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104 records · Page 6

Monitoring Potential Transport of Radioactive Contaminants in Shallow Ephemeral Channels: FY2019

Desert Research Institute (DRI) conducted a field assessment of the potential for contaminated soil to be transported from the Smoky Site Contamination Area (CA) because of storm runoff. This activity supported U.S. Department of Energy (DOE) Environmental Management Nevada Program (EM NV) efforts to establish post-closure monitoring plans for the Smoky Site Soils Corrective Action Unit (CAU) 550. The work was intended to confirm the likely mechanism of transport and determine the meteorological conditions that might cause the movement of contaminated soils, as well as determine the particle size fraction most closely associated with transported radionuclide-contaminated soils. These data will facilitate the design of the appropriate post-closure monitoring program. In 2011, DRI installed a meteorological monitoring station on the west side of the Smoky Site CA and a hydrologic (runoff) monitoring station within the CA, near the east side. The meteorological station collected air temperature, wind speed, wind direction, relative humidity, precipitation, solar radiation, barometric pressure, soil temperature, and soil water content data. The maximum, minimum, and average or total values (as appropriate) for each of these parameters were recorded for each 10-minute interval. The maximum, minimum, and average water depth in the flume installed at the hydrologic station were also recorded for each 10-minute interval. This report presents the data collected from these stations during fiscal year (FY) 2019. During the FY2019 reporting period, the warmest months were June, July, and August and the coldest were December and February. The highest monthly solar radiation (i.e., sunshine) values were recorded in June, July, and August, whereas December through February had the lowest solar radiation values. Monthly mean wind speeds were highest in the spring (April) and early summer (June). Winds were predominantly from the north, except in February, July, August, and September when winds were mostly from the west. The monthly average relative humidity ranged from 17 percent to approximately 60 percent. Humidity was lowest in the summer and highest in the winter. Monthly total precipitation ranged from 0.0 during August and September to 2.22 inches (in) (56.39 millimeters [mm]) in February. Total precipitation for FY2019 was 7.83 in (198.88 mm). During the reporting period, a single, nonzero, flow event was recorded at the flume. This occurred over two days between March 6 and 7, 2019, in response to 1.16 in (29.46 mm) of precipitation falling within 9.3 hours on March 6, 2019. This event produced a peak water depth of 0.39 in (0.99 centimeters [cm]) in the flume, and runoff was measured for approximately 23.5 hours. However, the maximum recorded flow depth was less than the limit for flow discharge and velocity that can be calculated for the six-inch (15 cm) throat of a Parshall flume. The runoff event produced insufficient flow velocities through the natural channel to cause local erosion and transport of bedload materials. No bedload samples were collected for radiological analysis. Observing meteorological and environmental conditions that lead to storm runoff will help identify the parameters and threshold conditions that should be incorporated into post-closure monitoring plans for this and similar Soils CAU sites. Routine monitoring of meteorological and hydrologic parameters at the Smoky Site CA has been discontinued at the request of EM NV, effective at the conclusion of FY2019. Environmental data acquisition was completed and the meteorological and runoff monitoring stations were removed from the Smoky Site on October 15, 2019.

54 ENVIRONMENTAL SCIENCES↗

The impact of tillage row orientation on physical and chemical sediment enrichment

