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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Spacecraft oxygen recovery system

A system which uses an electrochemical carbon dioxide concentrator to remove carbon dioxide from the cabin atmosphere and a Sabatier reactor to reduce carbon dioxide with hydrogen to form methane and water is described. Oxygen is recovered from water by means of a static-feed water electrolysis system. The hydrogen thus generated is reused in the carbon dioxide concentrator. The methane is a system byproduct. The CO2 removal reactions and the implementation of the CO2 concentration concept are discussed, and test results are examined.

Quattrone, P. D.↗
NASA NTRS1975

Evaluation and characterization of the methane-carbon dioxide decomposition reaction

A program was conducted to evaluate and characterize the carbon dioxide-methane (CO2-CH4) decomposition reaction, i.e., CO2 + CH4 = 2C + 2H2O. The primary objective was to determine the feasibility of applying this reaction at low temperatures as a technique for recovering the oxygen (O2) remaining in the CO2 which exits mixed with CH4 from a Sabatier CO2 reduction subsystem (as part of an air revitalization system of a manned spacecraft). A test unit was designed, fabricated, and assembled for characterizing the performance of various catalysts for the reaction and ultraviolet activation of the CH4 and CO2. The reactor included in the test unit was designed to have sufficient capacity to evaluate catalyst charges of up to 76 g (0.17 lb). The test stand contained the necessary instrumentation and controls to obtain the data required to characterize the performance of the catalysts and sensitizers tested: flow control and measurement, temperature control and measurement, product and inlet gas analysis, and pressure measurement. A product assurance program was performed implementing the concepts of quality control and safety into the program effort.

Davenport, R. J.↗
NASA NTRS1972

Soot formation in the methane oxygen and methane/oxygen/hydrogen flame

The feasibility of using methane, recovered from carbon dioxide by the Sabatier-Senderens reaction, was investigated as a fuel in a reaction control engine. A problem to be avoided is the emission of soot particles. It is thought that such particles would remain in the environment of the spacecraft and, thereby, adversely affect optical sightings and possibly have an effect upon communications. The initial studies were of a practical nature. The first was the influence of the spatial arrangement of the fuel and oxygen injectors on soot formation. In the second study, inhibition of soot formation was considered. Considering the given situation, it was impractical to use an additive. However, since methanol combustion does not produce soot, and methanol can be produced from methane in situ, the possibility that methanol could act as an inhibitor was studied. In the third study, since these are restartable engines, the effect of shutdown on the rapidity of soot formation was studied.

Dauerman, L.↗
NASA NTRS1977

Regenerative Life Support Evaluation

This paper describes the development plan and design concept of the Regenerative Life Support Evaluation (RLSE) planned for flight testing in the European Space Agency Spacelab. The development plan encompasses the ongoing advanced life support subsystem and a systems integration effort to evolve concurrently subsystem concepts that perform their function and can be integrated with other subsystems in a flight demonstration of a regenerative life support system. The design concept for RLSE comprises water-electrolysis O2 generation, electrochemically depolarized CO2 removal, and Sabatier CO2 reduction for atmosphere regeneration, urine vapor-compression distillation, and wash-water hyperfiltration for waste-water recovery. The flight demonstration by RLSE is an important step in qualifying the regenerative concepts for life support in space stations.

Kleiner, G. N.↗
NASA NTRS1979

Bosch - An alternate CO2 reduction technology

The Bosch process is the most promising CO2 reduction concept for future prolonged space missions. The paper presents the design of a three-person-capacity preprototype B-CRS (Bosch-based CO2 Reduction Subsystem). It is sized to reduce 3.0 kg/d CO2 generated by the crew and to supply the product water to an O2 generation subsystem to obtain O2. The design supports future development of the B-CRS as an alternative CO2 reduction subsystem to the Sabatier-based process presently under test at NASA. The discussion covers the Bosch CO2 reduction concept, process and hardware description, performance parameters, design specifications, subsystem schematic and operation, mechanical subsystem summary, control/monitor instrumentation, and subsystem packaging. A B-CRS with a proven technological base is an attractive CO2 reduction subsystem that eliminates overboard venting.

