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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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102 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

The 100 pc White Dwarf Sample in the SDSS Footprint

In this work, we present follow-up spectroscopy of 711 white dwarfs within 100 pc, and we present a detailed model atmosphere analysis of the 100 pc white dwarf sample in the Sloan Digital Sky Survey footprint. Our spectroscopic follow-up is complete for 83% of the white dwarfs hotter than 6000 K, where the atmospheric composition can be constrained reliably. We identify 1508 DA white dwarfs with pure hydrogen atmospheres. The DA mass distribution has an extremely narrow peak at 0.59 M ⊙ and reveals a shoulder from relatively massive white dwarfs with M = 0.7–0.9 M ⊙. Comparing this distribution with binary population synthesis models, we find that the contribution from single stars that form through mergers cannot explain the overabundance of massive white dwarfs. In addition, the mass distribution of cool DAs shows a near absence of M > 1 M ⊙ white dwarfs. The pile-up of 0.7–0.9 M ⊙ and the disappearance of M > 1 M ⊙ white dwarfs is consistent with the effects of core crystallization. Even though the evolutionary models predict the location of the pile-up correctly, the delay from the latent heat of crystallization by itself is insufficient to create a significant pile-up, and additional cooling delays from related effects like phase separation are necessary. We also discuss the population of infrared-faint (ultracool) white dwarfs and demonstrate for the first time the existence of a well-defined sequence in color and magnitude. Curiously, this sequence is connected to a region in the color–magnitude diagrams where the number of white dwarfs with a helium-dominated atmosphere is low. This suggests that the infrared-faint white dwarfs likely have mixed H/He atmospheres.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

High-spectral-resolution X-Ray Observations of the Evolved Supermassive Stellar Binary System η Carinae: Fe K α Band Profile Revealed with XRISM

The supermassive binary system, η Carinae, is experiencing enormous wind-driven mass loss at a rate unparalleled in the rest of the Galaxy. Their wind–wind collision (WWC) continuously produces shock heated, X-ray-emitting plasmas. The XRISM X-ray observatory observed the system in 2023 and 2024 when the X-ray emission began to increase toward periastron passage in 2025. This paper reports unprecedentedly high-resolution X-ray spectra in the Fe Kα band between 6.2 and 7.1 keV, obtained with the Resolve X-ray microcalorimeter. The hydrogen-like (Lyα) and helium-like (Heα) lines reveal three velocity components. Two of them are broadened with maximum velocities of 2000–3000 km s −1 , likely originating from the postshock companion wind. The other is relatively narrow, with a Gaussian broadening of only ∼290 km s −1 in 1σ, which may originate from the postshock companion wind at the WWC stagnation point or penetrating the primary wind. The Fe fluorescent lines exhibit a moderate blueshift and broadening with velocities at 100–200 km s −1 , consistent with the primary wind’s velocity field. The spectra also confirm a Compton shoulder of the Heα line complex for the first time. Both fluorescing and scattering spectral profiles indicate that the binary system is seen from the companion side during these observations. The flux ratio of the Compton-scattering emission to the fluorescent line suggests substantial hydrogen depletion of the primary wind, expected from CNO-cycled hydrogen nuclear fusion gas.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Improved ELMv1-ECA simulations of zero-curtain periods and cold-season CH 4 and CO 2 emissions at Alaskan Arctic tundra sites

Field measurements have shown that cold-season methane (CH 4 ) and carbon dioxide (CO 2 ) emissions contribute a substantial portion to the annual net carbon emissions in permafrost regions. However, most earth system land models do not accurately reproduce cold-season CH 4 and CO 2 emissions, especially over the shoulder (i.e., thawing and freezing) seasons. Here we use the Energy Exascale Earth System Model (E3SM) land model version 1 (ELMv1-ECA) to tackle this challenge and fill the knowledge gap of how cold-season CH 4 and CO 2 emissions contribute to the annual totals at Alaska Arctic tundra sites. Specifically, we improved the ELMv1-ECA soil water phase-change scheme, environmental controls on microbial activity, and the methane module. Results demonstrate that both soil temperature and the duration of zero-curtain periods (i.e., the fall period when soil temperatures linger around 0°C) simulated by the updated ELMv1-ECA were greatly improved; e.g., the mean absolute error (MAE) in zero-curtain durations at 12 cm depth was reduced by 62 % on average. Furthermore, the MAEs of simulated cold-season carbon emissions at three tundra sites were improved by 72 % and 70 % on average for CH 4 and CO 2 , respectively. Overall, CH 4 emitted during the early cold season (September and October), which often includes most of the zero-curtain period in Arctic tundra, accounted for more than 50 % of the total emissions throughout the entire cold season (September to May) in the model, compared with around 49.4 % (43 %–58 %) in observations. From 1950 to 2017, both CO 2 emissions during the zero-curtain period and during the entire cold season showed increasing trends, for example, of 0.17 and 0.36 gC m -2 yr -1 at Atqasuk. This study highlights the importance of zero-curtain periods in facilitating cold-season CH 4 and CO 2 emissions from tundra ecosystems.

