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At least 109 records · Page 6

Iodine Waste Form Corrosion: PNNL Summary Testing Report

A test method to correlate the laboratory corrosion behavior of iodine-containing waste forms (IWFs) to a conceptual long-term corrosion models is required. Several candidate methods have been evaluated previously, and each method presents unique challenges and limitations. Dynamic leach tests have emerged as the preferred candidate test method to evaluate IWFs and parameterize an eventual long-term corrosion model. This report was prepared in support of this effort to define the test suite to evaluate the corrosion of IWFs, with the goal of defining and parameterizing a conceptual long-term corrosion model. A review was presented highlighting the high degree of variability between the IWF corrosion data that is available in the literature and the need for a standardized test suite. The targeted test suite is composed of a single interval screening test, a dynamic leach test, and post-test solid characterization of the monolithic IWF samples. The data presented serves two purposes: to expand the range of IWFs evaluated with the test suite to assess method variability and to further understand the corrosion of IWFs to best inform conceptual long-term corrosion model development. A series of IWF types were included in the testing, including hot isostatically pressed Ag-mordenite, silver functionalized silica-based aerogels, iodosodalites (hot isostatic pressing, sintered, glass bonded ceramic), iodoapatite, tellurite glass and glass composite materials.

42 ENGINEERING↗

Correlation of Qualification and Accelerated Testing with Field Degradation

Qualification testing of solar photovoltaic (PV) modules per IEC 61215 standard encompasses a set of well-defined accelerated stress tests (irradiation, environmental, mechanical and electrical) with strict pass/fail criteria based on functionality/performance, electrical and mechanical safety, and visual requirements. The qualification testing does not identify all the possible reliability failures or durability issues witnessed in the actual field. However, it does identify the major/catastrophic design quality issues (infant mortality), which could occur early in a module’s field life. Unfortunately, in the industry, there is no consensus-based standard or protocol available to validate manufacturers’ warranty period claims based on the end-of-life wear-out failure mechanisms. Being able to predict the field degradation rates and lifetime using mode-specific accelerated tests on moderately field-aged modules, for example 10 years, for certain commonly occurring degradation modes would be a powerful contribution to all the stakeholders of the PV industry. There is a need to formulate guidelines to find the correlation of accelerated testing with field degradation for individual degradation modes observed in the field. Potential approaches to fulfill this need were experimented in this project and are presented in this report. Two of the most commonly seen degradation modes – encapsulant browning and solder bond thermomechanical fatigue – are addressed in this report through presenting the accelerated testing methods and physical modelling approaches. Two accelerated test methods (UV and thermal cycling) were designed to induce the wear-out mechanisms in the modules and not infant mortality failures. To focus on the wear-out failure modes, the tests were performed on field-aged modules, instead of fresh modules, with known degradation rates and degradation modes. The degradation rates were measured based on the degradation rates of individual cell parameters (short-circuit current, I sc and series resistance, R s ) instead of the degradation rate of maximum power (P max ) which cannot be used to study any specific/limited degradation mode as the P max degradation could be caused by many different degradation modes. The key characteristic parameter considered for encapsulant discoloration and solder bond degradation is I sc and R s , respectively. The developed physical models/equations relating the testing degradation data and field weather data were utilized to determine the acceleration factor (AF) and to predict the degradation rate for a specific degradation mode of PV modules installed in two different climates, Arizona (hot) and New York (cold). The predicted degradation rates for encapsulant browning and solder bond degradation have also been validated against the actual measured field degradation rates. UV testing cost reduction: To determine acceleration factor, single UV chamber was used for accelerated UV testing at three different temperatures simultaneously, instead of three chambers for three temperatures (or one chamber sequentially which is an extremely time-consuming approach). A passive heating approach was successfully used to achieve and maintain multiple temperatures in the accelerated UV chamber. Foam insulation boards of varying thicknesses were utilized to obtain three different temperatures for UV testing. However, these foam materials tend to disintegrate in the presence of moisture. To alleviate this problem, silicone heating blankets with temperature controls and humidifier can be used if the UV testing is to be performed under hot-humid conditions instead of conventional hot-dry conditions. Thermal cycling testing cost reduction: Single thermal cycling chamber was used for accelerated thermal cycling testing at three different upper temperatures simultaneously, instead of three chambers for three upper temperatures (or one chamber sequentially which is an extremely time-consuming approach). An active heating approach based on silicone heating blankets was successfully used to achieve and maintain multiple upper temperatures in the accelerated thermal cycling chamber. Such blankets provide stable temperature control and thereby more reliable and repeatable for replicate experiments.