Abstract This study aimed to better understand how tillage row orientation with respect to dominant flow‐pathway along hillslope impacts runoff and the transport of different sediment size fractions. Experimental plots were constructed in contour ridge till (CRT) and parallel ridge till (PRT) sites to monitor runoff and sediment fluxes. Particle size fractions of the sediment, along with organic C and N contents were measured to quantify physical and chemical enrichment ratios for the two tillage orientations. In the CRT plot, tillage produced large oriented roughness elements along the contours, which acted as little check dams, while in the PRT site, the roughness elements helped confine and concentrate the runoff. In the CRT, the “check dams” resulted in a runoff coefficient of .03, while in the PRT, the flow confinement between rows produced a runoff coefficient of .82. Moreover, the erosion rates at the CRT site were 97% less than those in the PRT plot. Large contours produced finer sediment fractions due to the selective sorting in ponded furrows. More aggregate sediment fractions were present in the PRT site, which was dominated by rill erosion. Physical enrichment revealed selective entrainment of finer sediment particles during erosion. Finer‐grain particles with higher specific surface areas, attached more organic C resulting in chemical enrichment. Physical and chemical enrichment methods were found to be in good agreement. These findings suggest transport models that can simulate size fraction updates to the soil active layer can be used to estimate SOC redistribution and hence more accurate C budgets.

Wacha, Kenneth M.↗

Observations and Machine-Learned Models of Near-Surface Permafrost along the Koyukuk River, Alaska, USA

This dataset contains GeoTIFs (raster) and GeoPackages (vector) that map observations of near-surface permafrost and not-permafrost from a field campaign conducted near the village of Huslia, AK along the Koyukuk River and its floodplain in July 2018. These data were collected as part of a campaign to understand if and how permafrost impacts riverbank erosion. This problem cannot be assessed without knowing where permafrost exists. Permafrost was observed via frost probing (to a maximum depth of one meter), coring (to a maximum depth of two meters) and bank/bar excavations. An additional boat survey was performed wherein expert (Joel Rowland) judgment assessed the presence or absence of distinctive permafrost features (e.g., overhanging tundra mats, thermoerosional niching, ice wedges, active drainage of ice melt from soils). This dataset also contains the input features and results of two machine learning models (random forest and convolutional neural network) that extrapolate the observations to the full floodplain that may be useful for building, testing, or validating other machine-learned permafrost models. Permafrost data are provided as georasters of the same shape and geovectors (polylines/polygons) and are all projected into EPSG:32605. All data can be visualized with a GIS (QGIS, ArcGIS, etc.).

54 ENVIRONMENTAL SCIENCES↗

How profitable is switchgrass in Illinois, USA? An economic definition of marginal land

Decisions regarding the conversion of land from an existing crop to bioenergy crops are critical for the sustainable production of both food and fuels. This study seeks to establish criteria for delineating land as “economically marginal”, and thus suited for growing switchgrass. In this case study of an Illinois agricultural field, the profitability of switchgrass, with farmgate prices of $\$44$ Mg –1 , $\$66$ Mg –1 , or $\$88$ Mg –1 , was compared to corn and soybean crop prices. Further, the study also evaluates the profitability of switchgrass when replacing corn-based yield estimates from the Soil Productivity Index (SPI) of Illinois. Based on a dry-matter yield of 10.45 Mg ha –1 , switchgrass can compete with soybeans only at the high price of $\$88$ Mg –1 , but depending on location, can compete with corn at $\$66$ Mg –1 . Across Illinois, at $\$88$ ha –1 , all Illinois land with SPI < 100% and 95% of land under SPI class C (SPI 100–116) is profitable under switchgrass. Switchgrass may not be profitable relative to corn grown in the SPI class A (SPI > 133) and only 7% of class B (SPI 117–132). Our results show that land with drainage and erosion limitations is economically marginal when corn and soybean yields are low, and the farmgate price for switchgrass is greater than $\$66$ Mg –1 . However, this may not be possible on land where switchgrass is replacing frequent soybean rotations (corn–soybean ratio ≤ 1). Land used to produce only soybeans may only be marginal at the farmgate price of $\$88$ Mg –1 . Further studies need to be conducted to identify how much land can be converted to switchgrass without harming corn production.

09 BIOMASS FUELS↗

Bulk density, grain size, carbon content and isotopes, and nitrogen content of floodplain sediment along the Koyukuk River, Alaska collected in Summer 2018.