58 GEOSCIENCES↗
DOE OSTI2020

NGEE Arctic Plant Traits: Plant Community Composition, Kougarok Road Mile Marker 64, Seward Peninsula, Alaska, 2016

This dataset reports the characteristics of the dominant vegetation communities at the NGEE Arctic Kougarok field site, Kougarok Road Mile Marker 64 on the Seward Peninsula. Selected plots were surveyed from 18-23 July 2016. Environmental data (e.g., elevation, slope, soil moisture regime, disturbance type and degree, mean canopy height, etc.) were also recorded for each plot. Elevation measurements were updated 2020-08-18. All plant species (vascular plants, bryophytes and lichens) were recorded along with their percent cover in the plots as determined visually by the lead author. Plots were chosen subjectively in areas of homogeneous and representative vegetation and varied in size from 1-25 m2 depending on canopy structure and height. The site is an east-facing hillslope with vegetation that varies from the summit to the toeslope. The 30 total plots were selected as five replicate plots sampled from each of the six identified habitat types: 1) non-acidic mountain complex at the hillcrest, 2) dwarf-shrub lichen tundra on the shoulder, 3) alder shrublands predominantly on an elevational band across the backslope, 4) willow-birch tundra on the upper backslope, 5) tussock tundra on the footslope in inter-water tracks, and 6) tussock tundra mixed with willow-birch tundra or alder savanna in poor developed water tracks on the footslope. This dataset is comprised of two comma-separated (*.csv) files containing species and environmental data for the plant community composition plots. It also contains seven zipped folders of plot photographs, one map showing plot locations (*.pdf), one blank datasheet with the key to codes used in the field (*.pdf), select photos organized in a (*.pdf), and one User file (*.pdf). The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Composite drill pipe

A metal to composite tube joint including an elongated interior fitting constructed with an exterior barrel, reduced in exterior diameter to form a distally facing annular shoulder and then projecting still further distally to form an interior sleeve having a radially outwardly facing bonding surface. An elongated metal outer sleeve formed proximally with a collar constructed for receipt over the barrel and increased in interior diameter and projecting distally to form an exterior sleeve having a radially inwardly facing bonding surface cooperating with the first bonding surface to form an annulus receiving an extremity of a composite tube and a bond bonding the extremity of the tube to the bonding surfaces.

Leslie, James C.↗
DOE OSTI2021

Configurable vehicle seat and method therefor

A conformal seat insert for an adjustable vehicle seat, the conformal seat insert comprising an insert frame, the insert frame having one or more insert reference features for locating the insert frame on a seat frame of the vehicle seat in a predetermined position relative to the seat frame, and a contoured support surface formed in the insert frame, the contoured support surface having a crew reference point corresponding to an acromial point of a shoulder of a seat occupant of the adjustable vehicle seat, the crew reference point being a datum from which an eye position of the seat occupant is established relative to instrumentation of an aerospace vehicle in which the adjustable vehicle seat is located.

