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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

NASA Tech Briefs, March 2006

Topics covered include: Medical Signal-Conditioning and Data-Interface System; Instruments for Reading Direct-Marked Data-Matrix Symbols; Processing EOS MLS Level-2 Data; Ground Processing of Data From the Mars Exploration Rovers; Estimating Total Electron Content Using 1,000+ GPS Receivers; NASA Solar Array Demonstrates Commercial Potential; Improved Control of Charging Voltage for Li-Ion Battery; Programmable Pulse-Position-Modulation Encoder; Wavelength-Agile External-Cavity Diode Laser for DWDM; Pattern-Recognition Processor Using Holographic Photopolymer; Submicrosecond Power-Switching Test Circuit; Three-Function Logic Gate Controlled by Analog Voltage; Integrated System for Autonomous Science; Montage Version 3.0; Utilizing AI in Temporal, Spatial, and Resource Scheduling; Satellite Image Mosaic Engine; Architecture for Control of the K9 Rover; HFGMC Enhancement of MAC/GMC; Automated Activation and Deactivation of a System Under Test; Cleaning Carbon Nanotubes by Use of Mild Oxygen Plasmas; Generating Aromatics From CO2 on Mars or Natural Gas on Earth; Attaching Thermocouples by Peening or Crimping; Heat Treatment of Friction-Stir-Welded 7050 Aluminum Plates; Generating Breathable Air Through Dissociation of N2O; High-Performance Scanning Acousto-Ultrasonic System; Correction for Thermal EMFs in Thermocouple Feedthroughs; Using Quasiparticle Poisoning To Detect Photons; Estimating Resolution Lengths of Hybrid Turbulence Models; Education and Training Module in Alertness Management; Cargo-Positioning System for Next-Generation Spacecraft; Micro-Imagers for Spaceborne Cell-Growth Experiments; Holographic Solar Photon Thrusters; Plasma-Based Detector of Outer-Space Dust Particles; and Generation of Data-Rate Profiles of Ka-Band Deep-Space Links.

Source record↗

Validation of chemistry models employed in a particle simulation method

The chemistry models employed in a statistical particle simulation method, as implemented in the Intel iPSC/860 multiprocessor computer, are validated and applied. Chemical relaxation of five-species air in these reservoirs involves 34 simultaneous dissociation, recombination, and atomic-exchange reactions. The reaction rates employed in the analytic solutions are obtained from Arrhenius experimental correlations as functions of temperature for adiabatic gas reservoirs in thermal equilibrium. Favorable agreement with the analytic solutions validates the simulation when applied to relaxation of O2 toward equilibrium in reservoirs dominated by dissociation and recombination, respectively, and when applied to relaxation of air in the temperature range 5000 to 30,000 K. A flow of O2 over a circular cylinder at high Mach number is simulated to demonstrate application of the method to multidimensional reactive flows.

Haas, Brian L.↗

A preferential vibration dissociation coupling model for nonequilibrium flowfields

A preferential vibration-dissociation coupling model is incorporated into a radiatively coupled viscous shock laver code that also includes chemical, radiative, and thermal nonequilibrium. Stagnation point flow profiles are obtained for various Fire 2 flight conditions and for a typical 14 km/sec AOTV case, and comparisons are made with Fire 2 experimental data. Adjustments in molecular absorption coefficients are also made for several diatomic species. Based on comparisons with experimental data, very little preferential dissociation behavior is present in the Fire 2 flight conditions.

Mcgough, David E.↗

Catalytic recombination of nitrogen and oxygen on iron-cobalt-chromia spinel

The energy-transfer catalytic recombination coefficient for nitrogen and oxygen recombination on iron-cobalt-chromia spinel is inferred from stagnation-point heat flux measurements in dissociated arc-jet flow. This material was coated on several Space Shuttle Orbiter thermal protection tiles. The resulting coefficients are correlated with an Arrhenius model for convenience, and these expressions may be used to account for catalytic recombination in predictions of the heat flux on the spinel-coated tiles flown on several Space Shuttle Orbiter flights. The results are compared with those inferred by Rakich, Stewart, and Lanfranco from an Orbiter flight and arc-jet experiments. Good agreement is obtained for oxygen recombination, but agreement for nitrogen is poor.

