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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Elevated temperature strain gages

The objective is to study the electrical resistance of materials that are potentially useful as resistance strain gages at 1000 C. A set of criteria were set and used to select strain gage candidate materials that are electrically stable and reproducible at all temperatures up to 1000 C. For the experimental phase of this research, the electrical resistance change with temperature of three groups of materials (solid solution alloys, transition metal carbides, and semiconductors) were studied with the intention of identifying materials with low temperature coefficient of resistance and low resistance drift rate at 1000 C. A preliminary study of the gage factor on one of the best candidate materials, B sub 4 C, was also undertaken. The results of these investigations are presented.

Lei, J. F.↗

The Origin of Dark Inclusions in Allende: New Evidence from Lithium Isotopes

Aqueous and thermal processing of primordial material occurred prior to and during planet formation in the early solar system. A record of how solid materials were altered at this time is present in the carbonaceous chondrites, which are naturally delivered fragments of primitive asteroids. It has been proposed that some materials, such as the clasts termed dark inclusions found in type III chondrites, suggest a sequence of aqueous and thermal events. Lithium isotopes (Li-6 and Li-7) can reveal the role of liquid water in dark inclusion history. During aqueous alteration, Li-7 passes preferentially into solution leaving Li-6 behind in the solid phase and, consequently, any relatively extended periods of interaction with Li-7-rich fluids would have left the dark inclusions enriched in the heavier isotope when compared to the meteorite as a whole. Our analyses of lithium isotopes in Allende and its dark inclusions reveal marked isotopic homogeneity and no evidence of greater levels of aqueous alteration in dark inclusion history.

Sephton, Mark A.↗

Aerogel Projects Ongoing in MSFC's Engineering Directorate

When we speak of an aerogel material, we are referring more to process and structure than to a specific substance. Aerogel, considered the lightest solid material, has been made from silica for seventy years. Resorcinol-formaldehyde, organic aerogels have been developed more recently. However, aerogel can be made from almost any type of substance, even lead. Because an aerogel is mostly air (about 99%), the solid substance used will affect the weight very little. The problem with aerogels is their low tensile strength and lack of elasticity. Therefore, the challenge is to find ways to make the stronger or ways to circumvent the strength issue. Organic aerogels have slightly higher strength than base silica aerogels, while the carbonized version has three to five times the break strength of the base aerogel.

Shular, D. A.↗

Acoustic field positioning for containerless processing

The non-contact positioning of materials in a space processing chamber is accomplished using a new type of acoustic levitator. Liquid and solid materials are positioned using a single source of sound. Fine control of position may be obtained by motion of an acoustical reflector. Electrical power required is usually less than 100 watts. The system operates satisfactorily at high and low temperatures and is adaptable as an add-on feature to existing space experiments. Containerless melting and solidification can be performed and a freely suspended liquid can be shaped to the contour of the sound field. Experiments are described in which aluminum, glass and plastic materials are melted and solidified in the containerless state. The system has applications to containerless crystal growth, melting and related processes.

Whymark, R. R.↗

Acoustic field positioning for containerless processing

The noncontact positioning of materials in a space processing chamber is accomplished using a new type of acoustic levitator. Liquid and solid materials are positioned using a single source of sound. Fine control of position may be obtained by motion of an acoustical reflector. The electrical power required is usually less than 100 watts. The system operates satisfactorily at high and low temperatures and is adaptable as an 'add-on' feature to existing space experiments. Containerless melting and solidification can be performed and a freely suspended liquid can be shaped to the contour of the sound field. Experiments are described in which aluminum, glass and plastic materials are melted and solidified in the containerless state. The system has applications to containerless crystal growth, melting and related processes.

Whymark, R. R.↗

'Domestic' origin of opaque assemblages in refractory inclusions in meteorites

Experimental studies indicate that opaque assemblages rich in refractory siderophile elements were formed within host calcium- and aluminum-rich inclusions (CAIs) by exsolution, oxidation and sulphidization of homogeneous alloys, rather than by aggregation of materials in the solar nebula before the formation of CAIs. These opaque assemblages are thus not the oldest known solid materials, as was once thought, and they do not constrain processes in the early solar nebula before CAI formation. Instead, the assemblages record the changing oxygen fugacity experienced by CAIs during slow cooling in nebular and/or planetary environments.

Blum, Joel D.↗

Thermal radiation heat transfer.

A comprehensive discussion of heat transfer by thermal radiation is presented, including the radiative behavior of materials, radiation between surfaces, and gas radiation. Among the topics considered are property prediction by electromagnetic theory, the observed properties of solid materials, radiation in the presence of other modes of energy transfer, the equations of transfer for an absorbing-emitting gas, and radiative transfer in scattering and absorbing media. Also considered are radiation exchange between black isothermal surfaces, radiation exchange in enclosures composed of diffuse gray surfaces and in enclosures having some specularly reflecting surfaces, and radiation exchange between nondiffuse nongray surfaces. The use of the Monte Carlo technique in solving radiant-exchange problems and problems of radiative transfer through absorbing-emitting media is explained.