Heppner, D. B.↗
NASA NTRS1980

Lightside Atmospheric Revitalization System

The system was studied as a replacement to the present baseline LiOH system for extended duration shuttle missions. The system consists of three subsystems: a solid amine water desorbed regenerable carbon dioxide removal system, a water vapor electrolysis oxygen generating system, and a Sabatier reactor carbon dioxide reduction system. The system is designed for use on a solar powered shuttle vehicle. The majority of the system's power requirements are utilized on the Sun side of each orbit, when solar power is available.

Colling, A. K.↗
NASA NTRS1983

Advanced air revitalization system testing

A previously developed experimental air revitalization system was tested cyclically and parametrically. One-button startup without manual interventions; extension by 1350 hours of tests with the system; capability for varying process air carbon dioxide partial pressure and humidity and coolant source for simulation of realistic space vehicle interfaces; dynamic system performance response on the interaction of the electrochemical depolarized carbon dioxide concentrator, the Sabatier carbon dioxide reduction subsystem, and the static feed water electrolysis oxygen generation subsystem, the carbon dioxide concentrator module with unitized core technology for the liquid cooled cell; and a preliminary design for a regenerative air revitalization system for the space station are discussed.

Heppner, D. B.↗
NASA NTRS1983

Integrated atmosphere revitalization system description and test results

The design and operation of several air revitalization subsystems are described, along with the testing of these subsystems separately and integrated in an air revitalization system for use in space stations. The subsystems are: one that generates O2 by water electrolysis, one that removes and concentrates CO2 using an electrochemical technique, and one that reduces concentrated CO2 by the Sabatier process. Results of the integrated testing include the observations that liquid cooling should be baselined for recovery of the CO2 reduction subsystem product water, continuous CO2 injection into the air supply unit is preferable, small changes in the current CO2 removal subsystem inlet PCO2 are detectable as changes in the CO2 reduction subsystem reactor temperatures, and hardwired shutdown of critical parameters is vital if computer-based controllers are not redundant. Several block diagrams are provided.

Martin, R. B.↗
NASA NTRS1984

Air Revitalization System integration

This paper presents a status review of Spacecraft Air Revitalization System (ARS) integration using regenerable techniques. The paper addresses concepts of integration of individual subsystems into an Air Revitalization System, as well as integration of components within subsystems. An ARS design is presented based on the Electrochemical Depolarized Carbon Dioxide Concentrator Subsystem, the Sabatier Carbon Dioxide Reduction Subsystem, the Static Feed Water Electrolysis Subsystem, a condensing Humidity Control Subsystem, and a Water Handling Subsystem to perform the functions of CO2 removal, CO2 reduction, O2 generation, humidity control and by-product water distribution, respectively. The paper also highlights the numerous advantages of this integration. Trace contaminant control and the nitrogen supply are not included in the ARS described in this paper.

Quattrone, P. D.↗
NASA NTRS1985

Initial development and performance evaluation of a process for formation of dense carbon by pyrolysis of methane

The three steps in pyrolytic carbon formation are: (1) gaseous hydrocarbon polymerization and aromatic formation; (2) gas-phase condensation and surface adsorption/impingement of polyaromatic hydrocarbon; and (3) final dehydration to carbon. The structure of the carbon in the various stages of formation is examined. The apparatuses and experimental procedures for the pyrolysis of methane in a 60 cm long quartz reactor tube at temperatures ranging from 1400-1600 K are described. The percentage of carbon converted and its density are calculated and tabularly presented. The results reveal that dense carbon formation is maximized and soot eliminated by this procedure. It is observed that conversion efficiency depends on the composition of the inlet gas and conversion increases with increasing temperature. Based on the experimental data a three-man carbon reactor subsystem (CRS) is developed; the functions of the Sabatier Methanation Reactor, two carbon formation reactors and fluid handling components of the CRS are analyzed. The CRS forms 16 kg of carbon at a rate of 0.8 kg/day for 20 days in a two percent volume density quartz wool packing at temperature of 1500-1600 K.