14 SOLAR ENERGY↗

Use of high throughput screening methods to study dual-functional crosslinkable latexes

Herein, structure-formulation-property relationships for crosslinkable core-shell latexes were studied initially using high throughput screening methods and then using conventional experimental methods to determine optimum coating formulations. Two approaches that are used within coatings technology to improve sustainability are reduction in volatile organic compounds (VOC) and reduction in energy needed to cure coatings. Hybrid crosslinkable core-shell latexes have shown potential in meeting these challenges where film properties provided by particle coalescence are not sufficient and chemical crosslinking is needed. However, with numerous parameters involved such as latex particle architecture, nature and amount of crosslinker, and curing conditions, the screening of formulations via conventional coating testing methods becomes laborious and time-consuming. The results from high-throughput dye extraction and puncture testing were compared to data from conventional testing methods such as chemical resistance (MEK double rubs), pendulum hardness, and tensile testing to identify correlations. The dye extraction results have shown a strong correlation to solvent resistance and pendulum hardness data whereas toughness from puncture testing data correlated to tensile testing. Both high throughput dye extraction and puncture testing methods can be used for the accelerated screening of crosslinkable coating formulations to optimize curing parameters to achieve the best coating performance.

36 MATERIALS SCIENCE↗

Dynamic Thermal Performance Analysis of PCM Products Used for Energy Efficiency and Internal Climate Control in Buildings

PCMs are attractive for the future generation of buildings, where energy efficiency targets and thermal comfort expectations are increasingly prioritized. Experimental analysis of local thermal processes in these dynamic components and whole-building energy consumption predictions are essential for the proper implementation of PCMs in buildings. This paper discusses the experimental analysis of the thermophysical characteristics of both a latent heat storage material (PCM) and a product containing this PCM. The prototype product under investigation is a panelized PCM technology containing inorganic, salt-hydrate-based PCM. The thermal analysis includes studies of melting and freezing temperatures, enthalpy changes during phase change processes, nucleation intensity, sub-cooling effects, and PCM stability. The PCM’s stability is also investigated, as is the ability of PCM products to control local temperatures and peak load transmission times. Two inorganic PCM formulations based on calcium chloride hexahydrate (CaCl 2 .6H 2 O) were prepared and tested in laboratory conditions. Material-scale testing results were compared with outcomes from the system-scale analysis, using both laboratory test methods as well as field exposure in test huts. This work demonstrates that PCM technologies used in buildings can effectively control both the magnitude of thermal storage capacity as well as the time of the peak thermal load. It was found that commonly used material-scale testing methods may not always be beneficial in assessing the dynamic thermal performance characteristics of building technologies containing PCMs.