McCarley, Michael C.↗
DOE OSTI2022

Illuminating the Photophysics of Oxygen Atom Transfer in Rare Earth Metal-Organic Complexes

Industrial separations of rare earth metals are reliant on selectivity based on ionic radii, which are time, energy, and resource consuming.1 The unique and discontinuous manifold of energy states associated with the f-electron configurations of the rare earth ions2 offer an opportunity to overcome some of these limitations by incorporating light into the separation process. Here, we use transient absorption spectroscopy to understand the differences in mechanism of light-initiated oxygen atom transfer (OAT) in yttrium (Y) and dysprosium (Dy) rare earth complexes. These metal-organic complexes are functionalized with hexfluoroacetyl-acetonate (hfac) and 4-methylmorpholine-N-oxide (NMMO). After light absorption in the presence of triphenyl phosphine (TPP), the NMMO in the Y-NMMO complex is replaced by the TPPO OAT reaction product. Because the Dy f-electron manifold is accessible to the ligand excited states, while there are no accessible states associated with f-electrons for Y, there are significant differences in reactivity. Transient absorption spectroscopy (TAS) was used to monitor changes after 340 nm photoexcitation of Dy/Y-NMMO or the product complex Dy/Y-TPPO. TAS is a pump-probe technique where a white light probe pulse is delayed relative to a visible pump pulse, which photoexcites a sample. Differences between the ground and excited states are monitored over time. With TAS, we access time scales from 100 fs-400 us to determine the photophysics of the complexes of interest. Photoexcitation of Y-NMMO (Fig. 1A) creates a broad photoinduced absorption (PIA) that evolves into a sharp positive feature over 4.2 ps centered at 450 nm. A secondary feature centered at 550 nm grows in with a 200 ps time constant and remains through the 5 ns time window of our experiment. Control experiments for Y-TPPO reveal that the feature at 450 nm is due to internal dynamics of the hfac ligand, while the 550 nm shoulder is due to the presence of the NMMO. Comparing kinetics at 550 nm for Y-NMMO and Dy-NMMO (Fig. 1B) shows that while Y exhibits a distinct growth in the NMMO feature, the Dy decays almost completely within 5 ns. Control experiments with Dy-TPPO prove that the ligand excited states centered on the hfac ligand are deactivated via energy transfer to the Dy manifold within 200 ps. This deactivation leads to significant differences in OAT reactivity between Y and Dy.

CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS↗
DOE OSTI2024

Grid-connected heat pump water heater benefits for low-income households in the Southeastern United States

Energy efficient heat pump water heaters (HPWHs) reduce customer energy costs; grid-connected controls further increase HPWH value by enabling energy storage and shifting demand to cheaper, off-peak periods. However, a HPWH’s first cost premium can put it out of reach for low-income customers. This paper will present results of an ongoing study exploring the benefits of load shifting HPWHs for 24 low-income households, aiming to support increased product deployment in this demographic. The study uses EcoPort modules to shift HPWH load for a study sample consisting primarily of low-income adults and seniors in North Carolina. Building upon prior studies, the study’s HPWH operating schedules are designed to maximize shifted energy and minimize participant electricity costs based on local time-of-use rates. The study documents load profiles of grid-connected HPWHs in a less-studied demographic group and explores how certain groups may have particularly flexible loads due to their unique usage profiles. The results are relevant for HPWH product performance in the Southeast. The study will quantify HPWH load shifting performance during North Carolina’s hot summer, temperate shoulder, and occasionally sub-freezing winter seasons, and the study includes installations in conditioned, semi-conditioned, and unconditioned spaces. Finally, study results will also explore how controlled HPWHs can provide value to the regional grid by reducing seasonal peaks via demand response. Lessons learned include HPWH acceptance for low-income and senior users, best practices for maintaining HPWH connectivity among users without prior product experience, and strategies to leverage remote monitoring to ensure optimal operation and enhance HPWH reliability.

Urigwe, Daniela↗
DOE OSTI2024

Performance Assessment of a Dual-purpose HP-TES for a Typical Year Comparing Different Climate Zones

Complete electrification of heating and cooling systems in the United States would overload the existing electrical grid. To this end, recent research efforts have focused on energy storage as one way to reduce ever-increasing peak electricity demands. One such technology is heat pump integrated thermal-energy storage (HP-TES) systems, which can enable load-shifting and reduce demand during peak hours. In this work, a Modelica model of a 4-Ton, dual-mode (heating and cooling) HP-TES system using a room-temperature phase-change material (PCM) integrated through a secondary hydronic loop was developed and simulated for a typical meteorological year in Riverside, CA (ASHRAE Climate Zone 2B), and Chicago, IL (ASHRAE Climate Zone 5A), for a DOE small office prototype building. The COP improvement and demand reduction were analyzed during the time-of-use peak hours along with the required recharge cycle energy demand. A typical summer in Riverside, CA resulted in model-predicted peak COP increases of 50 – 100% compared to the baseline heat pump, especially at higher outdoor temperatures, coupled with maximum peak energy reductions of 22%. During shoulder and winter season simulations, heating energy savings were higher as outdoor temperatures dropped below the PCM phase change temperature. For Chicago, IL, backup heating was necessary to meet the required system capacity for very cold ambient conditions, resulting in winter peak energy savings between 16 – 60% when accounting for backup heating requirements. The recharge energy was found to be mostly below the baseline HP energy during the peak. With improved component selections and controls, the recharge energy may be reduced. The outcomes from the simulations can provide first-order estimates for potential peak energy savings, challenges, and required controls in any location before conducting any field testing.

