Search NASA⌕ Search

SEARCH · Search NASA

Results for “Spent Fuel Management”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

Sensitivity Analysis Comparisons on Geologic Case Studies: An International Collaboration, Volume 2

Over the past six years, an informal working group has developed to investigate existing sensitivity analysis methods, examine new methods, and identify best practices. The focus is on the use of sensitivity analysis in case studies involving geologic disposal of spent nuclear fuel or nuclear waste. Three additional case studies are presented in this Volume 2 report, including more nonlinear behavior, outputs which exhibit bifurcation, regime changes, and nested sampling.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Salt International Collaborations FY24 Update

This report summarizes the international collaborations conducted by Sandia funded by the US Department of Energy Office (DOE) of Nuclear Energy (DOE-NE) Spent Fuel and Waste Science & Technology (SFWST) as part of the Sandia National Laboratories Salt R&D and Salt International work packages. This report satisfies the level-three milestone M3SF-24SN010303063. Several stand-alone sections make up this summary report, each completed by the participants. The sections discuss granular salt reconsolidation (KOMPASS/MEASURES), engineered barriers (RANGERS), numerical model comparison (DECOVALEX), an NEA Salt Club working group on the development of scenarios as part of the performance assessment development process, and progress on seal percolation experiments with German colleagues at Gesellschaft für Anlagen- und Reaktorsicherheit (GRS). Finally, we summarize events related to the US/German Workshop on Repository Research, Design and Operations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Comparison of Two Different Approaches to Hydrazine Loading of Spacecraft: The Use of SCAPE and Alternative Approaches

The loading of spacecraft with Hydrazine type fuels has long been recognized as a hazardous operation. This has led to safety strategies that include the use of SCAPE protective suits for personnel. The use of SCAPE suits have an excellent safety record, however there are associated drawbacks. Drawbacks include the high cost of maintaining and cleaning the suits, reduced mobility and dexterity when wearing the suits, the requirement for extensive specialized health and safety training, and the need to rotate personnel every two hours. A study was undertaken to look at procedures and/or equipment to eliminate or reduce the time spent in SCAPE-type operations. The major conclusions are drawn from observations of the loading of the JPL/NASA spacecraft Deep Space One (DS1) at KSC and the loading of a commercial communications satellite by Motorola at Vandenberg AF Base. The DS1 operations require extensive use of SCAPE suits, while the Motorola operation uses only SPLASH attire with a two-man team on standby in SCAPE. The Motorola team used very different loading equipment and procedures based on an integrated approach involving the propellant supplier. Overall, the Motorola approach was very clean, much faster and simpler than the DS1 procedure. The DS1 spacecraft used a bladder in the propellant tank, whereas the Motorola spacecraft used a Propellant Management Device (PMD). The Motorola approach cannot be used for tanks with bladders. To overcome this problem, some new procedures and new equipment are proposed to enable tanks with bladders to be loaded without using SCAPE, using a modified Motorola approach. Overall, it appears feasible to adopt the non-SCAPE approach while maintaining a very high degree of safety and reliability.

Houseman, John↗

GDSA Repository Systems Analysis Investigations in FY 2024

The Disposal Research and Development (R&D) Program of the US Department of Energy (DOE) office of Nuclear Energy (NE-8) Spent Fuel and Waste Science and Technology (SFWST) Campaign is to conduct R&D on disposal of spent nuclear fuel (SNF) and high-level waste (HLW). The goal of the Geologic Disposal Safety Assessment (GDSA) within this project is to develop a disposal system modeling and analysis capability that supports the integrated modeling of coupled processes controlling disposal system performance of deep geologic repositories, including uncertainty. This report describes specific activities in the Fiscal Year (FY) 2024 associated with the GDSA Repository Systems Analysis (RSA) work package. The overall objective of the GDSA RSA work package is to develop generic deep geologic repository concepts and repository system performance models in crystalline, argillite, salt, and unsaturated alluvium potential host-rock environments, and to simulate and analyze these generic repository concepts and models using GDSA Framework toolkit, and other tools as needed.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Connected Traffic Signal Coordination Optimization Framework through Network-Wide Adaptive Linear Quadratic Regulator–Based Control Strategy

