resultant mechanical and metallurgical properties are presented.

Zimmerman, Frank↗
NASA NTRS1993

Trace element compositions of spinel-rich refractory inclusions from the Murchison meteorite

Three spinel-rich, perovskite-bearing, pyroxene-rimmed, hibonite-free inclusions from the Murchison C2 chondrite have volatility controlled, modified group II REE patterns. Two have high Eu/Yb ratios, two have small positive Ce anomalies and one has high refractory siderophiles for a group II inclusion. Two additional spinel-rich inclusions have subchondritic Ce/La ratios and negative Eu and Yb anomalies, the Eu anomalies being larger than the Yb ones. One of these inclusions is enriched in La relative to all HREE and the other is enriched in HREE relative to all LREE except La, possibly suggesting the presence of an ultrarefractory component in the latter. One hibonite-rich inclusion has a group III REE pattern with a negative Ce anomaly. A calcium dialuminate-bearing inclusion known to have crystallized from a melt at 2100-1800K has a modified group II REE pattern, rather than a pattern which would be predicted from the evaporation expected from such a droplet, e.g., a group III or ultrarefractory pattern. Volatile element contents of these inclusions are among the lowest found in any refractory inclusions.

Yoneda, S.↗
NASA NTRS1994

Refractory Oxide Coatings on Sic Ceramics

Silicon carbide with a refractory oxide coating is potentially a very attractive ceramic system. It offers the desirable mechanical and physical properties of SiC and the environmental durability of a refractory oxide. The development of a thermal shock resistant plasma-sprayed mullite coating on SiC is discussed. The durability of the mullite/SiC in oxidizing, reducing, and molten salt environments is discussed. In general, this system exhibits better behavior than uncoated SiC. Areas for further developments are discussed.

Lee, Kang N.↗
NASA NTRS1994

The origin of refractory precursor components of chondrules

A percentage of all chondrules from carbonaceous chondrites are intermediate in major-element composition between the rare Ca,Al-rich chondrules and the more abundant ferromagnesian chondrules. Some of them possess fractionated REE and trace-element patterns similar to those in CAI's (Ca-Al-rich inclusions). The abundance patterns are controlled primarily by volatilities expected from a solar composition. On the basis of refractory lithophile fractionations, it is suggested that one of the refractory precursors of C chondrules is a condensate from the nebular gas or an evaporative residue of primitive dust clumps.

Misawa, K.↗
NASA NTRS1995

Forming Refractory Insulation On Copper Wire

Alternative insulating process forms flexible coat of uncured refractory insulating material on copper wire. Coated wire formed into coil or other complex shape. Wire-coating apparatus forms "green" coat on copper wire. After wire coiled, heating converts "green" coat to refractory electrical insulator. When cured to final brittle form, insulating material withstands temperatures above melting temperature of wire. Process used to make coils for motors, solenoids, and other electrical devices to be operated at high temperatures.

Setlock, J.↗
NASA NTRS1998

Feasibility Study for Casting of High Temperature Refractory Superalloy Composites

Abstract This study investigated the feasibility of using conventional casting technique to fabricate refractory wires reinforced superalloy composites. These composites were being developed for advanced rocket engine turbine blades and other high temperature applications operating up to 2000 F. Several types of refractory metal wires such as W- Th, W-Re, Mo-Hf-C and W-HF-C reinforced waspaloy were experimentally cast and heat treated at 2000 F up to 48 hrs. Scanning electron microscope analysis was conducted in regions adjacent to the wire-matrix interface to determine the reaction zone and chemical compatibility resulting from material interdiffusion. It was concluded that fabrication using conventional casting may be feasible because the wire-matrix reaction zone thickness was comparable to similar composites produced by arc-sprayed monotape with hot isostatic pressing technique, Moreover, it was also found that the chemical compatibility could be improved significantly through a slight modification of the superalloy matrix compositions.

Lee, Jonathan A.↗
NASA NTRS2006

Net Shaped Component Fabrication of Refractory Metal Alloys using Vacuum Plasma Spraying

The vacuum plasma spraying (VPS) technique was employed to produce dense and net shaped components of a new tungsten-rhenium (W-Re) refractory metal alloy. The fine grain size obtained using this technique enhanced the mechanical properties of the alloy at elevated temperatures. The alloy development also included incorporation of thermodynamically stable dispersion phases to pin down grain boundaries at elevated temperatures and thereby circumventing the inherent problem of recrystallization of refractory alloys at elevated temperatures. Requirements for such alloys as related to high temperature space propulsion components will be discussed. Grain size distribution as a function of cooling rate and dispersion phase loading will be presented. Mechanical testing and grain growth results as a function of temperature will also be discussed.