Siegel, R.↗

On the application of Chimera/unstructured hybrid grids for conjugate heat transfer

A hybrid grid system that combines the Chimera overset grid scheme and an unstructured grid method is developed to study fluid flow and heat transfer problems. With the proposed method, the solid structural region, in which only the heat conduction is considered, can be easily represented using an unstructured grid method. As for the fluid flow region external to the solid material, the Chimera overset grid scheme has been shown to be very flexible and efficient in resolving complex configurations. The numerical analyses require the flow field solution and material thermal response to be obtained simultaneously. A continuous transfer of temperature and heat flux is specified at the interface, which connects the solid structure and the fluid flow as an integral system. Numerical results are compared with analytical and experimental data for a flat plate and a C3X cooled turbine cascade. A simplified drum-disk system is also simulated to show the effectiveness of this hybrid grid system.

Kao, Kai-Hsiung↗

Latest Results from NASA Ames’ COSmIC and Optical Constants Facility (OCF): Determining Optical Constants for Titan, Pluto and Protoplanetary Disks Applications

The NASA Ames COsmic SImulation Chamber (COSmIC) is a unique experimental facility that can be used, among many applications, to produce solid particles from gas phase molecular precursors at low temperature (150 K) using a plasma discharge to induce the chemistry in the stream of a free jet expansion. The choice of the initial gas mixture used to produce the solid sample allows the simulation of either cold planetary atmospheres like Titan or Pluto (with N2/CH4-based initial mixtures), or circumstellar environments (with Ar/CxHy-based initial mixtures). The Ames Optical Constants Facility (OCF) allows the determination of optical constants covering a broad wavelength range with high spectral resolution for solid materials, analogs of organic refractory materials formed in planetary and astrophysical environments. The core of the OCF is a Fourier transform infrared (FTIR) spectrometer that allows the continuous characterization of solid samples in the visible to far-infrared (FIR) range (0.59–200 μm, 16,950–50 cm−1). Modeling of the laboratory measurements conducted with the OCF allows the determination of accurate optical constants, n and k, over the full vis-FIR range. Here we present the latest results of two studies that combined (1) experiments performed with COSmIC to produce analogs of aerosols forming in Titan’s atmosphere and analogs of cosmic grains forming in circumstellar envelops, and (2) the characterization of these analogs with the OCF to provide the real and imaginary parts of their refractive indices, n + ik, to the community, from the visible to the FIR. These optical constants can be used as critical input parameters in radiative transfer, atmospheric and reflectance models to interpret observational data of, e.g., Titan’s atmosphere and protoplanetary disks. Providing optical constants for various materials of different compositions allows to explore a broad range of composition by simulating mixtures of materials. We also present a new project to produce analogs of Pluto’s atmospheric aerosols with COSmIC and determine their optical constants with OCF, to be used in reflectance spectra models for the interpretation of New Horizons observations of Lowell Regio, Sputnik Planitia and Cthulhu.

COsmic SImulation Chamber (COSmIC)↗

Mathematical Analysis and Optimization of Infiltration Processes

A variety of infiltration techniques can be used to fabricate solid materials, particularly composites. In general these processes can be described with at least one time dependent partial differential equation describing the evolution of the solid phase, coupled to one or more partial differential equations describing mass transport through a porous structure. This paper presents a detailed mathematical analysis of a relatively simple set of equations which is used to describe chemical vapor infiltration. The results demonstrate that the process is controlled by only two parameters, alpha and beta. The optimization problem associated with minimizing the infiltration time is also considered. Allowing alpha and beta to vary with time leads to significant reductions in the infiltration time, compared with the conventional case where alpha and beta are treated as constants.

Chang, H.-C.↗

Global Evolution of Solid Matter in Turbulent Protoplanetry Disks: Aerodynamics of Solid Particles - Part 1

The problem of planetary system formation and its subsequent character can only be addressed by studying the global evolution of solid material entrained in gaseous protoplanetary disks. We start to investigate this problem by considering the space-time development of aerodynamic forces that cause solid particles to decouple from the gas. The aim of this work is to demonstrate that only the smallest particles are attached to the gas, or that the radial distribution of the solid matter has no momentary relation to the radial distribution of the gas. We present the illustrative example wherein a gaseous disk of 0.245 solar mass and angular momentum of 5.6 x 10(exp 52) g/sq cm/s is allowed to evolve due to turbulent viscosity characterized by either alpha = 10(exp -2) or alpha = 10(exp -3). The motion of solid particles suspended in a viscously evolving gaseous disk is calculated numerically for particles of different sizes. In addition we calculate the global evolution of single-sized, noncoagulating particles. We find that particles smaller than 0.1 cm move with the gas; larger particles have significant radial velocities relative to the gas. Particles larger than 0.1 cm but smaller than 10(exp 3) cm have inward radial velocities much larger than the gas, whereas particles larger than 10(exp 4) cm have inward velocities much smaller than the gas. A significant difference in the form of the radial distribution of solids and the gas develops with time. It is the radial distribution of solids, rather than the gas, that determines the character of an emerging planetary system.