42 ENGINEERING↗

A methodology for selection of solid desiccants in energy recovery ventilators

Controlling indoor humidity levels is essential for maintaining acceptable indoor air quality in buildings. The use of energy recovery ventilators (ERVs) is an energy-efficient way to regulate indoor air humidity. Fixed-bed regenerators and rotary wheels are widely used ERVs because of their high sensible and latent effectiveness. These ERVs are made of desiccant-coated substrates, which enable them to transfer moisture between the supply and exhaust air streams. However, the moisture transfer ability of ERVs depends on the physiochemical and sorption properties of desiccants. Extensive, full-scale experiments are required to determine the best desiccant material for these systems. This paper presents a simplified method of selecting suitable desiccant materials for ERVs. The methodology involves important characterization methods, literature correlations for performance prediction, and cost-effective testing methods prior to full-scale testing, and full-scale test methods are discussed in detail. Furthermore, the performance of a few newly derived materials is evaluated and compared with that of conventional desiccants such as silica gel and molecular sieves. The highest latent effectiveness was obtained for composite of super absorbent polymer (SAP) with potassium formate (SAP-HCO2K-50 %), all-polymer porous solid desiccant (APPSD) and metal organic framework (MOF)–MIL–101 (Cr), followed by activated carbon fibre felt (ACFF) Silica sol-LiCl30, SAP, silica gel, MOF–303, and molecular sieve. Researchers and manufacturers would benefit from the proposed methodology and presented data in developing new desiccant materials for ERV applications.

Energy recovery↗

Radiometric Testing of Germicidal UV Products, Round 1: UV-C Towers and Whole-Room Luminaires (CALiPER Summary Report)

This summary report analyzes the independently tested performance of 13 germicidal ultraviolet (GUV) products purchased between February and July 2022. A companion full report provides additional information and discussion of the tested products, test methods, and results. The products were of three different types: • Seven portable, consumer-oriented GUV towers designed to be placed on the floor or a desk of an unoccupied room to disinfect air and surfaces. Five of these products used LED sources and two products used low-pressure mercury (LPM) sources. • One non-portable GUV whole-room luminaire designed to be installed on a ceiling to disinfect air when a room is occupied. This product used an LED source. • Five non-portable GUV troffer or high-bay style whole-room luminaires designed to be installed in or suspended from a ceiling to disinfect air and surfaces when a room is unoccupied. All five used LPM sources. Radiometric and electrical performance was evaluated for all 13 products. Photobiological safety was also assessed for two of the products because their documentation included testable claims. The test results were compared across products and to manufacturer or vendor claims. The testing identified many issues related to the accuracy of reported GUV product performance. Claims were often untestable, contradictory, ambiguous, or used incorrect units and/or terminology. And when claims were testable, they often did not match test results. For example, three products that claimed to emit UV-C emitted only UV-A. These product claim issues were more numerous with consumer-oriented tower products, but problems with accurate performance claims were found across all products. The UV-C radiant efficiency of the products varied widely, even among similar products using the same source technologies. For example, the UV-C radiant efficiency of LPM products varied by greater than a factor of three for the same product type, indicating a large potential energy savings opportunity for products that are better designed for efficiency. LED products had orders-of-magnitude lower UV-C radiant efficiency than LPM products. Several testing challenges and limitations were identified. Most significant among these is the capability to accurately test and report the performance of larger GUV products. Integrating spheres require a specialized and costly coating to test UV, and the testing laboratory for this round of products had only a 20-inch diameter hemisphere with this capability. Only 2 of the 10 UV-C emitting products could be tested in this sphere. Goniometer testing had a different size limitation in that mirrors typically used to increase goniometer test distance to the far field are not reflective of UV and therefore could not be used to increase test distance. As a result, 7 of 13 products could not be tested far field. The implication is that electronic files of UV-C intensity data typically imported into design software for designing GUV applications may not be reliable for predicting irradiance at arbitrary far-field distances. It is currently unclear if these are industry-wide testing laboratory limitations, and what solutions may exist to address them. Specifiers and buyers of GUV products will need accurate performance claims and data to safely and effectively deploy GUV technology to reduce the transmission of diseases in buildings. This CALiPER GUV Round 1 report demonstrates the significant education and training that is needed for manufacturers and vendors to accurately test and report the performance of their GUV products. Further standards and guidelines are needed to improve test methods, address testing limitations, and improve reporting of product performance. Additionally, the wide range in UV-C radiant efficiency of GUV products means there is a large energy-savings opportunity for more energy efficient GUV products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Development of cone-wedge-ring-expansion test to evaluate the tensile HOOP properties of nuclear fuel cladding