Scott, C. D.↗

Direct simulation of aerothermal loads for an aeroassist flight experiment vehicle

Results of a numerical study using the direct simulation Monte Carlo (DSMC) method are presented for the hypersonic flow about an elliptically blunted cone. The flow conditions are those for a proposed Aeroassist Flight Experiment (AFE) vehicle. The altitude range considered is that from 130 to 90 km which encompasses most of the transitional flow regime for the AFE vehicle, that is, the region bounded by free molecular and continuum flow. Freestream velocities of 9.9 to 7.5 km/sec are considered. The numerical simulations show that noncontinuum effects are evident for all cases considered. The onset of chemical dissociation occurs at a simulated altitude of about 130 km. Results presented highlight the thermal and chemical nonequilibrium nature of the flowfield and the impact of these effects on the surface heating and body drag. A calculation which included the additional effects of ionization and thermal radiation demonstrates that the inclusion of such efects would not significantly alter the surface quantities calculated in the present study. The radiative heating is negligible when compared with the convective heating, and the same would be true for the other conditions considered.

Dogra, Virendra K.↗

Pick-Up Ion Instabilities at Planetary Magnetospheres

This effort involved the analysis of low frequency waves as observed by the Galileo spacecraft near the Galilean moon, Io. Io is a significant source of material, especially SO2, and various products of dissociation, and further these atoms and molecules are readily ionized. The initial velocity of the ions is essentially that of the neutral species, i.e., the Keplerian velocity. The plasma, on the other hand is co-rotating, and there is a differential flow of the order 57 km/s between the plasma and the neutral particles. Thus pick-up ion instabilities are Rely to occur within the Jovian magnetosphere. Indeed, magnetometer observations from the Galileo spacecraft clearly show ion cyclotron waves that have been identified with a large variety of plasma species, such as O+, S++ (which has the same gyro-frequency as O+), S+, and SO2+. Typically, however, the dominant frequency is near the SO2+ gyro-frequency. The research effort was originally planned to be a team effort between Robert J. Strangeway as the Principal Investigator, and Debbie Huddleston, who was an Assistant Research Geophysicist at UCLA. Unfortunately, Dr. Huddleston took a position within Industry. The effort was therefore descoped, and Dr. Strangeway instead pursued a collaboration with Dr. Xochitl Blanco-Cano, of the Instituto de Geofisica, Universidad Nacional Autonoma de Mexico. This has proved to be a productive collaboration, with several papers and publications arising out of the effort. The magnetic field oscillations near lo generally fall into two types: ion cyclotron waves, with frequencies near an ion gyro-frequency, and lower frequency mirror-mode waves. The ion cyclotron waves are mainly transverse, and frequently propagate along the ambient magnetic field. The mirror-mode waves are compressional waves, and they have essentially zero frequency in the plasma rest frame. One of the purposes of our investigation is to understand what controls the types of wave modes that occur, since both wave modes can be drive unstable by the pressure anisotropy associated with the pick up ions. The pick ion velocity is perpendicular to the ambient magnetic field, and is generally much larger than the thermal velocity, at least initially. At its simplest, we found that the ion cyclotron waves are controlled by the parameters of the species in gyro-resonance with the wave. Thus, while the growth rates for the lower mass (higher gyro-frequency) pick-up ions are generally larger, we found that the heavier SO2+ ion cyclotron waves are generally preferred. This is because one of the effects of the wave instability is to diffuse the ions in pitch angle and energy. The lower mass ions therefore consist of both a ring of recently created pick-up ions, and a thermal background. This thermal background quenches the ion cyclotron instability. SO2+ is different, however. Being a molecule, the species can also dissociate. Our analysis suggests that the dissociation acts on a time scale comparable to or faster than the velocity space diffusion time scale. There are consequently no thermal SO2+ ions to quench the instability. We have also investigated the mirror-mode. This mode can at times grow more rapidly than the individual ion cyclotron waves. This is mainly because the mirror-mode can grow off the pressure anisotropy of the individual species with which the waves are in resonance. Lastly, as part of this effort we have begun to investigate the instability for obliquely propagating modes. Galileo observations show that at times the ion cyclotron waves are significantly elliptically polarized, and further the wave vector is at a large angle to the field, significant growth can occur for oblique propagation. Depending on the group velocity of the waves, it is possible that obliquely propagating modes have higher advective growth rate, but this has yet to be determined.

Strangeway, Robert J.↗

Thermal Control Utilizing an Thermal Control Utilizing an Two-Phase Loop with High Heat Flux Source

The electric field applied in dielectric fluids causes an imbalance in the dissociation-recombination reaction generated free space charges. The generated charges are redistributed by the applied electric field resulting in the heterocharge layers in the Vicinity of the electrodes. Proper design of the electrodes generates net axial flow motion pumping the fluid. The electrohydrodynamic (EHD) conduction pump is a new device that pumps dielectric fluids utilizing heterocharge layers formed by imposition of electrostatic fields. This paper evaluates the experimental performance of a two-phase breadboard thermal control loop consisting of an EHD conduction pump, condenser, pre-heater, high heat flux evaporator (HE), transport lines, and reservoir (accumulator). The generated pressure head and the maximum applicable heat flux are experimentally determined at various applied voltages and sink temperatures. Recovery from dryout condition by increasing the applied voltage to the pump is also demonstrated.