Traffic congestion in metropolitan areas causes several significant challenges, such as longer travel times, decreased productivity, increased fuel consumption and vehicle emissions, and even severe injuries during crashes. Traffic signal control is a management approach to reduce traffic congestion and allocate the appropriate right of way for safety and mobility efficiency, both in temporal and spatial domains. Here, this study proposes a network-wide adaptive signal control coordination optimization framework based on the linear quadratic regulator algorithm. The traffic flow conditions driven by signal control inputs are formulated based on their network-wide state-space representation. After modeling traffic control regulation constraints, an adaptive linear quadratic regulator algorithm is designed to maximize the network-wide total throughput under the current conditions. Optimal signal control split time durations for multiple intersections in the network are derived by solving the algebraic Riccati equation. Furthermore, the recursive least square parameter estimation method is employed to quantify dynamic traffic condition changes. To verify the effectiveness of this proposed signal control framework, both simulation and real-world experimental tests are conducted for multiple intersections in downtown Chattanooga, Tennessee, United States. In preparation for real-world experimental tests, pipelines for real-time data processing implementation and historical traffic flow data analysis are conducted. The test results demonstrate that the proposed control framework achieves a decrease in travel time by up to 19.4%, total time spent (TTS) by up to 11.9%, and relative queue balance (RQB) by up to 15.6%. The research findings indicate that the proposed signal control framework can be generalized to handle large scale signal control optimization network-wide.

97 MATHEMATICS AND COMPUTING↗

Near Repository Unsaturated Alluvium Disposal Modeling with Improved Geological Realism

The Disposal Research and Development (R&D) Program of the US Department of Energy (DOE) office of Nuclear Energy (NE-8) Spent Fuel and Waste Science and Technology (SFWST) Campaign is to conduct R&D on disposal of spent nuclear fuel (SNF) and high-level waste (HLW). The goal of the Geologic Disposal Safety Assessment (GDSA) within this project is to develop a disposal system modeling and analysis capability that supports the integrated modeling of coupled processes controlling disposal system performance of deep geologic repositories, including uncertainty. This report describes a specific activity in the Fiscal Year 2024 (FY24) associated with the GDSA Repository Systems Analysis (RSA) work package in collaboration with the GDSA Geologic Modeling work package at Los Alamos National Laboratory (LANL). The overall objective of the GDSA RSA work package is to develop generic deep geologic repository concepts and repository system performance models in crystalline, argillite, salt, and unsaturated alluvium potential host-rock environments, and to simulate and analyze these generic repository concepts and models using GDSA Framework toolkit, and other tools as needed.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Utility of Waste Tank Historical Reviews in Bulk Waste Removal Operations at the Savannah River Site – 25271

SRMC is actively working to remove, treat, and dispose radioactive waste generated by the separation facilities at SRS since their initial operations in the 1950s. The separation facilities at SRS have produced nuclear materials for a variety of purposes, particularly national defense, and continue to support the disposition of spent fuel through the Accelerated Basin Deinventory program. In almost 70 years of operation, nearly 625,000 m3 (165 million gallons) of radioactive waste have been generated and transferred to the tank farm facilities at SRS [1]. As a result of volume reduction (e.g., evaporation) and waste solidification (e.g., vitrification), approximately 127,000 m3 (33.5 million gallons) of material remain as of June 30, 2024 [2]. This liquid waste has since been stored in 51 large underground waste tanks present on the site. These waste tanks may contain up to 4,921 m3 (1.3 million gallons) of radioactive waste each in the form of saltcake or sludge. SRMC’s contract is to treat and dispose of this waste, clean the tanks, and operationally close them. To date, 8 of the 51 waste tanks have been operationally closed. Waste retrieval and tank closure activities are ongoing in an additional 17 tanks through either operations in the field or in design [3].