Here, we report the development of a cone wedge ring expansion test method to determine the tensile hoop properties of irradiated nuclear fuel cladding in a hot cell. A closed-form solution was developed to explicitly relate the hoop stress σ θ to the axial piston loading using the scale factor χ and the shear stress correction factor α, where the χ and α factors are used to convert the applied piston load and the radial dilatation of the ring into the tensile hoop stress-strain curve. The applicability of this new test method was demonstrated by successfully evaluating ring specimens of Zr-4 alloy to failure. The ring specimens deformed uniformly in the axial and circumferential directions until onset of necking. The χ and α factors were successfully determined by using a finite-element stress analysis that benchmarked with applied test load and total work to account for frictional forces and the associated energies dissipation between the different sliding components of the testing system. The tensile hoop strength values obtained using the proposed cone-wedge-ring-expansion test method were 10% higher than values obtained from the tensile evaluation of the cladding material along the axial direction. In conclusion, the variability in results was found to be within the range reported in the literature.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Polymer Additive Manufacturing for Marine Renewable Energy Applications: Best Practices, Research Trends, and Current Challenges

Additive manufacturing (AM) is a rapidly growing technology space, not only for prototyping, but is also becoming more feasible at larger scales and increasing component quantities. There are a large variety of AM processes and materials available to users and effectively applying those processes and materials to a specific use case can be challenging. One specific area where AM could be particularly beneficial is marine renewable energy (MRE). Not only is MRE a relatively nascent industry with a near-term need for rapid deployments and prototype testing, but developers could also see long-term benefits from the broad variety of environmentally resistant materials available and the ability to manufacture complex geometries that AM technologies offer. Over the past 4 years, AM materials have played an increasing role in the Advanced Materials project; a multi-year, multi-laboratory research project funded by the U.S. Department of Energy's Water Power Technologies Office, with the main goal of reducing barriers to the adoption of complex materials in the MRE industry. The primary focus of this project is to develop test methods and generate datasets to understand the long-term performance of advanced materials in marine environmental and address specific material challenges as they arise. This report provides an extensive overview of the research that has been performed specific to AM polymers as part of the Advanced Materials project. The intention of this document is to provide recommendations of best practices with regards to material selection, mechanical test method development, and design practices, lessons learned along the way, current research trends, and ongoing challenges with regards to AM polymers in marine environments. In particular, this report focuses on several key aspects: Material and process selection, Environmental conditioning and subsequent degradation quantification through mechanical characterization, Composite reinforcements on AM polymer substrates, Adhesion of instrumentation for mechanical characterization and loads measurements, Protective coatings for preventing biofouling and water ingress, Other MRE case studies where AM has proved particularly useful. Ultimately, we hope that the test methods that have been developed, data generated, and lessons learned from this research will be valuable to the MRE community (researchers and developers alike), as well as other industries, and can be used as a reference point as the respective MRE and AM industries continue to grow and mature.

16 TIDAL AND WAVE POWER↗

Estimating Energy Consumption of Mobile Fluid Power in the United States

This report estimates the market size and energy consumption of mobile off-road applications utilizing hydraulic fluid power, and summarizes technology gaps and implementation barriers. Mobile fluid power is the use of hydraulic fluids under pressure to transmit power in mobile equipment applications. The mobile off-road fluid power sector includes various uses of hydraulic fluid power equipment with fundamentally diverse end-use application and operational requirements, such as a skid steer loader, a wheel loader or an agriculture tractor. The agriculture and construction segments dominate the mobile off-road fluid power market in component unit sales volume. An estimated range of energy consumed by the mobile off-road fluid power sector is 0.36 - 1.8 quads per year, which was 1.3 percent - 6.5 percent of the total energy consumed in 2016 by the transportation sector. Opportunities for efficiency improvements within the fluid power system result from needs to level and reduce the peak system load requirements and develop new technologies to reduce fluid power system level losses, both of which may be facilitated by characterizing duty cycles to define standardized performance test methods. There are currently no commonly accepted standardized test methods for evaluating equipment level efficiency over a duty cycle. The off-road transportation sector currently meets criteria emissions requirements, and there are no efficiency regulations requiring original equipment manufacturers (OEM) to invest in new architecture development to improve the fuel economy of mobile off-road fluid power systems. In addition, the end-user efficiency interests are outweighed by low equipment purchase or lease price concerns, required payback periods, and reliability and durability requirements of new architecture. Current economics, low market volumes with high product diversity, and regulation compliance challenge OEM investment in commercialization of new architecture development.

