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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal–Organic Frameworks

The isoreticular expansion and functionalization of charged-polarized porosity has been systematically explored by the rational design of 11 isostructural zwitterionic metal-organic frameworks (ZW-MOFs). This extended series of general structural composition {[M 3 F(L1) 3 (L2) 1.5 ]·guests} n was prepared by employing the solvothermal reaction of Co and Ni tetrafluoroborates with a binary ligand system composed of zwitterionic pyridinium derivatives and traditional functionalized ditopic carboxylate auxiliary ligands (HL1·Cl = 1-(4-carboxyphenyl)-4,4'-bipyridinium chloride, Hcpb·Cl; or 1-(4-carboxyphenyl-3-hydroxyphenyl)-4,4'-bipyridinium chloride, Hchpb·Cl; and H 2 L2 = benzene-1,4-dicarboxylic acid, H 2 bdc; 2-aminobenzene-1,4-dicarboxylic acid, H 2 abdc; 2,5-dihydroxy-1,4-benzenedicarboxylic acid, H 2 dhbdc; biphenyl-4,4'-dicarboxylic acid, H 2 bpdc; or stilbene-4,4'-dicarboxylic acid, H 2 sdc). Single-crystal structure analyses revealed cubic crystal symmetry ( I -43 m , a = 31-36 Å) with a 3D pore system of significant void space (73-81%). The pore system features three types of pores being systematically tunable in size ranging from 17.4 to 18.8 Å (pore I), 8.2 to 12.8 Å (pore II), and 4.8 to 10.4 Å (pore III) by the choice of auxiliary ligands. All members of this series have noninterpenetrating structures and exhibit robust architectures, as evidenced by their permanent porosity and high thermal stability (up to 300 °C). The structural integrity and specific surface areas could be systematically optimized using supercritical CO 2 exchange methods for framework activation resulting in BET surface areas ranging from 1250 to 2250 m 2 /g. Most interestingly, as a structural landmark, we found the pore surfaces lined with charge gradients employed by the pyridinium ligands. This key feature results in significant adsorption of carbon dioxide and methane which is attributed to polarization effects. With this contribution we pioneer the reticulation of pyridinium building blocks into extended zwitterionic networks in which specific properties can be targeted.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Penetration of Ar and He RF-driven plasma jets into micrometer-sized capillary tubes

The penetration and propagation of cold atmospheric pressure plasmas into volumes having sub-millimeter to micrometer sizes with large aspect ratios is required for enabling an effective disinfection of the inside of catheter tubes, tooth cavities, skin pores and enhance plasma catalysis in porous catalysts. Here, we report on a study using a low voltage RF driven argon and helium plasma jets with the plasma generation outside a capillary tube with a large aspect ratio followed by its penetration and propagation inside the capillary. We present the experimental determination of the limitations on the penetration diameter, and the underpinning mechanisms of the plasma propagation and penetration process. Experimental results include time resolved imaging of plasma propagation and penetration in capillaries with different internal diameter and surface electric field measurements. We found that the time between the plasma jet in first contact with the capillary tube surface and the subsequent penetration into the capillary tube spans several RF cycles due to electric fields at the plasma-tube interface below 4 kV cm –1 . These low electric fields require Penning ionization and/or stepwise ionization and hence a buildup of the metastable and electron density is required to achieve a sufficiently large ionization rate near the capillary tube inlet to enable penetration and propagation. Furthermore, it is found that the propagation of the argon jet into the capillary occurs during the positive half cycle of the RF waveform and is very similar to the propagation of the jet in surrounding air.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1995

Effect of particle size and particle size distribution on physical characteristics, morphology and crystal structure of explosively compacted high-T(sub c) superconductors

A superconductor, of composition Y(Ba,K,Na)2Cu3O(x)/F(y) and a composite of composition Y(Ba,K,Na)2Cu3O(x)/F(y) + Ag, with changing K, Na and F content but a constant silver content (Ag = 10 mass%) was prepared using a single heat treatment. the resulting material was ground in a corundum lined mill, separated to particle size fractions of 0-40 micron, 0-63 micron and 63-900 micron and explosively compacted, using an explosive pressure of 10(exp 4) MPa and a subsequent heat treatment. Best results were obtained with the 63-900 micron fraction of composition Y(Ba(1.95) K(0.01)Cu3O(x)F(0),(05)/Ag: porosity less than 0.01 cu cm/g and current density 2800 A/sq cm at 77K.

