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97 records · Page 6

Former Central Heat Plant SWMU 045 Year 2 Air Sparge System Performance Monitoring Report

This Air Sparge (AS) Performance Monitoring (PM) Report (PMR) presents Year 2 operation, maintenance, and monitoring (OM&M) activities, PM results, and monitoring well installations supporting the AS Interim Measure (IM) at the Former Central Heat Plant (CHP) at Kennedy Space Center (KSC), Florida. CHP has been designated Solid Waste Management Unit 045 under the KSC Resource Conservation and Recovery Act Corrective Action Program. An AS IM was installed at CHP between 2019 and 2021, which included the installation of an AS system to treat a chlorinated solvent groundwater plume. Contaminants of concern (COCs) identified at CHP for the AS IM include tetrachloroethene (PCE), trichloroethene (TCE), cis-1,2-dichloroethene (cDCE), and vinyl chloride (VC). The completed AS system includes a network of 267 AS wells, which treat approximately 1.3 acres of contaminated groundwater. “Hot” compressor technology is used to treat the source zone, while a “cold” compressor is used to treat two hot spot (HS) areas (HS1 and HS2) and the high concentration plume (HCP). The AS system began operation in June-July 2021 and this document includes Year 2 of operation. The overall runtimes for the AS system for the Year 2 reporting period (October 2022 to September 2023) were approximately 69 percent for the cold trailer and 71 percent for the hot trailer. Air samples and vapor screening results collected during the reporting period showed concentrations less than applicable human health and air emissions permit criteria. Groundwater performance monitoring results show that AS treatment continues to be effective in reducing COC concentrations at CHP. At the shallow interval, COC concentrations were all non-detect, less than, or met their respective State of Florida Groundwater Cleanup Target Levels (GCTLs) at the end of Year 2 in September 2023. In the deep interval, 10 of the 15 PM wells detected COCs greater than their respective GCTLs, with two of these wells also exceeding the Natural Attenuation Default Concentration for VC. Based on Year 2 OM&M and PM results, continued operation of the AS system is required to meet the IM objective. It is therefore recommended to continue with AS IM operations at CHP with the following plan for Year 3.

Kevin Alex Murphy↗

Converter Compressor Building, SWMU 089 Monitoring Well 21 Area Implementation Work Plan Kennedy Space Center, Florida

This Implementation Work Plan (IWP) was prepared by Tetra Tech, Inc., for the National Aeronautics and Space Administration (NASA) under Indefinite Delivery Indefinite Quantity (IDIQ) Contract 80KSC019D0011/80KSC019F0070, for the implementation of a bioremediation Interim Measure (IM) at the Converter Compressor Building (CCB) site located at Kennedy Space Center (KSC), Florida. The location of CCB within KSC is shown on Figure A-1. CCB has been designated as Solid Waste Management Unit (SWMU) 089 under KSC’s Resource Conservation and Recovery Act (RCRA) Corrective Action Program. The overall Corrective Action Objective (CAO) for CCB is to reduce concentrations of trichloroethene (TCE), cis-1,2-dichloroethene (cDCE), trans-1,2-dichloroethene (tDCE), and vinyl chloride (VC) to less than State of Florida Groundwater Cleanup Target Levels (GCTLs). The objective for the IM associated with this IM is to reduce groundwater concentrations for the contaminants of concern (COCs) to less than their Natural Default Attenuation Concentrations (NADCs) within the Monitoring Well 21 Area (herein referred to as MW21 Area) via bioremediation injections to support transition to long term monitoring (LTM). This IWP describes the activities that will be performed for the treatment of the MW21 Area. The Revision 1 CCB MW21 Area Interim Measure Work Plan (IMWP; NASA, 2024), which was approved by the Florida Department of Environmental Protection (FDEP) on December 26, 2024, was used as the design basis for this IWP.

