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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

A Sub-Threshold Low-Power Integrated Bandpass Filter for Highly-Integrated Spectrum Analyzers

Low-power analog filter banks provide frequency analysis with minimal power and space requirements, making them viable solutions for integrated remote audio- and vibration-sensing applications. Compared with their digital counterparts, analog filter banks are better suited to achieve the lower power consumption necessary for IoT applications, while maintaining high dynamic range and a wide operational frequency range. In this work, the design and implementation of a sub-threshold complementary metal-oxide semiconductor (CMOS) integrated low-power tunable analog filter channel for signal spectrum analysis and signal discrimination is presented. Project specifications required a programmable, high-order, monolithic bandpass filter channel with small chip area, low power consumption, high dynamic range, and wide operational frequency range. The 8th-order filter channel presented in this work provides an effective Q-factor of 4.5 and a minimum dynamic range (DR) of approximately 85 dB, while allowing for tuning across a range of center frequencies from 2 kHz to 100 kHz, with power consumption of a single 8th-order filter channel measured at 256 µW nominally at the highest center frequency. An integrated analog Gm-C filter topology was selected for this application. Functionally, the high-Q bandpass filter transfer function is implemented via four cascaded 2nd-order filter cells, resulting in a single 8th-order filter channel, fabricated in 130-nm 1.2-V CMOS technology, suitable for use in monolithic integrated spectral analysis (MISA1) applications.

Long, Gavin B.↗
DOE OSTI2021

The five line-of-sight neutron time-of-flight (nToF) suite on the National Ignition Facility (NIF)

Measurement of the neutron spectrum from inertial confinement fusion implosions is one of the primary diagnostics of implosion performance. Analysis of the spectrum gives access to quantities such as neutron yield, hot-spot velocity, apparent ion temperature, and compressed fuel ρr through measurement of the down-scatter ratio. On the National Ignition Facility, the neutron time-of-flight suite has been upgraded to include five independent, collimated lines of sight, each comprising a high dynamic range bibenzyl/diphenylacetylene-stilbene scintillator [R. Hatarik et al., Plasma Fusion Res. 9, 4404104 (2014)] and high-speed fused silica Cherenkov detectors [A. S. Moore et al., Rev. Sci. Instrum. 89, 10I120 (2018)].

Moore, A. S. (ORCID:0000000221258882)↗
DOE OSTI2024

Catalog-level blinding on the bispectrum for DESI-like galaxy surveys

We evaluate the performance of the catalog-level blind analysis technique (blinding) presented in Brieden et al. (2020) in the context of a fixed template power spectrum and bispectrum analysis. This blinding scheme, which is tailored for galaxy redshift surveys similar to the Dark Energy Spectroscopic Instrument (DESI), has two components: the so-called “AP blinding” (concerning the dilation parameters α$_{∥}$, α$_{⊥}$) and “RSD blinding” (redshift space distortions, affecting the growth rate parameter f). Through extensive testing, including checks for the RSD part in cubic boxes, the impact of AP blinding on mocks with realistic survey sky coverage, and the implementation of a full AP+RSD blinding pipeline, our analysis demonstrates the effectiveness of the technique in preserving the integrity of cosmological parameter estimation when the analysis includes the bispectrum statistic. We emphasize the critical role of sophisticated — and difficult to accidentally unblind — blinding methods in precision cosmology.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Computationally Guided Investigation of the Optical Spectra of Pure β-UO 3

Single-phase β-UO 3 is synthesized by flash heating UO 2 (NO 3 )·6H 2 O in air to 450 °C and annealing for 60 h under the same conditions. For the first time, we report the Raman spectra of pure β-UO 3 . To facilitate the assignment of Raman and infrared vibrational modes, we use density functional theory with density functional perturbation theory. By employing a novel analysis scheme that includes the mode frequencies as well as a quantitative analysis of the mode eigenvectors, we assign the observed spectral features to individual chemical modes. In particular, the density functional theory optimized structure, observed Raman spectrum, and eigenvector analysis suggest the presence of four crystallographically distinct uranyl ions, one more than has previously been suggested.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Understanding the Nature of an Unusual Post-starburst Quasar with Exceptionally Strong Ne v Emission