13 HYDRO ENERGY↗

Hydrogen-Assisted Fracture of Stainless Steel

Symmetric four-point bending (S4PB) and anti-symmetric four-point bending (AS4PB) were applied to assess the effect of hydrogen on crack initiation and propagation in a stable, nitrogen-strengthened austenitic stainless steel (21Cr-6Ni-9Mn). Specimens of a high strength aluminum alloy (AA2219-T851), which has also been identified as hydrogen-compatible, were used for test method development prior to completing the stainless steel test matrix. Single edge notched bend (SEN(B)) specimens were extracted from forged 21Cr-6Ni-9Mn bar and AA2219 plate. The 21Cr-6Ni-9Mn specimens were then hydrogen charged with ~200 wt. ppm hydrogen; AA2219 specimens were not charged. Aluminum specimens were tested in S4PB to induced mode I (pure bending), and AS4PB to attain varying levels of mode I/II mixity and mode II (pure shear), where the ratio of mode I to mode II varies with the position of the crack plane relative to the load line. After test method troubleshooting and validation, hydrogen charged stainless steel specimens were then subjected to mode I and two ratios of mixed mode I/II. Mode II loading was not achieved due to high load limitations. Analyses of fracture profiles for both materials reveal a marked effect of loading mode mixity on initial crack propagation orientation, however a specific contribution of hydrogen was not readily identifiable. Fracture initiation toughness in the presence of hydrogen, J IH , was calculated following the J-integral approach; the mode I J IH calculated for stainless steel samples fractured in S4PB were consistent with published values determined from compact tension specimens. The peak loads required to initiate fracture during AS4PB far exceeded those required during S4PB. This is attributed to the increasing shear force applied to the specimens as the degree of mode mixity increases. Ultimately, understanding the fracture response of hydrogen exposed stainless steels subjected to mixed mode I/II loading is critical for designing hydrogen containment vessels or gas transfer systems (GTS).

36 MATERIALS SCIENCE↗

Current Efforts in Immobilized Low-Activity Waste Glass Testing to Support the Hanford Site Integrated Disposal Facility - 17119

Cleanup plans for Hanford site high-level radioactive mixed tank waste calls for separating the waste into high-level waste (HLW) and low-activity waste (LAW) fractions. The fractions will be vitrified separately at the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The HLW glass will be sent to an offsite geological disposal facility while the immobilized low-activity waste (ILAW) glass will be disposed at the onsite Integrated Disposal Facility (IDF). In order to inform models used to predict the performance of ILAW glass at IDF, it is necessary to understand the corrosion behavior of the glass. In this paper, we discuss tests that account for the effects of 1) solution chemistry, 2) the ion exchange reaction, and 3) secondary phase formation on the glass dissolution rate. To quantify the effects of solution chemistry, specifically changes in pH, T, and Si concentration, the single-pass flow-through (SPFT) test method is applied. A designed set of these tests results in a set of kinetic rate law parameters that are used in a glass dissolution rate law based on transition-state theory. Furthermore, for SPFT tests with relatively high concentrations of Si, an ion exchange rate is provided. Additionally, through tests such as the pressurized unsaturated flow (PUF) test method, a suite of secondary phases can be compiled. The collection of kinetic rate law parameters, the ion exchange term, and the suite of secondary phases are provided to IDF performance assessment (PA) modelers. Lastly, we present a description of the efforts made to verify and validate the use of these parameters and secondary phases through the use of a field lysimeter present at the Hanford site. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DROP DURABILITY ASSESSMENT OF ELECTRONIC ASSEMBLIES UNDER OFF-AXIS LOADING WITH SKEWED FIXTURES

