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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Low gravity containerless processing of immiscible gold rhodium alloys

Under normal one-g conditions immiscible alloys segregate extensively during solidification due to sedementation of the more dense of the immiscible liquid phases. However, under low-g conditions it should be possible to form a dispersion of the two immiscible liquids and maintain this dispersed structure during solidification. Immiscible (hypermonotectic) gold-rhodium alloys were processed in the Marshall Space Flight Center 105 meter drop tube in order to investigate the influence of low gravity, containerless solidification on their microstructure. Hypermonotectic alloys composed of 65 atomic % rhodium exhibited a tendency for the gold rich liquid to wet the outer surface of the containerless processed samples. This tendency led to extensive segregation in several cases. However, well dispersed microstructures consisting of 2 to 3 micron diameter rhodium-rich spheres in a gold-rich matrix were produced in 23.4 atomic % rhodium alloys. This is one of the best dispersions obtained in research on immiscible alloy-systems to data.

Andrews, J. Barry↗
NASA NTRS1972

The chemical composition and structure of the moon.

It is assumed that most of the igneous rocks on the lunar surface are the product of partial melting in the lunar interior, followed by segregation and upward transport of an igneous liquid. An attempt is made to determine constraints on the composition of the lunar interior that derive from the chemical composition of the lunar igneous rocks. The salient chemical characteristics of igneous rocks from the lunar surface are summarized, and are compared to analogous characteristics of terrestrial volcanic rocks so that major similarities and differences between terrestrial and lunar basaltic rocks can be established.

Gast, P. W.↗
NASA NTRS1978

The suppression of low-temperature intergranular brittleness in ferritic Fe-Mn alloys

A method for obtaining cryogenic toughness in an Fe-12Mn-0.2Ti alloy by a controlled cooling technique is presented. The intergranular fracture surface of the quenched alloy, using an AES, revealed no significant difference from that obtained by the bulk transgranular fracture surface, indicating the absence of large-scale grain boundary segregation during the austenitizing treatment. Attention is given to the step cooling method, using a furnace at temperatures of 100 to 120 C, followed by fast cooling to ambient temperature, which in turn produces a high-impact toughness without intergranular brittleness. It is concluded that the sources of brittle intergranular fracture in the alloy are both chemical, operating in martensitic structure, and nonchemical, active during quenching from the austenitizing treatment.

Hwang, S. K.↗
NASA NTRS2019

Meta-Analysis of Electron Cyclotron Resonance Absorption Features Detected in High-Mass X-Ray Binaries

Using recent compilations of detailed X-ray observations and spectral models of exceptional quality, we record the electron cyclotron resonance absorption (ECRA) features that have been detected in 45 pulsating high-mass X-ray binaries (HMXBs) and ultraluminous X-ray (ULX) sources harboring neutron stars, although seven of these detections are still questionable and another 21 are single and/or not independently confirmed. From the comprehensive catalogs of Jaisawal & Naik and Staubert et al. and from several additional recent observations, we produce two lists of HMXB ECRA sources: a list of 17 sources in which multiple ECRA lines or single very low-energy lines are seen, in which we can reasonably assume that the lowest energy reveals the fundamental cyclotron level for each source; and a "contaminated" list of 38 sources including the 21 detections of single ECRA lines that may (not) be higher-level harmonics. Both lists confirm a previous result that we have obtained independently by modeling the propeller lines of Magellanic HMXB pulsars: the surface dipolar magnetic fields B * of HMXB neutron stars are segregated around five distinct values with B * = 0.28 ± 0.08, 0.55 ± 0.11, 1.3 ± 0.37, 3.0 ± 0.68 and 7.9 ± 3.1, in units of TG. However, an explanation of this phenomenon is currently lacking. We have found no correlation between these B * values and the corresponding observed spin periods, spin period derivatives, orbital periods, maximum X-ray luminosities, neutron star masses or companion star masses.