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Nuclear Safety [Vol. 36, No. 2, July-December 1995]

Nuclear Safety is a journal that covers significant issues in the field of nuclear safety. Its primary scope is safety in the design, construction, operation, and decommissioning of nuclear power reactors worldwide and the research and analysis activities that promote this goal, but it also encompasses the safety aspects of the entire nuclear fuel cycle, including fuel fabrication, spent-fuel processing and handling, and nuclear waste disposal, the handling of fissionable materials and radioisotopes, and the environmental effects of all these activities. Table of Contents for this issue follows. THE CHORNOBYL ACCIDENT: 195 The Chornobyl Accident Revisited, Part III: Chernobyl Source Term Release Dynamics and Reconstruction of Events During the Active Phase, A. R. Sich; GENERAL SAFETY CONSIDERATIONS: 218 Second ANS Workshop on the Safety of Soviet-Designed Nuclear Power Plants, R. A. Bari; 234 Elements of a Nuclear Criticality Safety Program, C. M. Hopper; 243 Rickover, Excellence, and Criticality Safety Programs, R. E. Wilson; ACCIDENT ANALYSIS: 249 Transient Analysis of the PIUS Advanced Reactor Design with the TRAC-PF1/MOD2 Code, B. E. Boyack, J. L Steiner, S. C. Harmony, H. J. Stumpf, and J. F. Lime; 278 The Hierarchy-By-Interval Approach to Identifying Important Models that Need Improvement in Severe-Accident Simulation Codes, T. J. Heames, M. Khatib-Rahbar, J. E. Kelly, R. P. Jenks-Johnson, and Y.-S. Chen; 290 RELAP5/MOD3 Code Coupling Model, R. P. Martin; 299 Missiles Caused by Severe Pressurized-Water Reactor Accidents, R. Krieg; DESIGN FEATURES: 310 Validation of COMMIX with Westinghouse AP-600 PCCS Test Data, J. G. Sun, T. H. Chien, J. Ding, and W T. Sha; ENVIRONMENTAL EFFECTS: 321 Spent Nuclear Fuel Characterization for a Bounding Reference Assembly for the Receiving Basin for Off-Site Fuel, S. D. Kahook, R. L. Garrett, L. R. Canas, and M J. Beckum; OPERATING EXPERIENCES: 332 Reactor Shutdown Experience, Compiled by J. W. Cletcher; U.S. NUCLEAR REGULATORY COMMISSION INFORMATION AND ANALYSES: 335 Reactor Coolant System Blowdown at Wolf Creek on September 17, 1994, J. V. Kauffman and S. L. Israel; RECENT DEVELOPMENTS: 344 Reports, Standards, and Safety Guides, D. S. Oueener; 349 Proposed Rule Changes as of June 30, 1995; ANNOUNCEMENTS: 320 Symposium on Acceptability of Risk From Radiation—Application to Manned Space Flight; 320 24th DOE/NRC Nuclear Air Cleaning and Treatment Conference; 361 Radiation Biology and Radiation Protection— Modern Developments and Tendencies in Radiation Biology; 362 1997 IEEE Sixth Conference on Human Factors and Power Plants; 354 The Authors; 360 Reviewers of Nuclear Safety, Vol. 36.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Energy and Water Management

Energy efficiency isn't just a good idea; it's a necessity, both for cost reasons and to meet federal regulatory requirements. First, rising energy unit costs continue to erode NASA's mission budget. NASA spent roughly $156M on facility energy in FY 2007. Although that represents less than one per cent of NASA's overall annual budget, the upward trend in energy costs concerns the agency. While NASA reduced consumption 13%, energy unit costs have risen 63%. Energy cost increases counteract the effects of energy conservation, which results in NASA buying less yet spending more. The second factor is federal energy legislation. The National Energy Conservation Policy Act, as amended by the Energy Policy Act of 2005, Executive Order (EO) 13423 (January, 2007), and the Energy Independence and Security Act (December, 2007), mandates energy/water conservation goals for all federal agencies, including NASA. There are also reporting requirements associated with this legislation. The Energy/Water Management Task was created to support NASA Headquarters Environmental Management Division (HO EMD) in meeting these requirements. With assistance from TEERM, HQ EMD compiled and submitted the NASA Annual Report to the Department of Energy FY 2007. The report contains information on how NASA is meeting federally mandated energy and water management goals. TEERM monitored input for timeliness, errors, and conformity to the new energy/water reporting guidelines and helped compile the information into the final report. TEERM also assists NASA Energy/Water Management with proposal and award calls, updates to the energy/water management database, and facilitating communication within the energy/water management community. TEERM is also supporting NASA and the Interagency Working Group (IWG) on Hydrogen and Fuel Cells. Established shortly after the President announced the Hydrogen Fuel Initiative in 2003, this IWG serves as the mechanism for collaboration among the Federal agencies involved in hydrogen-related research, development, and demonstration. TEERM developed a matrix showing all Hydrogen and Fuel Cell activities from the various NASA centers to be included in the Group's extensive hydrogen research taxonomy of past, present, and future hydrogen activities of the Federal government.

