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Results for “Structural Effects”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

The effects of structural flap-lag and pitch-lag coupling on soft inplane hingeless rotor stability in hover

A 1.62-m-diameter rotor model was tested in hover to examine the effects of structural flap-lag and pitch-lag coupling on isolated rotor blade lead-lag stability. Flap-lag coupling was introduced by inclining the principal axes of the blade structure up to 60 degrees. Pitch-lag coupling was obtained either alone or in combination with flap-lag coupling through the use of skewed flexural hinges. The principal results confirm the predictions of theory, and show that both structural flap-lag and pitch-lag coupling when used separately are beneficial to blade stability. Moreover, when the couplings are combined, the lead-lag damping is significantly greater than it would be if the individual contributions were superimposed. Pitch-flap coupling is shown to have only a minor effect on blade lead-lag damping. Differences between theory and experiment observed at zero blade pitch and flexure angles during the initial testing were determined in a second test to be caused by stand flexibility. Other differences between theory and experiment warrant further investigation.

Bousman, William G.↗
NASA NTRS1992

Study of InGaAs-based modulation doped field effect transistor structures using variable-angle spectroscopic ellipsometry

Variable-angle spectroscopic ellipsometry was used to estimate the thicknesses of all layers within the optical penetration depth of InGaAs-based modulation doped field effect transistor structures. Strained and unstrained InGaAs channels were made by molecular beam epitaxy (MBE) on InP substrates and by metal organic chemical vapor deposition on GaAs substrates. In most cases, ellipsometrically determined thicknesses were within 10 percent of the growth-calibration results. The MBE-made InGaAs strained layers showed large strain effects, indicating a probable shift in the critical point of their dielectric function toward the InP lattice-matched concentration.

Alterovitz, Samuel A.↗
NASA NTRS1991

Study of InGaAs-based modulation doped field effect transistor structures using variable-angle spectroscopic ellipsometry

Variable-angle spectroscopic ellipsometry was used to estimate the thicknesses of all layers within the optical penetration depth of InGaAs-based modulation doped field effect transistor structures. Strained and unstrained InGaAs channels were made by molecular beam epitaxy (MBE) on InP substrates and by metal-organic chemical vapor deposition on GaAs substrates. In most cases, ellipsometrically determined thicknesses were within 10% of the growth-calibration results. The MBE-made InGaAs strained layers showed large strain effects, indicating a probable shift in the critical points of their dielectric function toward the InP lattice-matched concentration.

Alterovitz, S. A.↗
DOE OSTI2024

A-site occupancy effects on structure, ionic conductivity, and thermodynamic stability of KxMgx/2Ti8−x/2O16

Abstract K x Mg x /2 Ti 8− x /2 O 16 (1.54 ≤ x ≤ 2) hollandite samples synthesized using a conventional solid-state route were used to investigate the effect of structure, ionic conductivity, and thermodynamic stability as a function of A-site (K) occupancy. The ionic conductivity, as measured using AC impedance spectroscopy, decreased as the A-site occupancy (and K content) increased. Titanate hollandite, of the form K x Mg x /2 Ti 8− x /2 O 16 , was measured using high-temperature oxide melt solution calorimetry in sodium molybdate (3Na 2 O $$\bullet$$ ∙ 4MoO 3 ) solvent at 804 $$^\circ{\rm C}$$ ∘ C . The enthalpies of formation are strongly exothermic indicating that they are thermodynamically stable relative to their constituent oxides. Previous studies have demonstrated increased stability with an increase in Cs content at fixed A-site occupancy. This work demonstrated an increase in the stability for the K-bearing hollandite samples with an increase in K content and tunnel occupancy. The measured enthalpies of formation (∆ H f,ox ) were in good agreement with density functional theory (DFT) predictions. Graphical abstract

Cassell, Nakeshma S.↗
DOE OSTI2019

Effect of structure and composition on the electronic excitation induced amorphization of La2Ti2−xZrxO7 ceramics