We present a z = 0.94 quasar, SDSS J004846.45-004611.9, discovered in the Sloan Digital Sky Survey III (SDSS-III) BOSS survey. A visual analysis of this spectrum reveals highly broadened and blueshifted narrow emission lines, in particular, [Ne v] λ3426 and [O III ] λ5007, with outflow velocities of 4000 km s -1 , along with unusually large [Ne v] λ3426/[Ne III ] λ3869 ratios. The gas shows higher ionization at higher outflow velocities, indicating a connection between the powerful outflow and the unusual strength of the high ionization lines. The spectral energy distribution and the i – W3 color of the source reveal that it is likely a core extremely red quasar (ERQ); a candidate population of young active galactic nuclei (AGN) that are violently blowing out gas and dust from their centers. The dominance of host galaxy light in its spectrum and its fortuitous position in the SDSS S82 region allows us to measure its star formation history and investigate variability for the first time in an ERQ. Our analysis indicates that SDSS J004846.45-004611.9 underwent a short-lived starburst phase 400 Myr ago and was subsequently quenched, possibly indicating a time lag between star formation quenching and the onset of AGN activity. We also find that the strong extinction can be uniquely attributed to the AGN and does not persist in the host galaxy, contradicting a scenario where the source has recently transitioned from being a dusty submillimeter galaxy. In our relatively shallow photometric data, the source does not appear to be variable at 0.24–2.4 μm in the rest frame, most likely due to the dominant contribution of host galaxy starlight at these wavelengths.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Analysis of the rotationally-resolved infrared spectrum of CD 3 79 Br and CD 3 81 Br between 900 and 1400 cm -1

We report the infrared spectrum of CD 3 79 Br and CD 3 81 Br between 900 cm -1 and 1400 cm -1 has been analyzed at high resolution. In this region, two fundamental vibrational states, v 2 = 1 and v 5 = 1, an overtone state, v 3 = 2, and a combination state, v 3 = v 6 = 1, have been analyzed for both isotopologues. As found in other halomethane molecules, strong Coriolis resonances couple the v 2 = 1 state to the v 5 = 1 state, and similar resonances were also used to describe the coupling found between the v 5 = 1 state to the v 3 = 2 state. A new determination of the K-dependent constant A 0 was performed for each isotopologue through the use of perturbation-allowed transitions. The values for A 0 determined from the analysis are 2.6001898(26) and 2.6001905(27) for CD 3 79 Br and CD 3 81 Br, respectively. Ab initio calculations were performed to examine the efficacy of high-level theoretical calculations to accurately predict spectroscopic constants. The ab initio calculations had variable success with the largest errors associated with the prediction of the ΔB rotational constants of the interacting states

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Security Analysis of a Class of Secured Spread Spectrum Systems

Abstract—A method of adding physical layer security to a class of spread spectrum systems has been recently proposed. In this paper, we look into the rate at which an eavesdropper may gain information about the system to decipher the data symbols. The Shannon mutual information is used to measure the rate of information that may be gained by an eavesdropper. The k-nearest neighbors (k-NN) method is used to obtain the estimates of relevant entropy values which will be then used to quantify the rate of information recovery as more data are being transmitted. It turns out that such information recovery requires adoption of special methods that avoid any destructive bias in the estimates. Details of these methods are also presented.

97 - MATHEMATICS AND COMPUTING↗
DOE OSTI2020

SDSS-IV MaNGA: Bayesian analysis of the star formation history of low-mass galaxies in the local Universe

ABSTRACT We measure the star formation histories (SFHs) of a sample of low-mass galaxies with M* < 109 M⊙ from the SDSS-IV MaNGA survey. The large number of IFU spectra for each galaxy are either combined to reach a high signal to noise ratio or used to investigate spatial variations. We use Bayesian inferences based on full spectrum fitting. Our analysis based on Bayesian evidence ratio indicates a strong preference for a model that allows the presence of an old stellar population, and that an improper model for the SFH can significantly underestimate the old population in these galaxies. The addition of near-infrared photometry to the constraining data can further distinguish between different SFH model families and significantly tighten the constraints on the mass fraction in the old population. On average more than half of the stellar mass in present-day low-mass galaxies formed at least 8 Gyr ago, while about 30 per cent within the past 4 Gyr. Satellite galaxies on average have formed their stellar mass earlier than central galaxies. The radial dependence of the SFH is quite weak. Our results suggest that most of the low-mass galaxies have an early episode of active star formation that produces a large fraction of their present stellar mass.

Zhou, Shuang↗
DOE OSTI2024

Design, Detection, and Countermeasure of Frequency Spectrum Attack and Its Impact on Long Short-Term Memory Load Forecasting and Microgrid Energy Management