Valek, Susan E.↗

Assessment of Technoeconomic Opportunities in Automation for Nuclear Microreactors

Achieving full decarbonization of all economic sectors remains a challenge, especially in niche markets. For example, remote communities and industrial or mining activities detached from the main electric grid heavily rely on fossil fuels, similar to urban and industrial microgrids with combined heat and power needs. A combination of renewables and energy storage is often not suitable due to cost, reliability, intermittency, and large storage requirements. Small nuclear reactors with a flexible purpose could serve these applications. Microreactors (MR) are a class of reactors that are compact, factory manufactured, transportable, and self-regulating. Typically, they generate much less power than their large reactor counterparts. The main advantages of microreactors include the versatile nature of the energy produced, the reliability of supply, and freedom from having to transport and store large quantities of fuels on-site, coupled with the absence of dependence on an electrical grid. A strong business case is needed to move from the microreactor prototype to the commercialization phase. In fact, fossil fuels are still relatively inexpensive, and in the near term, carbon credits will be available to virtually compensate for emissions. For microreactors, one of the main costs in operation and maintenance (O&M) is their staffing levels. In this study, we investigate how to optimize the number (and thus the cost) of workers, moving from a traditional, fully manned, on-site personnel approach to an unmanned, remote personnel approach. We examine four different staffing models that can be implemented as the technology matures and evolves. We estimate the staffing needs of each model and build a business case to justify the substitution of on-site personnel with adequate technologies. To do so, we propose a cost model to quantify potential cost reductions from automating O&M activities. The model accounts for both the reduction in cost derived from the reduced number of full-time-equivalent (FTE) employees and the increase in cost derived from the need to buy new control hardware as needed. Applying the cost model that we created to different scenarios, an on-site O&M cost reduction exceeding 80% can be expected. Additionally, we found that it is more impactful to focus on automating routine O&M tasks rather than attempting to automate transient management (shutdowns, restarts, monitoring condition deviations). In fact, transients typically account for less than 1% of the total FTE time spent on the reactors.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

L-SCIE and SUPCRTNE model and database development

This progress report (Level 3 Milestone Number M3SF-25LL010301052) summarizes research conducted at Lawrence Livermore National Laboratory (LLNL) within the Argillite Host Rock Properties & Processes Work Package SF-25LL01030105. The focus of this milestone is to create an initial SUPCRTNE database and extensively test the SUPCRTNE code. We prepared a draft manuscript describing our workflow and approach for developing a next-generation thermodynamic database for the Spent Fuel and High Level Waste Disposition campaign. The goal is to ease any future formal software qualification effort as was done on the Yucca Mountain Project for codes including SUPCRT92 and EQ3/6. We are attempting to extend the SUPCRTNE database to include more species, mainly from the NEA volumes. We can also take advantage of thermodynamic database activities that are ongoing at Thermochimie and as part of the EURADII program. However, our effort is limited by the funds available and the changes to program scope that was initiated in mid-FY25.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Past Approaches for Spent Nuclear Fuel, High-Level, and Transuranic Waste Disposal in the United States—Part 1: Safety Criteria and Treatment of Uncertainty

The United States (US), with its 50-year experience in developing deep geologic disposal for transuranic waste, spent nuclear fuel (SNF), and high-level radioactive waste (HLW), has much to share with other countries. Yet, other countries are better able to translate the US experience and corresponding policy decisions into solutions sensible for their country when they understand the compliance requirements in US laws and regulations. This paper presents past approaches in the generic and site-specific standards of the US Environmental Protection Agency (EPA) and implementing regulations of the US Nuclear Regulatory Commission (NRC) using the framework provided by (1) key questions of the Blue Ribbon Commission on America’s Nuclear Future, and (2) international consensus standards. Both the 1985 EPA generic standards, as updated in 1993 and applied at the operating Waste Isolation Pilot Plant in southern New Mexico for transuranic waste from atomic energy defense activities, and the EPA 2008 site-specific standards and implementing regulations, as applied at the proposed Yucca Mountain repository in southern Nevada for SNF and HLW, adopt the strategy of using quantitative, probabilistic analysis to assess performance and compliance.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Literature Review Investigating Historical Plutonium Solubility in SRS Tank Waste