Mark Jonnet↗

In-situ measurements of chemically and radiatively important atmospheric gases from the Advanced Global Atmospheric Gas Experiment (AGAGE) and affiliated stations.

In the ALE/GAGE/AGAGE global network program, continuous high frequency gas chromatographic measurements of four biogenic/anthropogenic gases (methane, CH4; nitrous oxide, N2O; hydrogen, H2; and carbon monoxide, CO) and several anthropogenic gases that contribute to stratospheric ozone destruction and/or to the greenhouse effect have been carried out at five globally distributed sites for several years. The program, which began in 1978, is divided into three parts associated with three changes in instrumentation: the Atmospheric Lifetime Experiment (ALE), which used Hewlett Packard HP5840 gas chromatographs; the Global Atmospheric Gases Experiment (GAGE), which used HP5880 gas chromatographs; and the present Advanced GAGE (AGAGE). AGAGE uses two types of instruments: a gas chromatograph with multiple detectors (GC-MD), and a gas chromatograph with mass spectrometric analysis (GC-MS). Beginning in January 2004, an improved cryogenic preconcentration system (Medusa) replaced the absorption-desorption module in the GC-MS systems at Mace Head and Cape Grim; this provided improved capability to measure a broader range of volatile perfluorocarbons with high global warming potentials. The Medusa GC-MS systems were subsequently used at other AGAGE stations (Trinidad Head, Barbados, American Samoa, Zeppelin, Jungfraujoch, and Goan) after the initial setup at Mace Head and Cape Grim. More information may be found at the AGAGE home page: https://agage.mit.edu/instruments.Compared to the previous version (https://data.ess-dive.lbl.gov/view/doi:10.3334/CDIAC/ATG.DB1001), the latest update (Agage_gcmd_gcms_data_2021_04_07_tar.gz) includes 6 months of new data through the end of March 2020. Two new compounds, HCFC-132b, and HCFC-133a, are also included in this version. For a complete list of released compounds and used standard scales, please see “AGAGE_scale_2021_v1.pdf” file. Additional information can also be found on the AGAGE website (https://agage.mit.edu).

54 ENVIRONMENTAL SCIENCES↗

The Advanced Global Atmospheric Gases Experiment (AGAGE) Data

In the ALE/GAGE/AGAGE global network program, continuous high frequency gas chromatographic measurements of four biogenic/anthropogenic gases (methane, CH4; nitrous oxide, N2O; hydrogen, H2; and carbon monoxide, CO) and several anthropogenic gases that contribute to stratospheric ozone destruction and/or to the greenhouse effect have been carried out at five globally distributed sites for several years. The program, which began in 1978, is divided into three parts associated with three changes in instrumentation: the Atmospheric Lifetime Experiment (ALE), which used Hewlett Packard HP5840 gas chromatographs; the Global Atmospheric Gases Experiment (GAGE), which used HP5880 gas chromatographs; and the present Advanced GAGE (AGAGE). AGAGE uses two types of instruments: a gas chromatograph with multiple detectors (GC-MD), and a gas chromatograph with mass spectrometric analysis (GC-MS). Beginning in January 2004, an improved cryogenic preconcentration system (Medusa) replaced the absorption-desorption module in the GC-MS systems at Mace Head and Cape Grim; this provided improved capability to measure a broader range of volatile perfluorocarbons with high global warming potentials. The Medusa GC-MS systems were subsequently used at other AGAGE stations (Trinidad Head, Barbados, American Samoa, Zeppelin, Jungfraujoch, and Goan) after the initial setup at Mace Head and Cape Grim. More information may be found at the AGAGE home page: https://agage.mit.edu/instruments.Compared to the previous version (https://data.ess-dive.lbl.gov/datasets/doi: doi:10.15485/1781803), the latest update (Agage_gcmd_gcms.data.2022_01_03.tar.gz) includes 6 months of new data through the end of September 2020. For a complete list of released compounds and used standard scales, please see “AGAGE_scale_2021_v1.pdf” file. Additional information can also be found on the AGAGE website (https://agage.mit.edu).