Sen, S.↗
NASA NTRS2007

Emissivity Results on High Temperature Coatings for Refractory Composite Materials

The directional emissivity of various refractory composite materials considered for application for reentry and hypersonic vehicles was investigated. The directional emissivity was measured at elevated temperatures of up to 3400 F using a directional spectral radiometric technique during arc-jet test runs. A laboratory-based relative total radiance method was also used to measure total normal emissivity of some of the refractory composite materials. The data from the two techniques are compared. The paper will also compare the historical database of Reinforced Carbon-Carbon emissivity measurements with emissivity values generated recently on the material using the two techniques described in the paper.

Ohlhorst, Craig W.↗
NASA NTRS1989

Catalytic, hollow, refractory spheres, conversions with them

Improved, heterogeneous, refractory catalysts are in the form of gas-impervious, hollow, thin-walled spheres (10) suitable formed of a shell (12) of refractory such as alumina having a cavity (14) containing a gas at a pressure greater than atmospheric pressure. The wall material may be itself catalytic or a catalytically active material coated onto the sphere as a layer (16), suitably platinum or iron, which may be further coated with a layer (18) of activator or promoter. The density of the spheres (30) can be uniformly controlled to a preselected value within .+-.10 percent of the density of the fluid reactant such that the spheres either remain suspended or slowly fall or rise through the liquid reactant.

Wang, Taylor G.↗
NASA NTRS1987

Catalytic, hollow, refractory spheres

Improved, heterogeneous, refractory catalysts are in the form of gas-impervious, hollow, thin-walled spheres (10) suitable formed of a shell (12) of refractory such as alumina having a cavity (14) containing a gas at a pressure greater than atmospheric pressure. The wall material may be itself catalytic or a catalytically active material coated onto the sphere as a layer (16), suitably platinum or iron, which may be further coated with a layer (18) of activator or promoter. The density of the spheres (30) can be uniformly controlled to a preselected value within .+-.10 percent of the density of the fluid reactant such that the spheres either remain suspended or slowly fall or rise through the liquid reactant.

Wang, Taylor G.↗
NASA NTRS2010

Refractory Materials for Flame Deflector Protection

Fondu Fyre (FF) is currently the only refractory material qualified for use in the flame trench at KSC's Shuttle Launch Pads 39A and 3913. However, the material is not used as it was qualified and has undergone increasingly frequent and severe degradation due to the launch blasts. This degradation is costly as well as dangerous for launch infrastructure, crew and vehicle. The launch environment at KSC is unique. The refractory material is subject to the normal seacoast environment, is completely saturated with water before launch, and is subjected to vibrations and aggressive heat/blast conditions during launch. This report presents results comparing two alternate materials, Ultra-Tek FS gun mix and Kruzite GR Plus, with Fondu Fyre. The materials were subjected to bulk density, porosity, compression strength, modulus of rupture and thermal shock tests. In addition, test specimens were exposed to conditions meant to simulate the launch environment at KSC to help better understand how the materials will perform once installed.

Calle, Luz M.↗
NASA NTRS2020

Oxygen Isotopic Imaging of Refractory Inclusions from the Miller Range (MIL) 090019 CO3 Chondrite: A Perovskite Perspective

Calcium-Aluminum-rich Inclusions (CAIs) in primitive meteorites are the first solids to condense in the Solar System. The oxygen isotopic compositions recorded in various mineral components of CAIs provide clues about their origins and post-formation histories, recording processes such as condensation, melting, nebular alteration, and fluidrock reactions on the parent body. MIL 090019 is similar to some rare carbonaceous chondrites such as Acfer 094, DOM 08004/6 and ALH 77303 that contain high abundances of a variety of refractory inclusions. This provides an opportunity to study the oxygen isotopic record of different types of refractory inclusions within the same meteorite. We analyzed CAIs specifically targeting primary minerals that are direct nebular condensates, such as corundum and perovskite, with the goal of gaining insights into the O isotopic composition of the nebular gas(es) from which these CAIs condensed. As MIL 090019 is a classified as CO3.1, it shows some signs of thermal metamorphism, compared to the more primitive CO3 meteorites (e.g., DOM 08004/06). A second goal of this study is to search for evidence of nebular processes in phases such as perovskite and melilite that are susceptible to parent body alteration to varying degrees. We analyzed the oxygen isotopic compositions of various CAIs from the MIL 090019 CO3 carbonaceous chondrite by ion imaging using the NanoSIMS 50L (Nano Secondary Ion Mass Spectrometer) at JSC following methods described in. An advantage of ion imaging over traditional spot analyses is that it provides spatial context to the oxygen isotopic data. This work builds on previously reported oxygen isotopic composition of two other CAIs (CAI-44 and CAI-E2) from the same meteorite thin section.