The Savannah River Site (SRS) has designed the Accelerated Basin De-inventory (ABD) program to accelerate the de-inventory of L-Basin and accelerate the Spent Nuclear Fuel (SNF) disposition mission. Similarly, the H-Canyon facility at SRS is reestablishing the 6.3D electrolytic dissolver for dissolving unirradiated stainless-steel (SS) clad Fast Critical Assembly (FCA) fuel. In both discard types (ABD and FCA), plutonium is present and its complex solubility when composited to Concentration, Storage, and Transfer Facility (CSTF) sludge is being investigated as it may have downstream impacts to the liquid waste (LW) organization. This literature review aims to highlight and compile the existing literature on plutonium solubility in waste streams relevant to ABD and FCA discards, as well as discuss some considerations in analyzing solubility data of plutonium. This review serves to help define the analysis methods for future experiments involving plutonium (and other actinides) and in designing appropriate testing conditions surrounding these studies. This review is broken up into five parts and will discuss: (i) The possible effects of testing hold time and temperature on plutonium solubility, (ii) the influence of neutralization rate and particle size of freshly precipitated discards, (iii) the coprecipitation of plutonium with iron and uranium, (iv) predictive solubility modeling and the influence of supernate anions on solubility, and (v) the speciation of plutonium in solutionas a result of supernate anions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Status of the Down-Blending of Irradiated IGR Graphite Fuel in Kazakhstan

Dry processing remains the primary solution for managing the down-blending of irradiated IGR HEU fuel. Several tasks have been initiated and completed to achieve this, including lab modernization, lab-scale and full-scale testing, designing and fabricating an in-paddle mixing drum, and commissioning both a down-blending system and a crushing and milling system. Additionally, a testing and training center was modernized, the equipment was successfully commissioned, and the IGR HEU fuel blocks were repackaged into daily containers. The training of operators and the construction of a new down-blending facility are tasks that will need to be completed in the near future. The progress in these areas continues to validate that the proposed method for down-blending irradiated HEU graphite fuel, followed by cementation of the down-blended material for permanent disposition, appears to be achievable.

12 - MGMT OF RADIOACTIVE AND NON-RADIOACTIVE WASTE↗

Plutonium Solubility and Supernate Concentration for Neutralized Fast Critical Assembly Discards to Savannah River Site Tank Waste

The Savannah River Site (SRS) plans to dissolve non-irradiated stainless steel (SS)-clad bundles of Fast Critical Assembly (FCA) materials in eighteen batches.1 FCA dissolution is currently underway in the 6.3D dissolver by simultaneous chemical and electrolytic dissolution, which is required to generate the harsh conditions necessary for dissolution of metal-oxide (MOX) and non-aluminum spent nuclear fuels (NASNFs).2 Nitric acid and potassium fluoride are used to promote chemical dissolution.2 Gadolinium will be added during processing as a thermal neutron poison for criticality control. There are no plans for recovering plutonium from this waste stream. After FCA dissolution, the acidic (HNO3/KF) “discards” containing the dissolved metals will be neutralized by addition of 50 wt% sodium hydroxide to a final free hydroxide concentration of 1.2 M.1 Neutralization will precipitate a slurry of insoluble solids, predominantly metal oxides/hydroxides of plutonium, uranium, and SS components. Small fractions of the SS components, Pu, U, and Gd will remain dissolved in the supernate. The neutralized slurry will be composited to existing radioactive waste storage tanks within the SRS Concentration, Storage, and Transfer Facilities (CSTF) containing other similar sludge batch (SB) materials.1 The fate of soluble plutonium and freshly-precipitated, colloidal plutonium from this process are of concern since the total Pu can challenge the waste acceptance criteria (WAC) at the downstream SRS Liquid Waste (LW) facility. Supernate decants including the neutralized FCA discards (nFCAd) within the CSTF will be composited with salt batch (StB) materials and transferred to the SRS Salt Waste Processing Facility (SWPF), where total plutonium is also of concern.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Brine Availability Test in Salt (BATS) FY24 Update