Noyes, G. P.↗
NASA NTRS1986

An advanced carbon reactor subsystem for carbon dioxide reduction

An evaluation is presented of the development status of an advanced carbon-reactor subsystem (ACRS) for the production of water and dense, solid carbon from CO2 and hydrogen, as required in physiochemical air revitalization systems for long-duration manned space missions. The ACRS consists of a Sabatier Methanation Reactor (SMR) that reduces CO2 with hydrogen to form methane and water, a gas-liquid separator to remove product water from the methane, and a Carbon Formation Reactor (CFR) to pyrolize methane to carbon and hydrogen; the carbon is recycled to the SMR, while the produce carbon is periodically removed from the CFR. A preprototype ACRS under development for the NASA Space Station is described.

Noyes, Gary P.↗
NASA NTRS1987

Preliminary experimental results of gas recycling subsystems except carbon dioxide concentration

Oxygen concentration and separation is an essential factor for air recycling in a controlled ecological life support system (CELSS). Furthermore, if the value of the plant assimilatory quotient is not coincident with that of the animal respiratory quotient, the recovery of oxygen from the concentrated CO2 through chemical methods will become necessary to balance the gas contents in a CELSS. Therefore, oxygen concentration and separation equipment using Salcomine and O2 recovery equipment, such as Sabatier and Bosch reactors, were experimentally developed and tested.

Otsuji, K.↗
NASA NTRS1988

Appendices to the model description document for a computer program for the emulation/simulation of a space station environmental control and life support system

A Model Description Document for the Emulation Simulation Computer Model was already published. The model consisted of a detailed model (emulation) of a SAWD CO2 removal subsystem which operated with much less detailed (simulation) models of a cabin, crew, and condensing and sensible heat exchangers. The purpose was to explore the utility of such an emulation simulation combination in the design, development, and test of a piece of ARS hardware, SAWD. Extensions to this original effort are presented. The first extension is an update of the model to reflect changes in the SAWD control logic which resulted from test. Also, slight changes were also made to the SAWD model to permit restarting and to improve the iteration technique. The second extension is the development of simulation models for more pieces of air and water processing equipment. Models are presented for: EDC, Molecular Sieve, Bosch, Sabatier, a new condensing heat exchanger, SPE, SFWES, Catalytic Oxidizer, and multifiltration. The third extension is to create two system simulations using these models. The first system presented consists of one air and one water processing system. The second consists of a potential air revitalization system.

Yanosy, James L.↗
NASA NTRS1988

Appendices to the user's manual for a computer program for the emulation/simulation of a space station environmental control and life support system

A user's Manual for the Emulation Simulation Computer Model was published previously. The model consisted of a detailed model (emulation) of a SAWD CO2 removal subsystem which operated with much less detailed (simulation) models of a cabin, crew, and condensing and sensible heat exchangers. The purpose was to explore the utility of such an emulation/simulation combination in the design, development, and test of a piece of ARS hardware - SAWD. Extensions to this original effort are presented. The first extension is an update of the model to reflect changes in the SAWD control logic which resulted from the test. In addition, slight changes were also made to the SAWD model to permit restarting and to improve the iteration technique. The second extension is the development of simulation models for more pieces of air and water processing equipment. Models are presented for: EDC, Molecular Sieve, Bosch, Sabatier, a new condensing heat exchanger, SPE, SFWES, Catalytic Oxidizer, and multifiltration. The third extension is to create two system simulations using these models. The first system presented consists of one air and one water processing system, the second a potential Space Station air revitalization system.

Yanosy, James L.↗
NASA NTRS1988

Air and water quality monitor assessment of life support subsystems

Preprotype air revitalization and water reclamation subsystems (Mole Sieve, Sabatier, Static Feed Electrolyzer, Trace Contaminant Control, and Thermoelectric Integrated Membrane Evaporative Subsystem) were operated and tested independently and in an integrated arrangement. During each test, water and/or gas samples were taken from each subsystem so that overall subsystem performance could be determined. The overall test design and objectives for both subsystem and integrated subsystem tests were limited, and no effort was made to meet water or gas specifications. The results of chemical analyses for each of the participating subsystems are presented along with other selected samples which were analyzed for physical properties and microbiologicals.