54 ENVIRONMENTAL SCIENCES↗

Contractors Road Heavy Equipment Area (SWMU 055) 2021 Annual Groundwater Monitoring Report

This document presents a summary of activities completed at the Contractors Road Heavy Equipment (CRHE) Area, located at Kennedy Space Center (KSC), Florida, from January through December 2021. The activities conducted at the CRHE Area include: - Annual groundwater sampling activities associated with site-wide plume monitoring and Underground Injection Control (UIC) monitoring in the former bioremediation Interim Measures (IM) Hot Spot 1 (HS1) area; - Direct push technology (DPT) groundwater investigation; and - Semi-annual vapor intrusion (VI) evaluation activities. This facility is designated Solid Waste Management Unit (SWMU) Number 055 (SWMU 055) under KSC’s Resource Conservation and Recovery Act Corrective Action program. This report was prepared by HydroGeoLogic, Inc. (HGL) for the National Aeronautics and Space Administration (NASA) under contract number 80KSC019F0096. The annual groundwater sampling results demonstrated that the footprint where chlorinated volatile organic compounds (VOC) are present above their State of Florida groundwater cleanup target levels (GCTLs) is not expanding overall. One non-chlorinated VOC (1,4-dioxane) is found above its GCTL at isolated points within the chlorinated VOC plume. The DPT groundwater investigation is being used to delineate the horizontal and vertical boundaries where chlorinated VOCs are present at levels above natural attenuation default concentrations. That data supports an evaluation of potential additional remedial actions. The potential for VI into the CRHE Area Office (K6-1996H) is evaluated by collected sub-slab vapor samples from four locations twice a year (once in the wet season and once in the dry season). The results for 2021 were all below the Environmental Protection Agency's vapor intrusion screening levels (VISLs) for both commercial and residential settings. The path forward for the site is to continue annual monitoring for chlorinated VOCs and 1,4-dioxane until additional remedies are implemented or the site is transitioned to long-term monitoring.

Contractors Road Heavy Equipment↗

Launch Complex 34 SWMU CC054 Hot Spot Area 6 Expansion - Phase Three Implementation Work Plan

This Hot Spot (HS) Area 6 Air Sparge Expansion – Phase Three Implementation Work Plan (IWP) was prepared by Tetra Tech, Inc., for the National Aeronautics and Space Administration (NASA) under the Indefinite Delivery Indefinite Quantity Contract 80KSC019D0011-80KSC019F0067, for the implementation of an Air Sparging (AS) Interim Measure (IM) at Launch Complex 34 (LC34), located at Cape Canaveral Space Force Station (CCSFS), Florida. LC34 has been designated as Solid Waste Management Unit (SWMU) CC054 under the Kennedy Space Center (KSC) Resource Conservation and Recovery Act (RCRA) operating permit. Expansion of the HS 6 IM will include installation of an additional 192 AS wells to depths of approximately 40 feet below land surface (bls) to remediate contaminated groundwater within two areas located west and northeast of the existing HS 6 AS treatment area. These areas were delineated via direct push technology investigations in September and October 2023. The expansion will target “hot spot” concentrations of cis-1,2-dichloroethene (cDCE) and vinyl chloride (VC), which are the contaminants of concern in these areas with concentrations greater than 10-times Florida Department of Environmental Protection Natural Attenuation Default Concentrations. The highest cDCE and VC concentrations detected in the proposed phase three expansion area were 58,000 micrograms per liter (μg/L) (32 to 36 feet bls) and 12,000 μg/L (23 to 27 feet bls), respectively. The objective for this expansion is to remediate contaminated groundwater within the treatment zone to support transition to long-term monitoring. This phase three expansion will add an additional 9.4 acres of treatment area to the HS 6 IM, which currently covers approximately 26.9 acres.

Launch Complex 34↗