This thesis studies drop durability of electronic assemblies when the acceleration vector is oriented at 45° to the out-of-plane direction of the circuit card. The off-axis drop tests are accomplished with a skewed fixture and are conducted as a proxy for multiaxial drop testing. Advanced shock testing and vibration test methods have been developed over the last few decades to better represent real-world field environments during ground-based laboratory testing. However, many of these test methods require expensive and specialized equipment not available in most laboratories. An alternative approach for approximating simultaneous loading along multiple axes on conventional equipment utilizes skewed fixtures which have seen use in off-axis random vibration and drop impact testing. These methods generally rely on the conversion of a uniaxial input load from the test equipment (using a uniaxial drop tower or shaker) into a multiaxial load when resolved in the reference frame of the test article (mounted on a skewed fixture). Skewed fixture design is presented and recommendations for conducting skewed angle drop testing are introduced based on local measurements along the skewed face of the fixture to accurately monitor the impact event. Characterization tests were performed with a skewed fixture, at simultaneous acceleration loads from 500 to 3,000 g in two (in-plane and out-of-plane) directions, while meeting standard time domain tolerances. Upon experimental characterization, drop shock durability tests were conducted on a printed circuit assembly (PCA). Mean drops-to-failure were measured and quantified with Weibull statistics. Dominant solder joint failure modes were identified via failure analysis. Prior work on inclined angle impact testing is limited, and the majority of solder joint interconnect level fatigue studies are conducted considering perpendicular loading normal the circuit card. Low-cycle fatigue curves are generated based on plastic strain and plastic work density within the solder joint. A multiscale nonlinear finite element model is used to relate board-level flexure to solder joint interconnect level plastic strain. A high strain rate solder constitutive model allows for accurate modeling of solder plasticity resulting from high-impact drop shock. Fatigue parameters are computed from the Coffin-Manson relation and Palmgren-Miner damage accumulation. This work serves to apply established low-cycle fatigue methods for conventional drop shock loading (impact normal to circuit card) to non-perpendicular loading with a skewed fixture.

Hower, Jonathan [Kansas City National Security Cam↗

Battery Test Manual For 48 Volt Mild Hybrid Electric Vehicles

This manual details the U.S. Advanced Battery Consortium and U.S. Department of Energy Vehicle Technologies Program goals, test methods, and analysis techniques for a 48 Volt Mild Hybrid Electric Vehicle system. The test methods are outlined stating with characterization tests, followed by life tests. The final section details standardized analysis techniques for 48 V systems that allow for the comparison of different programs that use this manual. An example test plan is included, along with guidance to filling in gap table numbers.

33 ADVANCED PROPULSION SYSTEMS↗

Directly Probing the Fracture Behavior of Ultrathin Polymeric Films

Understanding fracture mechanics of ultrathin polymeric films is crucial for modern technologies, including semiconductor and coating industries. However, up to now, the fracture behavior of sub-100 nm polymeric thin films is rarely explored due to challenges in handling samples and limited testing methods available. In this work, we report a new testing methodology that can not only visualize the evolution of the local stress distribution through wrinkling patterns and crack propagation during the deformation of ultrathin films but also directly measure their fracture energies. Using ultrathin polystyrene films as a model system, we both experimentally and computationally investigate the effect of the film thickness and molecular weight on their fracture behavior, both of which show a ductile-to-brittle transition. Furthermore, we demonstrate the broad applicability of this testing method in semicrystalline semiconducting polymers. We anticipate our methodology described here could provide new ways of studying the fracture behavior of ultrathin films under confinement.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Determination of Water Content in Bio-Oils by Volumetric Karl Fischer Titration: Laboratory Analytical Procedure (LAP)