The dataset is comprised of grain size, bulk density, carbon and nitrogen content, stable carbon isotopes, and radiocarbon content of soils sampled on the floodplain of the Koyukuk River near Huslia, AK. This dataset was collected to characterize sediment properties and floodplain organic carbon stocks in the discontinuous permafrost floodplain of the Koyukuk River. The data help quantify the flux and storage of sediment and carbon between the Koyukuk River and the surrounding floodplain as the river migrates laterally. The samples were collected in June 27 - July 9, 2018. The soil samples come from a total of 24 locations and were sampled in the upper 490 cm of the river cutbanks, point bars, and floodplain. Samples were analyzed for bulk density, full particle size distribution, nitrogen content and carbon content and isotopes, though not all samples were included in each analysis. An additional 10 samples of floodplain woody debris were measured for radiocarbon content. Data, detailed methods, analyses, and interpretations were previously published at: Douglas, M. M., Lingappa, U. F., Lamb, M. P., Rowland, J. C., West, A. J., Li, G., et al. (2021). Impact of river channel lateral migration on microbial communities across a discontinuous permafrost floodplain. Applied and Environmental Microbiology, 87(20), AEM.01339-21. https://doi.org/10.1128/AEM.01339-21 Douglas, M. M., Li, G. K., Fischer, W. W., Rowland, J. C., Kemeny, P. C., West, A. J., et al. (2022). Organic carbon burial by river meandering partially offsets bank erosion carbon fluxes in a discontinuous permafrost floodplain. Earth Surface Dynamics, 10(3), 421–435. https://doi.org/10.5194/esurf-10-421-2022 The dataset is comprised of a total of three separate data files based on the sample type and analysis, including a file that lists the sample locations, permafrost presence, and geomorphic landform.

54 ENVIRONMENTAL SCIENCES↗

Response of Stream Metabolism to Coarse Woody Debris Additions Along a Catchment Disturbance Gradient

We evaluated the ecological effectiveness of an in-stream restoration project involving coarse woody debris (CWD) additions to streams along an upland soil and vegetation disturbance gradient at the Fort Benning Military Installation near Columbus, GA. We examined short-term (immediate effectiveness) and longer-term (sustainability) responses to CWD additions by measuring ecosystem metabolism rates in 8 streams quarterly over a 6-year period, including 3 years before (2001–2003) and 3 years after (2004–2006) CWD additions that were made to half of the streams. Ecosystem respiration (ER) rates in most CWD addition streams increased relative to control streams from spring 2004 through autumn 2005, suggesting heterotrophic bacteria were the initial responders to CWD additions. Gross primary production (GPP) rates remained low (typically < 0.3 g O 2 m -2 d -1 ) but increased in some CWD addition streams relative to control streams in spring 2004 and 2005. The magnitude of ER increases in CWD addition streams during the first two years post-addition increased with catchment disturbance intensity, indicating that more heavily disturbed streams responded most strongly to restorations—an important consideration when targeting future restoration locations. Because restorations did not address actual upland disturbance, continued high erosion rates resulted in 32–77% of the added CWD being buried by year two and a corresponding return of GPP and ER rates to pre-CWD addition levels by year three. If restoration projects do not adequately address the source of catchment disturbances, CWD additions will provide only short-term increases in streambed structure and stability, hydrodynamic complexity, and nutrient and organic matter processing and retention.

54 ENVIRONMENTAL SCIENCES↗

Constraining Erosion Rates and Landscape Evolution With In Situ 10 Be and 26 Al Cosmogenic Nuclides at Table Mountain, Antarctica