25 ENERGY STORAGE↗
DOE OSTI2024

Energy Saving Estimation of ASHRAE Guideline 36 Supervisory Setpoint Reset Controls in a Commercial Large Office Building

Designing, commissioning, and retrofitting HVAC control systems for energy efficiency is crucial, but the use of ad-hoc control sequences by designers and contractors, based on scattered information, results in diverse and sub-optimal sequences. ASHRAE Guideline 36 (G36) addresses the challenge by providing standardized, rule-based HVAC control sequences that prioritize energy efficiency. However, there is limited evaluation of their energy performance at the building level, with only a few studies primarily focused on HVAC airside systems in small-to-medium-sized commercial buildings. In this study, the energy performance of ASHRAE Guideline 36 control sequences was assessed using a large office building emulator in Chicago. The emulator features a central plant system with multiple chillers and boilers as well as multiple variable air volume (VAV) systems with terminal reheat. To achieve a high-fidelity representation, we developed a Spawn-of-EnergyPlus-based model for the large office building, maintaining the DOE prototype large office building setup but substituting the HVAC system with its Modelica counterpart. This substitution ensures that the building thermal load, HVAC system's dynamics, and detailed control sequences are all accurately represented. The study involved evaluating and implementing control strategies outlined in ASHRAE Guideline 36-2021 to replace conventional controls. These strategies include the demand-based supply air temperature and duct static pressure setpoint reset and the request logic for demand-based reset of chilled/hot water supply temperature setpoints and pipe static pressure setpoints. Energy performance was evaluated under various load conditions, including cooling, heating, and transitional seasons, both for individual control strategies and in combination. The results indicate that the collective control strategies retrofit yield greater energy savings than the sum of individual strategies, highlighting the synergistic benefits of incorporating both airside and plant-side control retrofits. Additionally, energy savings of up to 41% in the heating season, 18% in the shoulder season, and 20 % in the cooling season were observed compared to baseline control while maintaining the thermal comfort level.

ASHRAE Guideline 36, Commercial buildings, Control↗
DOE OSTI2022

In vivo hypermutation and continuous evolution

Directed evolution has revolutionized biomolecular engineering by applying cycles of mutation, amplification and selection to genes of interest (GOIs). However, classical directed evolution methods that rely on manually staged evolutionary cycles constrain the scale and depth of the evolutionary search that is possible. Here we describe genetic systems that achieve cycles of rapid mutation, amplification and selection fully inside living cells, enabling the continuous evolution of GOIs as cells grow. These systems advance the scale, evolutionary search depth, ease and overall power of directed evolution and access important new areas of protein evolution and engineering.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

The immune-evasive proline-283 substitution in influenza nucleoprotein increases aggregation propensity without altering the native structure

Nucleoprotein (NP) is a key structural protein of influenza ribonucleoprotein complexes and is central to viral RNA packing and trafficking. NP also determines the sensitivity of influenza to myxovirus resistance protein 1 (MxA), an innate immunity factor that restricts influenza replication. A few critical MxA-resistant mutations have been identified in NP, including the highly conserved proline-283 substitution. This essential proline-283 substitution impairs influenza growth, a fitness defect that becomes particularly prominent at febrile temperature (39°C) when host chaperones are depleted. Here, we biophysically characterize proline-283 NP and serine-283 NP to test whether the fitness defect is caused by the proline-283 substitution introducing folding defects. We show that the proline-283 substitution changes the folding pathway of NP, making NP more aggregation prone during folding, but does not alter the native structure of the protein. These findings suggest that influenza has evolved to hijack host chaperones to promote the folding of otherwise biophysically incompetent viral proteins that enable innate immune system escape.

60 APPLIED LIFE SCIENCES↗