Abstract Understanding the response of ceramics operating in extreme environments is of interest for a variety of applications. Ab initio molecular dynamic simulations have been used to investigate the effect of structure and B -site (=Ti, Zr) cation composition of lanthanum-based oxides (La 2 B 2 O 7 ) on electronic-excitation-induced amorphization. We find that the amorphous transition in monoclinic layered perovskite La 2 Ti 2 O 7 occurs for a lower degree of electronic excitation than for cubic pyrochlore La 2 Zr 2 O 7 . While in each case the formation of O 2 -like molecules drives the structure to an amorphous state, an analysis of the polyhedral connection network reveals that the rotation of TiO 6 octahedra in the monoclinic phase can promote such molecule formation, while such octahedral rotation is not possible in the cubic phase. However, once the symmetry of the cubic structure is broken by substituting Ti for Zr, it becomes less resistant to amorphization. A compound made of 50% Ti and 50% Zr (La 2 TiZrO 7 ) is found to be more resistant in the monoclinic than in the cubic phase, which may be related to the lower bandgap of the cubic phase. These results illustrate the complex interplay of structure and composition that give rise to the radiation resistance of these important functional materials.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Experimental evidence of plasmarons and effective fine structure constant in electron-doped graphene/h-BN heterostructure

Electron-electron interaction is fundamental in condensed matter physics and can lead to composite quasiparticles called plasmarons, which strongly renormalize the dispersion and carry information of electron-electron coupling strength as defined by the effective fine structure constant $α$ $^{*}_{ee}$. Although h-BN with unique dielectric properties has been widely used as an important substrate for graphene, so far there is no experimental report of plasmarons in graphene/h-BN yet. Here, we report direct experimental observation of plasmaron dispersion in graphene/h-BN heterostructures through angle-resolved photoemission spectroscopy (ARPES) measurements upon in situ electron doping. Characteristic diamond-shaped dispersion is observed near the Dirac cone in both 0° (aligned) and 13.5° (twisted) graphene/h-BN, and the electron-electron interaction strength $α$ $^{*}_{ee}$ is extracted to be $α$ $^{*}_{ee}$ ≈ 0.9 ± 0.1, highlighting the important role of electron-electron interaction. Our results suggest graphene/h-BN as an ideal platform for investigating strong electron-electron interaction with weak dielectric screening, and lays fundamental physics for gate-tunable nano-electronics and nano-plasmonics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1986

Effects of structural error on the estimates of parameters of dynamical systems

In this paper, the notion of 'near-equivalence in probability' is introduced for identifying a system in the presence of several error sources. Following some basic definitions, necessary and sufficient conditions for the identifiability of parameters are given. The effects of structural error on the parameter estimates for both the deterministic and stochastic cases are considered.

Hadaegh, F. Y.↗
NASA NTRS1990

Effects of structural offset, axial shortening, and gravitational torque on the slewing of a flexible spacecraft

The large-angle maneuvering of a Shuttle-beam-reflector spacecraft in the plane of a circular earth orbit is examined by considering the effects of the structural offset connection, the axial shortening, and the gravitational torque on the slewing motion. The offset effect is analyzed by changing the attachment point of the reflector to the beam. As the attachment point is moved away from the mass center of the reflector, the responses of the nonlinear system deviate from those of the linearized system. The axial geometric shortening effect induced by the deformation of the beam contributes to the system equations through second order terms in the modal amplitudes and rates. The gravitational torque effect is relatively small.

Li, Feiyue↗
DOE OSTI2019

Structure–Property Effects in the Generation of Transient Aqueous Benzoic Acid Anhydrides by Carbodiimide Fuels