Whitley, Ken↗
NASA NTRS1993

Integrated oxygen recovery system

Life Systems has conceptualized an innovative Integrated Oxygen Recovery System (IORS) applicable to advanced mission air revitalization. The IORS provides the capability to electrochemically generate metabolic oxygen (O2) and recover O2 from the space habitat atmosphere via a carbon dioxide (CO2) reduction process within a single assembly. To achieve this capability, the IORS utilizes a Solid Metal Cathode (SMC) water electrolysis unit that simultaneously serves as the Sabatier CO2 reduction reactor. The IORS enables two major life support systems currently baselined in closed loop air revitalization systems to be combined into one smaller, less complex system. This concept reduces fluidic and electrical interface requirements and eliminates a hydrogen (H2) interface. Life Systems is performing an evaluation of the IORS process directed at demonstrating performance and quantifying key physical characteristics including power, weight, and volume. Technical progress achieved during the first two months of the program is summarized.

Lee, M. Gene↗
NASA NTRS1993

Integrated oxygen recovery system

Life Systems has conceptualized an innovative Integrated Oxygen Recovery System (IORS) applicable to advanced mission air revitalization. The IORS provides the capability to electrochemically generate metabolic oxygen (O2) and recover O2 from the space habitat atmosphere via a carbon dioxide (CO2) reduction process within a single assembly. To achieve this capability, the IORS utilizes a Solid Metal Cathode (SMC) water electrolysis unit that simultaneously serves as the Sabatier CO2 reduction reactor. The IORS enables two major life support systems currently baselined in closed loop air revitalization systems to be combined into one smaller, less complex system. This concept reduces fluidic and electrical interface requirements and eliminates a hydrogen (H2) interface. Life Systems is performing an evaluation of the IORS process directed at demonstrating performance and quantifying key physical characteristics including power, weight, and volume. The results of the checkout, shakedown, and initial parametric tests are summarized.

Lee, M. Gene↗
NASA NTRS1994

Project Genesis: Mars in situ propellant technology demonstrator mission

Project Genesis is a low cost, near-term, unmanned Mars mission, whose primary purpose is to demonstrate in situ resource utilization (ISRU) technology. The essence of the mission is to use indigenously produced fuel and oxidizer to propel a ballistic hopper. The Mars Landing Vehicle/Hopper (MLVH) has an Earth launch mass of 625 kg and is launched aboard a Delta 117925 launch vehicle into a conjunction class transfer orbit to Mars. Upon reaching its target, the vehicle performs an aerocapture maneuver and enters an elliptical orbit about Mars. Equipped with a ground penetrating radar, the MLVH searches for subsurface water ice deposits while in orbit for several weeks. A deorbit burn is then performed to bring the MLVH into the Martian atmosphere for landing. Following aerobraking and parachute deployment, the vehicle retrofires to a soft landing on Mars. Once on the surface, the MLVH begins to acquire scientific data and to manufacture methane and oxygen via the Sabatier process. This results in a fuel-rich O2/CH4 mass ratio of 2, which yields a sufficiently high specific impulse (335 sec) that no additional oxygen need be manufactured, thus greatly simplifying the design of the propellant production plant. During a period of 153 days the MLVH produces and stores enough fuel and oxidizer to make a 30 km ballistic hop to a different site of scientific interest. At this new location the MLVH resumes collecting surface and atmospheric data with the onboard instrumentation. Thus, the MLVH is able to provide a wealth of scientific data which would otherwise require two separate missions or separate vehicles, while proving a new and valuable technology that will facilitate future unmanned and manned exploration of Mars. Total mission cost, including the Delta launch vehicle, is estimated to be $200 million.

Acosta, Francisco Garcia↗