This report summarizes fiscal year 2024 (FY24) activities centered around a series of field tests in bedded salt at the Waste Isolation Pilot Plant (WIPP) funded by the Office of Spent Fuel and Waste Science and Technology in the Spent Fuel and Waste Disposition (SFWD) program of the US Department of Energy’s Office of Nuclear Energy (DOE-NE). High-level Purpose of Experiments: The Brine Availability Test in Salt (BATS) field tests are revealing both brine occurrence (i.e., where, and how much) and brine migration (i.e., how easily it moves) in the excavation damaged zone (EDZ). This understanding is foundational to develop a safety case for a future heat-generating waste repository in salt, and to starting up a generic repository program in salt to buy down risk. BATS seeks to predict how much brine can flow into both ambient and heated excavations (e.g., boreholes or rooms) in salt. This work is educating and empowering new repository scientists on two fronts: “design and execution of field tests” and “prediction and modeling of coupled processes.” DOE-NE capabilities in salt have grown and been tested through international modeling and benchmarking exercises (e.g., DECOVALEX, RANGERS, KOMPASS, and MEASURES; see Mills et al., 2024). The hands-on expertise we are building is a necessary step towards large-scale disposal demonstrations and eventual implementation.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

GDSA Framework Development and Process Model Integration FY2024

The Disposal Research & Development (Disposal R&D) Campaign of the U.S. Department of Energy (DOE) Office of Nuclear Energy (NE), Office of Spent Fuel & High-Level Waste Disposition is conducting research and development (R&D) on geologic disposal of spent nuclear fuel (SNF) and high-level nuclear waste (HLW). A high priority for Disposal R&D is disposal system modeling (Sassani et al. 2023). The Geologic Disposal Safety Assessment (GDSA) work package is charged with developing a disposal system modeling and analysis capability for evaluating generic disposal system performance for nuclear waste in geologic media.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Dissolution Flowsheet for Non-Aluminum Spent Nuclear Fuel Campaign 1

As part of the Accelerated Basin De-inventory (ABD) program, H Canyon plans to dissolve non-aluminum spent nuclear fuel (NASNF) in the 6.3D electrolytic dissolver. NASNF Campaign 1 plans to electrolytically dissolve 68 bundles of fuel assemblies from the Carolinas-Virginia Tube Reactor (CVTR), Heavy Water Components Test Reactor (HWCTR), and Experimental Boiling Water Reactor (EBWR). The fuel assemblies are intact Zircaloy or stainless steel (SS) clad UO 2 rods, tubes, and plates. The H Canyon electrolytic dissolver previously dissolved a variety of UO 2 core fuel types in SS, Zircaloy, Nichrome, or Incoloy cladding from 1969 to 1980. The objective of this study was to identify flowsheet conditions through literature review and laboratory experimentation to safely dissolve NASNF Campaign 1 bundles in the H Canyon electrolytic dissolver. Bench-scale electrolytic dissolution tests were performed to demonstrate a flowsheet for NASNF Campaign 1 bundles. The outer bundles are composed of SS or Al alloy, Al 6061-T6, and contain intact Zircaloy or SS clad UO 2 fuel assemblies. The key objectives of these tests were to determine bounding dissolver chemistries and the sparge requirement to ensure H 2 concentration remain less than 60 vol % of the lower flammability limit (LFL) during dissolution. The impact of HNO 3 concentration and the addition of fluoride on the dissolution efficiency of Zircaloy, 304L SS, Al 6061-T6, and Inconel 625 were examined. While SS, Al, and Inconel 625 readily dissolve utilizing electrolytic dissolution, Zircaloy disintegrated anodically; the surface of Zircaloy oxidized and the oxide layer spalled off and settled at the bottom of the dissolver as an insoluble material. The black flakes were identified as ZrO 2 and 85% of the Zr processed was converted to black ZrO 2 flakes when Zr was anodically disintegrated in 9.5 M HNO 3 .

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