Mane, P.↗
NASA NTRSDate not supplied

Additive Manufacture of Refractory Metal Green Propulsion Thrusters

High temperature refractory metals are required for a number of high temperature propulsion applications. Refractory metals are expensive, difficult to manufacture with high buy-to-fly ratios, and few vendors. Additive manufacture (AM) is used to produce C103, Molybdenum (Mo), and Tungsten (W) reaction chamber and thrust stand-off as well as Iridium ultra-fine lattice catalysts for integration into 1 N green propulsion thrusters. After printing components underwent post-processing to include heat treatment, surface finish modification, inspection, integration, and testing. Properly utilized AM overcomes existing manufacture limitations by greatly increasing design flexibility, material options, decrease price, decrease lead-time, and increase the commercial supply base.

Omar Mireles↗
NASA NTRSDate not supplied

Compositional Clues to the Origin of Refractory Metal Nuggets, Perovskite, and Zr-Rich Oxides in Hibonite from the Paris Cm Chondrite

Rare Ca-Al-rich inclusions (CAIs) in carbonaceous chondrites are dominated by Zr-, Sc-, Ti-,and/or Y-rich oxides and silicates, and often contain refractory metal nuggets (RMNs)[1-3]. These phases have ultra refractory (UR) rare earth element (REE)patterns that are complementary to Group II patterns[4]. Therefore, studies of such UR CAIs likely decipher a record of nebular conditions and processes at higher temperatures than other CAIs consisting mainly of spinel and melilite. Our previous TEM analyses reported a discovery of the assemblages of RMNs, perovskite, and Zr-rich oxides in hibonite from the Paris CM chondrite[5]. Here we present TEM results of a detailed chemical study of these UR phases to provide clues to their formation conditions in the early solar nebula.

J Han↗
NASA NTRS2019

Grossite-Rich Refractory Inclusions in Carbonaceous Chondrites: Evidence for Early Generation of Different O-Isotope Reservoirs in the Protoplanetary Disk and O-Isotope Exchange During Fluid-Rock Interaction

The oxygen isotopic composition of the Sun inferred from the measurements of the solar wind returned by the Genesis spacecraft is O-16-enriched (△O-17 = -28.4±3.6‰) relative to the whole-rock O-isotope compositions of chondrites and achondrites, and chondrule phenocrysts, which all plot close to the terrestrial fractionation line (△O-17 ∼ ±5‰). Vast majority of refractory inclusions (CAIs and AOAs) in carbonaceous chondrites of petrologic types 2-3.0 are iso-topically uniform and have solar-like △O-17. In contrast, CAIs and AOAs in metamorphosed CV and CO chondrites are isotopically heterogeneous with melilite, anorthite, perovskite, Zr- and Sc-rich oxides and silicates, and occasionally Al, Ti-diopside being O-16-depleted relative to hibonite, spinel, Al-diopside, and forsterite. The timing of generation of different O-isotope reservoirs and the nature of O-isotope heterogeneity in refractory inclusions in CO3 and CV3 chondrites are poorly known. Grossite (CaAl4O7) is one of the first minerals predicted to condense from a gas of solar composition and therefore it could have recorded isotopic compositions of reservoirs during the earliest stages of the Solar System evolution. Here we report on O-isotope compositions of grossite-rich CAIs in CH3 and CO3 chondrites measured in situ with the UH Cameca ims-1280. For analytical procedures see [9].

A N Krot↗
NASA NTRSDate not supplied

Analysis of Interlaminar Damage in Refractory Composites by In-Situ Micro-X-Ray Computed Tomography

Refractory composites are relevant for hot-structure applications on re-entry vehicles. To develop optimized high-performance hot structures, accurate material property data is required. Material properties that often limit design in two-dimensional (2-D) composites are interlaminar strengths. A better understanding of the failure mechanisms for interlaminar shear (ILS), interlaminar tension (ILT), and curved-beam interlaminar tension (CB-ILT) tests can provide insight on improving the design and fabrication of refractory composites. In-situ tests were performed to capture the progressive failure in American Society for Testing and Materials (ASTM) sized ILS (ASTM D3846), ILT (ASTM D7291), and CB-ILT (ASTM D6415) specimens. The present study investigates the change in material behavior by examining the macro porosity change in in-situ ILS tests, the mesoscale and inter-ply porosity changes in flatwise in-situ ILT tests and the change in per-ply delamination in in-situ CB-ILT tests.

In-situ Damage Characterization↗