Stepinski, T. F.↗

The Abundance and Isotopic Composition of Hg in Extraterrestrial Materials

During the past three year grant period we made excellent progress in our study of the abundances and isotopic compositions of Hg and other volatile trace elements in extraterrestrial materials. As part of my startup package I received funds to construct a state-of-the-art experimental facility to study gas-solid reaction kinetics. Much of our effort was spent developing the methodology to measure the abundance and isotopic composition of Hg at ultratrace levels in solid materials. In our first study, the abundance and isotopic composition of Hg was determined in bulk samples of the Murchison (CM) and Allende (CV) carbonaceous chondrites. We have continued our study of mercury in primitive meteorites and expanded the suite of meteorites to include other members of the CM and CV chondrite group as well as CI and CO chondrites. Samples of the CI chondrite Orgueil, the CM chondrites Murray, Nogoya, and Cold Bokkeveld, the CO chondrites Kainsaz, Omans, and Isna, and the CV chondrites Vigarano, Mokoia, and Grosnaja were tested. We have developed a thermal analysis ICP-MS technique and applied it to the study of a suite of thermally labile elements (Zn, As, Se, Cd, In, Sn, Sb, Te, Hg, Au, Tl, Pb, and Bi) in geologic materials as well.

Lauretta, D. S.↗

Emission spectrometric arcing procedure with minimal effect of chemical form of sample

Matrix effects related to the chemical form of analyzed materials were studied. An arc in argon was used which was buffered with silver chloride. The effect of chemical form was minimal for a variety of metals, oxides, and carbides representing the most refractory compounds and thermally stable metal-containing molecules. Only four of the most refractory materials known showed significant emission depressions due to incomplete volatilization in the arc system. These results are discussed in terms of vapor pressures of the solid materials placed on the anodes and dissociation reactions of the molecules in the gaseous environment.

Gordon, W. A.↗

Emission spectrometric arcing procedure with minimal effect of chemical form of sample

This paper describes a study of matrix effects related to the chemical form of materials analyzed. The study was made using an arc in argon buffered with silver chloride. The effect of chemical form was minimal for a variety of metals, oxides, and carbides representing the most refractory compounds and thermally stable metal-containing molecules. Among these, only four of the most refractory materials known showed significant emission depressions due to incomplete volatilization in the arc system. These results are discussed in terms of vapor pressure of the solid materials placed on the anodes and dissociation reactions of the molecules in the gaseous environment.

Gordon, W. A.↗

In situ analysis of organic material with a portable mass spectrometer

We have tested a portable mass spectrometer (MS) system, the Mini 10.5, for in situ applications including the analysis of volatile organic hydrocarbon (VOC) and water soluble organic components extracted from solid material using an automated sample processing system (ASPS), by doing so we intend to demonstrate the utility of in situ analysis compared to sample acquisition and return for analysis on future robotic space missions.

Beegle, L. W.↗

Coupling Carbon Oxidation and Surface Recession in Direct-Simulation Monte Carlo Code, SPARTA

Ablative thermal protection system (TPS) materials for spacecraft are composites that are often made out of carbon-based reinforcement and a polymeric matrix. They endure high-temperature oxidation and surface recession when re-entering Earth’s atmosphere. Ablation is the result of many coupled and competing thermal, mechanical, and chemical phenomena, and it is difficult to isolate the role of each on the overall degradation of the TPS. Here we develop an ablation model for material recession coupled explicitly to finite rate carbon oxidation in complex microstructures. In this work, Stochastic PArallel Rarified-gas Time-accurate Analyzer (SPARTA), a direct-simulation Monte Carlo (DSMC) code, is modified to allow oxidation-driven ablation of implicitly defined carbon surfaces. In SPARTA, implicit surfaces are generated from the grid corner point values via a marching cubes algorithm, therefore creating a new set of surface elements every time ablation is performed. The finite-rate oxidation model developed by Gopalan et. al, was adapted to tally surface reactions and other surface data on a per-grid cell basis. The ablation functionality was also adjusted so once the reactions have occurred, the number of reactions leading to CO formation can be converted to corner point reduction values; therefore, carbon removal is directly proportional to surface recession. We also develop robust algorithms which handle the evolution of the flow cells and solid material regions, including split cells (flow cell divided in two by a solid surface). Finally, we demonstrate our implicit chemistry model for 2D and 3D geometries by producing reaction statistics and detailed visualization of oxidation-induced material recession at the microscale.

V Arias↗

Trace elements in migrating high-temperature fluids: Effects of diffusive exchange with the adjoining solid

Trace element concentrations and isotopic ratios are frequently used to study the behavior of high-temperature fluids in both metamorphic and igneous systems. Many theoretical formulations of the effects of fluid migration on trace elements have assumed instantaneous reequilibration between the migrating fluid and the solid material through which it is passing. This paper investigates the additional effects which arise when equilibration is not instantaneous due to a limited rate of diffusion in the solid, using an analytical steady state solution to a set of partial differential equations describing the exchange of trace elements between the fluid and the solid during the migration of the fluid.

Kenyon, Patricia M.↗