The design of dissipative systems, which operate out-of-equilibrium by consuming chemical fuels, is difficult. As yet, there are a few examples of privileged fuel chemistries that can be broadly applied in abiotic systems in the same way that ATP hydrolysis is exploited throughout biochemistry. The key issue is that designing nonequilibrium systems is inherently about balancing the relative rates of coupled reactions. The use of carbodiimides as fuels to generate transient aqueous carboxylic anhydrides has recently been used in examples of new nonequilibrium materials and supramolecular assemblies. Here, we explore the kinetics of formation and decomposition of a series of benzoic anhydrides generated from the corresponding acids and EDC under typical conditions (EDC = N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride). The reactions can be described by a simple mechanism that merges known behavior for the two processes independently. Structure–property effects in these systems are dominated by differences in the anhydride decomposition rate. The kinetic parameters allow trends in concentration-dependent properties to be simulated, such as reaction lifetimes, peak anhydride concentrations, and yields. For key properties, there are diminishing returns with the addition of increasing amounts of fuel. These results should provide useful guidelines for the design of functional systems making use of this chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2020

Beam Propagation Through Atmospheric Turbulence Using an Altitude-Dependent Structure Profile with Non-Uniformly Distributed Phase Screens

Modeling the effects of atmospheric turbulence on optical beam propagation is a key element in the design and analysis of free-space optical communication systems. Numerical wave optics simulations provide a particularly useful technique for understanding the degradation of the optical field in the receiver plane when the analytical theory is insufficient for characterizing the atmospheric channel. Motivated by such an application, we use a split-step method modeling the turbulence along the propagation path as a series of thin random phase screens with modified von Karman refractive index statistics using the Hufnagel-Valley turbulence profile to determine the effective structure constant for each screen. In this work, we employ a space-to-ground case study to examine the irradiance and phase statistics for both uniformly and non-uniformly spaced screens along the propagation path and compare to analytical results. We find that better agreement with the analytical theory is obtained using a non-uniform spacing with the effective structure constant for each screen chosen to minimize its contribution to the scintillation in the receiver plane. We evaluate this method as a flexible alternative to other standard layered models used in astronomical imaging applications.

Chahine, Yousef K.↗
NASA NTRS1984

Modelling issues of the SCOLE control problem

Nonlinear and linear equations of motions were derived. The preliminary investigation consisted of model beam as truss structure, effects of truss structure on control design, and effects of reflector offset on control design. It was concluded that the offset of the reflector c.g. from the beam reflector attach point is dynamically significant. Also, truss effects may also significantly effect the performance of the controller if ignored. If the truss is included in the modeling of the NASA/SCOLE configuration, a practically implementable scheme is available to reduce the model order.

Hotz, A. F.↗
NASA NTRS1995

Optimization of composite box-beam structures including effects of subcomponent interactions

Minimum mass designs are obtained for a simple box beam structure subject to bending, torque and combined bending/torque load cases. These designs are obtained subject to point strain and linear buckling constraints. The present work differs from previous efforts in that special attention is payed to including the effects of subcomponent panel interaction in the optimal design process. Two different approaches are used to impose the buckling constraints. When the global approach is used, buckling constraints are imposed on the global structure via a linear eigenvalue analysis. This approach allows the subcomponent panels to interact in a realistic manner. The results obtained using this approach are compared to results obtained using a traditional, less expensive approach, called the local approach. When the local approach is used, in-plane loads are extracted from the global model and used to impose buckling constraints on each subcomponent panel individually. In the global cases, it is found that there can be significant interaction between skin, spar, and rib design variables. This coupling is weak or nonexistent in the local designs. It is determined that weight savings of up to 7% may be obtained by using the global approach instead of the local approach to design these structures. Several of the designs obtained using the linear buckling analysis are subjected to a geometrically nonlinear analysis. For the designs which were subjected to bending loads, the innermost rib panel begins to collapse at less than half the intended design load and in a mode different from that predicted by linear analysis. The discrepancy between the predicted linear and nonlinear responses is attributed to the effects of the nonlinear rib crushing load, and the parameter which controls this rib collapse failure mode is shown to be the rib thickness. The rib collapse failure mode may be avoided by increasing the rib thickness above the value obtained from the (linear analysis based) optimizer. It is concluded that it would be necessary to include geometric nonlinearities in the design optimization process if the true optimum in this case were to be found.