Christodoulou, Dimitris M.↗
NASA NTRS1975

Research on metal solidification in zero-g state

The containerless solidification of several pure metals and metallic alloys was studied in a low gravity environment. The tests were performed in the MSFC 4.2 s drop tower using a rapid wire melting apparatus designed and built for this purpose. Pure iron and nickel, and alloys of iron-nickel, iron-carbon, nickel-aluminum and tungsten-rhenium were all melted and solidified at a gravity level of approximately 100.000/-4 g. Interpretation of the results has led to an appreciation of the factors controlling the successful execution of this drop test experiment and to a delineation of the limits of applicability of the apparatus. Preliminary metallurgical evaluations are presented of the overall shapes, lattice parameters, surface microstructure,, cross-sectional microstructures, solidification and transformation sequences, evaporative segregation, and localized solute redistribution observed in the low-gravity specimens. The effects of low gravity on metallic solidification are discussed with particular emphasis on observations of spontaneous undercooling and evaporative segregation in uncontained melts.

Papazian, J. M.↗
NASA NTRS1987

Adherent Al2O3 scales formed on undoped NiCrAl alloys

Changes in the spalling behavior of Al2O3 scales formed on an undoped NiCrAl alloy are described. Two samples of Ni-15Cr-13Al (wt pct), one a control and the other sanded, were subjected to 25 oxidation cycles. It is observed that adherent scales formed on the sanded sample; however, the control sample had speckled, spalled scales. The data reveal that the adherent scales are caused by repeated removal of surface layers after each oxidation cycle. It is determined that interfacial segregation of sulfur influences spallation and sulfur removal increases bonding. The effect of moisture on scale adhesions is investigated.

Smialek, James L.↗
NASA NTRS1999

Detached Growth of Germanium and Germaniumsilicon

Up to now, detached growth was observed mainly under microgravity, i.e. under the absence of hydrostatic pressure that hinders the formation of a free melt meniscus. the detached growth of germanium doped with gallium was obtained under 1 g conditions, the growth was performed in quartz-glass ampoule. Part of the crystal grew without wall contact, the detached growth was observed in-situ with a CCD-camera as well as after the growth process in form of growth lines and the formation of <111> facets on the crystal surface. GeSi crystal (oriientation: <111>, maximum silicon content: 4 at%, seed material: Ge) was grown in a pBN crucible (excluding the possibility of in-situ monitoring of the growth process). The grown crystal exhibits three growth facets, indicating also wall free growth. Surface analysis of the crystals (NDIC, SEM) and characterization of crystal segregation (EDAX, resistivity measurement) and defect structure (EPD, x-ray diffraction measurements) will be presented.

Dold, P.↗
NASA NTRS2006

The Location of the CO2, Fundamental in Clathrate Hydrates and its Application to Infrared Spectra of Icy Solar System Objects

CO2 is present on the surface of many Solar System objects, but not always as a segregated, pure ice. In pure CO2-ice, the fundamental absorption is located near 4.268 micron (2343.3 wavenumbers). However, on several objects, the CO2 fundamental is shifted to higher frequency. This shift may be produced by CO2 gas trapped in another material, or adsorbed onto minerals. We have seen that a mixture of H2O, CH3OH4 and CO2 forms a type II clathrate when heated to 125 K and produces a CO2 fundamental near 4.26 micron. The exact location of the feature is strongly dependent on the initial ratio of the three components. We are currently exploring various starting ratios relevant to the Solar System to determine the minimum amount of CH3OH needed to convert all of the CO2 to the clathrate, i.e. eliminate the splitting of the CO2 fundamental. We are testing the stability of the clathrate to thermal processing and UV photolysis, and documenting the changes seen in the spectra in the wavelength range from 1-5 micron. We acknowledge financial support from the Origins of Solar Systems Program, the Planetary Geology and Geophysics and the NASA Postdoctoral Program.

Sandford, S. A.↗
NASA NTRS2003

Environmental Snapshots for Satellite Multi-Angle Aerosol Retrieval Validation During the ACE-Asia Field Campaign