Abstract This study investigates surface weathering and sediment preservation at Table Mountain, a high‐elevation, hyperarid, polar landscape in the Transantarctic Mountains. We report cosmogenic nuclide concentrations ( 10 Be and 26 Al) in quartz from bedrock surfaces, erratic boulder lag, and cobbles embedded within Sirius Group sediments to quantify erosion rates. In situ 10 Be and 26 Al depth profiles from a 2.95 m permafrost core in the Sirius Group further constrain surface erosion rates and elucidate landscape stability. Measured 10 Be and 26 Al concentrations from two sandstone bedrock surfaces adjacent to Sirius Group sediments give erosion rates of 0.18–0.28 m/Myr. An erratic sandstone boulder within the lag above the Sirius Group yields erosion rates of ∼0.42 ± 0.03 m/Myr, whereas two cobbles embedded within the Sirius Group yield higher rates of 0.81–1.12 m/Myr. Depth profiles of in situ 10 Be and 26 Al indicate no vertical mixing of Sirius Group permafrost since deposition. Depth profile models are best explained by erosion rates of 0.53 +0.13 / −0.12 m/Myr, and an exposure age of 0.78 +0.06 / −0.08 Ma. We view the model “age” to represent the ∼0.8‐million‐year time‐scale for surface lowering equivalent to one attenuation length of cosmic ray production to achieve steady‐state conditions. Continual exhumation of embedded clasts from within the Sirius Group results in an accumulation of clasts forming the observed erosional lag deposit covering the landscape. Our erosion rates of the Sirius Group surface based on in situ 10 Be and 26 Al depth profiles are an order‐of‐magnitude larger than those based on meteoric 10 Be infiltration and further clarification is required.

58 GEOSCIENCES↗

The Relationship Between Topography, Bedrock Weathering, and Water Storage Across a Sequence of Ridges and Valleys

Abstract Bedrock weathering regulates nutrient mobilization, water storage, and soil production. Relative to the mobile soil layer, little is known about the relationship between topography and bedrock weathering. Here, we identify a common pattern of weathering and water storage across a sequence of three ridges and valleys in the sedimentary Great Valley Sequence in Northern California that share a tectonic and climate history. Deep drilling, downhole logging, and characterization of chemistry and porosity reveal two weathering fronts. The shallower front is ∼7 m deep at the ridge of all three hillslopes, and marks the extent of pervasive fracturing and oxidation of pyrite and organic carbon. A deeper weathering front marks the extent of open fractures and discoloration. This front is 11 m deep under two ridges of similar ridge‐valley spacing, but 17.5 m deep under a ridge with nearly twice the ridge‐valley spacing. Hence, at ridge tops, the fraction of the hillslope relief that is weathered scales with hillslope length. In all three hillslopes, below this second weathering front, closed fractures and unweathered bedrock extend about one‐half the hilltop elevation above the adjacent channels. Neutron probe surveys reveal that seasonally dynamic moisture is stored to approximately the same depth as the shallow weathering front. Under the channels that bound our study hillslopes, the two weathering fronts coincide and occur within centimeters of the ground surface. Our findings provide evidence for feedbacks between erosion and weathering in mountainous landscapes that result in systematic subsurface structuring and water routing.

58 GEOSCIENCES↗

The Abrasion of Photovoltaic Glass: A Comparison of the Effects of Natural and Artificial Aging

Natural soiling and the subsequent requisite cleaning of photovoltaic (PV) modules result in abrasion damage to the cover glass. The durability of the front glass has important economic consequences, including determining the use of antireflective and/or antisoiling coatings as well as the method and frequency of operating maintenance (cleaning). The abrasion of coatings and glass has been explored in a field study, including the soiling-prone locations of Dubai (United Arab Emirates), Kuwait City (Kuwait), Mesa (Arizona), Mumbai (India), and Sacramento (California). Dry-brush-cleaned specimens will be compared to those subjected to artificial-brush testing. The characteristics of material integrity, surface energy, optical transmittance, surface roughness, and scratch size were examined using an optical microscope, contact goniometer (for water), spectrophotometer, interferometer, and atomic force microscope (AFM), respectively. The findings of this study will be used to provide feedback regarding the cleaning equipment, cleaning methods, and coatings used in the PV industry. The study here will also be used to aid in developing an abrasion standard for the PV industry.