Jeong, Seong-Il↗

Results of a flight experiment on the catalytic efficiency of the Space Shuttle heat shield

An experiment was performed on the second Space Shuttle flight to verify data from arc-heated wind-tunnel tests indicating that the thermal protection tiles used on the Shuttle's surface are noncatalytic to the recombination of dissociated air. The experiment indicates that the tiles are indeed noncatalytic, and explains the lower than expected temperatures observed in the first two Shuttle flights. The data are reasonably well predicted with computations, using a chemically reactive boundary-layer code. The experimental setup and the computational analysis are described.

Rakich, J. V.↗

The Combustion Phase of Burning Metals

Glassman's hypothesis and burn ratio are examined for their suitability for predicting the phase of combustion of metals. Neither criterion is validated based on either published property values or experimental evidence. Inconsistencies in published property values and definitions are noted. Computer calculations provide a more appropriate descriptions of the compositions of the combustion products and the adiabatic flame temperature of a burning metal at equilibrium. Dissociation temperatures (and product compositions) for 11 metals are computed using a specified quantity of thermal energy and compared with adiabatic flame temperatures.

Steinberg, Theodore A.↗

TEMPERATURE CONSTRAINT OF THE MISTASTIN LAKE IMPACT STRUCTURE IMPACT MELT ROCKS

Impact melt is a product of hypervelocity cratering events formed by the instantaneous melting of near-surface target rocks. The temperatures of impact melt upon formation are believed to be superheated, vastly exceeding the liquidus temperature of igneous rocks formed via endogenic processes. However, quantitative understanding of the formation and duration of superheated temperatures remains incomplete. To date, only one datum on the hottest post-shock temperature (>2370 °C) has been derived by Timms et al. (2017) [1]. These authors studied the microstructures and crystallographic orientations preserved within a rim of vermicular ZrO2 of a zircon grain entrained within impact glass at the Mistastin Lake impact structure, Canada. Diagnostic crystallographic orientation indicated the presence of cubic zirconia, requiring a minimum temperature for the impact melt of >2370°C from the dissociation of zircon to cubic zirconia and liquid SiO2. With only one temperature datum, it cannot be stated whether the temperature of the impact melt sheet was homogenous across the entire structure or if the thermal history of the melt varied with spatial distribution. In this study, we present a preliminary investigation of 70 zircon grains, 22 of which exhibit rims of vermicular ZrO2 dissociation textures, similar to those studied by Timms et al. (2017). To acquire a more accurate temperature profile representative of impact melt, zircon crystals were collected from different types of impact melt bearing units, including additional samples of the impact glass studied by Timms et al. (2017). Of the 22 zircon grains with dissociation textures, at least 4 grains in the impact glass show diagnostic evidence of pre-existing cubic zirconia, and 1 grain from a glass-bearing breccia exhibits granular zircon textures, possible evidence of a transition from high-P to high-T conditions. These results show the heterogeneous post-shock temperature distribution of superheated impact melt within the Mistastin impact structure. [1] Timms, N.E., Erickson, T.M., Zanetti, M.R., Pearce, M.A., Cayron, C., Cavosie, A.J., Reddy, S.M., Wittmann, A. and Carpenter, P.K., 2017. Cubic zirconia in> 2370° C impact melt records Earth's hottest crust. Earth and Planetary Science Letters, 477, pp.52-58.

rock↗

Models for direct Monte Carlo simulation of coupled vibration-dissociation

A new model for reactive collisions is developed within the framework of a particle method, which simulates coupled vibration-dissociation (CVD) behavior in high-temperature gases. The fundamental principles of particle simulation methods are introduced with particular attention given to the probability functions employed to select thermal and reactive collisions. Reaction probability functions are derived which favor vibrationally excited molecules as reaction candidates. The new models derived here are used to simulate CVD behavior during thermochemical relaxation of constant-volume O2 reservoirs, as well as the dissociation incubation behavior of postshock N2 flows for comparisons with previous models and experimental data.

Haas, Brian L.↗

Aeronomy of the current Martian atmosphere

The thermal structure of the Martian atmosphere, which varies diurnally, seasonally and episodically, is discussed. The atomic oxygen airglow at 1304 A is used to determine the density of atomic oxygen, and the 1216-A Lyman-alpha line is used to calculate the density of atomic hydrogen and, when coupled with the temperature measurement, the escape flux of atomic hydrogen. The most intense airglow is the IR atmospheric band of O2 at 1.27 micron that results from the photodissociation of ozone. The escape mechanism for atomic hydrogen is thermal, or Jeans, escape, while the atomic oxygen escape is caused by a nonthermal process, namely, the dissociative recombination of O2(+). The ratio of deuterium to hydrogen is enriched by a factor of 6. Three-dimensional models of the Mars thermospheric circulation show that planetary rotation has a significant effect on the wind, composition, and temperature structure.