On five occasions spanning the ACE-Asia field experiment in spring 2001, the multi-angle imaging MISR instrument, flying aboard the NASA Earth Observing System s Terra satellite, took quarter-kilometer data over a 400-km-wide swath, coincident with high-quality observations by multiple instruments on two or more participating surface and airborne platforms. The cases capture a range of clean, polluted, and dusty aerosol conditions. They represent some of the best opportunities during ACE- Asia for comparative studies among intensive and extensive aerosol observations in their environmental context. We inter-compare related measurements and discuss the implications of apparent discrepancies for each case, at a level of detail appropriate to the analysis of satellite observations. With a three-stage optical modeling process, we synthesize data from multiple sources into layer-by-layer snapshots that summarize what we know about the state of the atmosphere and surface at key locations during each event, to be used for satellite vicarious calibration and aerosol retrieval validation. Aerosols within a few kilometers of the surface were composed primarily of pollution and Asian dust mixtures, as expected. Accumulation and coarse-mode particle size distributions varied little among the events studied, but column aerosol optical depth changed by more than a factor of four, and the near-surface proportion of dust ranged from about 25% to 50%. The amount of absorbing material in the sub-micron fraction was highest when near-surface winds crossed Beijing and the Korean Peninsula, and was considerably lower for all other cases. Ambiguities remain in segregating size distributions by composition; having simultaneous single scattering albedo measurements at more than a single wavelength would significantly reduce the resulting optical model uncertainties, as would integral constraints from surface and atmospheric radiative flux observations. The consistency of component particle micro-physical properties among the five events, even in this relatively complex aerosol environment, suggests that global, satellite-derived maps of aerosol-air-mass-type extent, combined with targeted in situ measurements, can provide a detailed global picture of aerosol behavior. Further joint satellite and in situ analysis is needed to assess the spatial variability of both intensive and extensive aerosol properties within aerosol air masses in two spatial dimensions.

Kahn, Ralph↗
NASA NTRS2004

Origin of Domes on Europa: The Role of Thermally Induced Compositional Buoyancy,

The surface of Jupiter's moon Europa is peppered by topographic domes, interpreted as sites of intrusion and extrusion. Diapirism is consistent with dome morphology, but thermal buoyancy alone cannot produce sufficient driving pressures to create the observed dome elevations. Instead, diapirs may initiate by thermal convection that induces compositional segregation. Exclusion of impurities from warm upwellings allows sufficient buoyancy for icy plumes to create the observed surface topography, provided the ice shell has a small effective elastic thickness (0.2 to 0.5 km) and contains low-eutectic point impurities at the few percent level. This model suggests that the ice shell may be depleted in impurities over time.

Pappalardo, R. T.↗
NASA NTRS1974

Steady state growth and segregation under zero gravity: InSb

It was established that ideal diffusion controlled steady state conditions, never accomplished on earth, were achieved during the growth of Te-doped InSb crystals in Skylab. Surface tension effects were found to establish non-wetting conditions under which free surface solidification took place in confined geometry. It was further found that, under forced contact conditions, surface tension effects led to the formation of surface ridges (not previously observed on earth) which isolated the growth system from its container. In addition, it was possible for the first time to identify unambiguously: the origin of segregation discontinuities associated with facet growth, the mode of nucleation and propagation or rotational twin boundaries, and the specific effect of mechanical-shock perturbations on segregation. The results obtained prove the advantageous conditions provided by outer space. Thus, fundamental data on solidification thought to be unattainable because of gravity induced interference on earth are now within reach.

Witt, A. F.↗
NASA NTRS1981

Genesis of recent silicic magmatism in the Medicine Lake Highland, California - Evidence from cognate inclusions found at Little Glass Mountain

Sparse, granular inclusions of early-formed minerals found within the Little Glass Mountain rhyolite flows in northern California are shown to provide a means of characterizing the physical conditions, at depth, beneath the Medicine Lake Highland during the latest phase of volcanic activity. Mineral compositions, in combination with thermodynamic calculations and experiments, suggest crystalization at a pressure of 5,200 bars within a 966-836 C temperature range; implying that mineral segregation and equilibration occurred at a depth of 15-18 km beneath the surface. In addition, mass balance calculations indicate that the Medicine Lake flow is a close approximation to the parental magma for the latest silicic lavas.

Mertzman, S. A.↗
NASA NTRS1983

Mars - A contamination potential?

Three regions on Mars, Solis Lacus, Noachis-Hellespontus, and the Syrtis Major border areas, would appear to have generally less hostile environments than at the Viking lander sites. Significant soil moisture may extend to within about 1 cm of the surface. Water vapor pressures within the pore spaces may be near saturation, and brines may be physically segregated from pockets of relatively pure H2O. Temperatures reach above 0 C during southern spring and summer, with peak temperatures reaching +22 C. These regions should contain fewer oxidants, and primary synthesis of organics may occur. The potential for contamination of these sites by microbes transported from existing spacecraft should be assessed. The adequacy of proposed new planetary protection procedures for possible future United States Mars Surface Sample Return missions should also be assessed in light of these findings.