Ragon, Scott A.↗
DOE OSTI2024

Effects of Structural Constraints on Excited-State Properties in Dimeric Cu(I) Diimine Complexes

Copper(I) bis-diimine complexes have played important roles in light-activated processes that can lead to their potential applications in photocatalysis and chemical sensing. Their metal-to-ligand charge-transfer (MLCT) excited-state properties are tunable by various structural factors. Dimeric Cu(I) complexes with connecting diimine derivative ligands offer another structural tuning platform for the excited-state properties. Here, we investigate excited-state properties in two covalently connected dimeric Cu(I)'s with varying structural constraints exerted by the number of carbons in the polyethylene bridge (C0 and C4) connecting the two copper(I) diimine moieties. An interesting feature of Cu(I) diimine complexes is their ability to flatten following a photoinduced structural change. Herein, we observe larger structural constraints and more structural rearrangement required upon excitation of the longer bridged complex C4 to achieve a conformation toward a more flattened tetrahedral coordination geometry compared to the shorter bridged C0. Vibrational wavepacket analysis of these complexes further supports the effect of these structural constraints where we observe a more rapid dephasing of the C0 complex, as opposed to the C4 complex, despite similar normal mode vibrations. The experimental results were supplemented by TDDFT calculations. In conclusion, the studies provide insight into using metal-metal interactions through constraints to tune excited-state dynamics and pathways.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Electronic structure and effective mass of pristine and Cl-doped CsPbBr 3

Organic–inorganic lead halide perovskites (LHPs) have attracted great interest owing to their outstanding optoelectronic properties. Typically, the underlying electronic structure would determinate the physical properties of materials. But as for now, limited studies have been done to reveal the underlying electronic structure of this material system, comparing to the huge amount of investigations on the material synthesis. The effective mass of the valance band is one of the most important physical parameters which plays a dominant role in charge transport and photovoltaic phenomena. In pristine CsPbBr 3 , the Fröhlich polarons associated with the Pb–Br stretching modes are proposed to be responsible for the effective mass renormalization. In this regard, it would be very interesting to explore the electronic structure in doped LHPs. Here, we report high-resolution angle-resolved photoemission spectroscopy (ARPES) studies on both pristine and Cl-doped CsPbBr 3 . The experimental band dispersions are extracted from ARPES spectra along both $\overline{\Gamma}$–$\overline{M}$–$\overline{\Gamma}$ and $\overline{X}$–$\overline{M}$–$\overline{X}$ high symmetry directions. DFT calculations are performed and directly compared with the ARPES data. Our results have revealed the band structure of Cl-doped CsPbBr 3 for the first time, which have also unveiled the effective mass renormalization in the Cl-doped CsPbBr 3 compound. Doping dependent measurements indicate that the chlorine doping could moderately tune the renormalization strength. These results will help understand the physical properties of LHPs as a function of doping.

36 MATERIALS SCIENCE↗
NASA NTRS2000

Effects of Structure and Hydrodynamics on the Sooting Behavior of Spherical Microgravity Diffusion Flames

We have examined the sooting behavior of spherical microgravity diffusion flames burning ethylene at atmospheric pressure in the NASA Glenn 2.2-second drop tower. In a novel application of microgravity, spherical flames allowed convection across the flame to be either from fuel to oxidizer or from oxidizer to fuel. Thus, microgravity flames are uniquely capable of allowing independent variation of convection direction across the flame and stoichiometric mixture fraction, Z(sub st). This allowed us to determine the dominant mechanism responsible for the phenomenon of permanently-blue diffusion flames -- flames that remain blue as strain rate approaches zero. Stoichiometric mixture fraction was varied by changing inert concentrations such that adiabatic flame temperature did not change. At low and high Z(sub st) nitrogen was supplied with the oxidizer and the fuel, respectively. For the present flames, structure (Z(sub st)) was found to have a profound effect on soot production. Soot-free conditions were observed at high Z(sub st) (Z(sub st) = 0.78) and sooting conditions were observed at low Z(sub st) (Z(sub st) = 0.064) regardless of the direction of convection. Convection direction was found to have a lesser impact on soot inception, with formation being suppressed when convection at the flame sheet was directed towards the oxidizer.

Sunderland, P. B.↗