Barth, C. A.↗

An intercomparison technique for measuring thermal attachment cross sections and rate constants in distinct final channels

A new technique is introduced for comparing negative-ion signal rates in which a common ion is produced by dissociative attachment in a series of molecules. Measurements are carried out at electron energies less than 100 MeV and at resolutions of 6-8 MeV (FWHM). The technique is demonstrated by detection of the Cl(-) signal in CFCl3, CCl4, CF2Cl2, 1,1,2-C2Cl3F3, 1,1,1-C2Cl3F3 and C2Cl4. Measurements for 1,1,1-C2Cl3F3 show that there is a significant open channel, other than Cl(-) formation, which accounts for about 60 percent of negative-ion formation in thermal-multiple-collision (swarm) experiments. Channel cross sections and rate constants are given for the process Cl(-)/1,1,1-Cl2Cl3F3, as well as in C2Cl4, for the separate channels Cl(-)/C2Cl4 and C2Cl4(-)/C2Cl4.

Alajajian, S. H.↗

The doubly excited autoionizing states of H2

Neutral doubly excited states of H2 lie in the Franck-Condon region at energies beyound 23 eV above the ground state of H2. These repulsive resonance states may autoionize yielding H2(+) + e(-), H + H(+) + e(-) or dissociate to neutral ground and excited H atoms or H(+) + H(-). These processes are important in determining the thermal balance of interstellar clouds and the chemistry of the Jovian atmosphere. The present investigation is concerned with ab initio calculations of 24 autoionizing states of H2 which have mostly the 2 Sigma u + and first excited 2 Pi u states of H2(+) as the core orbital near R = 1. 4a(0). Of the 24 states reported, 14 have not appeared previously in the literature. For four of the remaining ten states an energy at only a single internuclear distance has been previously reported.

Guberman, S. L.↗

Parametric study of solar thermal rocket nozzle performance

This paper details a numerical investigation of performance losses in low-thrust solar thermal rocket nozzles. The effects of nozzle geometry on three types of losses were studied; finite rate dissociation-recombination kinetic losses, two dimensional axisymmetric divergence losses, and compressible viscous boundary layer losses. Short nozzle lengths and supersonic flow produce short residence times in the nozzle and a nearly frozen flow, resulting in large kinetic losses. Variations in geometry have a minimal effect on kinetic losses. Divergence losses are relatively small, and careful shaping of the nozzle can nearly eliminate them. The boundary layer in these small nozzles can grow to a major fraction of nozzle radius, and cause large losses. These losses are attributed to viscous drag on the nozzle walls and flow blockage by the boundary layer, especially in the throat region. Careful shaping of the nozzle can produce a significant reduction in viscous losses.

Pearson, J. Boise↗

Hot oxygen atoms in the upper atmosphere of Venus

Using data obtained by an ultraviolet spectrometer on the Pioneer-Venus Orbiter, energy and altitude distribution of nonthermal oxygen atoms in the Venus atmosphere for typical daytime and nighttime conditions are calculated using two different numerical methods. Agreement is found between results obtained by the two-stream transport method and the diffusion equation technique. Dissociative recombination of molecular oxygen ions and charge exchange of atomic oxygen ions with the neutral hydrogen and oxygen gas are the source terms, and calculations show that the dissociative recombination term is the dominant one. It is shown that measured hot atom concentrations exceed estimates of the thermal hydrogen atom concentrations derived from Brinton et al. (1980) over most of the daytime exosphere, and the calculated concentrations do so to an even greater extent. It is concluded that hot oxygen atoms are an important component of the dayside exosphere of Venus, their most important effect being the absorption of solar wind.

Nagy, A. F.↗

Vapor deposited emittance/catalysis coatings for superalloys in heatshield applications

Statically oxidized Inconel 617 and MA 956 superalloys were prepared with vapor deposited aluminosilicate layers and exposed to temperatures which simulated reentry conditions. The aluminosilicate layers were 1-2 microns thick. The trials consisted of exposures to 1500-2300 F heat while surface temperatures were monitored with pyrometers. Analyses were then performed of the catalytic activity, oxidation phenomena, and radiative properties after thermal cycling the specimens for 8 hr. Both alloys were found to be catalytic to the recombination processes of dissociated species in the reentry environment. The coatings reduced the catalytic activity by 40 percent for both alloys but did not change the emittance. An enhanced Cr depletion zone was detected in the Inconel samples, implying that the coating did not prevent diffusion loss of Cr. The coated MA 956, on the other hand, gained weight over the course of the trials.

Clark, R. K.↗