Huguenin, R. L.↗
NASA NTRS1984

Mechanical contact induced transformation from the amorphous to the crystalline state in metallic glass

Friction and wear tests were conducted with 3.2- and 6.4-millimeter-diameter aluminum oxide spheres sliding, in reciprocating motion, on a Fe67Co18B14Si1 metallic foil. Crystallites with a size range of 10 to 150 nanometers were produced on the wear surface of the amorphous alloy. A strong interaction between transition metals and metalloids such as silicon and boron results in strong segregation during repeated sliding, provides preferential transition metal-metalloid clustering in the amorphous alloy, and subsequently produces the diffused honeycomb structure formed by dark grey bands and primary crystals, that is, alpha-Fe in the matrix. Large plastic flow occurs on an amorphous alloy surface with sliding and the flow film of the alloy transfers to the aluminum oxide pin surface. Multiple slip bands due to shear deformation are observed on the side of the wear track. Two distinct types of wear debris were observed as a result of sliding: an alloy wear debris, and/or powdery-whiskery oxide debris.

Miyoshi, K.↗
NASA NTRS1984

Mechanical-contact-induced transformation from the amorphous to the partially crystalline state in metallic glass

Friction and wear tests were conducted with 3.2- and 6.4-millimeter-diameter aluminum oxide spheres sliding, in reciprocating motion, on a Fe67Co18B14Si1 metallic foil. Crystallites with a size range of 10 to 150 nanometers were produced on the wear surface of the amorphous alloy. A strong interaction between transition metals and metalloids such as silicon and boron results in strong segregation during repeated sliding, provides preferential transition metal-metalloid clustering in the amorphous alloy, and subsequently produces the diffused honeycomb structure formed by dark grey bands and primary crystals, that is, alpha-Fe in the matrix. Large plastic flow occurs on an amorphous alloy surface with sliding and the flow film of the alloy transfers to the aluminum oxide pin surface. Multiple slip bands due to shear deformation are observed on the side of the wear track. Two distinct types of wear debris were observed as a result of sliding: an alloy wear debris, and/or powdery-whiskery oxide debris.

Miyoshi, K.↗
NASA NTRS1984

Mechanical-contact-induced transformation from the amorphous to the partially crystalline state in metallic glass

Friction and wear tests were conducted with 3.2- and 6.4-millimeter-diameter aluminum oxide spheres sliding, in reciprocating motion, on a Fe67Co18B14Si1 metallic foil. Crystallites with a size range of 10 to 150 nanometers were produced on the wear surface of the amorphous alloy. A strong interaction between transition metals and metalloids such as silicon and boron results in strong segregation during repeated sliding, provides preferential transition metal-metalloid clustering in the amorphous alloy, and subsequently produces the diffused honeycomb structure formed by dark grey bands and primary crystals, that is, alpha-Fe in the matrix. Large plastic flow occurs on an amorphous alloy surface with sliding and the flow film of the alloy transfers to the aluminum oxide pin surface. Multiple slip bands due to shear deformation are observed on the side of the wear track. Two distinct types of wear debris were observed as a result of sliding: an alloy wear debris, and/or powdery-whiskery oxide debris.

Miyoshi, K.↗
NASA NTRS1979

Ultraviolet spectroscopic measurements of globular clusters

Ultraviolet spectra of six globular clusters (M15, M92, NGC 1851, NGC 6624, 47 Tuc, and NGC 6752) have been taken with the International Ultraviolet Explorer satellite in order to investigate the surface brightness distributions in the central regions. The ultraviolet emission indicates composite stellar spectra. Short-wavelength emission (1200-1900 A) arises from blue horizontal-branch stars; long-wavelength emission (2100-3000 A) is characteristic of late-type horizontal-branch and giant stars. The surface brightness distribution is more compact at short wavelengths than at long wavelengths, suggesting a segregation of horizontal-branch stars. A dense core appears to be present in X-ray-emitting clusters and absent in those clusters without X-ray sources. The X-ray source in NGC 6624 may have been detected at short wavelengths (1300-1900 A).

Dupree, A. K.↗