This paper introduces a frequency-domain false data injection attack called Frequency Spectrum Attack (FSA) and explores its effects on load forecasting and the energy management system (EMS) in a microgrid. The FSA analyzes time-series signals in the frequency domain to identify patterns in their frequency spectrum. It learns the distribution of dominant frequencies in a dataset of healthy signals. Subsequently, it manipulates the amplitudes of dominant frequencies within this healthy distribution, ensuring a stealthy attack against statistical analysis of the signal spectrum. We evaluated the performance of FSA on LSTM, a state-of-the-art network for load forecasting. The results show that FSA can triple the Mean Absolute Error (MAE) of predictions compared to the normal case and increase it by 70% compared to noise injection attacks. Furthermore, FSA indirectly enhances battery utilization in the EMS by 45%. We then proposed a detection method that combines statistical analysis and machine-learning-based classification techniques with features. The model effectively distinguishes FSA from healthy and noisy signals, achieving an accuracy of 98.7% and an F1-score of 98.1% on a load dataset, covering healthy, FSA, and noisy load data. Finally, a countermeasure was introduced based on the statistical analysis of the frequency spectrum of healthy signals to mitigate the impact of FSA. This countermeasure successfully reduces the MAE of the attacked model from 0.135 to 0.053, validating its effectiveness in mitigating FSA.

Nazeri, Amirhossein↗
DOE OSTI2024

The BOSS bispectrum analysis at one loop from the Effective Field Theory of Large-Scale Structure

Abstract We analyze the BOSS power spectrum monopole and quadrupole, and the bispectrum monopole and quadrupole data, using the predictions from the Effective Field Theory of Large-Scale Structure (EFTofLSS). Specifically, we use the one loop prediction for the power spectrum and the bispectrum monopole, and the tree level for the bispectrum quadrupole. After validating our pipeline against numerical simulations as well as checking for several internal consistencies, we apply it to the observational data. We find that analyzing the bispectrum monopole to higher wavenumbers thanks to the one-loop prediction, as well as the addition of the tree-level quadrupole, significantly reduces the error bars with respect to our original analysis of the power spectrum at one loop and bispectrum monopole at tree level. After fixing the spectral tilt to Planck preferred value and using a Big Bang Nucleosynthesis prior, we measureσ 8 = 0.794 ± 0.037,h = 0.692 ± 0.011, and Ω m = 0.311 ± 0.010 to about 4.7%, 1.6%, and 3.2%, at 68% CL, respectively.This represents an error bar reduction with respect to the power spectrum-only analysis of about 30%, 18%, and 13% respectively. Remarkably, the results are compatible with the ones obtained with a power-spectrum-only analysis, showing the power of the EFTofLSS in simultaneously predicting several observables. We find no tension with Planck.

Astronomy & Astrophysics↗
DOE OSTI2020

Boron-Made N 2 : Realization of a B$\equiv$B Triple Bond in the B 2 Al 3 – Cluster

Until now, all B≡B triple bonds have been achieved by adopting two ligands in the L→B≡B←L manner. Herein, we report an alternative route of designing the B≡B bonds based on the assumption that by acquiring two extra electrons, an element with the atomic number Z can have properties similar to those of the element with the atomic number Z + 2. Specifically, we show that due to the electron donation from Al to B, the negatively charged B≡B kernel in the B 2 Al 3 – cluster mimics a triple N≡N bond. Comprehensive computational searches reveal that the global minimum structure of B 2 Al 3 – exhibits a direct B–B distance of 1.553 Å, and its calculated electron vertical detachment energies are in excellent agreement with the corresponding values of the experimental photoelectron spectrum. Chemical bonding analysis revealed one σ and two π bonds between the two B atoms, thus confirming a classical textbook B≡B triple bond, similar to that of N 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Spontaneously broken subsystem symmetries

We investigate the spontaneous breaking of subsystem symmetries directly in the context of continuum field theories by calculating the correlation function of charged operators. Our methods confirm the lack of spontaneous symmetry breaking in some of the existing continuum field theories with subsystem symmetries, as had previously been established based on a careful analysis of the spectrum. We present some novel continuum field theory constructions that do exhibit spontaneous symmetry breaking whenever allowed by general principles. These interesting patterns of symmetry breaking occur despite the fact that all the theories we study are non-interacting.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Raman spectroscopic investigation of UCl 4

Uranium chloride salts are a proposed fuel source for molten salt reactors (MSRs). However, despite their relevance to nuclear energy, they remain understudied, in part because of their air and moisture sensitivity. Here, this work provides the first Raman spectra of UCl 4 from 45 to 3200 cm −1 collected with 532 and 785 nm excitation sources as well as the assignment of 10 identified peaks to their respective vibrational modes. These Raman bands are compared to those for isostructural ThCl 4 , the compositionally related UCl 3 , and the computed Raman bands for UCl 4 from local vibrational mode analysis. The observed spectrum of UCl 4 is in accord with that of ThCl 4 and the computed spectra of UCl 4 . We posit that the observed differences between the spectra of UCl 4 and UCl 3 are useful in differentiating these species for applications such as in situ monitoring of MSR operations.