Kotsis, I.↗
NASA NTRS2011

Light Scattering by Wavelength-Sized Particles "Dusted" with Subwavelength-Sized Grains

The numerically exact superposition T-matrix method is used to compute the scattering cross sections and the Stokes scattering matrix for polydisperse spherical particles covered with a large number of much smaller grains. We show that the optical effect of the presence of microscopic dust on the surfaces of wavelength-sized, weakly absorbing particles is much less significant than that of a major overall asphericity of the particle shape.

Mishchenko, Michael I.↗
DOE OSTI2018

The impact of alternative land and yield assumptions in herbaceous biomass supply modeling: one-size-fits-all resource assessment?: One-size-fits-all resource assessment?

The Billion-ton Reports series has addressed the technical economic potential of supplying additional biomass from farmland and forests.Underlying each of the reports and supporting scenarios is a series of assumptions that drive the modeled output. The assumptions have developed over time with the support of technical experts from industry, academia, and government. Energy crops have not yet reached commodity scale, and only exist in commercial production in a limited number of regions, so many of the key assumptions of biomass potential are not supported by commercial demonstrations across multiple regions. This report examines the biomass potential of herbaceous energy crops from US farmland when alternative assumptions concerning production are modeled. In particular, the assumption of energy grasses, both perennial and annual, is modified with respect to land eligibility, annual rotations, and yield growth. The results of these changes are presented in six scenarios – three of which are modifications to the base-case scenario and three to the high-yield scenario. Finally, the impact on land enrolled and biomass supply are discussed with respect to the most recent 2016 Billion-ton Report results.

09 BIOMASS FUELS↗
DOE OSTI2025

Comprehensive Analysis of the Relative Dispersion of Droplet-Size Distributions and Their Relationships to Key Physical Fog Processes Under Different Aerosol Conditions and Evolutionary Stages

The relative dispersion of cloud and fog droplets has significant impacts on aerosol indirect effects, radiative transfer, and microphysical processes. However, previous studies have been mostly concerned with clouds, with limited studies on fog, particularly those that examine the combined influences of all key physical processes and their roles during fog evolution. As such, this study aims to conduct a comprehensive investigation by examining the relationships between relative dispersion and other microphysical variables, as well as the underlying microphysical and dynamic processes, based on field fog campaigns in polluted and clean conditions. In polluted fog, droplet concentrations are higher, leading to smaller droplets and increased dispersion. The correlation between dispersion and droplet volume-mean radius is positive in the polluted fog, but shifts to negative in clean fog. Here, we attribute the difference to various microphysical processes like aerosol activation, condensation, collision-coalescence, and entrainment-mixing. In polluted fog, high aerosol concentrations, low supersaturations, and strong turbulence (entrainment-mixing) provide suitable conditions for the simultaneous occurrence of droplet condensation and aerosol activation, resulting in a positive correlation between dispersion and volume-mean radius, especially during the fog formation stage. In contrast, during the mature stage in clean fog, condensation is dominant with weak aerosol activation leading to a negative correlation between relative dispersion and volume-mean radius. The collision-coalescence process is more active in the mature stage, increasing radii and leading to the negative correlation between dispersion and volume-mean radius. This result sheds new light on understanding the relative dispersion and mechanisms in fog under different aerosol backgrounds.

54 ENVIRONMENTAL SCIENCES↗