14 SOLAR ENERGY↗

Supporting data for "Frozen flume experiments indicate rapid permafrost riverbank erosion depends on bank roughness"

This dataset contains supporting files detailing five frozen flume experiments conducted at the Caltech Earth Surface Dynamics Laboratory to investigate rates of ablation-limited permafrost riverbank erosion under controlled conditions. Water flowed past a bank of saturated, frozen sand and ice and gradually eroded the bank by thawing pore ice and immediately entraining sand and washing it downstream. Experiments were scaled for flow hydraulics and heat transfer allowing comparisons between our results and natural permafrost riverbanks. For each experiment, we measured the initial and final sand bank topography using a Keyence laser scanner, water surface slope at 3-min intervals throughout the experiment using a Massa sonar scanner, bank erosion using 10-sec overhead timelapse imagery taken by an overhead camera, water and bank temperature using thermistors frozen into the sand bank and sampling at 2 Hz, and water discharge using an in-line flow meter. We include calibration data for the carriage (engineered by the Saint Anthony Falls Laboratory) used to make sonar and laser topography measurements. We also include calibration data for temperature sensors, water discharge measurements, and images of a regular grid placed in the flume to align overhead camera images with the carriage datum. Grain size analysis for the channel bed (gravel) was produced using a pebble count and bank sand was measured using a Camsizer X2. In addition to the five frozen experiments, we include sonar scans of water surface slope and Keyence scans of bed and bank topography for calibration experiments ran with an immobile gravel bank and bed.

54 ENVIRONMENTAL SCIENCES↗

Antarctic permafrost processes and antiphase dynamics of cold-based glaciers in the McMurdo Dry Valleys inferred from 10 Be and 26 Al cosmogenic nuclides

Abstract. Soil and sediment mixing and associated permafrost processes are not widely studied or understood in the McMurdo Dry Valleys of Antarctica. In this study, we investigate the stability and depositional history of near-surface permafrost sediments to ∼ 3 m depth in the Pearse and lower Wright valleys using measured cosmogenic 10Be and 26Al depth profiles. In Pearse Valley, we estimate a minimum depositional age of ∼ 74 ka for the active layer and paleoactive-layer sediments (< 0.65 m). Combined depth profile modelling of 10Be and 26Al gives a depositional age for near-surface (< 1.65 m) permafrost in Pearse Valley of 180 +20/-40 ka, implying that the deposition of permafrost sediments predates MIS 5 advances of Taylor Glacier. Deeper permafrost sediments (> 2.09 m) in Pearse Valley are thus inferred to have a depositional age of > 180 ka. At a coastal, lower-elevation site in neighbouring lower Wright Valley, 10Be and 26Al depth profiles from a second permafrost core exhibit near-constant concentrations with depth and indicate the sediments are either vertically mixed after deposition or sufficiently young so that post-depositional nuclide production is negligible relative to inheritance. 26Al/10Be concentration ratios for both depth profiles range between 4.0 and 5.2 and are all lower than the nominal surface production rate ratio of 6.75, indicating that prior to deposition, these sediments experienced complex, yet similar, exposure–burial histories. Assuming a single-cycle exposure–burial scenario, the observed 26Al/10Be ratios are equivalent to a total minimum exposure–burial history of ∼ 1.2 Myr. In proximity to the depth profile core site, we measured cosmogenic 10Be and 26Al in three granite cobbles from thin, patchy drift (Taylor 2 Drift) in Pearse Valley to constrain the timing of retreat of Taylor Glacier. Assuming simple continuous exposure, our minimum, zero-erosion exposure ages suggest Taylor Glacier partially retreated from Pearse Valley no later than 65–74 ka. The timing of retreat after 65 ka and until the Last Glacial Maximum (LGM) when Taylor Glacier was at a minimum position remains unresolved. The surface cobble ages and permafrost processes reveal Taylor Glacier advances during MIS 5 were non-erosive or mildly erosive, preserving the underlying permafrost sediments and peppering boulders and cobbles upon an older, relict surface. Our results are consistent with U/Th ages from central Taylor Valley and suggest changes in moisture delivery over Taylor Dome during MIS 5e, 5c, and 5a appear to be associated with the extent of the Ross Ice Shelf and sea ice in the Ross Sea. These data provide further evidence of antiphase behaviour through retreat of a peripheral lobe of Taylor Glacier in Pearse Valley, a region that was glaciated during MIS 5. We suggest a causal relationship of cold-based glacier advance and retreat that is controlled by an increase in moisture availability during retreat of sea ice and perhaps the Ross Ice Shelf, as well as, conversely, a decrease during times of sea ice and Ross Ice Shelf expansion in the Ross Sea.