The water content of bio-oils is a key metric for several reasons. Water is typically the most concentrated single component of fast pyrolysis oils, though this will be much lower in catalytic fast pyrolysis and upgraded products. Reduced water content is preferable in bio-oil as water can contribute to phase separation, corrosivity, and instability. Additionally, lower water is beneficial for physical properties such as energy density. The percentage of water can also be used to correct the calculation for organic oxygen when determining total oxygen content of bio-oils via combustion-based ultimate analysis. The procedure described here is specifically written for the analysis of bio-oils, and is based on ASTM E203, Standard Test Method for Water Using Volumetric Karl Fischer Titration. This standard test method is specified for measuring the mass % water in pyrolysis liquid biofuels in ASTM D7544, Standard Specification for Pyrolysis Liquid Biofuel. Although the standard method is prescribed for the analysis of pyrolysis liquids for use in industrial and commercial burners, the method is not specifically written for this product. The method described with this Laboratory Analytical Procedure (LAP) provides specific guidance for the analysis of bio-oils. Both organic and aqueous phases can be measured with this technique.

09 BIOMASS FUELS↗

A practical method to test the validity of the standard Gumbel distribution in logit-based multinomial choice models of travel behavior

Most multinomial choice models (e.g., the multinomial logit model) adopted in practice assume an extreme-value Gumbel distribution for the random components (error terms) of utility functions. This distributional assumption offers a closed-form likelihood expression when the utility maximization principle is applied to model choice behaviors. As a result, model coefficients can be easily estimated using the standard maximum likelihood estimation method. However, maximum likelihood estimators are consistent and efficient only if distributional assumptions on the random error terms are valid. It is therefore critical to test the validity of underlying distributional assumptions on the error terms that form the basis of parameter estimation and policy evaluation. In this paper, a practical yet statistically rigorous method is proposed to test the validity of the distributional assumption on the random components of utility functions in both the multinomial logit (MNL) model and multiple discrete-continuous extreme value (MDCEV) model. Based on a semi-nonparametric approach, a closed-form likelihood function that nests the MNL or MDCEV model being tested is derived. The proposed method allows traditional likelihood ratio tests to be used to test violations of the standard Gumbel distribution assumption. Simulation experiments are conducted to demonstrate that the proposed test yields acceptable Type-I and Type-II error probabilities at commonly available sample sizes. The test is then applied to three real-world discrete and discrete-continuous choice models. For all three models, the proposed test rejects the validity of the standard Gumbel distribution in most utility functions, calling for the development of robust choice models that overcome adverse effects of violations of distributional assumptions on the error terms in random utility functions.

30 DIRECT ENERGY CONVERSION↗

Experimental Simulations of Field-Induced Mechanical Abuse Conditions

Mechanical failure of cell components is an important component to understanding safety outcomes for batteries subjected to external loading. Several key parameters governing the mechanical response at the component to the module level are discussed in this chapter. Specifically, nuances associated with experimental measurements of these properties – including development of test methods, fixturing the test articles, ways to minimize errors in measurements, and improving the repeatability of some of these experiments – are examined closely.

Torres-castro, Loraine↗

A Comparative Study on Representativeness and Stochastic Efficacy of Miniature Tensile Specimen Testing

Here, in this article, a miniature dog bone tensile coupon design was tested against the existing ASTM standard specimen design. Specimens were prepared from commercially sourced austenitic stainless steel 304 alloy, and a defect-ridden additively manufactured 304L alloy was studied. By utilizing a tensile specimen design that is 1/230th volume of the smallest ASTM E8-04(2016), Standard Test Methods for Tension Testing of Metallic Materials, dog bone specimen, coupled to a digital image correlation (DIC) setup, case studies were performed to compare tensile property measurements and strain field evolution. Whereas yield strength measurements were observed to be similar, post-yield, the ultimate strength measurements and ductility measurements from the miniature specimens were observed to be higher than the ASTM specimen design. Although the strength measurements were comparable, the strain evolution was found to differ in the miniature specimens. Studies to assess effects of varying thickness and defect population were also pursued on the miniature tensile specimen. From the DIC strain field estimations, the peak local strain values at ultimate tensile strength were observed to be increasing with reducing specimen thickness. Testing of defect ridden stainless steel revealed the sensitivity to failure through strain localization and the influence of defect size was captured in the strength measurements.

36 MATERIALS SCIENCE↗