Anoxic spectroscopy↗
DOE OSTI2026

Ligand Control of Ultrafast Hot-Carrier Cooling in CdSe Quantum Dots by a Coherent Nonadiabatic Mechanism

Using the results from global modeling of the broadband two-dimensional electronic spectrum and an analysis of the concurrent damping of excited-state vibronic coherences, we show herein that a coherent nonadiabatic mechanism converts the electronic excitation energy of the X3 (1P 3/2 –1P e ) exciton state to ligand vibrations on the <50 fs time scale in oleate- and hexadecylamine-capped CdSe quantum dots. A comparison of the rates for the two ligands suggests that this process is promoted by mid-frequency vibrations of the ligands due to modulation of their electron-donating tendency. An intramolecular vibrational redistribution process then follows on the ∼200 fs time scale with both ligands, which accompanies thermalization in the band-edge X1 (1S 3/2 –1S e ) state and dephasing of the spectator ligand vibrations. These findings suggest that charge-separated intermediates associated with photoinduced charge transfer or triplet–triplet excitation energy transfer will be produced with retention of phase coherence in the vibrations that modulate the charge-transfer character of surface-bound organic acceptors.

14 SOLAR ENERGY↗
DOE OSTI2023

Constraints on hadron resonance gas interactions via first-principles Lattice QCD susceptibilities

We investigate extensions of the Hadron Resonance Gas (HRG) Model beyond the ideal case by incorporating both attractive and repulsive interactions into the model. When considering additional states exceeding those measured with high confidence by the Particle Data Group, attractive corrections to the overall pressure in the HRG model are imposed. On the other hand, we also apply excluded-volume corrections, which ensure there is no overlap of baryons by turning on repulsive (anti)baryon-(anti)baryon interactions. We emphasize the complementary nature of these two extensions and identify combinations of conserved charge susceptibilities that allow us to constrain them separately. In particular, we find interesting ratios of susceptibilities that are sensitive to one correction and not the other. This allows us to constrain the excluded volume and particle spectrum effects separately. Analysis of the available lattice results suggests the presence of both the extra states in the baryonstrangeness sector and the repulsive baryonic interaction, with indications that hyperons have a smaller repulsive core than non-strange baryons. We note that these results are interesting for heavy-ion-collision systems at both the LHC and RHIC.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage

Water under nanoconfinement at ambient conditions has exhibited low-dimensional ice formation and liquid–solid phase transitions, but with structural and dynamical signatures that map onto known regions of water’s phase diagram. Using terahertz (THz) absorption spectroscopy and ab initio molecular dynamics, we have investigated the ambient water confined in a supramolecular tetrahedral assembly, and determined that a dynamically distinct network of 9 ± 1 water molecules is present within the nanocavity of the host. The low-frequency absorption spectrum and theoretical analysis of the water in the Ga 4 L 6 12– host demonstrate that the structure and dynamics of the encapsulated droplet is distinct from any known phase of water. A further inference is that the release of the highly unusual encapsulated water droplet creates a strong thermodynamic driver for the high-affinity binding of guests in aqueous solution for the Ga 4 L 6 12– supramolecular construct.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Rutin is a potent senomorphic agent to target senescent cells and can improve chemotherapeutic efficacy

Aging is a major risk factor for most chronic disorders, for which cellular senescence is one of the central hallmarks. Senescent cells develop the pro-inflammatory senescence-associated secretory phenotype (SASP), which significantly contributes to organismal aging and age-related disorders. Development of senotherapeutics, an emerging class of therapeutic agents to target senescent cells, allows to effectively delay aging and alleviate chronic pathologies. Here we report preliminary outputs from screening of a natural medicinal agent (NMA) library for senotherapeutic candidates and validated several agents with prominent potential as senomorphics. Rutin, a phytochemical constituent found in a number of plants, showed remarkable capacity in targeting senescent cells by dampening expression of the full spectrum SASP. Further analysis indicated that rutin restrains the acute stress-associated phenotype (ASAP) by specifically interfering with the interactions of ATM with HIF1α, a master regulator of cellular and systemic homeostasis activated during senescence, and of ATM with TRAF6, part of a key signaling axis supporting the ASAP development toward the SASP. Conditioned media produced by senescent stromal cells enhanced the malignant phenotypes of prostate cancer cells, including in vitro proliferation, migration, invasion, and more importantly, chemoresistance, while rutin remarkably downregulated these gain-of-functions. Although classic chemotherapy reduced tumor progression, the treatment outcome was substantially improved upon combination of a chemotherapeutic agent with rutin. Our study provides a proof of concept for rutin as an emerging natural senomorphic agent, and presents an effective therapeutic avenue for alleviating age-related pathologies including cancer.

60 APPLIED LIFE SCIENCES↗