58 GEOSCIENCES↗

The weathered bedrock vadose zone: A hidden control on water availability in the western United States (Final Technical Report)

This report summarizes the research completed during the project entitled "The weathered bedrock vadose zone: A hidden control on water availability in the western United States" (Award: DE-SC0018039). The report covers work completed between 9/15/17 and 9/14/20. The objective of the exploratory project work was to evaluate the overarching hypothesis that the subsurface underlying actively eroding landscapes is systematically structured as a result of a balance between weathering and erosion and that this structure leads to dynamic moisture storage within weathered rock. To accomplish project objectives, we characterized hillslope weathering profile structure and conducted subsurface moisture monitoring across four study sites with comparable bedrock types but differing erosion rate and hydroclimate: The Angelo Coast Range Reserve (ACRR), Sagehorn-Russell Ranch (SRR), Antelope Valley Ranch (AVR), and the LBNL Watershed Function Scientific Focus Area (SFA). New characterization and monitoring infrastructure at the AVR and SFA sites was established through this project and enables long-term monitoring of hydrologic and carbon fluxes at the sites for comparison with long-term monitoring in other sites. Deep drilling, downhole logging, and characterization of chemistry and porosity of rock recovered from drilling reveals two weathering fronts across the sites. A shallower front is marked by the extent of pervasive fracturing and oxidation of pyrite and organic carbon. A deeper weathering front is marked by the appearance of open fractures and discoloration. At the AVR site, multiple ridge tops of different hillslope length were investigated to establish the relationship between the weathering front and topography. Drilling reveals that the fraction of the hillslope relief that is weathered scales with hillslope length, consistent with the theoretical framework that guided the project relating groundwater drainage with landscape evolution. With the establishment of new boreholes, we have documented significant water storage in weathered bedrock using low-field borehole nuclear magnetic resonance (NMR) across all four sites. In the upper 4 m of bedrock, the average water contents at ACRR, AVR, SRR, and SFA are approximately 25%, 16%, 25%, 23% respectively. At the ACRR site, where long-term monitoring via neutron probe surveys and time-domain transmission sensors are available, we have demonstrated that NMR reliably records moisture content and importantly, moisture content dynamics in weathered bedrock. Across all sites, our NMR monitoring has also revealed that a considerable fraction of the water storage occurs in fractures or pores that are significantly larger than the fine-grained bedrock matrix of the parent rock. To identify the proportion of water storage occurring in fractures and large pores, we analyzed the NMR signal by evaluating both the sum of echoes and an inversion of the NMR signal for a distribution of T2 relaxation times. Both methods reveal that at least 20% of the water storage occurs in fractures and larger pores across all sites. To constrain the interpretation of the in-situ field-scale NMR measurements, we compare the NMR response in the field to independent pore-structure information obtained via helium pycnometry. Results support the inference that dynamic seasonal water storage is dominantly restricted to the fracture network, which can reach 7% of the total volume. This dynamic range in water content is comparable to that of some soils, underscoring the need to understand how this region of the Earth System is structured, and functions as a hydrologic reservoir.

58 GEOSCIENCES↗